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Acrylic polymeric binder for leather finishing application / Michael Ifeanyichukwu Ugbaja / Saarbrücken [Germany] : Lambert Academic Publishing (2016)
Titre : Acrylic polymeric binder for leather finishing application : Water vapour permeability and some other physical properties of leathers - Effect of finish formulations Type de document : texte imprimé Auteurs : Michael Ifeanyichukwu Ugbaja, Auteur ; Ejila Amali, Auteur Editeur : Saarbrücken [Germany] : Lambert Academic Publishing Année de publication : 2016 Importance : IX-84 p. Présentation : ill. Format : 22 cm ISBN/ISSN/EAN : 978-3-659-91685-4 Prix : 49,90 E Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Agents de tannage
Cuirs et peaux -- Finition
Cuirs et peaux -- Propriétés physiques
Formulation (Génie chimique)
Liants
Perméabilité
Plan d'expérience
Polyacryliques
Polymérisation en émulsion
Retannage
Tannage
Vapeur d'eauIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : This book is a simple and concise introduction to the effect of polymeric binders in the performance of a finished leather. It aims at exposing the formulation requirements of certain acrylic resin binder suitable for leather finishing applications. The materials are presented in a manner to benefit both the students studying leather science and technology or leather engineering in tertiary institutions as well as those in the leather industry whose knowledge in this technology is deficient. Students of polymer science and technology will also appreciate the contents of this book as it tries to study the effect acrylic polymer resin in the performance of finished leathers. This book will assist mostly undergraduates in understanding the processes of leather making,formulation of finishing agents, properties and behavior of finished leather. It will also benefit those with little or no technical background in leather processes as well as those who have sophisticated background in science but no experience in the leather industry. It will also make for a good reading material for the general public that are yet to know what synergy exist between polymers and leather. Note de contenu : - GENERALITES : Description of leather - Forms of leather - Types of leather - Leather manufacturing processes - Acrylic polymer - Polymerisation techniques - Components of emulsion polymerisation reaction - Principle of emulsion polymerisation - Leather finishing
- REVIEW OF LITERATURE : General introduction - Synthetic resin dispersions for leather finishing - Synthesis of polymer dispersions - Characterisation of polymer dispersions and effect on properties of retanned leathers - Factors affecting physical properties of finished leathers - Retannage and properties of finished leathers - Water vapour permeability, wvp of finished leathers - Effect of important variables on water vapor permeability
- DESIGN OF EXPERIMENT : Experimental procedures
- RESULTS : Examination of resin binder - Physical testing of the finished leather substrate
- DISCUSSION
- CONCLUSION AND RECOMMENDATIONS
- ANNEXES : A. Some chemicals used in leather processing - B. Definition of some leather processing termsPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=36813 Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23152 675 IFE Monographie Bibliothèque principale Documentaires Disponible Documents numériques
Acrylic polymeric binder for leather finishing application : Water vapour permeability and some other physical properties of leathers - Effect of finish formulationsURL Adsorption behaviour of carbon black/latex by cationised cotton fabrics / Chunxia Wang in COLORATION TECHNOLOGY, Vol. 131, N° 6 (12/2015)
[article]
Titre : Adsorption behaviour of carbon black/latex by cationised cotton fabrics Type de document : texte imprimé Auteurs : Chunxia Wang, Auteur ; Benjamin Tawiah, Auteur ; Rongrong Cui, Auteur ; Liping Zhang, Auteur ; Shaohai Fu, Auteur Année de publication : 2015 Article en page(s) : p. 644-450 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adsorption
Cationisation
CotonLe coton est une fibre végétale qui entoure les graines des cotonniers "véritables"(Gossypium sp.), un arbuste de la famille des Malvacées. Cette fibre est généralement transformée en fil qui est tissé pour fabriquer des tissus. Le coton est la plus importante des fibres naturelles produites dans le monde. Depuis le XIXe siècle, il constitue, grâce aux progrès de l'industrialisation et de l'agronomie, la première fibre textile du monde (près de la moitié de la consommation mondiale de fibres textiles).
