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Effect of curing process on simulated antisoiling properties of sol–gel coating on pine sapwood / Juha Nikkola in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 7, N° 4 (07/2010)
[article]
Titre : Effect of curing process on simulated antisoiling properties of sol–gel coating on pine sapwood Type de document : texte imprimé Auteurs : Juha Nikkola, Auteur ; Riitta Mahlberg, Auteur ; Juha Mannila, Auteur ; Saila Jämsä, Auteur Année de publication : 2010 Article en page(s) : p. 441-448 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Bois -- Revêtements protecteurs
Matériaux hybrides
Revêtements:Peinture
Sol-gel, ProcédéTags : 'Revêtement hybride' 'Propriétés antisalissures' 'Aubier du pin' Hydrophobicité Oléophobicité Index. décimale : 667.9 Revêtements et enduits Résumé : Recently, inorganic–organic hybrid coatings produced by the sol–gel route have proven to be a potential protective treatment for wooden surfaces. In this study, the effect of curing process on simulated antisoiling properties of sol–gel coating was investigated. The sol–gel coating was spray-coated on pine sapwood and cured with different temperature and time combinations. The antisoiling properties were studied by measuring the water contact angle of the coating after different curing processes. In addition, abrasion resistance and contact angle of oleic acid were measured. An optical profilometer was used to investigate surface roughness of the coating. Sufficient hydro- and oleophobicity were obtained with all of the curing parameters. The comparison between curing parameters showed that lower temperature and 1–3 h curing time leads to significant improvement in the durability of the water and oil repellent properties of the coating. DOI : 10.1007/s11998-009-9217-x En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-009-9217-x.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=9766
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Code-barres Cote Support Localisation Section Disponibilité 012362 - Périodique Bibliothèque principale Documentaires Disponible Effect of different structured POSS/GMA-containing copolymers on the morphology of porous coating by breath-figures method / YanLi Ma in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 15, N° 4 (07/2018)
[article]
Titre : Effect of different structured POSS/GMA-containing copolymers on the morphology of porous coating by breath-figures method Type de document : texte imprimé Auteurs : YanLi Ma, Auteur ; Ling He, Auteur Année de publication : 2018 Article en page(s) : p. 737-742 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Copolymères
Matériaux poreux
Méthacrylate de glycidyle
Morphologie (matériaux)
Revêtements
Silsesquioxanes oligomères polyhèdresTags : 'Méthode des figures respiratoires' 'POSS/GMA' 'Effet solvant' Coolymères 'Revêtement organique' Index. décimale : 667.9 Revêtements et enduits Résumé : Polyhedral oligomeric silsesquioxane (POSS) and glycidyl methacrylate (GMA) are used to synthesize linear L-(PGMA-b-MA-POSS), dicephalous D-(PGMA-b-MA-POSS)2, and four-armed T-(PGMA-b-MA-POSS)4 through atom transfer radical polymerization (ATRP). These different structured POSS/GMA-containing copolymers are applied to build the porous films through breath-figures (BF) method. L-(PGMA-b-MA-POSS) is easy to form the ordered porous BF film, and T-(PGMA-b-MA-POSS)4 tends to form well-distributed BF film due to its high segment density which is beneficial to stabilize water drop. It is proven that solvent has a great effect on the morphologies of BF film. The perfect BF film is developed in the relatively wet atmosphere as 5–8 μm diameter of pores casted in THF and 2–4 μm diameter of pores casted in CH2Cl2 with regular morphology. The developed BF film has superior stability than the film developed in natural conditions due to the shorter stable balancing time. Therefore, it is believed that the obtained porous films show great potential in coating application. Note de contenu : - EXPERIMENT METHODS AND MATERIALS : Materials - Synthesis of POSS/GMA-containing copolymers - Preparation of BF porous films - Measurements
- RESULTS AND DISCUSSIONS : The surface morphology of BF films - The water adsorption behavior of BF filmsDOI : 10.1007/s11998-018-0083-2 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-018-0083-2.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=30851
