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Specific crosslinking effects of poly(epichlorohydrin)-triol on urethane polymer matrix of castor seel oil-based coatings / T. O. Siyanbola in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 1 (01/2021)
[article]
Titre : Specific crosslinking effects of poly(epichlorohydrin)-triol on urethane polymer matrix of castor seel oil-based coatings Type de document : texte imprimé Auteurs : T. O. Siyanbola, Auteur ; R. Enishetty, Auteur ; R. Kumar, Auteur ; O. O. james, Auteur ; G. I. Olasehinde, Auteur ; S. Kaki, Auteur ; R. Nayaran, Auteur ; K. V. S. N. Raju, Auteur Année de publication : 2021 Article en page(s) : p. 129-141 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acier L'acier est un alliage métallique utilisé dans les domaines de la construction métallique et de la construction mécanique.
L'acier est constitué d'au moins deux éléments, le fer, très majoritaire, et le carbone, dans des proportions comprises entre 0,02 % et 2 % en masse1.
C'est essentiellement la teneur en carbone qui confère à l'alliage les propriétés du métal qu'on appelle "acier". Il existe d’autres métaux à base de fer qui ne sont pas des aciers comme les fontes et les ferronickels par exemple.
Adhésion
Antibactériens
Anticorrosion
Caractérisation
Huile de ricin et constituants
Hydrophobie
Métaux -- Revêtements protecteurs
Polyépichlorhydrine
Polyuréthanes
Résistance chimique
Revêtements -- Propriétés mécaniques
Revêtements organiques
Stabilité thermiqueIndex. décimale : 667.9 Revêtements et enduits Résumé : The contributions of castor seed oil (CSO) as a useful, nontoxic, and sustainable base material for coating systems cannot be overemphasized. This paper took advantage of the predominant fatty acid composition in CSO (i.e., ricinoleic acid). It blended a synthesized crosslinker, poly(epichlorohydrin-triol) (PECH-triol), in percentages within its polymeric matrix. Physicochemical and spectroscopic (FTIR, 1H-NMR, and 13C-NMR) examinations were carried out on the polyols. Thermal stability, hydrophobicity, anticorrosion, mechanical, and antibacterial properties of the prepared polyurethane (PU) coatings were examined. The 20% PECH-triol–CSO-PU film having its TON and TEND at 230.5 and 511.0°C, respectively, showed improved thermal stability when compared with the pristine film (CSO-PU). The derivative of TGA reveals a three-stage degradation step. Hydrophobicity was seen to increase from 73.3° to 92.2°, a reflection of the crosslinking effect of PECH-triol within the urethane matrix. The improved adhesion of 20% PECH-triol–CSO-PU coating on mild steel gave a better chemical resistance. Note de contenu : - EXPERIMENTAL : Materials - Preparation - Characterization
- RESULTS AND DISCUSSION : Physicochemical properties CSO and PECH-triol - Flow curve analysis and molecular weight of CSO and PECH-triol - Spectroscopic analyses of synthesized compounds - Thermal analysis of PU films - Contact angle - Electrochemical analysis - UTM analysis of coating films - Antimicrobial study of the films - Chemical resistance and drying behavior of coating films
- Table 1 : Physicochemical properties of CSO and PECH-triol
- Table 2 : Thermal behavior data of polyurethane films
- Table 3 : Corrosion parameters of coated and uncoated mild steel in 3.5% NaCl
- Table 4 : UTM analysis of polyurethane coating films
- Table 5 : Antimicrobial activities of pristine and blended polyurethanes
- Table 6 : Drying time and chemical resistance of resinsDOI : https://doi.org/10.1007/s11998-020-00387-4 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-020-00387-4.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=35357
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 18, N° 1 (01/2021) . - p. 129-141[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 22605 - Périodique Bibliothèque principale Documentaires Disponible
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Titre : Sticking to polymers : Wetting agent and substrate interactions in waterborne finishes for the automotive industry Type de document : texte imprimé Auteurs : Rainer Erhardt, Auteur ; Sascha Oestreich, Auteur Année de publication : 2016 Article en page(s) : p. 22-27 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adhésion
Agents mouillants
Automobiles -- Revêtements:Automobiles -- Peinture
Essais (technologie)
Fluoropolymères
Formulation (Génie chimique)
Matières plastiques -- Revêtement:Matières plastiques -- Peinture
Polyacryliques
Revêtements en phase aqueuse:Peinture en phase aqueuse
Tension superficielleIndex. décimale : 667.9 Revêtements et enduits Résumé : Good substrate wetting may be particularly difficult to achieve on plastic substrates, which are increasingly used in the automotive industry. Tests with a range of different types of wetting agents showed pronounced and possibly unexpected differences. A fluorinated acrylic polymer gave the best overall results. Note de contenu : - Surface defects and substrate wetting issues
- Main wetting agent types and their key properties
- Application technique may effect surfactant choice
- Wetting agents show pronounced differences in foaming
- Test formulation and application details
- Test procedures summarised
- Additional tests confirm best productEn ligne : https://drive.google.com/file/d/1-0Sio43PQ9ebe85PG82tq_NrnYYbBERw/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=26460
in EUROPEAN COATINGS JOURNAL (ECJ) > N° 6 (06/2016) . - p. 22-27[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 18147 - Périodique Bibliothèque principale Documentaires Disponible
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Titre : Sticking to the subject : Bio-oligomer improves adhesion of UV coatings on difficult substrates Type de document : texte imprimé Auteurs : Matt Terwillegar, Auteur Année de publication : 2017 Article en page(s) : p. 34-38 Langues : Anglais (eng) Catégories : Adhésion
Biopolymères
Essais (technologie)
Matières plastiques -- Revêtement
Méthacrylates
Oligomères
Réticulation (polymérisation)
Revêtements -- Séchage sous rayonnement ultraviolet
Succinique, AcideL'acide succinique est un diacide carboxylique aliphatique, dénommé également acide butane-1,4-dioïque et de formule semi-développée HOOC–CH2–CH2–COOH.
