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JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH . Vol. 19, N° 2Mention de date : 03/2022Paru le : 30/03/2022 |
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Ajouter le résultat dans votre panierPolyols and polyurethanes from renewable sources : past, present, and future - part 2 : plant-derived materials / Ritesh S. Malani in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Polyols and polyurethanes from renewable sources : past, present, and future - part 2 : plant-derived materials Type de document : texte imprimé Auteurs : Ritesh S. Malani, Auteur ; Vinod C. Malshe, Auteur ; Bhaskar Narayan Thorat, Auteur Année de publication : 2022 Article en page(s) : p. 361-375 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Glucides
Matières premières
Polyols
Polyuréthanes
Protéines
Recyclage (déchets, etc.)
Ressources renouvelablesIndex. décimale : 667.9 Revêtements et enduits Résumé : Polyols are basically compounds containing multiple reactive hydroxyl groups and one of the major constituting elements in making polyurethane and polyurethane foam. Traditionally, the polyols are obtained from fossil fuels. The limited availability of fossil fuels and exponentially increasing demand of polymers including PUs enforce the scientific society to explore the possible alternate sources for obtaining polyols. In order to reduce the dependency of polyols on fossil fuels, renewable polyols have gained significant importance over the last few decades. Various biomass and renewable sources have been explored to obtain the polyols. The present review, which is a continuation of our earlier work, highlights various other starting raw materials of plant origin for obtaining the renewable polyols and corresponding methodologies. The review also attempts to make a strong connection between the starting material for making polyols, chemical transformations employed, and the properties of polyols as well as final PUs. The comprehensive analysis of renewable polyols and corresponding PUs will help researchers in making commercially viable renewable polyols to fulfill the increasing demand. Note de contenu : - Carbohydrate-derived polyols and polyurethanes
- Starch-derived polyols and polyurethane
- Protein-derived polyols and polyurethane
- Other plant-derived polyols and polyurethane : Eugenol - Cardanol and CNSL - Terpenes, terpenoids, and rosins - Methanol and ethanol derivatives
- Table 1 : Carbohydrate-derived short-chain polyols with basic properties
- Table 2 : Alcohol-derived short-chain polyols with basic propertiesDOI : https://doi.org/10.1007/s11998-021-00534-5 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00534-5.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37267
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Review on thermochromic materials : development, characterization, and applications / Abdullatif Hakami in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Review on thermochromic materials : development, characterization, and applications Type de document : texte imprimé Auteurs : Abdullatif Hakami, Auteur ; Sesha S. Srinivasan, Auteur ; Prasanta K. Biswas, Auteur ; Ashwini Krishnegowda, Auteur ; Scott L. Wallen, Auteur ; Elias K. Stefanakos, Auteur Année de publication : 2022 Article en page(s) : p. 377-402 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
Composés organiques -- Synthèse
Construction -- Matériaux
Dépôt en phase vapeur
Dépôt par laser pulsé
Encapsulation
Fragmentation
Irradiation
Micro-ondes
Microémulsions
Photodétérioration
Polymères
Polymérisation
PyrolyseLa pyrolyse est la décomposition ou thermolyse d'un composé organique par la chaleur pour obtenir d'autres produits (gaz et matière) qu'il ne contenait pas. L'opération est réalisée en l'absence d'oxygène ou en atmosphère pauvre en oxygène pour éviter l'oxydation et la combustion (L’opération ne produit donc pas de flamme). Il s'agit du premier stade de transformation thermique après la déshydratation.
Elle permet généralement d'obtenir un solide carboné, une huile et un gaz. Elle débute à un niveau de température relativement bas (à partir de 200 °C) et se poursuit jusqu'à 1 000 °C environ. Selon la température, la proportion des trois composés résultants est différente.
Rayonnement ultraviolet
Revêtements organiques
Sol-gel, Procédé
Thermochromie
Transition de phaseEn physique, une transition de phase est une transformation du système étudié provoquée par la variation d'un paramètre extérieur particulier (température, champ magnétique...).
Cette transition a lieu lorsque le paramètre atteint une valeur seuil (plancher ou plafond selon le sens de variation). La transformation est un changement des propriétés du système.Index. décimale : 667.9 Revêtements et enduits Résumé : Thermochromism and thermochromic materials research and development are of great interest because of their importance in versatile applications with respect to energy-efficient building structures, textile industries, thermal or heat storage, antique maintenance processing and sensors. In general, thermochromic materials have been classified into four categories including inorganic, organic, polymeric, and hybrid systems, based on their unique material properties and operating conditions. Thermochromic materials have been prepared via different physicochemical techniques with some of them combined to maximize the yield, stability, and efficiency of the prepared TCMs. Pristine TCMs often undergo severe degradation when exposed to various external stimuli including UV irradiation from sunlight and ambient environmental conditions such as temperature, pressure, and humidity variations. Such degradation causes property and physical behavioral changes in TCMs. Various microencapsulation procedures and coating techniques are utilized to enhance the thermochromic performance of the materials and to protect the core TCMs from the degradation. Many desirable candidate materials have been developed, and extensive metrological tools have been deployed to understand the structural, morphological, microstructural, thermal, chemical, surface, and interfacial characteristics of these TCMs and their microencapsulated variants. The potential applications of the microencapsulated TCMs in industrial, commercial, and residential sectors are briefly discussed in this review paper. The future looks bright for the development of novel microencapsulated TCMs possessing nanostructural derived properties that can be effectively used in inks, paints, and coating agents for sustainable energy efficiency and many other applications. Note de contenu : - THERMOCHROMISM : Crystal field effect on the d-d orbital transition of transition metal ions - Band gap energy change of a semiconductor - Phase transitions of solid electrolytes - Change in coordination geometry of metal-complex species - Change in coordination number of metal complex species - Interconversion of stereoisomeric forms with conformational inversion - Change in molecular structure - Change in crystal structure
- CLASSIFICATION OF TCMS : Inorganic thermochromic materials (ITCM) - Organic thermochromic materials (OTCMs) - Organic–inorganic hybrid thermochromic materials (OIHTCMs) - Polymeric thermochromic materials (PTCMs) - Polymers with inherent thermochromism
- SYNTHESIS AND CHARACTERIZATION OF TCMS : Microemulsion technique - Solvothermal technique - Solgel technique - Chemical and electrochemical polymerization technique - Mechanical grinding technique - UV Irradiation technique - Schiff base synthesis technique - Microwave irradiation technique
- MICROENCAPSULATION OF TCMS : Overview of different techniques of microencapsulation - Physical methods - Chemical methods - Physicochemical method
- THERMOCHROMIC COATINGS : Physical vapor deposition (PVD) - Pulsed laser deposition (PLD) - Solgel depositions - Chemical vapor deposition (CVD) - Advantages and disadvantages of the coating methods
- PHOTODEGRADATION AND THERMAL DEGRADATION OF TCMS
- APPLICATIONS OF TCMSDOI : https://doi.org/10.1007/s11998-021-00558-x En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00558-x.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37275
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Effect of siloxane chain length on thermal, mechanical, and chemical characteristics of UV (ultraviolet)-curable epoxy acrylate coatings in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Effect of siloxane chain length on thermal, mechanical, and chemical characteristics of UV (ultraviolet)-curable epoxy acrylate coatings Type de document : texte imprimé Année de publication : 2022 Article en page(s) : p. 439-451 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
Copolymère époxy acrylate
Formulation (Génie chimique)
Résistance chimique
Revêtements -- Propriétés mécaniques
Revêtements -- Séchage sous rayonnement ultraviolet
Revêtements organiques
SiloxanesLes siloxanes sont une classe de composés du silicium dont la formule empirique est R2SiO, où R est un groupe radical qui peut être organique. Des exemples représentatifs sont [SiO(CH3)2]n (diméthylsiloxane) et [SiO(C6H5)2]n (diphénylsiloxane), où n est typiquement supérieur à 4. Ces composés peuvent être des hybrides organiques et inorganiques. Les chaînes organiques confèrent au composé des propriétés hydrophobes alors que la chaîne principale -Si-O-Si-O- est purement inorganique.
Le mot siloxane est dérivé de Silicium, Oxygène et alkane.
Des siloxanes peuvent être trouvés dans des produits tels que des cosmétiques, des déodorants, des enduits hydrophobes pour pare-brise, des peintures et certains savons.
Les siloxanes polymérisés (polysiloxanes) sont appelés silicones1,2.
Le siloxane est massivement utilisé dans l'industrie cosmétique (rouges à lèvre, conditionneurs et shampooings, déodorants, etc.).
