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JOURNAL OF LEATHER SCIENCE AND ENGINEERING . Vol. 2Mention de date : Année 2020Paru le : 15/12/2020 |
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Ajouter le résultat dans votre panierThe center of pressure progression characterizes the dynamic function of high-arched feet during walking / Bo Li in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : The center of pressure progression characterizes the dynamic function of high-arched feet during walking Type de document : texte imprimé Auteurs : Bo Li, Auteur ; Qipeng Xiang, Auteur ; Xianyi Zhang, Auteur Année de publication : 2020 Article en page(s) : 10 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse des données
Marche
PiedTags : 'Haute-arche' 'Marche' 'Centre de pression' Rapidité Index. décimale : 613.71 Exercice et activités sportives Résumé : - Background : The medial longitudinal arch height has an effect on kinetic parameters during gait and might be related to the risk of injury. For the assessment of foot structures, the center of pressure (COP) trajectory is a more reliable and practical parameter than plantar pressure. This study aimed to clarify the COP trajectory and velocity characteristics in the medial-lateral and anterior-posterior direction of individuals with a high-arched foot during barefoot walking.
- Methods : Sixty-two healthy young adults were asked to walk over a Footscan pressure plate to record the COP parameters during the stance phase of walking.
- Results : Compared to normal arched feet, the COP during forefoot contact and foot flat phases of high-arched feet shifted anteriorly (19.9 mm and 15.1 mm, respectively), and the mean velocity of COP in anterior-posterior direction decreased by 0.26 m/s and increased by 0.044 m/s during these two phases respectively.
- Conclusions : The findings of this study suggest that the displacement and velocity of COP in anterior-posterior direction was different between high-arched and normal-arched subjects during barefoot walking, which can be used for the assessment of gait characteristics for high-arched individuals. The results of this study may provide insights into modifying clinical intervention for individuals with high-arched feet to enhance rehabilitation and prevent injuries and have implications for assessing the design of footwear and foot orthotics.Note de contenu : - Participants
- Materials and apparatus
- Procedures
- Data analysis
- Table 1 : Statistics of subjects
- Table 2 : Comparison of ML-COP deviation and velocity between high-arched and normal feet
- Table 3 : Comparison of AP-COP deviation and velocity between high-archedes and normal feetDOI : 10.1186/s42825-019-0016-6 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-019-0016-6.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37137
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 10 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire A facile preparation of a novel non-leaching antimicrobial waterborne polyurethane leather coating functionalized by quaternary phosphonium salt / Wang Chunhua in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : A facile preparation of a novel non-leaching antimicrobial waterborne polyurethane leather coating functionalized by quaternary phosphonium salt Type de document : texte imprimé Auteurs : Wang Chunhua, Auteur ; Jianhui Wu, Auteur ; Changdao Mu, Auteur ; Wei Lin, Auteur Année de publication : 2020 Article en page(s) : 12 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Ammoniums quaternaires
Antibactériens
Caractérisation
Composés organiques -- Synthèse
Cuir
Essais (technologie)
Formulation (Génie chimique)
Polymères en émulsion
Polyuréthanes
RevêtementsIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : The aim of this research is to develop a novel non-leaching antimicrobial waterborne polyurethane (WPU) leather coating material with covalently attached quaternary phosphonium salt (QPS). The structure of the QPS-bearing WPU has been identified, and their thermal stability, mechanical property, and antimicrobial performance have been investigated. The results reveal that the incorporation of QPS slightly reduces the thermal stability of WPU material but would not affects its usability as leather coating. Despite the presence of hydrophobic benzene in QPS structure, the strong hydration of its cationic groups leads to the increased surface contact angle (SCA) and water absorption rate (WAR) of the films, suggesting that the water resistance of the films needs to be improved for the purpose of leather coatings. Antibacterial tests demonstrate that when the QPS content is 20 wt%, QPS-bearing WPU shows effective antimicrobial activity against bacteria. The WPU containing QPS prepared in this study is a non-leaching antimicrobial material and has great potential application as leather coating. Note de contenu : - Materials
- Synthesis of dihydroxy-terminated QPS (HQPS)
- Synthesis of QPS-bearing WPU
- Characterization methods
- Testing of antibacterial property
- Table 1 : Formulations and characteristics of WPU
DOI : 10.1186/s42825-019-0014-8 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-019-0014-8.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37138
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 12 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Raman and ATR-FTIR spectroscopy towards classification of wet blue bovine leather using ratiometric using ratiometric and chemometric analysis / Megha Mehta in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Raman and ATR-FTIR spectroscopy towards classification of wet blue bovine leather using ratiometric using ratiometric and chemometric analysis Type de document : texte imprimé Auteurs : Megha Mehta, Auteur ; Rafea Naffa, Auteur ; Catherine Maidment, Auteur ; Geoff Holmes, Auteur ; Mark Waterland, Auteur Année de publication : 2020 Article en page(s) : 15 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse multivariée
Cuirs et peaux -- Analyse
Cuirs et peaux -- Défauts
Cuirs et peaux de bovins
Réflexion totale atténuée
Spectroscopie Raman
Wet-blue (tannage)Peau tannée au chrome (le chrome donne une couleur bleue)Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : There is a substantial loss of value in bovine leather every year due to a leather quality defect known as “looseness”. Data show that 7% of domestic hide production is affected to some degree, with a loss of $35 m in export returns. This investigation is devoted to gaining a better understanding of tight and loose wet blue leather based on vibrational spectroscopy observations of its structural variations caused by physical and chemical changes that also affect the tensile and tear strength. Several regions from the wet blue leather were selected for analysis. Samples of wet blue bovine leather were collected and studied in the sliced form using Raman spectroscopy (using 532 nm excitation laser) and Attenuated Total Reflectance - Fourier Transform InfraRed (ATR-FTIR) spectroscopy. The purpose of this study was to use ATR-FTIR and Raman spectra to classify distal axilla (DA) and official sampling position (OSP) leather samples and then employ univariate or multivariate analysis or both. For univariate analysis, the 1448 cm− 1 (CH2 deformation) band and the 1669 cm− 1 (Amide I) band were used for evaluating the lipid-to-protein ratio from OSP and DA Raman and IR spectra as indicators of leather quality. Curve-fitting by the sums-of-Gaussians method was used to calculate the peak area ratios of 1448 and 1669 cm− 1 band. The ratio values obtained for DA and OSP are 0.57 ± 0.099, 0.73 ± 0.063 for Raman and 0.40 ± 0.06 and 0.50 ± 0.09 for ATR-FTIR. The results provide significant insight into how these regions can be classified. Further, to identify the spectral changes in the secondary structures of collagen, the Amide I region (1600–1700 cm− 1) was investigated and curve-fitted-area ratios were calculated. The 1648:1681 cm− 1 (non-reducing: reducing collagen types) band area ratios were used for Raman and 1632:1650 cm− 1 (triple helix: α-like helix collagen) for IR. The ratios show a significant difference between the two classes. To support this qualitative analysis, logistic regression was performed on the univariate data to classify the samples quantitatively into one of the two groups. Accuracy for Raman data was 90% and for ATR-FTIR data 100%. Both Raman and ATR-FTIR complemented each other very well in differentiating the two groups. As a comparison, and to reconfirm the classification, multivariate analysis was performed using Principal Component Analysis (PCA) and Linear Discriminant Analysis (LDA). The results obtained indicate good classification between the two leather groups based on protein and lipid content. Principal component score 2 (PC2) distinguishes OSP and DA by symmetrically grouping samples at positive and negative extremes. The study demonstrates an excellent model for wider research on vibrational spectroscopy for early and rapid diagnosis of leather quality. Note de contenu : - EXPERIMENTAL : Sample preparation - Data acquisition and spectral processing
- RESULTS AND DISCUSSION : Peaks of interest - Univariate analysis - Multivariate analysis
- Table 1 : Raman and infrared spectroscopic band assignments for Wet Blue leather
- Table 2 : Raman band assignments distinguishing loose and tight wet blue leather
- Table 3 : Deconvoluted amide I band assignments for protein secondary structures
- Table 4 : Confusion matrix for Raman univariate analysis
- Table 5 : Confusion matrix for IR univariate analysis
- Table 6 : Confusion matrix for the classification of OSP and DA based on the PCA-LDA modelDOI : 10.1186/s42825-019-0017-5 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-019-0017-5.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37139
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 15 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Amphiphilic hyperbranched polymers : synthesis, characterization and self-assembly performance / Ren Longfang in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Amphiphilic hyperbranched polymers : synthesis, characterization and self-assembly performance Type de document : texte imprimé Auteurs : Ren Longfang, Auteur ; Qiaoxuan Niu, Auteur ; Jing Zhao, Auteur ; Taotao Qiang, Auteur Année de publication : 2020 Article en page(s) : 12 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Composés amphiphiles
Encapsulation
Polymères -- Synthèse
Polymères amphiphiles
Systèmes auto-assemblésIndex. décimale : 668.9 Polymères Résumé : A series of amphiphilic hyperbranched polymers (AHP-s, the “s” refers to the algebra of AHP) were synthesized by the reaction between hydroxyl-terminated hyperbranched polymers (HBP-s, the “s” refers to the algebra of HBP) and palmitoyl chloride. FTIR, NMR and GPC were used to determine the structure of AHP-s, the results showed that AHP-s exhibits core-shell structure. The thermal properties of polymers were investigated by DSC and TGA. It was found that AHP-2, AHP-3 and AHP-4 display higher thermal stability than AHP-1 (AHP-1, AHP-2, AHP-3 and AHP-4 represent the first, second, third and fourth generation AHP, respectively). Furthermore, the self-assembly performance of AHP-s in THF solvent was investigated by TEM and SEM. Finally, the encapsulation capacity of the AHP-s for methyl orange (MO) was explored at different concentrations of AHP-s and pH conditions. It was found that AHP-s is capable of accommodating hydrophilic guest MO. Moreover, the higher generation of AHP-s, the stronger encapsulation capacity obtained. And the encapsulation capacity closely associated with the pH of encapsulation system. Note de contenu : - EXPERIMENTAL SECTION : Materials - Synthesis of amphiphilic hyperbranched polymers (AHP-s) - Characterization - Self-assembly experimental method in THF - Methodology for dye extraction phase transfer processes - Phase transfer experiment under different pH
- RESULTS AND DISCUSSION : Characterization of amphiphilic hyperbranched polymers - Thermal properties of amphiphilic hyperbranched polymers - Self-assembly of amphiphilic hyperbranched polymers in THF - Phase transfer mechanism - Phase transfer mechanism under different pHDOI : https://doi.org/10.1186/s42825-019-0015-7 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-019-0015-7.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37328
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 12 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire A leather coating with self-healing characteristics / Feifei Liang in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : A leather coating with self-healing characteristics Type de document : texte imprimé Auteurs : Feifei Liang, Auteur ; Tianyou Wang, Auteur ; Haojun Fan, Auteur ; Jun Xiang, Auteur ; Yi Chen, Auteur Année de publication : 2020 Article en page(s) : 5 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Cuir
Polymères autoréparants
Polyuréthanes
Revêtement autoréparantIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Genuine leather is often coated before making daily necessities such as shoes, clothing, bags, sofas, car seats, etc., so as to impart leather products various colours, higher wear resistance and water resistance and so on. However, the coating of these products is often damaged in daily use which will decrease its aesthetic effect and practicability. Therefore, how to improve the scratch resistance of leather coatings has been puzzling people all the time. It is a common knowledge that animals and plants can repair the injured biological tissues by himself. According to this principle, here, we prepared a type of self-healing water-borne polyurethane with disulfide bond in the main chain by using HEDS as chain extender, and the self-healing system was triggered by the disulfide bonds with the help of shape memory function of waterborne Polyurethane, self-healing experiments how that the damaged of leather coating can be repaired fully at 60 °C for 12 h. Note de contenu : - Table 1 : Mechanical properties variation of polyurethane film before and self-healing DOI : https://doi.org/10.1186/s42825-020-0018-4 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-0018-4.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37329
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 5 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Facile fabrication of functional cellulose paper with high-capacity immobilization of Ag nanoparticles for catalytic applications for tannery wastewater / Ruiquan Yu in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Facile fabrication of functional cellulose paper with high-capacity immobilization of Ag nanoparticles for catalytic applications for tannery wastewater Type de document : texte imprimé Auteurs : Ruiquan Yu, Auteur ; Tianxiang Lan, Auteur ; Jing Jiang, Auteur ; Hao Peng, Auteur ; Ruifeng Liang, Auteur ; Gongyan Liu, Auteur Année de publication : 2020 Article en page(s) : 11 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Argent
Catalyseurs
CelluloseLa cellulose est un glucide constitué d'une chaîne linéaire de molécules de D-Glucose (entre 200 et 14 000) et principal constituant des végétaux et en particulier de la paroi de leurs cellules.
