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Ability of metallic nano-particles to provide UV protection to wood surface : a preliminary experiment / Tengfei Yi in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 5 (09/2022)
[article]
Titre : Ability of metallic nano-particles to provide UV protection to wood surface : a preliminary experiment Type de document : texte imprimé Auteurs : Tengfei Yi, Auteur ; Jeffrey J. Morrell, Auteur Année de publication : 2022 Article en page(s) : p. 1535-550 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Alumine
Bois -- Revêtements protecteurs
Caractérisation
Colorimétrie
Dioxyde de silicium
Dioxyde de titane
Evaluation
Fourier, Spectroscopie infrarouge à transformée de
Mouillabilité
Nanoparticules
Oxyde de fer
Oxyde de zinc
Pins et constituants
Protection contre le rayonnement ultravioletIndex. décimale : 667.9 Revêtements et enduits Résumé : The effects of various nano-particle types and sizes on color, wettability, and surface chemistry of radiata pine (Pinus radiata) sapwood samples were investigated over 6 weeks of outdoor exposure. Specimens were treated with 0.2% wt/wt water dispersions of zinc oxide (ZnO), titanium dioxide (TiO2), aluminum oxide (Al2O3), silica dioxide (SiO2), cerium dioxide (CeO2), and iron oxide (Fe2O3), and four nano-sizes of Fe2O3. Color changes during exposure were characterized by measuring CIE L*a*b* color parameters, surface wettability changes were assessed using water droplet contact angle, and chemical changes were characterized by Fourier transform infrared spectroscopy (FTIR). Nano-particles protected wood from photo-discoloration to differing degrees with iron oxide providing the most effective and consistent protection. Smaller alpha Fe2O3 nano-particles provided better UV protection. Nano-particles did not reduce wettability of wood after UV exposure nor were they able to completely prevent lignin degradation. Zinc oxide nano-particles provided some cellulose and hemicellulose protection during UV exposure. Iron oxide nano-particles exhibited some potential for limiting degradation, but the differences were small and not significant from untreated controls. The results suggest that combinations of zinc and iron oxide might be useful for UV protection, and further trials are planned with these mixtures. Note de contenu : - MATERIALS AND METHODS : Materials - Characterization of nano-particles - Preparation of nano-particle solutions and treatment of wood surfaces - Exterior exposure - Color measurements - Wettability assessment - Fourier transform infrared spectroscopy (FTIR)
- RESULTS AND DISCUSSION : Nano-particle size analysis - Color changes - Surface wettability changes - FTIR spectroscopic analysis
- Table 1 : Reported and actual dimensions of nano-particles used in this study
- Table 2 : Average solution uptakes of water alone or with 0.2% wt/wt of selected nano-particles
- Table 3 : Climate conditions at the test site over the 6-week field exposure
- Table 4 : Assignments of infrared bands to molecular bonds in wood
- Table 5 : Ratios of selected peaks on the FTIR spectra with the peak at 1057 cm−1 for non-coated radiata pine wood samples before and after 6 weeks of outdoor exposure
- Table 6 : Comparisons between ratios of peak heights at 3343 or 2921/2899 cm−1 with those at 1057 cm−1 for radiata pine sapwood treated with selected nano-particles and exposed outdoors for 6 weeks
- Table 7 : Comparisons between peak heights of selected peaks with the peak at 1057 cm−1 for radiata pine sapwood treated with selected nano-particles and exposed outdoors for 6 weeksDOI : https://doi.org/10.1007/s11998-022-00628-8 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-022-00628-8.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=38288
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Code-barres Cote Support Localisation Section Disponibilité 23672 - Périodique Bibliothèque principale Documentaires Disponible Addressing single-layer protective coatings / Goeffrey R. Webster in EUROPEAN COATINGS JOURNAL (ECJ), N° 12 (12/2018)
[article]