Une application récente du Siloxane D5 (2001) a été trouvée dans le nettoyage à sec des textiles en remplacement du perchloroéthylène. Ce procédé est très répandu aux États-Unis et au Royaume-Uni. Il devient de plus en plus courant en Europe continentale dont la France, afin de promouvoir l'usage de procédés écologiques et respectueux de la santé humaine.Index. décimale : 667.9 Revêtements et enduits Résumé : In this research, high-performance epoxy acrylate (EA) coating formulations that contain various acrylate-modified diepoxy siloxane (DESA) intermediates were synthesized and characterized. Firstly, diepoxy siloxane (DES) intermediates, which have varying chain lengths (Mw = 370–3300 Da), were modified by acrylic acid via the ring-opening reaction oxirane group. DESA intermediates were then used in the preparation of ultraviolet (UV)-curable EA formulations. EA was also synthesized via acrylic acid modification of a commercial bisphenol-A-based epoxy resin, used as the standard formulation. EA-based UV-curable formulas were applied on substrates and then cured by UV irradiation for investigating the coating performances. Subsequently, performances of the UV-cured coatings were evaluated by the various test techniques, such as hardness, gloss, cross-cut adhesion force scratch resistance, contact angle, yellowing resistance, abrasion resistance, chemical resistance, and color measurement. The effect of DESA variety on the formations was examined compared to both themselves and the standard formulation. The results showed that the varying amounts and chain lengths of DESA influenced UV-curable coatings’ properties; particularly, the scratch resistance, contact angle, and yellowing resistance significantly enhanced with the increasing chain length of DESA. High-performance UV-curable EA formulations could be produced with the scratch resistance of 4 N, the contact angle of 95°, and high yellowing resistance (ΔE = 0.35). Note de contenu : - EXPERIMENTAL : Materials - Characterization and instruments - Preparation of epoxy acrylate (EA) and diepoxy siloxane acrylate intermediates (DESA) - Preparation of coating formulations and films - Film properties
- RESULTS AND DISCUSSION : Synthesis and characterization - Physical and mechanical properties - Thermal performance analysis
- Table 1 Formulations of different compositions of UV-curable coatings
- Table 2 Formulations of DESA-based UV-curable coatings
- Table 3 Specific properties of diepoxy polysiloxane-based intermediates
- Table 4 Color of intermediate products
- Table 5 Physical and mechanical properties of UV-cured epoxy acrylate films
- Table 6 Physical and mechanical properties of DESA films
- Table 7 The contact angle values of UV-cured films
- Table 8 Chemical resistance of UV-cured filmsDOI : https://doi.org/10.1007/s11998-021-00548-z En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00548-z.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37276
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Comparative study of fire-resistant coatings based on high and low molecular weight tannins / J. Ramirez in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Comparative study of fire-resistant coatings based on high and low molecular weight tannins Type de document : texte imprimé Auteurs : J. Ramirez, Auteur ; M. E. Berrio, Auteur ; A. Diaz-Gomez, Auteur ; L. F. Montoya, Auteur ; A. F. Jaramillo, Auteur ; C. Montalba, Auteur ; K. Fernà ndez, Auteur ; C. Medina, Auteur ; M. F. Meléndrez, Auteur Année de publication : 2022 Article en page(s) : p. 453–465 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
CatéchineLa catéchine est une molécule de la famille des flavonoïdes de la sous-classe des flavanols. Elle est aussi connue sous le nom de catéchol, avec le risque de confusion avec le pyrocatéchol parfois dénommé lui aussi catéchol. L’usage dans la communauté scientifique a fini par imposer le terme de catéchine, dérivé du terme anglais catechin.
Initialement découverte dans les fruits de l'acacia à cachou (Acacia catechu) duquel elle dérive son nom, la catéchine et ses nombreux isomères sont de puissants antioxydants qui aident à prévenir les maladies inflammatoires et coronariennes.
Le terme de catéchine est aussi parfois utilisé pour désigner la classe des flavanols (flavan-3-ols, flavan-3,4-ols et leurs esters galliques). Pour éviter la confusion entre la classe et le composé, ce dernier est désigné dans ce contexte par (+/-)-catéchine.
Enrobage (technologie)
Extraction (chimie)
Formulation (Génie chimique)
IgnifugeantsComposé chimique utilisé pour réduire l'inflammabilité. Il peut être incorporé au produit durant sa fabrication ou appliqué ultérieurement à sa surface.
Poids moléculaires
Revêtements -- Propriétés filmogènes
Revêtements -- Propriétés mécaniques
Revêtements en phase aqueuse -- Additifs
Revêtements protecteurs
Tanins
TaxifolineLa taxifoline ou dihydroquercétine est un composé organique de la famille des flavanonols, un sous-groupe de flavonoïdes. Elle est naturellement présent dans l'açaï (Euterpe oleracea), le mélèze de Sibérie (Larix sibirica) et la silymarine extraite des graines de chardon-Marie. Elle est aussi présente en faible quantité dans l'oignon rouge.
C'est le dérivé 2,3-dihydrogéné de la quercétine.Index. décimale : 667.9 Revêtements et enduits Résumé : In order to provide adequate fire resistance to construction materials, such as steel and wood, the use of high and low molecular weight tannins (TMw-H and TMw-L), extracted from the bark of Pinus radiata, as carbonaceous agents, was studied. The extracts were fully characterized by GPC, HPLC, and UV to determine the total amount of phenols, percentage of the monomers, and total yield. The molecular weights of both extracts varied between 2986 and 5573 Da, and they were mainly composed of catechin and taxifolin. Eco-friendly water-based formulations were obtained, without producing volatile organic compounds (VOCs), by varying the extract content between 15.5 and 37.8% w/w. The coatings, varying in thickness and substrates, were evaluated for their film-forming properties, covering power, mechanical properties, such as adhesion, embossing, abrasion, and flexibility, as well as their resistance to fire. The results indicated that good mechanical properties were obtained when using coatings containing TMw-L compared with those obtained when using TMw-H. The carbonization index (28%) and the mass loss percentage (9.35%) of the coatings containing TMw-L compared well to commercial coatings, indicating that they have excellent fire-retardant properties. However, the behavior of the TMw-H containing coatings was rather intumescent. Note de contenu : - MATERIALS AND METHODS : Extraction and characterization of the TMw-H and TMw-L - Formulation of coatings and surface preparation of steel and wood substrates - Evaluation of the mechanical properties of the coatings - Fire-resistant behavior
- RESULTS AND DISCUSSION : Characterization of the tannin extracts obtained from the bark of Pinus radiata - Formulation of coatings - Evaluation of the coating properties - Evaluation of the fire-resistant properties of the coatings
- Table 1 : Variation of the percentage of the compositions in the formulations for TMw-L and TMw-H
- Table 2 : Characterization of the tannin extracts obtained from the bark of Pinus radiata
- Table 3 : PVC, CPVC, and λ values for the formulations
- Table 4 : Evaluation of film properties of formulations and commercial coatings
- Table 5 : Evaluation of the mechanical properties of the coatings
- Table 6 : Mass loss and carbonization index of the coatingsDOI : https://doi.org/10.1007/s11998-021-00532-7 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00532-7.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37277
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Coating of modified ZnO nanoparticles on cotton fabrics for enhanced functional characteristics / Muhammad Usman Munir in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
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Titre : Coating of modified ZnO nanoparticles on cotton fabrics for enhanced functional characteristics Type de document : texte imprimé Auteurs : Muhammad Usman Munir, Auteur ; Munir Ashraf, Auteur ; Hafiz Affan Abid, Auteur ; Amjed Javid, Auteur ; Shagufta Riaz, Auteur ; Haleema Khanzada, Auteur ; Abdur Rehman, Auteur ; Kashif Iqbal, Auteur Année de publication : 2022 Article en page(s) : p. 467-475 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Antimicrobiens
CotonLe coton est une fibre végétale qui entoure les graines des cotonniers "véritables"(Gossypium sp.), un arbuste de la famille des Malvacées. Cette fibre est généralement transformée en fil qui est tissé pour fabriquer des tissus. Le coton est la plus importante des fibres naturelles produites dans le monde. Depuis le XIXe siècle, il constitue, grâce aux progrès de l'industrialisation et de l'agronomie, la première fibre textile du monde (près de la moitié de la consommation mondiale de fibres textiles).