Eaux usées
Nanoparticules
Papier
Tannage -- DéchetsIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : It has been a research goal to develop macroscopic materials with an optimized surface structure to affix silver nanoparticles which could contaminate water and maximize their practical functions. Cellulose paper is a versatile biomass material valued for its abundance, low cost, biocompatibility, and natural composition. Until now, its potential application in water purification has not been adequately explored. In this study, gallic acid-modified silver nanoparticles (GA@AgNPs) were loaded onto commercial cellulose filter paper using a simple lipoic acid modification process (GA@AgNPs-LA-CP). Scanning electron microscopy (SEM), X-ray photoelectron spectroscopy (XPS), and X-ray diffraction (XRD) were used to characterize the GA@AgNPs-LA-CP. The catalytic activity of the GA@AgNPs-LA-CP was evaluated by the reduction reaction of methylene blue (MB), Rhodamine B (RhB), and 4-nitrophenol (4-NP) with sodium borohydride (NaBH4). The GA@AgNPs-LA-CP exhibited excellent catalytic activity toward MB, RhB, and 4-NP, taking advantage of its high specific surface area generated by the cellulose fiber network structure. Interestingly, due to the electrostatic interactions between the cationic dyes and the GA@AgNPs, the as-prepared catalytic composite material serves as a better catalyst for MB and RhB, suggesting dual applications of the composite materials for organic wastewater treatment and the removal of harmful dyes. This implies that the immobilization of AgNPs on cellulose papers is an effective method and can be applied to efficient wastewater treatment applications. Note de contenu : - EXPERIMENTAL SECTION : Materials - Preparation of lipoic acid-modified cellulose paper (LA-CP) - Preparation of GA@AgNPs immobilized cellulose paper by lipoic acid modification (GA@AgNPs-LA-CP) - Characterizations - Measurement of Ag content on GA@AgNPs-LA-CP - Catalytic reduction of 4-NP, MB and RhB
- RESULTS AND DISCUSSION : Preparation and characterization of GA@AgNPs-LA-CP
- CATALYTIC PROPERTIES OF GA@AgNPs-LA-CPDOI : https://doi.org/10.1186/s42825-020-00019-y En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00019-y.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37330
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 11 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Denatured proteins as a novel template for the synthesis of well-defined, ultra-stable and water-soluble metal nanostructures for catalytic applications / Chaojian Chen in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Denatured proteins as a novel template for the synthesis of well-defined, ultra-stable and water-soluble metal nanostructures for catalytic applications Type de document : texte imprimé Auteurs : Chaojian Chen, Auteur ; David Yuen Wah Ng, Auteur ; Tanja Weil, Auteur Année de publication : 2020 Article en page(s) : 11 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Catalyse
Nanoparticules
Nanostructures
Or
Platine
ProtéinesIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : The templated synthesis of noble metal nanoparticles using biomass, such as proteins and polysaccharides, has generated great interest in recent years. In this work, we report on denatured proteins as a novel template for the preparation of water-soluble metal nanoparticles with excellent stability even after high speed centrifugation or storage at room temperature for one year. Different noble metal nanoparticles including spherical gold and platinum nanoparticles as well as gold nanoflowers are obtained using sodium borohydride or ascorbic acid as the reducing agent. The particle size can be controlled by the concentration of the template. These metal nanoparticles are further used as catalysts for the hydrogenation reaction of p-nitrophenol to p-aminophenol. Especially, spherical gold nanoparticles with an average size of 2 nm show remarkable catalytic performance with a rate constant of 1.026 × 10− 2 L s− 1 mg− 1. These metal nanoparticles with tunable size and shape have great potential for various applications such as catalysis, energy, sensing, and biomedicine. Note de contenu : - EXPERIMENTAL SECTION : Materials - Synthesis of cationic HSA (cHSA) - Preparation of PEGylated cHSA (PEG-cHSA) - Synthesis of denatured PEG-cHSA (PEG-dcHSA) - Synthesis of AuNPs using NaBH4 as the reducing agent - Synthesis of AuNFs using ascorbic acid as the reducing agent - Synthesis of PtNPs using NaBH4 as the reducing agent - Catalytic reduction of p-nitrophenol to p-aminophenol - Characterization
- RESULTS AND DISCUSSION : Unfolding native proteins to well-defined biopolymers - Ultrasmall AuNPs prepared using NaBH4 as the reducing agent - AuNFs prepared using ascorbic acid as the reducing agent - Catalytical reduction of p-nitrophenol by Au nanostructures
Synthesis of PtNPs and their catalytic performance
- Table 1 : Conditions for the synthesis of ultrasmall AuNPs using NaBH4 as the reducing agentDOI : https://doi.org/10.1186/s42825-020-00020-5 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00020-5.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37331
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 11 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Interaction between retanning agents and wet white tanned by a novel bimetal complex tanning agent / Wanli Huang in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Interaction between retanning agents and wet white tanned by a novel bimetal complex tanning agent Type de document : texte imprimé Auteurs : Wanli Huang, Auteur ; Ying Song, Auteur ; Yue Yu, Auteur ; Ya-Nan Wang, Auteur ; Bi Shi, Auteur Année de publication : 2020 Article en page(s) : 9 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Complexes métalliques
Cuirs et peaux -- Analyse
Point isoélectriqueEn biochimie, le point isoélectrique (pI) ou potentiel hydrogène isoélectrique (pHI) est le pH auquel une molécule est sous forme d'ion mixte ou, en physico-chimie, le pH d'une solution aqueuse dans laquelle un solide existe sous un potentiel électrique neutre.
En physico-chimie : Selon Bolger, le caractère acide ou basique d'une surface s'exprime par son point isoélectrique " Is ou IEPS (Iso Electric point for the surface) " ou point de charge nulle " PCN ou PZC (Point of Zero Charge) ", défini comme étant le pH de la solution aqueuse dans laquelle le solide existe sous un potentiel électrique neutre. Si le pH de la solution est basique, la surface est acide, et inversement. La différence entre le PZC et l'IEPS est basée sur le phénomène d'adsorption spécifique. On peut considérer que si la grandeur mesurée ne dépend pas de la solution utilisée pour la mesurer (pH, concentration, nature des ions), alors on a affaire à un PZC. Dans le cas contraire, c'est un IEPS que l'on mesure. Par exemple, quand la mesure de goutte sessile à deux liquides est utilisée, on considère en général qu'il n'y a pas adsorption des ions de cette goutte et que la goutte déplace complètement l'alcane qui sert de deuxième liquide: on est alors en présence d’un PZC. Au contraire, dans les mesures de potentiel d'écoulement (streaming potential), la solution joue un rôle important et c'est un IEPS que l'on mesure. Enfin, la charge nette se définit grâce au pH de la solution aqueuse dans laquelle la surface métallique existe, dans un état électriquement neutre (c’est-à-dire [M-OH2+ surf]=[M-O- surf]) et au PZC.
- Si pH < PZC alors la charge nette est positive
- Si pH > PZC alors la charge nette est négative.
Il existe plusieurs méthodes expérimentales permettant de décrire l’état acido-basique de la surface : la mesure du potentiel d’écoulement, la photoélectrochimie, la mesure de l’angle de contact, et la spectroscopie XPS.
