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JOURNAL OF COATINGS TECHNOLOGY (JCT) . Vol. 74, N° 924Mention de date : 01/2002Paru le : 04/02/2002 |
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Ajouter le résultat dans votre panierPerspectives on weatherability testing of automotive coatings / David R. Bauer in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 74, N° 924 (01/2002)
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Titre : Perspectives on weatherability testing of automotive coatings Type de document : texte imprimé Auteurs : David R. Bauer, Auteur Année de publication : 2002 Article en page(s) : p. 33-38 Note générale : Bibliogr. Langues : Américain (ame) Tags : Exposition intempérie Comportement service Performance Essai vieillissement accéléré Peinture Matériau revêtement Industrie automobile Index. décimale : 667.9 Revêtements et enduits Résumé : Automotive coatings continue to evolve rapidly in order to reduce the environmental impact of coating operations and to meet rising customer expectations for appearance and performance. The anticipated changes in chemistry, together with improved appearance retention and the need to respond rapidly to customer desires, have placed new challenges on weathering protocols. This paper discusses these issues and describes several methodologies that are likely to be part of the next generation of accelerated testing protocols. Of critical importance is the need to understand and minimize where possible sources of variability in testing that can lead to uncertain results and increased risk of failure in service. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5678
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Code-barres Cote Support Localisation Section Disponibilité 001233 - Périodique Bibliothèque principale Documentaires Disponible 001232 - Périodique Bibliothèque principale Documentaires Disponible Anticipating paint cracking / Mark E. Nichols in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 74, N° 924 (01/2002)
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Titre : Anticipating paint cracking : The application of fracture mechanics to the study of paint weathering Type de document : texte imprimé Auteurs : Mark E. Nichols, Auteur Année de publication : 2002 Article en page(s) : p. 39-46 Note générale : bibliogr. Langues : Américain (ame) Tags : Essai vieillissement Mécanique rupture Fissuration Feuil Exposition intempérie Dégradation Industrie automobile Vernis Peinture Matériau revêtement Index. décimale : 667.9 Revêtements et enduits Résumé : The relationships between the fracture energy (Gc), film thickness, stress level, and weathering time were investigated for a number of automotive clearcoats. As weathering progressed, most clearcoats embrittled due to the combined effects of photooxidation, hydrolysis, and other degradation mechanisms. This embrittlement was measured and related to the chemical composition changes that take place in the clearcoat during weathering. When the fracture energy dropped below the driving energy for cracking, G, brittle cracking occurred. The driving force for cracking was shown to depend on stress level and film thickness. The importance of fatigue loading was also qualitatively investigated. These techniques were successfully used to anticipate the long-term weathering behavior of automative clearcoats. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5679
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Code-barres Cote Support Localisation Section Disponibilité 001233 - Périodique Bibliothèque principale Documentaires Disponible 001232 - Périodique Bibliothèque principale Documentaires Disponible Chemical depth profiling of automotive coating systems using slab microtome sectioning with IR/UV-VIS spectroscopy and optical microscopy / Karlis Adamsons in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 74, N° 924 (01/2002)
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Titre : Chemical depth profiling of automotive coating systems using slab microtome sectioning with IR/UV-VIS spectroscopy and optical microscopy Type de document : texte imprimé Auteurs : Karlis Adamsons, Auteur Année de publication : 2002 Article en page(s) : p. 47-54 Note générale : Bibliogr. Langues : Américain (ame) Tags : Essai vieillissement Dégradation photochimique Revêtement multicouche Etude expérimentale Microscopie optique Spectrométrie UV visible IR Microtomie Profil profondeur Feuil Analyse chimique Vernis Peinture Matériau revêtement Industrie automobile Index. décimale : 667.9 Revêtements et enduits Résumé : Chemical surface/near-surface analysis and depth profiling of high performance automotive coating systems can be done efficiently by commonly available infrared (IR), ultraviolet-visible (UV-VIS) and optical microscopy (OM) measurement technologies. The different stages of mass loss for acrylic/melamine-crosslinked clearcoats modeled after those used in high performance automotive coating systems were explored as a function of exposure time/conditions. Two