Nanoparticules
Oxyde de zinc
Potentiel zeta
Protection contre le rayonnement ultraviolet
Réaction de couplage
Surfaces fonctionnelles
Textiles et tissusIndex. décimale : 667.9 Revêtements et enduits Résumé : The incorporation of nanoparticles (NPs) into textile fabrics can transform ordinary products to endow the new functional characteristics owing to their interesting surface characteristics. The surface functionalization of NPs can play a key role in controlling the colloidal stability followed by interactions between substrate and NPs leading to enhanced functional characteristics. Here, the synthesis of ZnO NPs was carried out through hydrothermal method. The surface of NPs was modified using silanol and tertiary amine-based coupling agents. The functionalized NPs were characterized using zeta potential, size distribution, XRD, EDX, and FTIR. The size of prepared NPs was observed as 34 nm. The disperse stability of functionalized NPs was studied by varying the concentration of coupling agent and assessed through the ultraviolet protection factor (UPF) and antibacterial activity of the fabrics treated with functionalized NPs. The functionalized NPs exhibited stable dispersion with higher zeta potential and have a smaller size. A significant improvement in the UPF value and antibacterial activity of treated cotton fabrics was observed. Note de contenu : - EXPERIMENTAL : Preparation of ZnO NPs - Preparation of coupling agent - Modification of ZnO NPs - Application of ZnO NPs on fabric
- RESULTS AND DISCUSSION : Size optimization and zeta potential of ZnO NPs - Effect of pH on zeta potential and size of modified ZnO NPs - Crystal structure of Synthesized NPs - Vibrational analysis of ZnO NPs - UV resistance of treated fabrics - Antimicrobial activity of treated fabrics
- Table 1 : Description of process conditions to optimize the size of NPs
- Table 2 : Description of factors to study colloidal stability of NPsDOI : https://doi.org/10.1007/s11998-021-00533-6 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00533-6.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37278
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Microwave thermally expanded graphene/polyaniline conductive paste for elaborate conductive pattern and conductive polyester fabric fabrication via screen printing / Junrong Zhu in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Microwave thermally expanded graphene/polyaniline conductive paste for elaborate conductive pattern and conductive polyester fabric fabrication via screen printing Type de document : texte imprimé Auteurs : Junrong Zhu, Auteur ; Weihua Song, Auteur ; Jun Peng, Auteur ; Yunjie Yin, Auteur ; Bo Xu, Auteur ; Chaoxia Wang, Auteur Année de publication : 2022 Article en page(s) : p. 477-485 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
Conducteurs organiques
GraphèneLe graphène est un cristal bidimensionnel (monoplan) de carbone dont l'empilement constitue le graphite. Il a été isolé en 2004 par Andre Geim, du département de physique de l'université de Manchester, qui a reçu pour cette découverte le prix Nobel de physique en 2010 avec Konstantin Novoselov. Il peut être produit de deux manières : par extraction mécanique du graphite (graphène exfolié) dont la technique a été mise au point en 2004, ou par chauffage d'un cristal de carbure de silicium, qui permet la libération des atomes de silicium (graphène epitaxié). Record en conduction thermique jusqu'à 5300 W.m-1.K-1. C'est aussi un matériaux conducteur.
Matériaux expansés
Micro-ondes
Polyacrylonitrile
Polyesters
Textiles et tissus synthétiques
Traitement thermiqueIndex. décimale : 667.9 Revêtements et enduits Résumé : This work reports the preparation and application of microwave thermally expanded graphene (G)/polyaniline (PANI) conductive paste. The results from XRD revealed that the polyaniline did not change its crystal structure after being combined with microwave thermally expanded graphene. FTIR and Raman spectra revealed that there was a strong π–π interaction between polyaniline and microwave thermally expanded graphene. The resultant conductive pastes possess obvious shear-thinning phenomenon, which are suitable for screen printing to produce conductive circuits. The printed polyester fabric showed significant conductivity which can be tuned by changing the printing time and line length. This study paves the way to large-scale fabrication of flexible conductive circuits for various applications. Note de contenu : - Experimental : Materials
- Preparation of thermally expanded graphene by microwave
- Preparation of G/PANI conductive paste
- Preparation of G/PANI conductive paste fabric with screen printing
- Characterization
- Result and discussionDOI : https://doi.org/10.1007/s11998-021-00530-9 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00530-9.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37279
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Shear orientation of nematic phases of clay nanosheets : processing of barrier coatings / Maximilian Röhrl in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Shear orientation of nematic phases of clay nanosheets : processing of barrier coatings Type de document : texte imprimé Auteurs : Maximilian Röhrl, Auteur ; Judith H. Mettke, Auteur ; Sabine Rosenfeldt, Auteur ; Holger Schmalz, Auteur ; Ulrich Mansfeld, Auteur ; Renee L. Timmins, Auteur ; Christoph Habel, Auteur ; Josef Breu, Auteur ; Franz Durst, Auteur Année de publication : 2022 Article en page(s) : p. 487-495 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Argile
Caractérisation
Dispersions et suspensions
Enduction par filière
Matériaux -- Propriétés barrières
Matières plastiques -- Revêtement
Nanoparticules
Oxygène
Perméabilité
Polyéthylène téréphtalate
RhéologieIndex. décimale : 667.9 Revêtements et enduits Résumé : When suspensions are exposed to shear forces, the particles may form ordered structures depending on their shapes, concentrations, and the material. For some processes, e.g., for wet-film coating, it is important to know how fast these structures form in shear fields and for how long the structures persist when the shear is relaxed. To obtain information on the particle structure formation and the decay time, the effective viscosity of nematic suspensions of Na-hectorite nanosheets was investigated by rheology employing a cone-plate measurement geometry. The necessary time for the formation textured nematic films could be deduced by carrying out effective viscosity measurements at constant time steps. Information could also be obtained on the lifetime of the platelet textures when shear is relaxed. All this information was employed to identify geometrical requirements for slot dies to produce barrier liners with nanosheet layers oriented parallel to PET substrates. Thereby, we obtained green and simple coatings that are in line with state-of-the-art high-performance materials such as metalized plastic foils in terms of oxygen barrier properties. Note de contenu : - EXPERIMENTAL : Materials and sample preparation - Characterization methods - Coating experiments
- RESULTS AND DISCUSSION : Shear orientation of NaHec nanosheets - Slot die coating
- Table 1 : OTRs of slot die coated NaHec films (1.5 µm) measured at 23°C and different r.h.DOI : https://doi.org/10.1007/s11998-021-00535-4 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00535-4.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37280
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Development of leachable enalapril tablets by controlled porosity osmotic pump technique ; a unique approach to enhance its sustained release effect / Muhammad Faheem Akhtar in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Development of leachable enalapril tablets by controlled porosity osmotic pump technique ; a unique approach to enhance its sustained release effect Type de document : texte imprimé Auteurs : Muhammad Faheem Akhtar, Auteur ; Hira Ashraf, Auteur ; Muhammad Uzair, Auteur ; Shabbir Ahmad, Auteur ; Akhtar Rasul, Auteur ; Ghulam Abbas, Auteur ; Shahid Shah, Auteur ; Muhammad Hanif, Auteur Année de publication : 2022 Article en page(s) : p. 497-507 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acétate de cellulose L'acétate de cellulose est une matière plastique inventée en 1865. C'est l'ester acétate de la cellulose.