Retannage
Tannage chrome free
Traçage fluorescent
Wet-white (tannage)Index. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : A promising and practical chrome-free tanning system has been developed based on a novel Al–Zr bimetal complex tanning agent. However, to achieve satisfactory resultant leather, the retanning process that is compatible with this emerging tannage needs to be investigated systematically. This paper aims to explore the interaction between the bimetal complex tanned wet white and retanning agents. The isoelectric point (pI) of wet white was 7.2, which was nearly the same as wet blue. The electropositivity of wet white was even higher than that of wet blue during post-tanning processes, resulting in higher uptake rate of retanning agents. The distribution of various retanning agents in wet white was analyzed by pI measurement of layered leather and fluorescent tracing technique. The retanning agents were unevenly distributed throughout the cross-section, which might be an important restriction factor in obtaining satisfactory organoleptic properties of the crust leather. This fact is mainly due to the strong electrostatic interaction between anionic retanning agents and wet white. Applying a high dosage of multiple retanning agents in a proper sequence of addition benefited the full penetration of retanning agents in leather matrix and thus improved the organoleptic properties of crust leather. This work provides guidance for optimizing retanning process of the wet white leather. Note de contenu : - EXPERIMENTAL : Materials - Post-tanning processes of wet white and wet blue - Retanning trials of wet white - Observation of retanning agents distribution in leather - Analytical methods
- RESULTS AND DISCUSSION : Charge properties of leather during post-tanning - Interaction between wet white and single retanning agent - Interaction between wet white and multiple retanning agents
- Table 1 : Retanning trialsDOI : https://doi.org/10.1186/s42825-020-00023-2 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00023-2.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37332
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 9 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire A simple approach with scale-up potential towards intrinsically flame-retardant bio-based co-plasticizer for PVC artificial materials / Yong Xu in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : A simple approach with scale-up potential towards intrinsically flame-retardant bio-based co-plasticizer for PVC artificial materials Type de document : texte imprimé Auteurs : Yong Xu, Auteur ; Songhang Wang, Auteur ; Jinming Chang, Auteur ; Zhou Xu, Auteur ; Qi Zeng, Auteur ; Zhonghui Wang, Auteur ; Jun Yan, Auteur ; Yi Chen, Auteur Année de publication : 2020 Article en page(s) : 9 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Biomatériaux
Chlore
Chlorure de polyvinyle
Cuir synthétique
Esters méthyliques d'acides gras
IgnifugeantsComposé chimique utilisé pour réduire l'inflammabilité. Il peut être incorporé au produit durant sa fabrication ou appliqué ultérieurement à sa surface.
PlastifiantsIndex. décimale : 668.9 Polymères Résumé : As an imitation of genuine leather, polyvinyl chloride (PVC) artificial materials are versatile, but suffers from being flammable due to the presence of large amounts of combustible plasticizers. Under such circumstance, intrinsically flame-retardant plasticizers displaying dual functions have been a subject of intensive research interest. However, previous strategies attempting to covalently attach flame-retardant moiety to plasticizers invariably required either expensive starting materials or laborious and tedious procedures, ultimately limiting their scale-up application in industry. In addition, driven by escalating demand of halogen-free flame retardants worldwide from an environmental health perspective, previously reported intrinsically flame-retardant plasticizers were mainly halogen-free, less attractive in PVC artificial material industry simply because PVC itself is a halogen-containing polymer. Here, we report an approach to introduce chlorine moieties into unsaturated fatty acid methyl ester by a simple addition reaction occurring on carbon-carbon double bonds, yielding a chlorine-containing, intrinsically flame-retardant bio-plasticizer. When combined with di-(2-ethylhexyl) phthalate (DOP) in PVC formulations, the chlorinated fatty acid methyl ester is qualified as a co-plasticizer while conferring flame retardancy upon the PVC coatings. This approach involves only a one-step procedure that employs renewable fatty acid methyl esters and cheap chlorine gas as raw materials, thus being of great potential to enable intrinsically flame-retardant bio-plasticizers on a large scale to manufacture functional PVC artificial materials for application in fire-prone scenarios. Note de contenu : - Materials
- Synthesis of chlorinated fatty acid methyl ester (CFAME)
- Preparation of plasticized PVC coating
- Characterization
- Table 1 : Composition of PVC/CFAMEx
- Table 2 : Composition of CFAME identified by comparing the experimental mass spectra of the components in Fig. 3 against NIST08 mass spectral library
- Table 3 : Glass transition temperatures of PVC/CFAMEx coatings as determined by DMA analysis
- Table 4 : TGA data of PVC/CFAMEx coatingsDOI : https://doi.org/10.1186/s42825-020-00022-3 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00022-3.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37333
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 9 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Influence of microwave on chromium complex composition in tanning liquor / Jinwei Zhang in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Influence of microwave on chromium complex composition in tanning liquor Type de document : texte imprimé Auteurs : Jinwei Zhang, Auteur ; Wuyong Chen, Auteur ; Carmen Gaidau, Auteur Année de publication : 2020 Article en page(s) : 11 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Chromatographie par échange d'ions
Chromatographie sur gel
Complexes métalliques
Liqueurs de tannage
Micro-ondesIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : Since microwave irradiation could promote hydrolysis and olation of chromium tanning liquor, but the influence of microwave on chromium complex component in the liquor was still unknown. Chromium sulphate solution (0% basicity) and 33% basicity chromium tanning liquor were subjected microwave (MW) and water bath (WB) heating, and the samples without any warming were regarded as control. Ion exchange chromatography (IEC) and gel filtration chromatography (GFC) were used to measure the charge composition and molecular size of chromium complexes in each sample. FT-IR was used to characterize the structure of chromium complexes in each composition separated by IEC. Moreover, the chromium tanning liquor after warming was used in hide powder tanning trials to illustrate whether microwave would affect its tanning ability. The results show there are more high positive charge and large molecular size complexes in chromium tanning liquor after warming but the phenomena are more significant in MW samples compared with WB due to non-thermal effect of microwave. In addition, microwave has more powerful effect on 33% basicity chromium tanning liquor hydrolysis and olation to generate larger molecular size complexes. In FT-IR results, the combination pattern between chromium and ligands are changed after warming but there is no difference between WB and MW. The chromium exhaustion and thermal stability of hide powder tanned with chromium tanning liquor after microwave irradiation are both higher. It could conclude that both thermal and non-thermal effects of microwave promote the process together, and the non-thermal effect leads to more high positive charge and large molecular size complexes and has stronger influence on high polarity system. In short, this work would provide theoretical basis for applying microwave in tanning agent modification and chrome tanning process further. Note de contenu : - EXPERIMENTAL : Reagents and materials - Instruments - Sample preparation - Determination methods
- RESULTS AND DISCUSSION : The influence of microwave on chromium charge composition in tanning liquor - The influence of microwave on chromium molecular size in tanning liquors - The influence of microwave on chromium complex structure - The influence of microwave on tanning ability of chromium tanning liquor
- Table 1 : The content of each component in 0% basicity chromium sulphate tanning liquor warmed under different methods
- Table 2 : The content of each component in 33% basicity chromium sulphate tanning liquor warmed under different methods
- Table 3 : FT-IR absorption peaks of SO42− in chromium complex from each component in 0% basicity chromium sulphate tanning liquor
- Table 4 : FT-IR absorption peaks of SO42− in chromium complex from each component in 33% basicity chromium sulphate tanning liquor
- Table 5 : The thermal behaviors and chrome content of hide powder tanned by chrome tanning liquor treated by different methodDOI : https://doi.org/10.1186/s42825-020-00024-1 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00024-1.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37334
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 11 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Differences in loading patterns between fast walking and jogging at the same speed in male adults / Ruoyi Li in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Differences in loading patterns between fast walking and jogging at the same speed in male adults Type de document : texte imprimé Auteurs : Ruoyi Li, Auteur ; Hao Liu, Auteur ; Mengyuan Guo, Auteur ; Jitka Badurova, Auteur ; Luming Yang, Auteur ; Haojun Fan, Auteur Année de publication : 2020 Article en page(s) : 7. p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Biomécanique
Course à pied
Hommes
Marche
Pied
Statistique
Transfert de chargeIndex. décimale : 796.51 Marche Résumé : Fast walking and jogging are two common exercises for people to maintain health in daily life. But the differences in loading patterns of fast walking and jogging are still unclear. The purpose of this study was to compare loading patterns in fast walking and jogging at the same speed, and to identify how differences in foot mechanics influence plantar pressure distribution between the two modes of gait. Totally, 49 healthy males participated in this study. Data of pressure parameters, including maximum force (MF), peak pressure (PP), contact area (CA), force-time integral (FTI), were recorded by Pedar-X insole plantar pressure measurement system in participants’ fast walking and jogging process at 7 km/h. A Load transfer analysis method was used to quantify the plantar load transference from fast walking to jogging. The results showed that MF, PP and CA increased in metatarsal regions and midfoot regions while decreased in toes regions and heel during jogging when compared with fast walking. FTI decreased in all foot regions during jogging compared to fast walking. Under the effects of spring mechanics and the varus of rearfoot during jogging, fast walking and jogging reveal different loading patterns. Compared jogging to fast walking, load transferred as follow : 1) in transverse direction, load transferred from lateral foot to medial foot in metatarsal regions and midfoot regions, 2) in longitudinal direction, load transferred from toes to the metatarsal, and from heel to the metatarsal and midfoot. These results also provide suggestions for footwear designs. Note de contenu : - Participants
- Speed selects
- Procedure
- Statistical analysis
- Load transfer analysis method
- Table 1 Relative FTI (%) in fast walking and jogging at 7 km/hDOI : https://doi.org/10.1186/s42825-020-00021-4 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00021-4.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37335
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 7. p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Progress and mechanism of breaking glycoconjugates by glycosidases in skin for promoting unhairing and fiber opening-up in leather manufacture. A review / Fengxiang Luo in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Progress and mechanism of breaking glycoconjugates by glycosidases in skin for promoting unhairing and fiber opening-up in leather manufacture. A review Type de document : texte imprimé Auteurs : Fengxiang Luo, Auteur ; Xiang Zhong, Auteur ; Mengchu Gao, Auteur ; Biyu Peng, Auteur ; Zhongzhen Long, Auteur Année de publication : 2020 Article en page(s) : 16 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Epilage
Follicule pileux
Glycoprotéines
Glycosaminoglycanes
GlycosidasesLes Glycoside hydrolases (ou glycosidases) catalysent l'hydrolyse de liaisons glycosidiques et libèrent au moins un composé osidique. Ce sont des enzymes extrêmement communes, dont les rôles sont aussi divers que la dégradation des glucides complexes (cellulose et hémicellulose), les défenses anti-bactériennes (ex. le lysozyme), la pathogénicité (ex. les neuraminidases virales) ou le métabolisme cellulaire (amylases ou enzyme de débranchement du glycogène pour le métabolisme énergétique, mannosidases comme modulateur de glycosylation des protéines, ...). Les glycosyltransférases et les glycosides hydrolases sont les deux classes majeures d'enzymes impliquées dans la synthèse et la rupture des liaisons osidiques.