Dispersions et suspensions
Latex
Noir de carbone
Polymérisation en émulsion
Teinture -- Fibres textilesIndex. décimale : 667.3 Teinture et impression des tissus Résumé : A carbon black/latex dispersion was prepared by mini-emulsion polymerisation, and its absorption behaviour towards cationised cotton fabric was investigated. The results indicated that the prepared carbon black/latex dispersion had excellent freeze–thaw stability. Cotton fabric that was cationised with 3 g/l of 3-chloro-2-hydroxypropyltrimethyl ammonium chloride at a liquor ratio of 30:1 can be optimally dyed with 4% owf carbon black/latex under the conditions of pH 7.2, 60 °C, and 1 h. The adsorption behaviour of the carbon black/latex towards cationised cotton fabric followed the Langmuir adsorption isotherm, with a lower dyeing rate and a better colour levelness than the ordinary carbon black dispersion with binder. Note de contenu : - EXPERIMENTAL : Materials - Preparation of the carbon black/latex dispersion - Dyeing of cotton fabric - Characterisation of the carbon black/latex dispersion - Colour performance of the dyed cotton fabric
- RESULTS AND DISCUSSION : Properties of the carbon black/latex dispersion - Dyeing conditions - Adsorption behaviour of the carbon black/latex towards cationised cotton fabrics - Properties of dyed cotton fabricsDOI : 10.1111/cote.12186 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12186 Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25091
in COLORATION TECHNOLOGY > Vol. 131, N° 6 (12/2015) . - p. 644-450[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 17685 - Périodique Bibliothèque principale Documentaires Disponible Advances in fluoropolymer dispersions / T. Poggio in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 87, B1 (02/2004)
[article]
Titre : Advances in fluoropolymer dispersions Type de document : texte imprimé Auteurs : T. Poggio, Auteur ; V. Kapeliouchko, Auteur ; V. Arcella, Auteur ; E. Marchese, Auteur Année de publication : 2004 Article en page(s) : p. 51-56 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Alliages polymères
Dispersions et suspensions
Emulsions
Microémulsions
Polymérisation en émulsion
Polytétrafluoréthylène
Résistance à l'abrasion
Revêtements organiques
Stabilisants (chimie)
SurfactantsIndex. décimale : 667.9 Revêtements et enduits Résumé : Multimodal high-performance fluoropolymer dispersions have been developed thanks to Solvay Solexis' proprietary technology which permits bimodal particle-size distributions to be obtained, not only by blending standard fluoropolymer dispersions (diameter 250nm) with nano-latexes (diameter from 10 to 60nm), but also directly from polymerisation, exploiting a competitive homogeneous/coagulative and droplet nucleation mechanism. It has been found that poly(tetra-fluoroethylene) (PTFE) bimodal dispersions have optimal film-forming and particle-packing behaviour at a size ratio of about 0.15, corresponding with the best fit to the random close-packing model, while no significant improvements are observed when the aforesaid size ratio is 0.3. Note de contenu : - LATEX PREPARATION AND CHARACTERISATION : Emulsion polymerisation - Microemulsion polymerisation - Direct polymerisation of bimodal dispersions
- RESULTS AND DISCUSSION : Dispersions stabilised with phenol-free non-ionic surfactants - Coating characteristics - Further developments
- Table 1 : PTFE dispersion characteristics
- Table 2 : Nano-PTFE dispersion characteristics
- Table 3 : Composition ranges of PTFE/nano-PTFE blends
- Table 4 : PTFE bimodal dispersions obtained directly from polymerisation
- Table 5 : Film roughness measured by AFM analysis
- Table 6 : Coating anticorrosive characteristics. All blends contain 15% of nano-particles
- Table 7 : Low-APFO coating characteristicsDOI : 10.1007/BF02699565 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699565.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5502
in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 87, B1 (02/2004) . - p. 51-56[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 000392 - Périodique Bibliothèque principale Documentaires Disponible Alternative to alkyl phenol ethoxylates in emulsion polymerization & pigment dispersion / Anju Gidwani in PAINTINDIA, Vol. LIX, N° 7 (07/2009)
[article]