Agent osmotique
Médicaments -- Mise au point
Membranes (technologie)Tags : CPOP 'Membrane lixiviable' 'Agent osmotique' 'Acétate de cellulose' 'Conception surface réponse optimale D' Index. décimale : 667.9 Revêtements et enduits Résumé : The present study aimed to design and evaluate controlled porosity osmotic pump (CPOP) tablets of enalapril maleate (ENP) being used for the treatment of hypertension. D-optimal response surface design was used, considering cellulose acetate and osmotic agents (lactose and fructose) as variables while physicochemical parameters of tablets were taken as responses. The asymmetric, leachable membrane of cellulose acetate on ENP tablets was applied and an increase in the thickness of core tablets from 5 ± 0.01 to 5.4 ± 0.17 mm was observed. The average weight of all CPOP formulations ranged from 376.7 ± 0.4 to 389.1 ± 0.3 mg and hardness was 6.2 ± 0.02 to 6.32 ± 0.06 Kg/cm2. The friability of all formulations was less than 1%. 89.53 ± 1.05% of ENP release was observed in phosphate buffer pH 6.8 after 12 h. Due to the smallest AIC (Akaike information criteria) and the greatest r2 values, zero-order release kinetics model with non-Fickian diffusion behavior was observed in all proposed formulations. f1 (difference factor) values were 1.28 ± 0.06 to 12.64 ± 0.41% and f2 (similarity factor) values were 59.75 ± 0.24 to 94.03 ± 1.36% in the same dissolution medium. pH-independent behavior was observed in pH-responsive study. Dissolution efficiency (DE) ranged from 51.49 ± 0.23 to 53.52 ± 0.52% and mean dissolution time (MDT) values ranged from 5.27 ± 0.05 to 5.59 ± 0.23 h. No interaction between the ingredients was found in FTIR analysis. The optimized formulation with improved drug release property was found stable in the accelerated stability study of six months. CPOP tablets of ENP can be considered as an effective substitute for immediate-release tablets to control hypertension in chronic conditions. Note de contenu : - MATERIALS AND METHODS : Materials - Experimental design - Preformulation studies - Preparation of core tablets - Preparation of CPOP tablets - Physicochemical evaluation of core and CPOP tablets - In vitro ENP release studies - Effects of osmotic agent and cellulose acetate concentrations - Effects of pH and agitational intensity - FTIR analysis and stability study
- RESULTS AND DISCUSSION : Preformulation properties of powder blends - Physical properties of core and CPOP tablets - D-optimal design responses - In vitro ENP release studies - Effects of osmotic agent and cellulose acetate concentrations on %ENP release - Effects of pH and agitational intensity on % ENP release through CPOP tablets - FTIR analysis and stability study
- Table 1 : Coded factors* for D-optimal design
- Table 2 : Composition of controlled porosity osmotic pump tablets with varying concentrations of osmotic agents and coating polymer. ENP, magnesium stearate, and average weight of core tablet were kept constant at 5.33% (20 mg), 1%, and 375 mg, respectively. DCM/methanol (1:1) was used as a coating solvent, PEG-400 used in coating solution was 15% of CA*
- Table 3 : Micromeritic and physicochemical properties of core and CPOP tablets
- Table 4 : Statistics obtained from in vitro model-dependent kinetic approaches of controlled porosity osmotic pump tablets
- Table 5 : Values of difference factor (f1) and similarity factor (f2) for CPOP tablets
- Table 6 : Characteristics of optimized formulation (CPOP2) stored at 40 ± 2°C/75 ± 5% RH for six monthsDOI : https://doi.org/10.1007/s11998-021-00536-3 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00536-3.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37281
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Phytic acid based novel optically transparent intumescent fire-retardant coating for protection of combustible substrates with retention of aesthetic appearance / Raj Shree in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Phytic acid based novel optically transparent intumescent fire-retardant coating for protection of combustible substrates with retention of aesthetic appearance Type de document : texte imprimé Auteurs : Raj Shree, Auteur ; R. Baloji Naik, Auteur ; G. Gunasekaran, Auteur Année de publication : 2022 Article en page(s) : p. 509-525 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
Composés organiques -- Synthèse
Ester de phosphate
IgnifugeantsComposé chimique utilisé pour réduire l'inflammabilité. Il peut être incorporé au produit durant sa fabrication ou appliqué ultérieurement à sa surface.
Intumescence (chimie)
Phytique, Acide
Polymères ramifiés
Polyols
Revêtements -- Propriétés mécaniques
Revêtements -- Propriétés physiques
Revêtements organiques
Revêtements protecteurs
Transparence (optique)Index. décimale : 667.9 Revêtements et enduits Résumé : Phosphorus source in transparent intumescent fire-retardant (IFR) coatings plays a crucial role in determining its performance against protecting structures from fire. In the present work, naturally occurring environmentally benign phosphorus-rich phytic acid (PA) was used as a phosphorus source. Phosphate ester resin (PER) was synthesized using PA and hyperbranched polyol (HBP), which was then used as a precursor for preparing optically transparent IFR coatings. The prepared PER was further modified with hydrogenated bisphenol-A (DGEHBA)-based epoxy resin in different wt% (25–100) to get PER-1, PER-2, PER-3, and PER-4, respectively. The formation of the PER resins was confirmed by Fourier transform infrared spectroscopy (FTIR), 13C-nuclear magnetic resonance, 31P-nuclear magnetic resonance spectroscopy (31P-NMR), and acid value analysis. The transparent IFR coatings were prepared by suitably mixing PER with hexamethoxy methyl melamine (HMMM) resin, and their performance was studied by measuring mechanical properties, optical transparency, thermal stability, fire retardancy, and smoke emission characteristics using various analytical instruments. The combination of PA and hyperbranched polyol improved the physicomechanical properties of PER-based transparent IFR coatings. The char formed after burning was also analyzed using FESEM and UTM. Results revealed that phytic acid and HBP combination increased the height as well as strength of the char. Among the prepared transparent IFR coatings, PER-0 and PER-1 have shown higher char height and strength. Note de contenu : - EXPERIMENTAL : Materials - Synthesis and modification of phosphate ester resin (PER) - Preparation of transparent IFR coating
- CHARACTERIZATION
- RESULTS AND DISCUSSION : Characterization of synthesized resins - Transparency characterization - Physicomechanical properties of the coatings - Characterization of char
- Table 1 : Composition of different PER resins
- Table 2 : Assignment of the peaks in FTIR spectra of raw materials and the synthesized resins
- Table 3 : Physicomechanical properties of the transparent IFR coating
- Table 4 : TGA data of the transparent IFR coatings
- Table 5 : Fire-retardant properties of transparent IFR coatingsDOI : https://doi.org/10.1007/s11998-021-00537-2 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00537-2.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37284
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Tamarind shell tannin-doped hybrid sol-gel coatings on mild steel in acidic medium toward improved corrosion protection / Abdullahi Abdulmajid in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Tamarind shell tannin-doped hybrid sol-gel coatings on mild steel in acidic medium toward improved corrosion protection Type de document : texte imprimé Auteurs : Abdullahi Abdulmajid, Auteur ; Tuan Sherwyn Hamidon, Auteur ; M. Hazwan Hussin, Auteur Année de publication : 2022 Article en page(s) : p. 527-542 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acier L'acier est un alliage métallique utilisé dans les domaines de la construction métallique et de la construction mécanique.
L'acier est constitué d'au moins deux éléments, le fer, très majoritaire, et le carbone, dans des proportions comprises entre 0,02 % et 2 % en masse1.
C'est essentiellement la teneur en carbone qui confère à l'alliage les propriétés du métal qu'on appelle "acier". Il existe d’autres métaux à base de fer qui ne sont pas des aciers comme les fontes et les ferronickels par exemple.