Peau -- Anatomie
ProtéoglycanesUn protéoglycane est une glycoprotéine, combinaison d'une protéine et d'un glycosaminoglycane (GAG). L'association entre les deux types de chaîne s'effectue essentiellement dans l'appareil de Golgi, mais également au niveau du réticulum endoplasmique d'une cellule. La proportion de glucides des protéoglycanes peut atteindre 95 %. Ceux-ci se présentant sous la forme d'une ou plusieurs chaînes de glycosaminoglycanes non ramifiées. Les chaînes de sucres sont très longues mais pas ramifiées. Ils sont O-glycosylés, se lient à l'acide aminé sérine à l'extrémité OH. Les protéoglycanes peuvent être soit transportés à l'extérieur de la cellule par exocytose (s'intégrant alors à la matrice extracellulaire sous forme de chondroïtine-sulfate, kératan-sulfate, héparan-sulfate, dermatan-sulfate, etc.), soit entrer dans la constitution de la membrane plasmique ou du glycocalyx, jouant alors un rôle dans les relations cellule-matrice.
Les PG (protéoglycanes) ont des compositions et poids moléculaire très variés et sont hétérogènes au niveau de leur structure et de leur fonction.
Les protéoglycanes sont des composants essentiels de la matrice extracellulaire. Ce sont des pièges à eau qui sont importants pour les propriétés mécaniques des tissus cartilagineux par exemple. Les héparan sulfates peuvent avoir un rôle dans la signalisation : ce sont des co-récepteurs pour les FGF (Fibroblast Growth Factor). Les protéoglycanes jouent aussi un rôle dans la diffusion des molécules de signalisation (Wnt, Shh), ou bien en interagissant avec des inhibiteurs (Noggin). (Wikipedia)Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : The glycoconjugates, herein glyco-proteins, existing in animal skins are closely related to the effectiveness of unhairing and fiber opening-up. Glycosidases have been used in leather making processes to reduce pollutants and improve leather quality. But the selection of glycosidases is still blind because the related mechanisms are not well understood yet. Hence, the animal skin structures and glycoconjugates components, the advances in the methods and mechanisms of removing glycoconjugates related to unhairing and fiber opening-up in leather manufacture, the kinds, compositions, structures and functions of typical glycoconjugates in skin are summarized. Then the approaches to destroy them, possible glycosidases suitable for leather making and their acting sites are analyzed based on the recognition of glycoconjugates in skin and the specificities of glycosidases toward substrates. It is expected to provide useful information for the optimization of glycosidases and the development of new enzymes and the cleaner technologies of unhairing and opening up fiber bundles assisted by glycosidases. Note de contenu : - ANIMAL SKIN AND HAIR FOLLICLE STRUCTURES : Structure of animal skin - Structure of hair follicle
- ADVANCES IN THE METHODS AND MECHANISM OF REMOVING GLYCO-PROTEIN CONJUGATES RELATED TO UNHAIRING AND FIBER OPENING-UP IN LEATHER MANUFACTURE : Glycosidase assisting soaking - Glycosidase assisting opening up fiber bundles - Glycosidase assisting unhairing
- RECOGNITION OF GLYCO-PROTEIN CONJUGATES IN SKIN : Recognition of glyco-protein conjugates in skin - Glycoproteins(GPs) in skin - Proteoglycans (PGs) in skin - Relationship with collagen microfibrils - Relationship with hair follicle - Structures of decorin and biglycan - Perlecan - Versican
- POSSIBLE GLYCOSIDASES SUITABLE FOR BREAKING GLYCO-PROTEIN CONJUGATES IN LEATHER MAKING
- Table 1 : Similarities and differences of PG and GP
- Table 2 : The possible acting sites and products of some typical commercial glycosidases hydrolyzing glyco-protein conjugates in skinDOI : https://doi.org/10.1186/s42825-020-00025-0 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00025-0.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37336
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 16 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire The supramolecular redox functions of metallomacromolecules / Didier Astruc in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : The supramolecular redox functions of metallomacromolecules Type de document : texte imprimé Auteurs : Didier Astruc, Auteur Année de publication : 2020 Article en page(s) : 17 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Batteries électriques
Capteurs chimiques
Catalyseurs
Chimie supramoléculaire
DendrimèresUn dendrimère 1,2est une molécule dont la forme reprend celle des branches d'un arbre. Le nom vient du grec "δενδρον"/dendron, signifiant "arbre". En 1979, le premier dendrimère a été synthétisé par D.A. Tomalia3 et d'autres chercheurs de la Dow Chemical Company, et des dendrimères ont depuis été étudiés partout dans le monde pour leur forme unique.
Dans la synthèse des dendrimères, les monomères mènent à un polymère monodisperse, tel un arbre4. Il y a deux méthodes définies de synthèse des dendrimères: synthèse divergente5,6 et synthèse convergente7. La première assemble la molécule du noyau jusqu'à la périphérie et le second de l'extérieur vers le noyau.
Les propriétés des dendrimères sont engendrées par les structures moléculaires présentes sur sa surface. Par exemple, un dendrimère peut être hydrosoluble quand son extrémité-groupe est un groupe hydrophile, comme un groupe carboxylique. Il est théoriquement possible de concevoir un dendrimère hydrosoluble avec l'hydrophobicité interne, qui lui permettrait de porter un composé hydrophobe dans son intérieur (afin de transporter un composé thérapeutique hydrophobe dans le sang par exemple).
Une autre propriété est que le volume d'un dendrimère augmente quand il a une charge positive. Si cette propriété peut être appliquée, des dendrimères peuvent être employés pour les systèmes de transport d'éléments chimiques qui peuvent donner le médicament à la partie visée à l'intérieur du corps d'un patient directement (tumeur par exemple).
Les applications sont très diverses comme un élément organique électroluminescent, comme substitut sanguin, traitement anti-cancer, outils pour la multiplication de cellules, mais aussi en matériaux lors d'associations avec des nanotubes ou comme sondes sélectives et efficaces.
Dispositifs électrochromiques
FerrocèneLe ferrocène est un composé organométallique de formule Fe(C5H5). Il fait partie de la famille des métallocènes, un type de composé sandwich dans lequel le centre métallique est entouré de deux cycles cyclopentadiényle. La découverte d'un tel composé et de ses analogues a précipité la croissance dans le domaine de la chimie organométallique donnant suite à un prix Nobel.
Machines moléculaires
Oxydoréduction
Polymères
Réactions de transfert d'électronsIndex. décimale : 547.84 Composés macromoléculaires et composés connexes. Polymères Résumé : Metallomacromolecules are frequently encountered in redox proteins including metal-tanned hide collagen and play crucial roles involving supramolecular properties in biological electron-transfer processes. They are also currently found in non-natural families, such as: metallopolymers, metallodendrimers and metallodendronic polymers. This mini-review discusses the supramolecular redox functions of such nanomaterials developed in our research group. Electron-transfer processes are first examined in mono-, bis- and hexa-nuclear ferrocenes and other electron-reservoir organoiron systems showing the influence of supramolecular and reorganization aspects on their mechanism. Then applications of electron-transfer processes using these same organoiron redox systems in metallomacromolecules and their supramolecular functions are discussed including redox recognition/sensing, catalysis templates, electrocatalysis, redox catalysis, molecular machines, electrochromes, drug delivery device and nanobatteries. Note de contenu : - Electron transfer by Electron-rich Organo-Iron Sandwich complexes
- From single to simultaneous multi-Electron transfer
- Electron transfers from Hexa-Iron redox centers : A new electrostatic paradigm
- Multi-Electron transfers in redox-active polymers
- Electron transfers with Metallodendrimers and Metallodendronic polymersDOI : https://doi.org/10.1186/s42825-020-00026-z En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00026-z.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37337
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 17 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Investigation of different pre-treatments of chromium leather shavings to improve biogas production in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Investigation of different pre-treatments of chromium leather shavings to improve biogas production Type de document : texte imprimé Année de publication : 2020 Article en page(s) : 14 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Biogaz
Chimie analytique
Cuirs et peaux -- Déchets -- Recyclage
Digestion anaérobie
Extrusion (mécanique)
Traitement hydrothermiqueIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Chromium shavings are wet by-products of the leather industry, of which thousands of tons accrue worldwide during leather manufacture. Due to their chromium content, chromium shavings are responsible for the most important ecological challenges caused by the leather industry. They are stable towards temperatures of up to 110 °C and enzymatic degradation. This high stability is caused by the three-dimensional native structure, typical for collagen, and additional chemical cross-links between the collagen fibres achieved by Cr3+ salts in the tanning process. Therefore, hitherto chromium shavings are not utilized industrially to produce biogas. In order to generate biogas, this stable structure has to be denatured. Chromium shavings were pre-treated by extrusion and hydrothermal methods. To prove the enzymatic degradability, the different pre-treatments were evaluated by differential scanning calorimetry (DSC), enzymatic assays, and by measuring the solubility in water. The biogas production potential was investigated using batch trials to examine feasibility. Results demonstrated that both pre-treatments allowed enzymatic attack and increased degradability of the chromium shavings reducing the lag-phase of biogas production and the remaining waste. Note de contenu : - INTRODUCTION : Anaerobic digestion of chromium leather waste - Collagen structure and stability - Destabilization of chromium leather waste
- MATERIAL AND METHODS : Material - Pre-treated samples - Extrusion - Hydrothermal treatment - Scanning electron microscope (SEM) - Differential scanning calorimetry (DSC) - Enzyme assays - Solubility in water - Biogas production
- RESULTS AND DISCUSSION : Assessment of the pre-treated samples - Biogas production
- Table 1 : Pre-treatment conditions and sample nomenclatureDOI : https://doi.org/10.1186/s42825-020-00028-x En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00028-x.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37338
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 14 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Utilization of waste wool fibers for fabrication of wool powders and keratin : a review / Chunhua Zhang in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Utilization of waste wool fibers for fabrication of wool powders and keratin : a review Type de document : texte imprimé Auteurs : Chunhua Zhang, Auteur ; Liangjun Xia, Auteur ; Jiajing Zhang, Auteur ; Xin Liu, Auteur ; Weilin Xu, Auteur Année de publication : 2020 Article en page(s) : 15 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Biomatériaux
Biosorbant
Dissolution (chimie)
Fraisage
Ingrédients cosmétiques
kératinesLa kératine est une protéine, synthétisée et utilisée par de nombreux êtres vivants comme élément de structure, et également l'exemple-type de protéine fibreuse.