Il est présent dans tous les organismes vivants et intervient dans le métabolisme cellulaire, en particulier dans le métabolisme des lipides entre l'acide cétoglutarique et l'acide fumarique lors du cycle de Krebs dans la mitochondrie.Index. décimale : 667.9 Revêtements et enduits Résumé : A UV curable bio-oligomer on succinic acid and having three different reactive carbon-carbon double bonds on the backbone was evaluated. Good adhesion was obtained on low surface energy substrate, while an acide functional variant performed well on other 'difficult' substrates. Note de contenu : - General characteristics of the new oligomers
- Test procedures designed to avoid bias
- Initial evaluation : good adhesion to plastics
- Change of monomer yields varied results
- Methacrylate monomer can improve results
- Different formulations tested in Chicago laboratory
- Details of cure speed test procedure
- IR spectroscopy confirms slow curing of new oligomer
- Slower cure offset by additional cure mechanismsEn ligne : https://drive.google.com/file/d/1BtDF3QHm6ZgXgGzJSaJDWhV88ll2CvtI/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=27821
in EUROPEAN COATINGS JOURNAL (ECJ) > N° 2 (02/2017) . - p. 34-38[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 18679 - Périodique Bibliothèque principale Documentaires Disponible Strength characterization of assemblies of polymers made by laser welding / Vladimir Gantchenko in MATERIAUX & TECHNIQUES, Vol. 103, N° 5 (2015)
[article]
Titre : Strength characterization of assemblies of polymers made by laser welding Type de document : texte imprimé Auteurs : Vladimir Gantchenko, Auteur ; Jacques Renard, Auteur ; Alexander Olowinsky, Auteur ; Otto Gerhard, Auteur Année de publication : 2016 Article en page(s) : 8 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adhésion
Eléments finis, Méthode des
Matières plastiques -- Soudage
Polyamide 66
Soudage laser
Terpolymère acrylonitrile butadiène styrène
Thermoplastiques -- Propriétés mécaniquesIndex. décimale : 668.4 Plastiques, vinyles Résumé : We experimentally establish a plastic and breaking intrinsic stress criterion for welded joints made by laser radiation using the TWISTr configuration. This welding is used in junction of two plastics materials, one laser transparent, one no laser transparent as control panels. Two types of plastic materials have been studied, ABS and PA66 polymers. The yield surface which characterize the limit of elasticity and the rupture surface have been described by a modified Drucker-Prager criterion identified in the case of complex mixed modes state of stresses coupling tensile and shear stresses. The conclusion is that ABS is a good candidate for laser welding application, whereas PA66 presents lower mechanical properties in the welding area. For design purpose of welded zones, the proposed Drucker-Prager criterion has been used for the calculation and the simulation of breaking welded ABS plates and welded PA66 step plates. The comparison between experimental and numerical simulation values shows a relatively good agreement. Note de contenu : - LASER PROCESSING AND BEAM SOURCES DESCRIPTION
- PLASTIC AND RUPTURE CRITERIA OBTAINED BY ARCAN-MINES TEST : Specimen geometry - Arcan-mines testing device - Results on ABS - Results on PA66
- VALIDATION ON WELDED STRUCTURES : Specimen - ABS plates - PA66 platesRéférence de l'article : 503 DOI : http://dx.doi.org/10.1051/mattech/2015032 En ligne : http://www.mattech-journal.org/articles/mattech/pdf/2015/05/mt140080.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25359
in MATERIAUX & TECHNIQUES > Vol. 103, N° 5 (2015) . - 8 p.[article]Réservation
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Titre : A strong bond despite weld lines : Relationship between material, manufacturing parameters and morphological structure Type de document : texte imprimé Auteurs : M. J. Gebhart, Auteur ; Christian Hopmann, Auteur Année de publication : 2023 Article en page(s) : p. 49-53 Langues : Anglais (eng) Catégories : Adhésion
Analyse morphologique
Matières plastiques -- Moulage par injection
Polyamide 6
Polybutylène téréphtalate
Polypropylène
SouduresIndex. décimale : 668.4 Plastiques, vinyles Résumé : Weld lines in injection molded parts represent a challenge in product development that can hardly be circumvented. Therefore, the influence of the weld line on the yield strength of components made of PA6, PP and PBT as well as the morphology of the weld line depending on manufacturing parameters were investigated at the Institute for Plastics Processing (IKV) at RWTH Aachen University, Germany. Note de contenu : - Comparison of test specimens with and without weld line
- Results of the morphological analyses
- Results of the mechanical analyses
- Recommendations for action to avoid component weakening
- Fig. 1 : Main factors influencing the weld line as well as dimensions of the sample plates and flow path obstacles
- Table 1 : The four process parameters investigated in specimen production were each varied in three stagesEn ligne : https://drive.google.com/file/d/1JGym9GpTku31q6De2o827p6tpsLAcCAl/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=40554
in PLASTICS INSIGHTS > Vol. 113, N° 8 (2023) . - p. 49-53[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 24338 - Périodique Bibliothèque principale Documentaires Disponible Structural analysis of polymer-metal laminates by electron microscopy and infrared spectroscopy / E. Zumelzu in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 89, B1 (03/2006)
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