Anticorrosifs
Anticorrosion
Caractérisation
Extraction (chimie)
Métaux -- Revêtements protecteurs
Sol-gel, Procédé
Tanins végétauxIndex. décimale : 667.9 Revêtements et enduits Résumé : This study investigated the application of tamarind shell tannin extracts (TSTE) [isolated using methanol (TME) and 70% acetone (TAE)]-doped hybrid sol-gel coatings prepared using (3-Glycidyloxypropyl)trimethoxysilane (GPTMS) and tetraethoxysilane (TEOS) in 0.5 M HCl solution. The anticorrosion properties of these hybrid coatings on the surface of mild steel electrodes were described using potentiodynamic polarization (PD) and electrochemical impedance spectroscopy (EIS) measurements. The hybrid sol–gel coatings were characterized via FTIR. Also, the hydrophobicity of the coated plates was determined through water contact angle measurement. Meanwhile, the surface morphology and elemental compositions were determined using SEM/EDX analyses. The electrochemical measurements showed that the mixture of doped TME and TAE hybrid sol-gel coating resulted in higher corrosion resistance. The corrosion inhibition efficiency (CE) was CETME = 94.02 % and CETAE = 91.35 %, respectively. The Tafel slopes revealed a mixed form of corrosion protection with the main effect at cathodic sites. FTIR absorption bands attained at 945 cm-1 for TME and 961 cm-1 for TAE revealed Fe-O-Si bond formation. The higher corrosion inhibition capability of the coating matrix corroborates to higher water contact angle (θTME = 107.64°, θTAE = 104.62°) values. SEM analysis revealed coatings' improved corrosion protection due to the doping's enhanced inhibitive performance. Note de contenu : - Table 1 : Nyquist impedance parameters at various concentrations of TME- and TAE-doped hybrid sol-gel in 0.5 M HCl solution at 303 K
- Table 2 : Tafel parameters of undoped and TME- and TAE-doped hybrid sol–gel and their comparison with the bare mild steel in 0.5 M HCl solution at 303 K
- Table 3 : The FTIR bands of hybrid sol-gel matrix, coated hybrid sol–gel, and TAE- and TME-doped sol-gel coating
- Table 4 : The percentage of an element for the uncoated mild steel and hybrid sol-gel coated with TME and TAE extracts on mild steel acquired using EDX analysisDOI : https://doi.org/10.1007/s11998-021-00539-0 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00539-0.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37285
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Relative permeability of barrier dispersion coatings applied on paper-based materials ; mathematical modeling and experimental validation / Gonzalo A. Martinez-Hermosilla in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Relative permeability of barrier dispersion coatings applied on paper-based materials ; mathematical modeling and experimental validation Type de document : texte imprimé Auteurs : Gonzalo A. Martinez-Hermosilla, Auteur ; Beko Mesic, Auteur ; John E. Bronlund, Auteur Année de publication : 2022 Article en page(s) : p. 543-558 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caoutchouc styrène-butadiène
Copolymères -- Propriétés physiques
Eléments finis, Méthode des
Matériaux -- Propriétés barrières
Modèles mathématiques
Papier -- Revêtements
Perméabilité
Revêtements
Transmission de vapeur d'humiditéIndex. décimale : 667.9 Revêtements et enduits Résumé : Barrier dispersion coatings have been used to improve barrier properties of paper-based materials. Like other technologies such as thermoplastic composites, dispersion coatings include fillers to create obstacles that complicate the pathways for permeants through coatings. The development of these technologies has received significant attention where even predictive barrier performance models have been created. However, to the best of our knowledge, none of them are applicable to barrier dispersion coatings. This research proposed a mathematical model to predict the relative permeability of barrier dispersion coatings applied on paper-based materials based on Fick’s law. The uncertainty of the barrier properties due to variation in filler orientation and spatial location was included through Monte Carlo simulation. Model validation against four models previously published by other authors, and water vapor transmission rate measured on three coating formations and two coating thicknesses was also conducted. The model predictions and experimental results showed that the increase in the amount of fillers reduces the relative permeability, and this reduction can be higher if the size of the fillers is larger. The predictions agreed with experimental results particularly at volume fractions below 10%. In most of the cases, the proposed model achieved better prediction in comparison with those already published. The model is useful to predict relative barrier performance of different coating formulations and can be used as a tool for future developments. Note de contenu : - MODEL DEVELOPMENT : Conceptual model - Model assumptions - Mathematical solution - Generation of barrier dispersion coating geometry - Mathematical solution of the model by finite element method (FEM) - Estimation of the required number of geometries to represent barrier dispersion coating performance
- MODEL VALIDATION : Preparation of barrier dispersion coating for model validation
- RESULTS AND DISCUSSION : Dimension of the dispersion coating geometry based on REV - WVTR of the dispersion coatings - Comparison between model predictions and experimental data
- Table 1 : List of assumptions taken to develop the predictive model and their justification
- Table 2 : List of selected models
- Table 3 : Summary of the geometrical distribution parameters of Clay A, B, and C
- Table 4 : Physical properties of the styrene-butadiene latex DL629
- Table 5 : Mass and volume fraction for different formulations and filler types
- Table 6 : Average and standard deviation of the coating thickness at different mass fraction of filler (w/dw) for the three selected fillers including coating thickness with no fillers coated with rod size R#3
- Table 7 : Coating density as a function of mass fraction of fillersDOI : https://doi.org/10.1007/s11998-021-00552-3 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00552-3.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37286
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Detection of different chemical binders in coatings using hyperspectral imaging / Bahman Raeissi in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Detection of different chemical binders in coatings using hyperspectral imaging Type de document : texte imprimé Auteurs : Bahman Raeissi, Auteur ; Muhammad Ahsan Bashir, Auteur ; Joseph L. Garrett, Auteur ; Milica Orlandic, Auteur ; Tor Arne Johansen, Auteur ; Torbjorn Skramstad, Auteur Année de publication : 2022 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Analyse spectrale
Diluants
Données massives
Epoxy amine
Epoxy novolac
Imagerie (technique)
Liants
Métaux -- Revêtements protecteurs
Ondes décamétriques
Organosilanes
Polyuréthanes
Produits chimiques -- Détection
Rayonnement infrarougeIndex. décimale : 667.9 Revêtements et enduits Résumé : Organic coatings protect metallic structures of significant commercial value. Regular inspections of coatings are required to ensure their integrity and, therefore, to verify their stated performance. However, for metallic structures located in harsh places, coating inspection can pose significant safety and logistical challenges. Near-infrared (NIR) spectroscopy is a rapid, nondestructive and relatively inexpensive analytical technique. It is currently employed to analyze different chemicals in fields like agriculture, food, and pharmaceuticals. Similarly, hyperspectral imaging (HSI) creates a spatial map of spectral information by measuring light reflected from a material. In this work, hyperspectral imaging in the NIR portion of the electromagnetic spectrum (NIR-HSI) is used to accurately distinguish between the chemically different binders employed in commercial organic coatings. In addition, k-means clustering is explored as a tool to provide diagnostic information about the spatial inhomogeneities in the chemical structure of an applied coating, which, if undetected, can lead to coating defects during service life. The results of this work suggest that the NIR-HSI could be used for remote inspections of organic coatings. Note de contenu : - EXPERIMENTAL WORK : Chemicals and panels preparation - Hyperspectral imaging system and data acquisition - Methods
- RESULTS AND DISCUSSIONS : Epoxy-amine systems - Epoxy novolac cured with amine curing agent - Silicone resin with organosilane - Polyurethane - Different extenders used in model epoxy-amine systems - Distinguishing between bindersDOI : https://doi.org/10.1007/s11998-021-00544-3 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00544-3.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37287
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Corrosion protection of benzoxazine and cardanol-doped polyaniline coatings / Raiane Valenti Gonçalves in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Corrosion protection of benzoxazine and cardanol-doped polyaniline coatings Type de document : texte imprimé Auteurs : Raiane Valenti Gonçalves, Auteur ; Isadora Quinhones Liposki, Auteur ; Lucas Weber Dias, Auteur ; Alessandra Fiorini Baldissera, Auteur ; Mauro Ricardo da Silva Silveira, Auteur ; Carlos Arthur Ferreira, Auteur ; Leila Bonnaud, Auteur ; Nara Regina de Souza Basso, Auteur Année de publication : 2022 Article en page(s) : p. 575-586 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Anticorrosifs
Anticorrosion
Benzoxazine
Caractérisation
Cardanol
Essais d'adhésion
Formulation (Génie chimique)
Polyacrylonitrile
Polymères -- Synthèse
Revêtements organiques
Revêtements protecteurs
Spectroscopie d'impédance électrochimiqueIndex. décimale : 667.9 Revêtements et enduits Résumé : In this work a corrosion protection material formed by commercial benzoxazine and polyaniline (PAni) for coatings applications was developed. PAni doped with a natural phenolic compound, cardanol, was used in the coating preparation, and conventional hydrochloric acid-doped PAni was also used for comparative purposes. Cardanol is a reddish-brown liquid obtained from the by-product of cashew nut processing. The presence of the aliphatic group and the hydroxyl of the cardanol, as well as the amine groups of the PAni, can enhance the corrosion barrier of a benzoxazine coatings. The anticorrosive properties of the coatings were evaluated by electrochemical impedance spectroscopy in 3.5% NaCl solution for a total period of 168 h. The coatings of benzoxazine filled with PAni showed better anticorrosion performance and adhesion strength on carbon steel substrate when compared to pristine benzoxazine and PAni doped with 3 wt% cardanol exhibits the best performances. This last result can be explained by both the presence of PAni and the better PAni dispersion within benzoxazine when doped with cardanol. In addition, the incorporation of cardanol-doped PAni in the benzoxazine reduced the cure temperature of the benzoxazine. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of cardanol-doped polyaniline - Benzoxazine/PAni coatings preparation - Characterization
- RESULTS AND DISCUSSION : Benzoxazine/Jeffamine® ED 600 curing systems - Benzoxazine/PAni coatings characterizations - Anticorrosive performance of benzoxazine/PAni coatings - Adhesion strength test
- Table 1 Formulation of benzoxazine /PAni coatings
- Table 2 Data of TGA curves of pure Bz and Bz
- Table 3 Data of DSC associated with curing process of benzoxazines coatings
- Table 4 Coating’s values of average thickness and adhesion strengthDOI : https://doi.org/10.1007/s11998-021-00545-2 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00545-2.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37288
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Super-hydrophobic coating prepared by mechanical milling method / Haiyang Wang in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Super-hydrophobic coating prepared by mechanical milling method Type de document : texte imprimé Auteurs : Haiyang Wang, Auteur ; Miaomiao Liang, Auteur ; Jianjing Gao, Auteur ; Zemin He, Auteur ; Shaopeng Tian, Auteur ; Kexuan Li, Auteur ; Yuzhen Zhao, Auteur ; Zongcheng Miao, Auteur Année de publication : 2022 Article en page(s) : p. 587-595 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Aluminium L'aluminium est un élément chimique, de symbole Al et de numéro atomique 13. C’est un métal pauvre, malléable, de couleur argent, qui est remarquable pour sa résistance à l’oxydation13 et sa faible densité. C'est le métal le plus abondant de l'écorce terrestre et le troisième élément le plus abondant après l'oxygène et le silicium ; il représente en moyenne 8 % de la masse des matériaux de la surface solide de notre planète. L'aluminium est trop réactif pour exister à l'état natif dans le milieu naturel : on le trouve au contraire sous forme combinée dans plus de 270 minéraux différents, son minerai principal étant la bauxite, où il est présent sous forme d’oxyde hydraté dont on extrait l’alumine. Il peut aussi être extrait de la néphéline, de la leucite, de la sillimanite, de l'andalousite et de la muscovite.