La kératine est insoluble, et peut être retrouvée sur l'épiderme de certains animaux, notamment les mammifères, ce qui leur garantit une peau imperméable. Parfois, lors d'une friction trop importante, la kératine se développe à la surface de la peau formant une callosité. Les cellules qui produisent la kératine meurent et sont remplacées continuellement. Les morceaux de kératine qui restent emprisonnés dans les cheveux sont couramment appelés des pellicules.
La molécule de kératine est hélicoïdale et fibreuse, elle s'enroule autour d'autres molécules de kératine pour former des filaments intermédiaires. Ces protéines contiennent un haut taux d'acides aminés à base de soufre, principalement la cystéine, qui forment un pont disulfure entre les molécules, conférant sa rigidité à l'ensemble. La chevelure humaine est constituée à 14 % de cystéine.
Il y a deux principales formes de kératines : l'alpha-kératine, ou α-keratin, présente chez les mammifères notamment, dont l'humain, et la bêta-kératine, ou β-keratin, que l'on retrouve chez les reptiles et les oiseaux. Ces deux types de kératines ne présentent clairement pas d'homologie de séquence.
Chez l'être humain, la kératine est fabriquée par les kératinocytes, cellules se trouvant dans la couche profonde de l'épiderme. Les kératinocytes absorbent la mélanine (pigment fabriqué par les mélanocytes), se colorent et ainsi cette pigmentation de l'épiderme permet de protéger les kératinocytes des rayons ultraviolets du Soleil. (Wikipedia)
Laine -- Déchets
Particules (matières)
Poudres
Recyclage (déchets, etc.)
Textiles et tissusIndex. décimale : 677.31 Laine Résumé : Wool fiber contains approximately 95% keratinous proteins, which is one of the most abundant sources of structural protein. However, a large amount of wool waste is underutilized. Developing appropriate approaches to recycle wool waste and produce value-added products is vital for sustainable development and reducing environmental burden. Thus, this paper reviews the mechanical methods of fabricating wool powder, including pan milling, combined wet and air-jet milling, steam explosion, freeze milling, and three-stage milling. The influencing factors of shape and size, structure, and properties are highlighted to overview of the possible controlling methods. Then, this review summarizes various chemical methods for the extraction of wool keratin, underlining the dissolution efficiency and the structure of wool keratin. Furthermore, the application of reused wool particles in textile, biosorbent, and biomaterials are also reported. Finally, several perspectives in terms of future research on the fabrication and application of wool particles are highlighted. Note de contenu : - PREPARATION METHODS OF WOOL PARTICLE : Mechanical method - First stage - Second stage - Third stage - Chemical method
- CURRENT APPLICATIONS OF WOOL PARTICLES : Wool particle-based textiles - Wool particle-based biosorbent - Wool particle-based cosmetic materials Wool particle-based biomaterials
- Table 1 Characteristics of wool keratin dissolution conditions using the ILs method
- Table 2 Metal ions adsorption performances of various wool particle-based materialsDOI : https://doi.org/10.1186/s42825-020-00030-3 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00030-3.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37448
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 15 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Visible-light-driven photocatalytic degradation of rhodamine B using Bi2WO6/GO deposited on polyethylene terephthalate fabric / Zoufei Du in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Visible-light-driven photocatalytic degradation of rhodamine B using Bi2WO6/GO deposited on polyethylene terephthalate fabric Type de document : texte imprimé Auteurs : Zoufei Du, Auteur ; Ce Cui, Auteur ; Sihang Zhang, Auteur ; Hongyan Xiao, Auteur ; Erhui Ren, Auteur ; Ronghui Guo, Auteur ; Shouxiang Jiang, Auteur Année de publication : 2020 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Lumière visible
Oxyde de graphène
Photocatalyse
Polyéthylène téréphtalate
Rhodamine
Textiles et tissus synthétiques
Tungstate de bismuthIndex. décimale : 677.4 Textiles artificiels Résumé : The environmental repercussions of wastewater from the dye process mean that it is very important to obtain an eco-friendly photocatalyst that would degrade wastewater. Herein, bismuth tungstate/graphene oxide (Bi2WO6/GO) composites are fabricated through in-situ hydrothermal reaction and then the Bi2WO6/GO photocatalysts are deposited onto polyethylene terephthalate (PET) fabric. The obtained Bi2WO6/GO deposited PET fabrics are then characterized through XPS, Raman, SEM, TEM, XRD, UV-vis, BET method and photoluminescence spectroscopy (PL) to investigate their chemical and crystal structures, morphology, optical property, surface area and photochemical properties. Photocatalytic performance is studied through examining the rate of degrading rhodamine B (RhB) under visible light. Surface of PET fibers is densely covered with Bi2WO6/GO. Bi2WO6/GO deposited PET fabrics show a broad absorption band in the visible spectra. Removal rate of RhB on the Bi2WO6/GO deposited PET fabric is the highest with the GO content of 2 g/L (labeled as Bi2WO6/2 g/LGO). The result of active species experiment shows that superoxide radicals (·O2−) plays a major role in the degradation of RhB. Moreover, Bi2WO6/2 g/LGO deposited PET fabric shows excellent cycle stability of photocatalytic degradation for RhB. The findings in this work can be extended to preparation other types of composite on the textile for photocatalysis, which can be applied to remove dyes in the wastewater produced by the textile or leather industry. Note de contenu : - EXPERIMENTAL : Materials - Preparation of Bi2WO6/GO deposited PET fabric - Characterizations - Photocatalytic activity evaluation
- RESULTS AND DISCUSSION : XPS and Raman spectra - Morphology - Crystal structure - UV-vis DRS - Surface area - PL analysis - Photocatalytic properties of Bi2WO6/GO deposited PET fabrics - Effects of Bi2WO6/2 g/L GO content and concentration of RhB on photocatalytic performance - Recycle stability and trapping experiment of Bi2WO6/2 g/L GO deposited PET fabricDOI : https://doi.org/10.1186/s42825-020-00029-w En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00029-w.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37449
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020)[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Highly selective and sensitive colorimetric chemosensor based on tricarboyanine for detection of Ag+ in industrial wastewater / Xiaolong Zeng in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Highly selective and sensitive colorimetric chemosensor based on tricarboyanine for detection of Ag+ in industrial wastewater Type de document : texte imprimé Auteurs : Xiaolong Zeng, Auteur ; Xuezhao Li, Auteur ; Wen Sun, Auteur Année de publication : 2020 Article en page(s) : 11 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Argent
Capteurs chimiques
Eaux usées -- Analyse
Fluorescence
Ions
Ions métalliquesIndex. décimale : 631.7 Conservation des eaux Résumé : An efficient fluorescent probe 1 based on tricarbocyanine derivative was designed and synthesized, which can detect Ag+ in real industrial wastewater. UV-Vis absorption and fluorescent emission spectra of probe 1 were carried out and indicated this probe can bind Ag+ via complexation reaction, then leading to a remarkable color change from blue to light red. Furthermore, probe 1 showed high sensitive performance and excellent selectivity toward Ag+ over other common metal ions in neutral pH. The sensing mechanism was proposed and further confirmed by 1H NMR, which demonstrate analyte-induced destruction of the π-electron system could be shorten by the disruption of the pull-push π-conjugation system in probe 1. Moreover, a test strip was prepared by filter paper immersing in probe 1 solution, which further provide its potential application for trace Ag+ detection in real industrial wastewater. Note de contenu : - EXPERIMENTAL METHODS : Materials and reagents - Instrumentations - Synthesis - Measurement method
- RESULTS AND DISCUSSION : Construction and characterization of intermediate and probe 1 - Fluorescence and UV-Vis spectral response of probe 1 to Ag+ - The selectivity to various metal ion as well as common anion and pH effect of probe 1 - Investigation of binding mechanism - Preliminary application for preparing test strips and applicability for real wastewater samples
- Table 1 : Determination of Ag+ from real wastewater samplesDOI : https://doi.org/10.1186/s42825-020-00031-2 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00031-2.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37450
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 11 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Screening of additives to reduce grain damage risk on unhairing by proteinase K / Mei Chen in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Screening of additives to reduce grain damage risk on unhairing by proteinase K Type de document : texte imprimé Auteurs : Mei Chen, Auteur ; Mingfang Jiang, Auteur ; He Li, Auteur ; Cheng Haiming, Auteur Année de publication : 2020 Article en page(s) : 9 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Additifs
Criblage
Cuirs et peaux de bovins
Epilage enzymatique
Hydrolyse enzymatique
Inhibiteurs (chimie)
Ions métalliquesIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Enzymatic unhairing is a cleaner strategy for leather-making. It is a potential alternative to the traditional hair-burning process. However, several shortcomings, such as uncontrolled enzymatic reaction, and risk of grain looseness and damage have restricted the broad application of enzymatic unhairing. In this work, metal ions and organic additives were screened for lessening the hydrolytic activity of proteinase K to collagen fiber. Then, the selected additives were applied to the enzymatic unhairing process for bovine hide. The results showed that a suitable concentration of metal ions (Cu (II), Fe (III) and Al (III)) and organic additives (salicylate, laurate, adipate, gallate and epicatechin (ECG)) could diminish approximately 35% of the hydrolytic activity of proteinase K to collagen fibers. Then, the additives were applied for the bovine hide enzymatic unhairing process. Hydroxyproline determination in the unhairing float shows that applying additives could reduce collagen hydrolysis. The morphology results showed that the grain damage could be significantly reduced with the addition of the screened additives in the proteinase K enzymatic unhairing system, whereas the addition of ECG and gallate significantly slowed down the unhairing speed. This outcome provides new potential to reduce the risk of grain damage in enzymatic unhairing process. Note de contenu : - MATERIALS AND METHODS : Materials - Enzymatic activity assays - Effect of additives on hydrolytic activities of proteinase K - Determination of total protein (TP) content - Determination of hydroxyproline (Hyp) content - Scanning electron microscopy (SEM)
- RESULTS AND DISCUSSION : Screening of additives - Enzymatic unharing by proteinase K with additives
- Table 1 : The effect of the additives on the hydrolytic activity of proteinase K
- Table 2 : The results of enzymatic unhairing by proteinase K (150 U/g hide) with additives at 35 °C, pH 8.0DOI : https://doi.org/10.1186/s42825-020-00032-1 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00032-1.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37451
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 9 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Factors affecting thermal stability of collagen from the aspects of extraction, processing and modification / Xiaoxia Zhang in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Factors affecting thermal stability of collagen from the aspects of extraction, processing and modification Type de document : texte imprimé Auteurs : Xiaoxia Zhang, Auteur ; Songcheng Xu, Auteur ; Lirui Shen, Auteur ; Guoying Li, Auteur Année de publication : 2020 Article en page(s) : 29 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Acétique, Acide L'acide acétique (du latin acetum) ou acide éthanoïque est un acide carboxylique de formule chimique : C2H4O2 ou CH3COOH.