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Code-barres Cote Support Localisation Section Disponibilité 20078 - Périodique Bibliothèque principale Documentaires Disponible Effect of heat treatment at 1300°C on W coating prepared by double-glow plasma on carbon/carbon composite / Ying Zhang in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 6, N° 2 (06/2009)
[article]
Titre : Effect of heat treatment at 1300°C on W coating prepared by double-glow plasma on carbon/carbon composite Type de document : texte imprimé Auteurs : Ying Zhang, Auteur ; Dan Fang, Auteur ; Wangping Wu, Auteur ; Chen Liangbing, Auteur ; Zhaofeng Chen, Auteur Année de publication : 2009 Article en page(s) : p. 237-241 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Composites à fibres de carbone
Revêtements:Peinture
Technique des plasmasIndex. décimale : 667.9 Revêtements et enduits Résumé : W-coated carbon/carbon composite has been considered as an attractive ITER plasma facing material in fusion devices. In this paper, W coating was prepared on the carbon/carbon composite substrate by double-glow plasma method using pure W as target. Argon was input into the chamber as the plasma and the reactive gas. W-coated carbon/carbon composite was heat-treated in vacuum furnace at 1300°C for 1 h. Phase and microstructure of W coating were examined by X-ray diffraction and scanning electron microscopy, respectively. The chemical composition of W coating was analyzed by energy dispersive spectroscopy. The micro-hardness of the W coating was estimated by nano-indentation instrument. The results indicated that a continuous and dense W-modified layer could be successfully coated on the carbon/carbon composite surface by double-glow plasma method. W coating completely reacted with C to form WC at 1300°C. WC almost completely diffused into the carbon/carbon composite after heat treatment. The great decrease in elemental W on the carbon/carbon composite surface after heat treatment led to a significant reduction in micro-hardness. DOI : 10.1007/s11998-008-9109-5 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-008-9109-5.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5624
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Code-barres Cote Support Localisation Section Disponibilité 011361 - Périodique Bibliothèque principale Documentaires Disponible Effect of itaconic acid on the wet scrub resistance of highly pigmented paints for architectural coatings / Mauricio Pinheiro de Oliveira in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 8, N° 4 (07/2011)
[article]
Titre : Effect of itaconic acid on the wet scrub resistance of highly pigmented paints for architectural coatings Type de document : texte imprimé Auteurs : Mauricio Pinheiro de Oliveira, Auteur ; Caroline Reggiani Silva, Auteur ; Lilia Müller Guerrini, Auteur Année de publication : 2011 Article en page(s) : p. 439-447 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Itaconique, Acide
Latex
Pigments
Polymérisation en émulsion
Résistance aux frottements humides
RevêtementsTags : 'Latex fonctionnalisé' 'Résistance à la friction' 'Acide itaconique' 'Polymérisation en émulsion' 'Peintures hautement pigmentées' Index. décimale : 667.9 Revêtements et enduits Résumé : This study investigates the influence of carboxylic monomers, such as itaconic acid (IA), on the colloidal properties of the latexes made by semi-continuous emulsion copolymerization of styrene (STy) with n-butyl acrylate (BA). A number of copolymerization runs were carried out with different IA concentrations. The effect of functional monomer on the overall conversion, the colloidal properties of the latexes, and the distribution of the carboxylic groups (buried, particle surface and aqueous phase) were examined. The carboxylic groups present in the latexes were analyzed using conductimetric and potentiometric titrations. The behavior of the IA on the wet scrub resistance of highly pigmented paints for architectural coatings was examined and correlated with the distribution of the carboxylic groups. The results obtained showed that the properties of highly pigmented paints are greatly dependent on the amount and distribution of the carboxylic groups. The carboxylic acid distributed in the aqueous phase has a strong influence on the wet scrub resistance and on the characteristics of the final products. Note de contenu : EXPERIMENTAL : Materials - Polymerization - Composition and paint formulation