L'aluminium métallique est très oxydable, mais est immédiatement passivé par une fine couche d'alumine Al2O3 imperméable de quelques micromètres d'épaisseur qui protège la masse métallique de la corrosion. On parle de protection cinétique, par opposition à une protection thermodynamique, car l’aluminium reste en tout état de cause très sensible à l'oxydation. Cette résistance à la corrosion et sa remarquable légèreté en ont fait un matériau très utilisé industriellement.
L'aluminium est un produit industriel important, sous forme pure ou alliée, notamment dans l'aéronautique, les transports et la construction. Sa nature réactive en fait également un catalyseur et un additif dans l'industrie chimique ; il est ainsi utilisé pour accroître la puissance explosive du nitrate d'ammonium.
Caractérisation
Cuivre
Enrobage (technologie)
Fragmentation
Hydrophobie
Métaux -- Revêtements protecteurs
Poudres
Rugosité
Stéarique, AcideL'acide stéarique ou acide octadécanoïque (nom IUPAC) est un acide gras à chaîne longue, qu'on symbolise par les nombres 18:0 pour indiquer qu'il a 18 atomes de carbone et aucune liaison covalente double : c'est un acide gras saturé. À température ambiante, il forme un solide blanc. Sa température de fusion est d'environ 70 °C. L'acide stéarique est abondant dans toutes les graisses animales sous la forme de l'ester tristéarate de glycérine (stéarine) C57H110O6 (surtout chez les ruminants) ou végétales. Il sert industriellement à faire des huiles, des bougies et des savons. Sa formule chimique semi-développée est : CH3-[CH2]16-COOH.
Les acides stéarique, laurique, myristique et palmitique constituent un groupe important d'acides gras.
UTILISATIONS : L'acide stéarique est utilisé comme liant ou pigments pour le caoutchouc, agent de polymérisation du phényléthylène (styrolène ou vinylbenzène) et du butadiène afin d'obtenir du caoutchouc synthétique, siccatif de vernis, bougies en cire, craie de cire, savon (l'acide stéarique et l'hydroxyde de sodium forment un savon : le stéarate de sodium) ou émulsifiant et stabilisant en alimentaire E570 (ou stéarate de magnésium E572).Index. décimale : 667.9 Revêtements et enduits Résumé : In mechanical milling, stearic acid can be used as a process control agent to reduce the interface energy between powders and contribute to the crushing of powder particulates. In this study, a super-hydrophobic coating with a contact angle of 153° ± 2° was fabricated by ball milling a copper powder and stearic acid mixture onto an aluminum foil. Fourier-transform infrared spectroscopy demonstrated that stearic acid was successfully transferred to the surface of the copper powder, and scanning electron microscopy revealed that the structure of the super-hydrophobic coating consisted of irregular particles and sheets. The combined effect of low surface free energy and rough structure of the copper-based coating contributed to the super-hydrophobicity. The reported method is beneficial to preparing super-hydrophobic materials by the solid-state synthesis. Note de contenu : - Materials
- Preparation of stearic acid-copper powder mixture
- Preparation of super-hydrophobic aluminum foil
- Experimental characterization
- Fig. 1 : The contact angle of samples after ball-milling treatment
- Fig. 2 : SEM images of ball-milled stearic acid-modified copper powder and super-hydrophobic aluminum foil with different magnifications
- Fig. 3 : A macro-photo of water drops on copper-coated aluminum foil and the SEM images of copper powder-coated aluminum foil at different magnifications
- Fig. 4 : A macro-photo of water drops on alcohol-copper powder mixture coated aluminum foil and the SEM images of alcohol-added copper powder-coated aluminum foil
- Fig. 5 : FTIR spectra of stearic acid, ball-milled copper powder, and stearic acid-modified ball-milled powder, respectively
- Fig. 6 : The contact angle and SEM images of stearic acid-modified copper powder after ball milling for 1 h
- Fig. 7 : The formation mechanism of super-hydrophobic filmDOI : https://doi.org/10.1007/s11998-021- En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00546-1.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37289
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Development of thin-film hydroxyapatite coatings with an intermediate shellac layer produced by dip-coating process on Ti6Al4V implant materials / A. Ritwik in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Development of thin-film hydroxyapatite coatings with an intermediate shellac layer produced by dip-coating process on Ti6Al4V implant materials Type de document : texte imprimé Auteurs : A. Ritwik, Auteur ; K. K. Saju, Auteur ; Ajith Vengellur, Auteur ; P. P. Saipriya, Auteur Année de publication : 2022 Article en page(s) : p. 597-605 Langues : Américain (ame) Catégories : Adhésion
Dip-coating
Gomme-laque
HydroxyapatiteL'hydroxyapatite est une espèce minérale de la famille des phosphates, de formule Ca5(PO4)3(OH), usuellement écrite Ca10(PO4)6(OH)2 pour souligner le fait que la maille de la structure cristalline comprend deux molécules. L'hydroxyapatite est le membre hydroxylé du groupe apatite. L'ion OH- peut être remplacé par le fluor, le chlore ou le carbonate.
L'hydroxyapatite cristallise dans le système hexagonal. La poudre d'hydroxyapatite pure est blanche. Celles que l'on trouve dans la nature peuvent cependant être de couleur marron, jaune ou verte.
Métaux -- Revêtements
Titane -- AlliagesIndex. décimale : 667.9 Revêtements et enduits Résumé : A thin layer of hydroxyapatite (HAp) coating has been developed on Ti6Al4V substrates using a dip-coating process. An intermediate layer of shellac (natural resin) was applied in between the substrate and the coating film to improve the adhesion strength without the need for any secondary annealing process. The adhesion strength was measured as 7.14 MPa. The surface of the developed coating was characterized using a scanning electron microscope. The total coating thickness was found to be 30 microns, and the surface roughness parameters were measured as 0.93 μm (Ra), 1.17 μm (Rq), and 6.67 μm (Rz). The dip-coated samples were also subjected to dissolution behavior study and in vitro study. The measured parameters of the coating suggest the use of this method as an alternative to other expensive and temperature-dependent coating methods for producing HAp coating with better adhesion strength. Note de contenu : - Table 1 : Adhesion strength & coating thickness
- Table 2 : The dissolution rate of Ca and P ions for the different time periods
- Table 3 : Atomic% of Ca and P in coated substrate immersed in SBF for different time periodsDOI : https://doi.org/10.1007/s11998-021-00549-y En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00549-y.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37290
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Modification of styrene-acrylic emulsion by organic UV absorber in synergy with fluorine and silicon monomers for weatherable coatings / Wei Dong in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Modification of styrene-acrylic emulsion by organic UV absorber in synergy with fluorine and silicon monomers for weatherable coatings Type de document : texte imprimé Auteurs : Wei Dong, Auteur ; Lei Zhou, Auteur ; Yanni Guo, Auteur ; Yining Tang, Auteur ; Rong Pan, Auteur ; Mengli Liu, Auteur ; Deliang He, Auteur Année de publication : 2022 Article en page(s) : p. 607-616 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Benzotriazole
Caractérisation
Copolymère styrène acrylique
Copolymères en émulsion
Enrobage (technologie)
Essais accélérés (technologie)
Fluorure de silicium
Formulation (Génie chimique)
Polymérisation en émulsion
Potentiel zeta
Rayonnement ultraviolet -- Absorption
Résistance aux conditions climatiques
Revêtements organiques