L'acide acétique pur est aussi connu sous le nom d'acide acétique glacial. C'est un des plus simples des acides carboxyliques. Son acidité vient de sa capacité à perdre le proton de sa fonction carboxylique, le transformant ainsi en ion acétate CH3COO-. C'est un acide faible.
L'acide acétique pur est un liquide très faiblement conducteur, incolore, inflammable et hygroscopique. Il est naturellement présent dans le vinaigre, il lui donne son goût acide et son odeur piquante (détectable à partir de 1 ppm21).
C'est un antiseptique et un désinfectant.
L'acide acétique est corrosif et ses vapeurs sont irritantes pour le nez et les yeux.
Il doit être manipulé avec soin. Quoi qu'il n'ait pas été jugé cancérigène ou dangereux pour l'environnement, il peut causer des brûlures ainsi que des dommages permanents à la bouche, au nez, à la gorge et aux poumons. À certaines doses et en co-exposition chronique avec un produit cancérigène, son caractère irritant en fait un promoteur tumoral de tumeurs (bénignes et malignes)21. Ceci a été démontré expérimentalement chez le rat.
Collagène
Extraction (chimie)
Ions inorganiques
Liquides ioniques
Polymères
Réticulation (polymérisation)
solvants
Stabilité thermiqueIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Collagen, as a thermal-sensitive protein, is the most abundant structural protein in animals. Native collagen has been widely applied in various fields due to its specific physicochemical and biological properties. The beneficial properties would disappear with the collapse of the unique triple helical structure during heating. Understanding thermal stability of collagen is of great significance for practical applications. Previous studies have shown the thermal stability would be affected by the different sources, extraction methods, solvent systems in vitro and modified methods. Accordingly, the factors affecting thermal stability of collagen are discussed in detail in this review. Note de contenu : - THE EFFECT OF EXTRACTION METHODS ON THERMAL STABILITY : Acid extraction and enzyme extraction - Alkali extraction - Ultrasonic assisted and microwave assisted extraction - Ionic liquids pretreatment extraction
- THE EFFECT OF COLLAGEN EXTRACTED FROM DIFFERENT
- THE EFFECT OF DFFERENT SOLVENT SYSTEMS ON THERMAL STABILITY : The concentration of collagen - The concentration of acetic acid - Different inorganic ion concentrations and species -
Ionic liquids (ILs) - Alcohols - Natural polymers - Biocompatible synthetic polymers
- THE EFFECT OF CROSSLINKING ON THERMAL STABILITY : Physical crosslinking - Chemical crosslinkingDOI : https://doi.org/10.1186/s42825-020-00033-0 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00033-0.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37452
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 29 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Chromium and leather : a review on the chemistry of relevance for allergic contact dermatitis to chromium in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Chromium and leather : a review on the chemistry of relevance for allergic contact dermatitis to chromium Type de document : texte imprimé Année de publication : 2020 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Air -- Humidité
Allergies
Antioxydants
Chrome hexavalent
Chrome trivalent
Dermatite de contact
Eczéma professionnel
Normalisation
Spéciation (chimie)
ToxicologieIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : As other causes decline in importance, chromium-tanned leather has become a more important source for chromium allergy, which affects around 1% of the general population. The aim of this review is to give suggestions on how to minimize the risk of leather-related allergic contact dermatitis, which can be elicited in chromium-allergic persons by hexavalent and trivalent chromium released from leather. Hexavalent chromium is the more potent chromium form and requires a lower skin dose to elicit allergic reactions. It is formed on the surface of some, antioxidant-free, leathers at dry conditions (< 35% relative humidity) and is influenced by the tanning process and other conditions, such as UV irradiation, contact with alkaline solutions, and leather age. Trivalent chromium is the dominant form released from chromium-tanned leather and its released amount is sufficient to elicit allergic reactions in some chromium-allergic individuals when they are exposed repetitively and over longer time (days – months). A low initial test result (< 3 mg/kg) for hexavalent chromium with the current standard test (ISO 17075) does not guarantee a low release of chromium from the leather or a low release of hexavalent chromium under typical exposure conditions during the service life of the leather. Information, labels, and certificates regarding leather products are often insufficient to protect chromium-allergic individuals. Correct labelling and information on the possible content of different allergens, as well as different tanning alternatives for certain leather products, are crucial. Note de contenu : - INTRODUCTION : Chromium speciation – toxicological considerations - Chromium tanning - Chromium allergy and allergic contact dermatitis (ACD) - Relevant chemical speciation of chromium for ACD - Prevalence of chromium allergy - Severity and persistence of chromium allergy and ACD
- TRIVALENT VERSUS HEXAVALENT CHROMIUM FROM AN ALLERGIC PERSPECTIVE : Release of trivalent and hexavalent chromium from leather - Allergic reactions to trivalent and hexavalent chromium, and chromium-tanned leather
- THE FORMATION OF HEXAVALENT CHROMIUM DURING USE OF CHROMIUM-TANNED LEATHER : Age of chromium-tanned leather article in use - Environmental factors during use of leather articles
- OBSTACLES RELATED TO THE STANDARD TEST FOR HEXAVALENT CHROMIUM IN LEATHER (ISO 17075)
- PRACTICAL IMPLICATIONS FOR CHROMIUM-ALLERGIC INDIVIDUALS AS CONSUMERS OF LEATHER PRODUCTS
- ALTERNATIVES TO CHROMIUM-TANNING FROM AN ALLERGY PERSPECTIVE
- Table 1 : Summary of selected data on the prevalence of chromium allergy in the general population and different clinical/occupational groups in different continents and countries. The data are merged for Europe, Asia, and North America. A detailed overview is given in the supplementary file, Table S
- Table 2 : Most important tanning, leather, and exposure factors/conditions for the release of trivalent and hexavalent chromium from chromium-tanned leatherDOI : https://doi.org/10.1186/s42825-020-00027-y En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00027-y.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37453
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020)[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Alternative uses for tannery wastes : a review of environmental, sustainability, and science / Cesar Vinicius Toniciolli Rigueto in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Alternative uses for tannery wastes : a review of environmental, sustainability, and science Type de document : texte imprimé Auteurs : Cesar Vinicius Toniciolli Rigueto, Auteur ; Marieli Rosseto, Auteur ; Daniela Dal Castel Krein, Auteur ; Bruna Elisangela Pessini Ostwald, Auteur ; Lillian Avila Massuda, Auteur ; Bárbara Belém Zanella, Auteur ; Aline Dettmer, Auteur Année de publication : 2020 Article en page(s) : 20 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adsorption
Biocarburants
Biogaz
Biopolymères
Carburants diésel
Cuirs et peaux -- Industrie -- Aspect de l'environnement
Déchets industriels -- Recyclage
Tannage -- DéchetsIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : The manufacture of leather covers a wide productive chain and beyond contributes to the economic flow. The various stages of leather processing result in high volumes of solid waste. In Brazil, a daily generation of 375 tons of solid waste is estimated, and landfills are still the most used route to its destination. In this review, emphasis will be given to researches that have sought alternatives for the use of solid waste from the tannery industry. Among the main applications of solid tannery wastes, the following stand out production of adsorbent materials, biodiesel, biogas, biopolymers, applications in agriculture and other applications involving extraction/recovery of compounds of industrial/commercial interest, isolation of microorganisms and production of enzymes and applications in the animal diet. In each alternative of waste application, the technologies used, the opportunities, and the challenges faced are mentioned. We hope that this review can provide valuable information to promote the broad understanding of the possibilities that tannery solid wastes has for the development of biodegradable and agricultural products, wastewater treatment, extraction of compounds of industrial and commercial interest, among others. Note de contenu : - METHODOLOGY
- MAIN APPLICATIONS STUDIED FOR TANNERY WASTES : Adsorption - Biodiesel - Biogas - Biopolymers - Agriculture - Other applications
- Table 1 : Studies that used tannery wastes from various stages of leather processing as an adsorbent material
- Table 2 : Main fatty acids present in the fat extracted from tannery wastes
- Table 3 : Comparison of studies involving biodiesel from tannery waste, petro-diesel, and B100
- Table 4 : Biodiesel characteristics in different world regulations
- Table 5 : Pretreatments to increase biogas production
- Table 6 : Main parameter analyzed to obtain biogasDOI : https://doi.org/10.1186/s42825-020-00034-z En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00034-z.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37454
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 20 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Facile preparation of hierarchical porous polydopamine microspheres for rapid removal of chromate from the wastewater / Lin Xiang in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Facile preparation of hierarchical porous polydopamine microspheres for rapid removal of chromate from the wastewater Type de document : texte imprimé Auteurs : Lin Xiang, Auteur ; Jiayou Lin, Auteur ; Qin Yang, Auteur ; Shaojian Lin, Auteur ; Sheng Chen, Auteur ; Bin Yan, Auteur Année de publication : 2020 Article en page(s) : 10 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adsorption
Chrome hexavalent
Chrome trivalent
Eaux usées -- Décontamination
Microsphères
PolydopamineIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Cr(VI) containing industrial wastewaters are highly toxic and carcinogenic, and severely threats living creatures and the environment. Therefore, it is highly desired yet challenging to develop an available and economical adsorbent for simultaneously detoxifying Cr(VI) anions to Cr(III) ions and removing them from the wastewater. Here we propose a facile method for rapid removal of Cr(VI) ions from the wastewater by using a synthetic polydopamine microsphere (PPM) adsorbent with hierarchical porosity. The as-prepared PPM exhibits high Cr(VI) removal capacity of 307.7 mg/g and an outstanding removal efficiency. They can effectively decrease the Cr(VI) concentration to lower than 0.05 mg/L well below the limits for drinking water standard of WHO regulations in 60 s at pH 2. More importantly, PPMs can reduce the lethal Cr(VI) anions to Cr(III) ions with low toxicity, and simultaneously immobilize them on the matrices of PPMs. Note de contenu : - MATERIALS AND METHODS : Material - Synthesis of PPMs - PPMs material characterization - Cr(VI) removal experiments
- RESULTS AND DISCUSSION : Synthesis and characterizations of the PPMs - High Cr(VI) removal capacity of PPMs - Rapid Cr(VI) adsorption kinetics of PPMs - Highly selectivity of PPMs to Cr(VI) from complex wastewater - Easy regeneration and recovery of adsorbents for recycling - Cr(VI) adsorption mechanisms of PPMs via reduction and immobilization
- Table 1 : Fitting parameters of thermodynamic adsorption under different temperatures
- Table 2 : The thermodynamic parameters of △H0, △S0 and △G0
- Table 3 : Kinetic adsorption model fitting dataDOI : https://doi.org/10.1186/s42825-020-00036-x En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00036-x.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37455
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 10 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Aluminum tanning of hide powder and skin pieces under microwave irradiation / Yue Liu in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Aluminum tanning of hide powder and skin pieces under microwave irradiation Type de document : texte imprimé Auteurs : Yue Liu, Auteur ; Bin Song, Auteur ; Jinwei Zhang, Auteur ; Carmen Gaidau, Auteur ; Haibin Gu, Auteur Année de publication : 2020 Article en page(s) : 13 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Aluminium L'aluminium est un élément chimique, de symbole Al et de numéro atomique 13. C’est un métal pauvre, malléable, de couleur argent, qui est remarquable pour sa résistance à l’oxydation13 et sa faible densité. C'est le métal le plus abondant de l'écorce terrestre et le troisième élément le plus abondant après l'oxygène et le silicium ; il représente en moyenne 8 % de la masse des matériaux de la surface solide de notre planète. L'aluminium est trop réactif pour exister à l'état natif dans le milieu naturel : on le trouve au contraire sous forme combinée dans plus de 270 minéraux différents, son minerai principal étant la bauxite, où il est présent sous forme d’oxyde hydraté dont on extrait l’alumine. Il peut aussi être extrait de la néphéline, de la leucite, de la sillimanite, de l'andalousite et de la muscovite.