approaches were used. Transmission mode IR experiments were conducted to monitor mass loss in isolated clearcoats. OM was used to monitor mass loss in clearcoats that are part of actual multilayered coating systems. UV-screener (UVA) permanence and interphase mixing (i.e., between clearcoat and basecoat layers) as well as general chemistry depth profiling studies of model acrylic/melamine-crosslinked and acrylic/melamine+silane-crosslinked clearcoats were done as a function of system preparation and exposure time/conditions. UVA depth profiles were obtained using slab microtomy sectioning co-planar to the surface, followed by solvent extraction and UV-VIS solution analysis to monitor UVA content as a function of section mass and thickness. General chemistry depth profiles were obtained using slab microtomy sectioning (as mentioned previously), followed by ATR (IR) analysis to monitor changes in the photooxidation index balues and the spectral envelop in the 2600-3800 cm-1 range. The approaches described herein de not require expertise/equipment that is available to only a few, thus increasing the potential utility of such tools. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5680
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Code-barres Cote Support Localisation Section Disponibilité 001233 - Périodique Bibliothèque principale Documentaires Disponible 001232 - Périodique Bibliothèque principale Documentaires Disponible Unexpected electronic effects on benzotriazole UV absorber photostability / Joseph C. Suhadolnik in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 74, N° 924 (01/2002)
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Titre : Unexpected electronic effects on benzotriazole UV absorber photostability : Mechanistic implications beyond excited state intramolecular proton transfer Type de document : texte imprimé Auteurs : Joseph C. Suhadolnik, Auteur ; Anthony D. DeBellis, Auteur ; Carmen Hendricks-Guy, Auteur ; Revathi Lyengar, Auteur ; Mervin G. Wood, Auteur Année de publication : 2002 Article en page(s) : p. 55-61 Note générale : Bibliogr. Langues : Américain (ame) Tags : Etude expérimentale Acrylique dérivé polymère Thermoplastique Mélamine résine Transfert proton Réaction intramoléculaire Etat excité Effet électronique Benzotriazole Absorbant UV Adjuvant Stabilité photochimique Peinture Matériau revêtement Dégradation Polymère Index. décimale : 667.9 Revêtements et enduits Résumé : Electron withdrawing groups at the 5-position of beazotriazole ultraviolet absorbers (UVA) surprisingly improve photopermanence despite weakening the intramolecular hydrogen bond believed to be responsible for photostability. These results, encountered in coatings, thermplastics, and solvents, contradict the assumption from the widely accepted view of UVA photostability that a stronger H-bond would generate a more stable UVA. Calculations suggest the involvement of a conical intersection in benzotriazole excited state deactivation and support a significant role for charge transfer. Modifications to the traditional model of UVA photostability are discussed which more fully consider electronic factors and molecular motions other than H-transfer. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5681
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Code-barres Cote Support Localisation Section Disponibilité 001233 - Périodique Bibliothèque principale Documentaires Disponible 001232 - Périodique Bibliothèque principale Documentaires Disponible Patterns of erosion from acrylic and fluoropolymer coatings in accelerated and natural weathering tests / Kurt A. Wood in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 74, N° 924 (01/2002)
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Titre : Patterns of erosion from acrylic and fluoropolymer coatings in accelerated and natural weathering tests Type de document : texte imprimé Auteurs : Kurt A. Wood, Auteur ; Lotfi Hedhli, Auteur ; Jeanene Willcox, Auteur Année de publication : 2002 Article en page(s) : p. 63-68 Note générale : Bibliogr. Langues : Américain (ame) Tags : Etude expérimentale Microscopie électronique balayage Feuil Dégradation Erosion Essai vieillissement accéléré naturel Vinylidène fluorure polymère Polymère fluor Acrylique dérivé Peinture Matériau revêtement Index. décimale : 667.9 Revêtements et enduits Résumé : Commercial poly(vinylidene difluoride) (PVDF)/acrylic coatings show minimal gloss loss or bulk chemical change even after sustained Florida or accelerated weathering testing. Previously, we showed that QUV-B weight loss rates can be used as an early predictor of the weatherability of fluoropolymer/acrylic biend clearcoats. In this work, we study the microscopic basis for differences seen between various blends and pure acrylic coatings. Scanning electron microscopy (SEM) images reveal different characteristic patterns of degradation. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5682