Titre : Alternative to alkyl phenol ethoxylates in emulsion polymerization & pigment dispersion Type de document : texte imprimé Auteurs : Anju Gidwani, Auteur ; Suhas Deshpande, Auteur Année de publication : 2009 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Dispersions et suspensions
Ethoxylate d'alkylphénol
Milieux dispersés
Pigments
Polymérisation en émulsion
Revêtements -- Additifs
Revêtements -- Additifs:Peinture -- AdditifsIndex. décimale : 667.9 Revêtements et enduits Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=6263
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Code-barres Cote Support Localisation Section Disponibilité 011630 - Périodique Bibliothèque principale Documentaires Disponible An acrylic resin retanning agent with a reinforcing effect - Synthesised by hihg solids content microemulsion copolymerization / Wang Xuechuan in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 89, N° 4 (07-08/2005)
[article]
Titre : An acrylic resin retanning agent with a reinforcing effect - Synthesised by hihg solids content microemulsion copolymerization Type de document : texte imprimé Auteurs : Wang Xuechuan, Auteur ; An Huari, Auteur ; Sun Ming, Auteur ; Luo Yanhong, Auteur ; Feng Jianyan, Auteur Année de publication : 2005 Article en page(s) : p. 164-168 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Agents de tannage
Caractérisation
Copolymères en émulsion
Croûte (cuir)On entend par "cuir en croûte" des cuirs ayant subi les opérations jusqu'au tannage, à l'exclusion de toute opération de corroyage ou de finissage, mais qui, par opposition aux wet-blue ont été séchés.
Cuirs et peaux -- Propriétés mécaniques
Cuirs et peaux de porcs
Granulométrie laser
Haut extrait sec
Latex
Microémulsions
Polyacryliques
Polymérisation en émulsion
Retannage
Tannage organique
Wet-blue (tannage)Peau tannée au chrome (le chrome donne une couleur bleue)Index. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : An acrylic resin nano-size latex whose colloidal particle size was about 20nm and solids content about 25% was prepared by a high solids content semicontinuous microemulsion copolymerization. The experimental product was employed in retanning drop [bottom] splits of pigs aiming to reinforce the leather. The offer of cross-linking agent and functional monomer were varied in the copolymerization experiment and their effect on the reinforcing function was investigated. The effect of colloidal particle size and dosage of nano-size latex on the reinforcing function also was verified.
The particle size of the latex was tested with a laser particle size analyzer, and the composition of the copolymer was analyzed by infrared spectrometry. Multifunction material test equipment was used in the physical testing of the retanned leather.
The result of the experiment showed: when the dosage of divinylbenzene (DVB) was 1.2% and the dosage of acrylic acid (AA) 0.8%, the reinforcing performance was the highest. When the colloidal particle size decreased from 64.2nm to 16.3nm, the reinforcing effect was also enhanced.
The tensile strength increased by 68%, and the tear strength improved 44% after the drop splits of pigs were retanned with 2% acrylic resin nano-size latex (with respect to the shaved wet blue weight). The effect of the dosage of sodium lauryl sulphate (SLS), n-pentanol (PA), ammonium persulfate (ASP) and AA on the colloidal particle size was also studied.Note de contenu : - EXPERIMENTAL DETAILS : Materials - Synthesis
- APPLICATION OF NANO-SIZE LATEX IN RETANNING CHROME TANNED PIG DROP SPLITS : Characterization
- RESULTS AND DISCUSSION : Colloidal particle size of the microemulsion copolymer - The IR spectra of BA/MMA/DVB copolymers prepared by microemulsion copolymerization - The effect of functional monomer on the reinforcing function - The effect of cross-linking agent on the reinforcing function - The effect of colloidal particle size on the reinforcing function - The relationship between dosage of retanning agent and reinforcing effect
- Table 1 : Recipes used in the series of experiments and average particle size of synthesized latexes
- Table 2 : Process details for the retanning applications of nano-size latex on wet blue pig drop splitsEn ligne : https://drive.google.com/file/d/1GoIENUWkqhu85g-LTxdP-0cZzXD-IvPo/view?usp=share [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39249
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