CHARACTERIZATIONS : Particle size analysis - Viscosity and pH - Coagulum formation - Freeze-thaw stability - Carboxylic group distribution - Web scrub test - Optical property
RESULTS AND DISCUSSION : Overall conversion and particle size - Distribution of carboxyl groups - Scrub resistance of dried paint filmDOI : 10.1007/s11998-010-9317-7 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-010-9317-7.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=12131
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Code-barres Cote Support Localisation Section Disponibilité 013158 - Périodique Bibliothèque principale Documentaires Disponible Effect of methyl methacrylate content on coatings’ properties of palm oleic acid-based macromer / Shahla Ataci in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 8, N° 6 (11/2011)
[article]
Titre : Effect of methyl methacrylate content on coatings’ properties of palm oleic acid-based macromer Type de document : texte imprimé Auteurs : Shahla Ataci, Auteur ; Rosiyah Yahya, Auteur ; Seng Neon Gan, Auteur Année de publication : 2011 Article en page(s) : p. 719-725 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Copolymérisation
Fourier, Spectroscopie infrarouge à transformée de
Macromolécules -- Synthèse
Méthacrylate de méthyle
Oléique, AcideL'acide oléique vient du latin oleum et veut dire huile. C'est le plus abondant des acides gras monoinsaturés à chaîne longue dans notre organisme. Sa formule chimique brute est C18H34O2 (ou CH3(CH2)7CH=CH(CH2)7COOH). Son nom IUPAC est acide cis-9-octadécénoïque, et son nom court de lipide est 18:1 cis-9. La forme saturée de cet acide est l'acide stéarique.
On le symbolise par les nombres 18:1 pour indiquer qu'il possède 18 atomes de carbone et une liaison éthylénique. Pour indiquer la position de la double liaison, on préfère indiquer le nombre de carbones entre le dernier carbone (n° 18) et le carbone où commence la double liaison (n° 9), d'où 18 - 9, qu'on écrit n - 9, en désignant par n le nombre de carbones de la chaîne. L'acide oléique est donc un acide gras insaturé, plus précisément monoinsaturé.
La double liaison agit sur la forme de la molécule et des triglycérides qu’elle forme avec le glycérol. Comme la molécule ne peut pas pivoter autour de C = C, la chaîne est beaucoup moins flexible que l’acide stéarique et ne peut pas former de boule. Les molécules des esters de cet acide sont beaucoup moins compactes que la tristéarine: ces sont des huiles.
À la température de notre corps c'est un liquide (huile), qui ne se solidifie qu'à 13,4 °C.
Revêtements:Peinture
Spectroscopie de la résonance magnétique nucléaireIndex. décimale : 667.9 Revêtements et enduits Résumé : The macromer was synthesized using medium oil length oleic acid, phthalic anhydride, and glycerol. The synthesized macromer and methyl methacrylate (MMA) were copolymerized by free radical polymerization in toluene. The ratio between the macromer and MMA changed, and the effects on different properties of the copolymers, such as glass transition temperature (T g) and film properties, were studied. The macromer and copolymer structures were characterized by FTIR and 1H NMR spectroscopies. The coatings prepared with the highest ratio of MMA exhibited better overall physico-chemical properties. Alternatively, Tafel polarization curves showed that the corrosion rate value in NaCl solution decreases significantly when the MMA content is increased. Dynamic mechanical analysis results revealed that the increasing amounts of MMA lead to increasing T g values of copolymers. Note de contenu : - EXPERIMENTAL METHODS AND MATERIALS : Synthesis of macromer - Synthesis of macromer-methyl methacrylate copolymers (MC copolymers) - Characterizations
- RESULTS AND DISCUSSION : Infrared spectroscopy - Percentage of swelling in toluene - Evaluation of physico-mechanical characteristics of the copolymers as coating - Tafel polarization - Dynamic mechanical analysis (DMA)DOI : 10.1007/s11998-011-9363-9 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-011-9363-9.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=12598
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