Stabilité thermiqueIndex. décimale : 667.9 Revêtements et enduits Résumé : To improve the weather ability and thermal stability of styrene-acrylic polymer emulsion coatings, a series of novel styrene-acrylic polymer emulsion modified with 2-[2-hydroxy-5-[2-(methacryloyloxy)ethyl]phenyl]-2H-benzotriazole (HMEB), hexafluorobutyl methacrylate (HFMA), and vinyl-trimethoxysilane (VTMS) were prepared through semi-continuous seed emulsion polymerization. The emulsions and their coatings were characterized by Fourier transform infrared spectroscopy, ultraviolet absorption spectroscopy (UV-Vis), X-ray photoelectron spectroscopy, dynamic laser scattering, transmission electron microscopy, zeta potential, thermogravimetric analysis, and artificially accelerated aging test. According to the results, the new polymer emulsion had superior UV absorption from 308 to 364 nm. Moreover, the coating performed the best anti-aging stability when the content of HMEB, HFMA, and VTMS reached 4%, 2%, and 3%, respectively. After the 1000 h aging test, the color difference (ΔE) and rate of loss of gloss (ΔG) were only 6.86% and 51.10%, while the unmodified coatings were 16.05% and 72.22%, respectively. Furthermore, the thermal stability and water resistance of the coating were improved by fluorine and silicon monomers. The initial decomposition temperature was increased from 327 to 339°C. Moreover, the UV stabilization mechanism is preliminarily discussed. Note de contenu : - EXPERIMENTAL : Materials - Pre-emulsification - Emulsion polymerization - Coating preparation - Characterization
- RESULTS AND DISCUSSION : Basic properties of emulsions and the coatings - Zeta potential and DLS of emulsions - Morphology of emulsion particles - Chemical structure of emulsion polymer - Chemical composition of emulsion coatings - UV absorption property of coatings - Thermal stability of emulsion coating - The aging acceleration test of emulsion coatings - Protective properties of emulsion coatings
- Table 1 : Emulsion polymerization formula
- Table 2 : Basic properties of emulsions and the coatings
- Table 3 : Surface composition of different coatings/atomic %DOI : https://doi.org/10.1007/s11998-021-00550-5 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00550-5.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37291
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Effects of surface fluorination on the dyeing of polycarbonate (PC) resin / Jae-Ho Kim in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Effects of surface fluorination on the dyeing of polycarbonate (PC) resin Type de document : texte imprimé Auteurs : Jae-Ho Kim, Auteur ; Toshihiro Mishina, Auteur ; Masanari Namie, Auteur ; Fumihiro Nishimura, Auteur ; Susumu Yonezawa, Auteur Année de publication : 2022 Article en page(s) : p. 617-624 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
Fluoration
Polycarbonates
Polymères -- Coloration
Polymères -- Surfaces
Rugosité
Traîtements de surfaceIndex. décimale : 667.9 Revêtements et enduits Résumé : The surface of polycarbonate (PC) was fluorinated with a mixed gas of F2 and O2 at 25 °C for 1 h. The surface roughness (Ra) of the fluorinated PC samples was about double that of the untreated sample (0.685 nm), while the water contact angle of the fluorinated PC samples decreased from 80° to 12°. The dyeing properties of the PC surface were enhanced after surface fluorination due to the increased roughness and hydrophilicity. Fluorination using a mixed gas with a higher F2 proportion led to the formation of a thicker dyeable fluoride layer, thereby giving a deeper color after staining of the PC surface. Note de contenu : - EXPERIMENTAL DETAILS : Surface fluorination of polycarbonate - Material characterization - Dye staining of polycarbonate
- RESULTS AND DISCUSSION : Dyeing of surface-modified PC plates
- Table 1 : Untreated and fluorinated PC samples and the various F2 and O2 gas mixing ratios
- Table 2 : Elemental composition contents of PC samples evaluated from XPS resultsDOI : https://doi.org/10.1007/s11998-021-00551-4 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00551-4.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37292
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Advanced poly(aniline-aminosalicylic acid) nanofiber functionalized with modified GO environment friendly coatings on steel surfaces with water resistance and long-term active anticorrosion performance / Meng Wang in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Advanced poly(aniline-aminosalicylic acid) nanofiber functionalized with modified GO environment friendly coatings on steel surfaces with water resistance and long-term active anticorrosion performance Type de document : texte imprimé Auteurs : Meng Wang, Auteur ; Fengjuan Xiao, Auteur ; Longfei Kong, Auteur ; Guyu Yin, Auteur ; Changbiao Ni, Auteur ; Xuefei Zhang, Auteur ; Cheng Qian, Auteur ; Lu Yan, Auteur ; Mengya Li, Auteur ; Jun Li, Auteur ; Kaixi Zhou, Auteur Année de publication : 2022 Article en page(s) : p. 625-642 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acier au carbone
Anticorrosifs
Anticorrosion
Caractérisation
Copolymérisation
Hydrophobie
Métaux -- Revêtements protecteurs
Nanofibres
Polyacide aniline-aminosalicylique
Résistance à l'humidité:Résistance à l'eau
Revêtements en phase aqueuse
Revêtements organiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : An advanced long-term active corrosion protection coating for carbon steel was proposed using poly(aniline-aminosalicylic acid) nanofiber (PACA-f) covalently linked with cetyltrimethyl ammonium bromide (CTAB)-modified graphene oxide (CTGO). The proton-doped PACA-f functionalized CTGO (PACA-f/CTGO) exhibits excellent hydrophobicity and outstanding water resistance in waterborne epoxy polymer (WEP) coatings and better compatibility with WEP due to the formation of organic–inorganic networks. PACA-f/CTGO composite coating has a self-repairing function and shows superior corrosion resistance on Q235 steel. The surface-corrosion inhibition of PACA-f/CTGO on steel was investigated by molecular dynamics simulation(MD) which confirmed the chemical adsorption of the PACA-f/CTGO on the steel surface. The excellent water resistance and anticorrosion property of PACA-f/CTGO are ascribed to the high hydrophobicity of the hybrid coatings, the formation of intelligent passivation layer after the corrosive medium invading, and the barrier performance of CTGO. Note de contenu : - EXPERIMENTAL SECTION : Materials - Preparation of PACA-f/CTGO composite - Preparation of waterborne anticorrosive coating samples - Molecular dynamics (MD) simulations - Characterization
- RESULTS AND DISCUSSION : Morphological studies of CTGO, PACA-f and PACA-f/CTGO composite - Elemental composition and chemical state of the samples - XRD and UV–Vis spectroscopy analyses of PACA-f/CTGO composites - Electrochemical activity - Cross-sectional morphology of coating - Corrosion behaviorDOI : https://doi.org/10.1007/s11998-021-00553-2 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00553-2.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37293
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Valorization of almond shells' lignocellulosic microparticles for controlled release urea production : interactive effect of process parameters on longevity and kinetics of nutrient release / Babar Azeem in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Valorization of almond shells' lignocellulosic microparticles for controlled release urea production : interactive effect of process parameters on longevity and kinetics of nutrient release Type de document : texte imprimé Auteurs : Babar Azeem, Auteur ; Noureddine Elboughdiri, Auteur ; Kuzilati Kushaari, Auteur ; Bassem Jamoussi, Auteur ; Djamel Ghernaout, Auteur ; Saad Ghareba, Auteur ; Shahid Raza, Auteur ; Aicha Gasmi, Auteur Année de publication : 2022 Article en page(s) : p. 643-660 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Analyse de variance En statistique, l'analyse de la variance (terme souvent abrégé par le terme anglais ANOVA : ANalysis Of VAriance) est un ensemble de modèles statistiques utilisés pour vérifier si les moyennes des groupes proviennent d'une même population. Les groupes correspondent aux modalités d'une variable qualitative (p. ex. variable : traitement; modalités : programme d'entrainement sportif, suppléments alimentaires ; placebo) et les moyennes sont calculés à partir d'une variable continue (p. ex. gain musculaire).