L'aluminium métallique est très oxydable, mais est immédiatement passivé par une fine couche d'alumine Al2O3 imperméable de quelques micromètres d'épaisseur qui protège la masse métallique de la corrosion. On parle de protection cinétique, par opposition à une protection thermodynamique, car l’aluminium reste en tout état de cause très sensible à l'oxydation. Cette résistance à la corrosion et sa remarquable légèreté en ont fait un matériau très utilisé industriellement.
L'aluminium est un produit industriel important, sous forme pure ou alliée, notamment dans l'aéronautique, les transports et la construction. Sa nature réactive en fait également un catalyseur et un additif dans l'industrie chimique ; il est ainsi utilisé pour accroître la puissance explosive du nitrate d'ammonium.
Analyse thermique
Cuirs et peaux
Cuirs et peaux de chèvres
Eaux usées -- Analyse
Fourier, Spectroscopie infrarouge à transformée de
Micro-ondes
Microscopie électronique à balayage
Poudre de peaux
Tannage minéralTannage dans lequel interviennent différents minéraux. Le plus répandu est le tannage aux sels de chrome, mais aussi à l’aluminium
ThermogravimétrieIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : The application and mechanism study of microwave irradiation in traditional industries have attracted considerable attention owing to the unique thermal and athermal effects that could lead to unexpected benefits in high-efficiency and clean production. Herein, we report the investigation of the aluminum tanning under microwave irradiation upon using hide powder and skin pieces, respectively, as simulants of real hide or skin. The aluminum tanning process and the tanned products under microwave heating (MWH) were studied and compared with those of conventional water bath heating (WBH) as the controls. For the tanning system of hide powder, the tanning effluents were analyzed in terms of pH, conductivity, dielectric constant and aluminum content, and the tanned powder was investigated by differential scanning calorimetry (DSC), thermogravimetric (TG) analysis, and FT-IR spectroscopy. For the skin piece system, the pH and aluminum content of tanning effluents were also determined, and at the same time, DSC, TG, SEM, FT-IR and shrinkage temperature were used to illustrate the actions of microwaves on the structure and properties of the tanned pieces. The results show that aluminum reactivity in the penetration and binding process of collagen fibers in hide powder and skin pieces improved using microwave treatment. The residual aluminum content was greatly reduced by microwave heating action, and the increased amount of aluminum with evener distribution was observed in the tanned products. Microwave irradiation also resulted in the tanned products with better thermal stability and thermal decomposition resistance. This work further promotes application of microwave treatments for aluminum-based tanning in leather industry. Note de contenu : - EXPERIMENTAL : Materials - Aluminum tanning of hide powder - Aluminum tanning of goatskin pieces - Analysis of tanning effluent, tanned hide powder and skin pieces
- RESULTS AND DISCUSSION : Effect of microwave irradiation on the aluminum tanning of hide powder - Effect of microwave irradiation on the aluminum tanning of skin pieces
- Table 1 : Analysis for the tanning effluents of hide powder under different heating methods
- Table 2 : TG analysis of tanned hide powder obtained under different heating methodsDOI : https://doi.org/10.1186/s42825-020-00037-w En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00037-w.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37456
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 13 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Characteristics of natural biopolymers and their derivative as sorbents for chromium adsorption : a review / Ruoshi Zhang in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
[article]
Titre : Characteristics of natural biopolymers and their derivative as sorbents for chromium adsorption : a review Type de document : texte imprimé Auteurs : Ruoshi Zhang, Auteur ; Yongqiang Tian, Auteur Année de publication : 2020 Article en page(s) : 15 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Absorbants et adsorbants
Adsorption
Biopolymères
CelluloseLa cellulose est un glucide constitué d'une chaîne linéaire de molécules de D-Glucose (entre 200 et 14 000) et principal constituant des végétaux et en particulier de la paroi de leurs cellules.
Chitine
ChitosaneLe chitosane ou chitosan est un polyoside composé de la distribution aléatoire de D-glucosamine liée en ß-(1-4) (unité désacétylée) et de N-acétyl-D-glucosamine (unité acétylée). Il est produit par désacétylation chimique (en milieu alcalin) ou enzymatique de la chitine, le composant de l'exosquelette des arthropodes (crustacés) ou de l'endosquelette des céphalopodes (calmars...) ou encore de la paroi des champignons. Cette matière première est déminéralisée par traitement à l'acide chlorhydrique, puis déprotéinée en présence de soude ou de potasse et enfin décolorée grâce à un agent oxydant. Le degré d'acétylation (DA) est le pourcentage d'unités acétylées par rapport au nombre d'unités totales, il peut être déterminé par spectroscopie infrarouge à transformée de Fourier (IR-TF) ou par un titrage par une base forte. La frontière entre chitosane et chitine correspond à un DA de 50 % : en deçà le composé est nommé chitosane, au-delà, chitine. Le chitosane est soluble en milieu acide contrairement à la chitine qui est insoluble. Il est important de faire la distinction entre le degré d'acétylation (DA) et le degré de déacétylation (DD). L'un étant l'inverse de l'autre c'est-à-dire que du chitosane ayant un DD de 85 %, possède 15 % de groupements acétyles et 85 % de groupements amines sur ses chaînes.
Le chitosane est biodégradable et biocompatible (notamment hémocompatible). Il est également bactériostatique et fongistatique.
Le chitosane est également utilisé pour le traitement des eaux usées par filtration ainsi que dans divers domaines comme la cosmétique, la diététique et la médecine.
Chrome
Eaux usées -- Epuration
Eaux usées -- Teneur en chrome
LignineLa lignine est un des principaux composants du bois, avec la cellulose, l'hémicellulose et des matières extractibles. La lignine est présente principalement dans les plantes vasculaires et dans quelques algues. Ses principales fonctions sont d'apporter de la rigidité, une imperméabilité à l'eau et une grande résistance à la décomposition. Toutes les plantes vasculaires, ligneuses et herbacées, fabriquent de la lignine. Quantitativement, la teneur en lignine est de 3 à 5 % dans les feuilles, 5 à 20 % dans les tiges herbacées, 15 à 35 % dans les tiges ligneuses. Elle est moindre pour les plantes annuelles que pour les vivaces, elle est maximum chez les arbres. La lignine est principalement localisée entre les cellules (voir parois pectocellulosiques), mais on en trouve une quantité significative à l'intérieur même de celles-ci. Bien que la lignine soit un réseau tridimensionnel hydrophobe complexe, l'unité de base se résume essentiellement à une unité de phénylpropane. La lignine est le deuxième biopolymère renouvelable le plus abondant sur la Terre, après la cellulose, et, à elles deux, elles cumulent plus de 70 % de la biomasse totale. C'est pourquoi elle fait l'objet de recherches en vue de valorisations autres que ses utilisations actuelles en bois d'œuvre et en combustible.
Voie de biosynthèse : La lignine est une molécule dont le précurseur est la phénylalanine. Cet acide aminé va subir une cascade de réactions faisant intervenir une dizaine de familles d'enzymes différentes afin de former des monolignols. Ces enzymes sont : phénylalanine ammonia-lyase (PAL), cinnamate 4-hydroxylase (C4H), 4-coumarate:CoA ligase (4CL), hydroxycinnamoyl-CoA shikimate/quinate hydroxycinnamoyl transferase (HCT), p-coumarate 3-hydroxylase (C3H), caffeoyl-CoA o-methyltransferase (CCoAOMT), cinnamoyl-CoA reductase (CCR), ferrulate 5-hydroxylase (F5H), caffeic acid O-methyltransferase (COMT) et cinnamyl alcohol deshydrogenase (CAD). Dans un certain nombre de cas, des aldéhydes peuvent également être incorporés dans le polymère.