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Code-barres Cote Support Localisation Section Disponibilité 001233 - Périodique Bibliothèque principale Documentaires Disponible 001232 - Périodique Bibliothèque principale Documentaires Disponible New accelerated weathering tests including acid rain / Magnus Palm in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 74, N° 924 (01/2002)
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Titre : New accelerated weathering tests including acid rain Type de document : texte imprimé Auteurs : Magnus Palm, Auteur ; Bo Carlsson, Auteur Année de publication : 2002 Article en page(s) : p. 69-74 Note générale : Bibliogr. Langues : Américain (ame) Tags : Durabilité Industrie automobile Pluie acide Essai vieillissement accéléré Peinture Matériau revêtement Index. décimale : 667.9 Revêtements et enduits Résumé : A procedure for the design of reliable accelerated weathering tests for service life prediction of automotive coatings was developed and used in designing an accelerated test based on SAE method J 1960. The influence of exposure conditions was investigated in several accelerated tests. Results from these tests and from Florida exposures were used to optimize test conditions. A test cycle that includes acid rain spraying was developed and evaluated by exposing 16 different coating systems using various methods. The results indicate that the new cycle is more reliable than a cycle commonly used today. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5683
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Code-barres Cote Support Localisation Section Disponibilité 001233 - Périodique Bibliothèque principale Documentaires Disponible 001232 - Périodique Bibliothèque principale Documentaires Disponible Computer analysis of a polymer coating exposed to field weather conditions / Doug Burch in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 74, N° 924 (01/2002)
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Titre : Computer analysis of a polymer coating exposed to field weather conditions Type de document : texte imprimé Auteurs : Doug Burch, Auteur ; Jonathan W. Martin, Auteur ; Mark R. VanLandingham, Auteur Année de publication : 2002 Article en page(s) : p. 75-86 Note générale : Bibliogr. Langues : Américain (ame) Tags : Simulation numérique Modélisation Transfert masse chaleur Feuil Dégradation photochimique Exposition intempérie Peinture Matériau revêtement Index. décimale : 667.9 Revêtements et enduits Résumé : A heat and moisture transfer model was used to study weathering of polymeric materials, such as paint, asphalt, sealants, plastics, textiles, and poly meric composites. Three damage indices, related to temperature changes, humidity changes, and time of wetness, respectively, were introduced to quantify adverse effects of climate. The variation of these indices was investigated for a hot and humia climate (Miami, FL) and a hot and dry climate (Phoenix, AZ). In addition, the relative effects of solar radiation, surface wetting by rain and dew condensation, and variations in outdoor tempera ture and relative humidity on the three damage indices were investigated. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5684
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Code-barres Cote Support Localisation Section Disponibilité 001233 - Périodique Bibliothèque principale Documentaires Disponible 001232 - Périodique Bibliothèque principale Documentaires Disponible Weathering performance of thermoset and photoset acrylate coatings / C. Decker in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 74, N° 924 (01/2002)
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Titre : Weathering performance of thermoset and photoset acrylate coatings Type de document : texte imprimé Auteurs : C. Decker, Auteur ; Khalid Zahouily, Auteur Année de publication : 2002 Article en page(s) : p. 87-92 Note générale : Bibliogr. Langues : Américain (ame) Tags : Etude expérimentale Vernis Feuil Dégradation photochimique Acrylate polymère Essai vieillissement accéléré Durcissement Thermodurcissable Peinture photodurcissable Matériau revêtement Index. décimale : 667.9 Revêtements et enduits Résumé : Thermosetting and photosetting acrylate polymers have been tested for their resistance to acceleraled weathering. The chemical changes occurring both upon curing and upon photoaging have been followed by infrared spectroscopy. In the photodegraded polymers some functional groups are lost (ether, amide, CH groups) and oxidation products are formed (carbonyl and hydroxyl groups). The UV-cured polyurethane-acrylate coatings were found to be more resistant to accelerated weathering than the melamine/acrylate thermosets currently used as automotive finishes. The light stability of both thermoset and photoset acrylate clearcoats was substantially increased by the addition of a hydroxy-phenyltriazine UV-absorber and a HALS radical scavenger. The weathering resistance of painted metallic panels has been markedly enhanced by means of properly stabilized UV-cured acrylic coatings. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5685
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