Ce test s'applique lorsque l'on mesure une ou plusieurs variables explicatives catégorielles (appelées alors facteurs de variabilité, leurs différentes modalités étant parfois appelées "niveaux") qui ont de l'influence sur la loi d'une variable continue à expliquer. On parle d'analyse à un facteur lorsque l'analyse porte sur un modèle décrit par un seul facteur de variabilité, d'analyse à deux facteurs ou d'analyse multifactorielle sinon. (Wikipedia)
Coquilles d'amande
Dispersions et suspensions
Lignocellulose
Morphologie (matériaux)
Revêtements -- Propriétés thermiques
Revêtements organiques
Rhéologie
Système de libération contrôlée (technologie)
UréeIndex. décimale : 667.9 Revêtements et enduits Résumé : In this study, almond shell lignocellulosic bio-waste material is utilized as a spray suspension for the production of controlled release urea in a rotary pan coater. For this purpose, the almond shell particles are chemically modified to enhance the spray characteristics and mechanical properties of the coating film. Response surface methodology is employed to investigate the interactive effect of process parameters on time and kinetics of urea release from controlled release product. The FTIR spectrum of the coating suspension vindicates the acetylation of the lignocellulosic particles of almond shells. TGA reveals an enhancement of thermal stability of the chemically modified almond shell particles. The viscosity of spray suspension decreases with increase in temperature and increases with increase in the particle size of the spray suspension. The release experiments indicate that complete urea dissolution took place in a couple of minutes, whereas it took more than 20 h for the 100% release of urea from coated product. The analysis of variance reveals that spray rate is the most influential process parameter among the other studied parameters. Note de contenu : - MATERIALS AND METHODS : Materials - Methods
- RESULTS AND DISCUSSION : Thermal, structural, rheological, and morphological properties - Interactive effect of process parameters on urea release time - Interactive effect of process parameters on diffusion coefficient of nitrogen
- Table 1 : Minimum and maximum values of operating parameters from trial runs
- Table 2 : Experimental matrix from design expert® and mean film thickness of corresponding coated samples
- Table 3 : Analysis of variance results for nutrient release time and diffusion coefficientDOI : https://doi.org/10.1007/s11998-021-00554-1 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00554-1.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37294
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Role of an interface crack for the blistering mode of a stiff film on a compliant substrate / Peixia Gu in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Role of an interface crack for the blistering mode of a stiff film on a compliant substrate Type de document : texte imprimé Auteurs : Peixia Gu, Auteur ; Xuejun Chen, Auteur Année de publication : 2022 Article en page(s) : p. 661-669 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Cloquage (défauts)
Couches minces -- Défauts
Eléments finis, Méthode des
Interfaces (Sciences physiques)
Revêtements -- Défauts
Revêtements -- FissurationIndex. décimale : 667.9 Revêtements et enduits Résumé : A stiff thin film deposited over an underlying compliant substrate is susceptible to blistering when it is subjected to excessive in-plane compressive stresses. Two kinds of blistering modes (wrinkling and buckling) have been revealed in experiments, depending on the properties of film/substrate pair as well as that of interface adhesion. The purpose of this work is to quantify the role of an interface crack for the selection of such blistering modes in compressed thin films. By a semi-analytical approach, the transitional size of an interface crack is identified at which both wrinkling mode and buckling mode may arise. The mode selection diagram is constructed and characterized with respect to the normalized interface crack size and compressive strain. The theoretical estimations are validated by a finite element method incorporating an interface cohesive zone model and are demonstrated to be in reasonable agreement with experimental observations in previous literature. The results in this work are expected to be helpful in the effective design and evaluation of thin-film devices. Note de contenu : - MODEL DESCRIPTION
- FINITE ELEMENT SIMULATION : Finite element model - Interface cohesive zone model
- RESULTS AND DISCUSSION : Mode selection diagram - ValidationsDOI : https://doi.org/10.1007/s11998-021-00556-z En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00556-z.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37295
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Deep learning-based automated characterization of crosscut tests for coatings via image segmentation / Gaoyuan Zhang in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Deep learning-based automated characterization of crosscut tests for coatings via image segmentation Type de document : texte imprimé Auteurs : Gaoyuan Zhang, Auteur ; Christian Schmitz, Auteur ; Matthias Fimmers, Auteur ; Christoph Quix, Auteur ; Sayed Hoseini, Auteur Année de publication : 2022 Article en page(s) : p. 671-683 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Adhésion
Analyse d'imageL'analyse d'image est la reconnaissance des éléments contenus dans l'image. Il ne faut pas confondre analyse (décomposition en éléments) et traitement (action sur les composantes) de l'image.
Analyse de dommages (matériaux)
Autoapprentissage
Automatisation
Caractérisation
Enrobage (technologie)
Essais de quadrillage
Imagerie (technique)
Logiciels
Rayures
Résistance à l'abrasion
Revêtements -- Détérioration
Surfaces (Physique)Index. décimale : 667.9 Revêtements et enduits Résumé : A manual scratch test to measure the scratch resistance of coatings applied to a certain substrate is usually used to test the adhesion of a coating. Despite its significant amount of subjectivity, the crosscut test is widely considered to be the most practical measuring method for adhesion strength with a good reliability. Intelligent software tools help to improve and optimize systems combining chemistry, engineering based on high-throughput formulation screening (HTFS) technologies and machine learning algorithms to open up novel solutions in material sciences. Nevertheless, automated testing often misses the link to quality control by the human eye that is sensitive in spotting and evaluating defects as it is the case in the crosscut test. In this paper, we present a method for the automated and objective characterization of coatings to drive and support Chemistry 4.0 solutions via semantic image segmentation using deep convolutional networks. The algorithm evaluated the adhesion strength based on the images of the crosscuts recognizing the delaminated area and the results were compared with the traditional classification rated by the human expert. Note de contenu : - BACKGROUND : Neural networks - Convolutional neural networks and image segmentation tasks
- SOLUTION APPROACH AND EXPERIMENTAL SETUP : Sample preparation - Automated crosscutting - Data preprocessing - Data augmentation - Architectures Loss functions
- EVALUATION : Training - Results
- Table 1 : Summary of the applied data augmentation methods
- Table 2 : Confusion matrices of the various models being applied for the segmentation into delaminated and intact area
- Table 3 : Comparison between human and algorithmic rating for samples selected across all six levels defined in the norm
- Table 4 : Mean Dice coefficient in % calculated over all 31 test images with standard deviation, inference time for the test set and the number of parameters for each model paired with each of the different lossesDOI : https://doi.org/10.1007/s11998-021-00557-y En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00557-y.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37296
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Code-barres Cote Support Localisation Section Disponibilité 23408 - Périodique Bibliothèque principale Documentaires Disponible Biosynthesis of ZnO nanoparticles and effect of silver doping in gas sensing characteristics of volatile organic compounds / Anil Kumar in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
[article]
Titre : Biosynthesis of ZnO nanoparticles and effect of silver doping in gas sensing characteristics of volatile organic compounds Type de document : texte imprimé Auteurs : Anil Kumar, Auteur ; Ravi Kumar, Auteur ; Rakesh Singh, Auteur ; B. Prasad, Auteur ; Dinesh Kumar, Auteur ; Mukesh Kumar, Auteur Année de publication : 2022 Article en page(s) : p. 685-697 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Analyse structurale (ingénierie)
Argent
Biosynthèse
Capteurs (technologie)
Composés inorganiques -- Synthèse
Détecteurs de gaz
Fourier, Spectroscopie infrarouge à transformée de
Granulométrie
Morphologie (matériaux)
Nanoparticules
Oxyde de zinc
Résistance chimiqueIndex. décimale : 667.9 Revêtements et enduits Résumé : This experimental study describes the gas sensing characteristics of biosynthesized ZnO nanoparticles toward a group of volatile organic compounds (VOCs) like benzene, acetone, formaldehyde, methanol and ethanol. The effect of doping of different concentrations of silver nanoparticles in ZnO to improve the sensing response of the mentioned VOCs has also been studied. The structural analysis of the synthesized nanoparticles was carried out using X-ray diffraction (XRD) and Fourier transform infrared (FTIR) spectroscopy. The morphological investigations were performed using high-resolution transmission electron microscopy (HRTEM). Elemental analysis of the synthesized thin film was carried out by energy-dispersive X-ray spectroscopy (EDX). The gas sensing properties for pure ZnO and Ag-doped ZnO thin films were carried out for different (VOCs). On the basis of experimental results, the optimized Ag-doped ZnO nanoparticles were used for the measurement of gas sensing properties of ethanol gas. The observed gas sensor response has been explained using a chemisorption-based sensing mechanism in metal oxide semiconductor devices. Different sensing parameters like sensitivity, sensor response and recovery time have been measured. The sensor response of both materials has been compared with different concentrations of targeted VOCs. It has been observed that Ag-ZnO exhibits improved sensitivity as compared to pure ZnO. The optimized Ag(15%)ZnO thin films were found to be more selective toward ethanol with ~81% sensor response at 250 °C. Note de contenu : - BIOSYNTHESIS OF ZNO NANOPARTICLES
- SYNTHESIS OF AG NANOPARTICLES : Preparation of Ag-doped ZnO and fabrication of sensor device
- RESULTS AND DISCUSSION, I : Structural analysis - FTIR spectra analysis - Surface morphological, grain size, and elemental composition studies
- GAS SENSING MEASUREMENT SETUP
- RESULTS AND DISCUSSION, II : Sensing characteristics of ZnO and Ag-doped ZnO nanoparticles - Sensing mechanism and gas sensing measurements
- Table 1 : Ethanol sensing characteristics of different ZnO-based nanomaterialsDOI : https://doi.org/10.1007/s11998-021-00543-4 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00543-4.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37297
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