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Cerium acetate-modified aminopropylsilane triol : A precursor of corrosion-preventing coating for aluminum-finned condensers / T. Sugama in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 2, N° 8 (10/2005)
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Titre : Cerium acetate-modified aminopropylsilane triol : A precursor of corrosion-preventing coating for aluminum-finned condensers Type de document : texte imprimé Auteurs : T. Sugama, Auteur Année de publication : 2005 Article en page(s) : p. 649-659 Note générale : Bibliogr. Langues : Américain (ame) Tags : Propriété thermique Etude expérimentale Corrosion sel Protection corrosion Stabilité Effet concentration Polycondensation solution Préparation Acier Aluminium Couche protectrice anticorrosion Cérium Acétate Inhibiteur Amine polymère Siloxane Matériau revêtement Index. décimale : 667.9 Revêtements et enduits Résumé : A poly-acetamide-acetoxyl methyl-propylsiloxane (PAAMPS) polymer containing a cerium (Ce) oxide derivative was synthesized through three spontaneous reactions: condensation, amidation, and acetoxylation. The PAAMPS synthesizing took place between the Ce acetate dopant and aminopropylsilane triol (APST) as the film-forming precursor aqueous solution at 150°C. PAAMPS was evaluated for use as a corrosion-preventing coating for air-cooled condensers consisting of two metal components : aluminum fins and carbon steel tube. The key factors to ensuring the maximum performance of the PAAMPS/Ce oxide coating system in mitigating the corrosion of both aluminum and steel included (1) minimizing the content of non-reacted water-soluble APST and Ce acetate remaining in the coating, (2) lowering the susceptibility of the coating's surface to moisture, (3) precipitating a passive Ce3+ oxide (Ce2O3( film insensitive to Cl dissolution over the metal's surfaces, and (4) possessing excellent adhesion to the metal's surfaces. The combination of these factors considerably decreased the rate of the cathodic oxygen reduction reaction at the corrosion site of the metals. In fact, the corrosion rate, measured in milli-inches per year (mpy), of bare steel was reduced more than one order of magnitude by applying this coating. Correspondingly, the coating extended the useful lifetime of steel exposed in a salt-fog chamber at 35°C from only ~10 hr to ~768 hr. Furthermore, tins coating system far better protected an aluminum substrate from the corrosion than it did one of steel. Even a very thin nanoscale coating film deposited on the aluminum's surfaces reduced the corrosion rate, (mpy), by nearly two orders of magnitude over that of the bare aluminum. Also, the salt-spray resistance of aluminum panels covered by this nanoscale film was strikingly extended to more than 1440 hr, compared with -40 hr for bare aluminum. DOI : 10.1007/BF02774594 En ligne : https://link.springer.com/content/pdf/10.1007%2FBF02774594.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=3790
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 2, N° 8 (10/2005) . - p. 649-659[article]Réservation
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