PolypeptidesUn polypeptide est une chaîne d'acides aminés reliés par des liaisons peptidiques. On parle de polypeptide lorsque la chaîne contient entre 10 et 100 acides aminés. Au-dessus de 100 acides aminés on parle généralement de protéine.
Parmi eux, les peptides multi-cycliques, les peptides phosphorylés ou encore ceux intégrant des liaisons non-peptidiques ou des peptides conjugués.
Certains polypeptides constituent une famille d'antibiotiques dont les molécules très toxiques n'en permettent qu'un usage très limité. D'autres s’imposent aujourd’hui comme des éléments essentiels à la mise au point de vaccins ou de principes actifs destinés aux traitements de certaines pathologies telles que les cancers, les déficiences hormonales, l’ostéoporose.
TaninsIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Chromium is widely used in industry, and improper disposal of wastewater and industrial residues containing excessive chromium can contaminate water and soil, endangering both environmental and human health. Natural biopolymers and their derivatives have been investigated for removal of chromium (Cr) from wastewater. Cellulose, lignin, tannin, chitin, chitosan, and polypeptides are abundant in nature, and have high potential as adsorbents due to their easy access, low cost, and the recyclability of the captured heavy metals. In order to improve their mechanical strength, recyclability, specific surface area, binding site number, and adsorption rate as adsorbents, native materials have also been modified. This review discusses the source of chromium contamination and the main species of interest, as well as their toxicity. The structures of the aforementioned biopolymers were analyzed, and the adsorption mechanism of chromium and the main influencing factors on this process are discussed. The modification methods of various adsorbents and their adsorption effects on chromium are also detailed, and the developmental direction of research on the use of biopolymer adsorption remediation to control chromium contamination is discussed. Note de contenu : - CHROMIUM SPECIES AND THEIR TOXICITY : Adsorption mechanisms - Ionic adsorption mechanism
- ADSORPTION-COUPLED REDUCTION MECHANISM
- ADSORBENTS : Cellulose - Lignin - Tannin - Chitin and chitosan - Polypeptide
- Table 1 : pH at maximum adsorption and adsorption capacity of different types of celluloseDOI : https://doi.org/10.1186/s42825-020-00038-9 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00038-9.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37457
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 15 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire An insight into artisanal leather making in Ghana / Miriam Appiah-Brempong in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
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Titre : An insight into artisanal leather making in Ghana Type de document : texte imprimé Auteurs : Miriam Appiah-Brempong, Auteur ; Helen M. K. Essandoh, Auteur ; Nana Yaw Asiedu, Auteur ; Samuel Kwame Dadzie, Auteur ; Francis Warings Yao Momade, Auteur Année de publication : 2020 Article en page(s) : 14 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Artisanat
Cuirs et peaux -- Industrie -- Ghana
Post-tannage
Prétannage
TannageIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : The production of leather from animal skins and hides through tanning processes began in the pre-historic ages. Despite the origination of new leather making techniques such as chrome tanning which is being employed extensively today, the traditional method of leather production primarily through vegetable tanning is still being practised mostly in artisanal tanneries in developing nations including Ghana. Artisanal leather making, thus, contributes beneficially to rural livelihood. Nevertheless, the growth of this sector has been stifled by the lack of innovative technologies to enhance productivity. This challenge could be partly linked to the knowledge gap on the scientific principles governing artisanal leather production processes. This study, therefore, elaborates on various process steps and materials employed in traditional leather making in Ghana and the scientific principles underlying each of the processes. It also makes a comparison between traditional and modern leather manufacturing processes and identifies knowledge and technological gaps which would inspire in-depth scientific research into artisanal leather making. Note de contenu : - OVERVIEW OF LEATHER MAKING PROCESSES IN ARTISANAL TANNERIES : Pre-tanning phase - Tanning phase - Post tanning phase - Black dyeing - Red dyeing - Brown dyeing
- FURTHER RESEARCH
- Table 1 : Comparison between artisanal and modern-day leather making processesDOI : https://doi.org/10.1186/s42825-020-00039-8 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00039-8.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37458
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 14 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Life cycle assessment and leather production / Diego Navarro in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
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Titre : Life cycle assessment and leather production Type de document : texte imprimé Auteurs : Diego Navarro, Auteur ; Jianhui Wu, Auteur ; Wei Lin, Auteur ; Pere Fullana-i-Palmer, Auteur ; Rita Puig, Auteur Année de publication : 2020 Article en page(s) : 13 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Cuir
Cuirs et peaux -- Déchets
Durée de vie (Ingénierie)
ProductionIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Leather industry is facing new trends on production and consumption patterns due to society concerns. Circular economy is proposing a transition from the current economic model to a more sustainable one, in which waste is designed out and resources will be reused and recycled as long as possible. In this transition, Life Cycle Assessment (LCA) is an important tool to help decision-making. In the present review, 39 English-written peer-reviewed papers related to LCA and leather have been found, 30 of which were published in the last 6 years, meaning LCA is nowadays an important subject. Papers are presented within 4 types, focused on: 1) the whole leather production process, 2) a single step in the production process (e.g, new technologies for unhairing), 3) waste treatment and recycling, and 4) life cycle thinking with ideas on long-term strategies for leather industries. As discussed in the literature review, leather industry has important challenges to address: increasing sustainability and transparency on the supply chain, and strengthening the beauty of leather. Taking up these challenges from a life cycle perspective will help leather industry flourish in the coming future. Note de contenu : - Details on LCA methodology
- Methodology
- Table 1 : LCA studies which include the complete leather production process
- Table 2 : LCA papers found in the literature, studying a specific part of the leather production
- Table 3 : LCA papers studying leather-waste treatment processes
- Table 4 : Life cycle thinking papers related to leather productionDOI : https://doi.org/10.1186/s42825-020-00035-y En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00035-y.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37459
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 13 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Effects of collagen fiber addition on the combustion and thermal stability of natural rubber / Weixing Xu in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
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Titre : Effects of collagen fiber addition on the combustion and thermal stability of natural rubber Type de document : texte imprimé Auteurs : Weixing Xu, Auteur ; Xintao Wu, Auteur ; Qilin Wen, Auteur ; Shuangyang Li, Auteur ; Yongjiao Song, Auteur ; Bi Shi, Auteur Année de publication : 2020 Article en page(s) : 10 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caoutchouc
Caractérisation
Charges (matériaux)
Collagène
Combustion
Inflammabilité
Polymères à silane modifié
Polymères ignifuges
Réaction de couplage
Stabilité thermique
Thermocinétique
Wet-blue (tannage)Peau tannée au chrome (le chrome donne une couleur bleue)Index. décimale : 678 Elastomères et produits élastomères Résumé : Collagen fiber (CF) and silane coupling agent-modified collagen fiber (MCF) were used as flame retardant filler for natural rubber (NR) modification. The combustion phenomena and properties of composites blended with different dosages of CF or MCF were compared to elucidate the flame retardant mechanism of the composites. The flame retardancy of NR can be enhanced effectively by increasing nitrogen content (the nitrogen content of CF is about 18%), creating air pockets, and structuring the flame retardant network in the composites. MCF failed to structure a flame retardant network in the composite, indicating that its modification effects of MCF are weaker than those of CF. When CF dosage was 30 wt%, the composite can achieve the best flame retardancy, with limited oxygen index of 29.4% and without smoke and dripping during burning. This study demonstrated a new method for the flame retardant modification of NR. Note de contenu : - EXPERIMENTAL : Materials - Preparation of collagen fiber powder - Preparation of modified collagen fiber powder - Preparation of the CF/NR and the MCF/NR composites - Characterizations
- RESULTS AND DISCUSSION : Effect of CF dosage on the flammability of CF/NR composites - Effect of MCF dosage on the flammability of MCF/NR composites - Flame retardant mechanism of NR modified with CF
- Table 1 : Pretreatment processes of wet-blue split
- Table 2 : The LOI and combustion phenomena of NR and the CF/NR composites
- Table 3 : The LOI and combustion phenomena of the MCF/NR composites
- Table 4 : The thermal conductivity of NR, C-30 and MC-30DOI : https://doi.org/10.1186/s42825-020-00040-1 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00040-1.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37460
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 10 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Current trends in leather science / Anthony D. Covington in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
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Titre : Current trends in leather science Type de document : texte imprimé Auteurs : Anthony D. Covington, Auteur ; William R. Wise, Auteur Année de publication : 2020 Article en page(s) : 9 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Chaulage
Chimie -- Essais et réactifs
Cuir -- Séchage
Cuir végétal
Cuirs et peaux -- Finition
Cuirs et peaux -- Séchage
Cuirs et peaux -- Teinture
Epilage
Produits de nourriture du cuir
Tannage
Tannage au chrome
Tannage minéralTannage dans lequel interviennent différents minéraux. Le plus répandu est le tannage aux sels de chrome, mais aussi à l’aluminium
Tannage végétalIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : In preparing the second edition of ‘Tanning Chemistry. The Science of Leather.’, the literature was updated and the content was revised and reviewed. Here, the new findings are presented and discussed.
Notable developments include the necessary rethinking of the mechanism of sulfide unhairing because of new understanding of the aqueous chemistry of sulfide species. Revision upwards of the value of the second pKa for sulfide species ionisation means that S2− cannot exist in an aqueous medium, so the unhairing species in hair burn reactions is HS−. Although the technology remains the same, this means the mechanisms of associated reactions such as immunisation must be revised.
Rawstock preservation has benefitted from studies of the potential role of materials from plants which accumulate salt, but which also contribute terpene compounds. There is also further discussion on the continuing issue of chromium (VI) in the leather industry.
The application to processing of new solvents, ionic liquids and deep eutectics, is the coming technology, which offers transforming options for new chemistries and products. Renewed interest in vegetable tanning and methods of wet white processing are current trends. Also, within the topic of reagent delivery is processing in a solid medium of plastic beads.Note de contenu : - Preservation
- Unhairing
- Liming
- Chrome tanning
- Mineral tanning
- Vegetable tanning
- Other tannages
- Post tanning
- Dyeing
- Fatliquoring
- Reagent delivery
- Drying
- Finishing
Table 1 : Melting points of some ionic compoundsDOI : https://doi.org/10.1186/s42825-020-00041-0 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-020-00041-0.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37461
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 2 (Année 2020) . - 9 p.[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire
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