Titre : Addressing single-layer protective coatings : A new resin for improved direct-to-metal coatings has been developed Type de document : texte imprimé Auteurs : Goeffrey R. Webster, Auteur ; Gianluigi Cassin, Auteur ; Jens Duereth, Auteur ; Curt Cleven, Auteur ; Todd Wallis, Auteur Année de publication : 2018 Article en page(s) : p. 42-47 Langues : Anglais (eng) Catégories : Anticorrosifs
Anticorrosion
Application directe sur le métal
Essais de brouillard salin
Fourier, Spectroscopie infrarouge à transformée de
Homopolymères
Métaux -- Revêtements protecteurs
Photo-oxydation
Polyacryliques
Polyesters
Résistance à l'hydrolyse
Résistance aux conditions climatiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : A great many DTM coatings have difficulty providing weatherability or corrosion performance or both. Direct-to-metal coatings formulated with resins made using 2,2,4,4-tetramethyl-1,3-cyclobutanediol not only are rugged and deliver bestin-class weathering and corrosion resistance but can also be a potential replacement for 2-coat systems. Note de contenu : - Identifying a persistent problem
- A new solution
- Hydrolysis resistance
- Moisture barrier
- Corrosion resistance
- Weathering resistance
- Fig. 1 : 2,2,4,4-tetramethyl-1,4-cyclobutanediol monomer (TMCD)
- Fig. 2 : Comparison of hydrolysis of homopolymers
- Fig. 3 : Coatings - 36 day 50% H2SO4 exposure : PE coating with no TMCO ; centre : the same resin with partial replacement of the glycol by TMCO and 100% of the glycol replaced by TMCO
- Fig. 4 : Water vapour transmission rates (ASTM E-96) of a coating prepared with "Tetrashield PC4000" to a standard protective coating of acrylic polyol crosslinked with "Desmodur 3390"
- Fig. 5 : 500 hours ASTM B117 corrosion over shot blasted steel. 2,2,4,4-tetramethyl 1,4-cyclobutanediol 2K coating and commercial acrylic. For testing, the panels were removed from the salt fog chamber, allowed to dry for a minimum of 12 hrs., then immersedin hot tap water for 30 minutes followed by scraping with a steel spatula to remove all loose paint
- Fig. 6 : Xenon ASTM 2527 accelerated weathering of "Tetrashield" resins compared to conventional polyesters and commercial acrylics
- Fig. 7 : FTIR spectra of unweathered and weathered coatings showing the NH OH and CH stretch region
- Fig. 8 : Plot of POV vs. time in xenon for conventional polyesters, "Tetrashield" resins and conventional acrylics in refinish clearcoat formulations
- Fig. 9 : Rate of photo-oxidation by IR spectroscopy. Lower rate indicates better weathering
- Table 1 : Homopolymers prepared for hydrolysis testingEn ligne : https://drive.google.com/file/d/1ECUdCGhb8mphL0JaxP4UVC3GBRPnj39n/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=31508
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Code-barres Cote Support Localisation Section Disponibilité 20474 - Périodique Bibliothèque principale Documentaires Disponible Adsorption kinetics of cu(II) from aqueous solution by low cost chemically modified saw dust of morus alba / Sultan Alam in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 49, N° 6 (11-12/2012)
[article]
Titre : Adsorption kinetics of cu(II) from aqueous solution by low cost chemically modified saw dust of morus alba Type de document : texte imprimé Auteurs : Sultan Alam, Auteur ; Azmat Ullah, Auteur ; Noor-ul-Amin, Auteur ; Najeeb-ur-Rehman, Auteur Année de publication : 2012 Article en page(s) : p. 466-471 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adsorption
Cinétique chimique
Diffractométrie de rayons X
Fourier, Spectroscopie infrarouge à transformée de
Potentiel zeta
Sciure de bois
Solutions aqueuses (chimie)
Spectrométrie à énergie dispersiveIndex. décimale : 668.1 Agents tensioactifs : savons, détergents Résumé : Adsorption kinetics of Cu(II) from aqueous solution by low cost chemically modified saw dust of Morus alba was investigated. The samples were characterized by FT-IR, EDS, BET surface area and Zeta potential technique. The surfaces contain carbonyl and hydroxyl functional groups which act as a binding sites for Cu(II) ion. Adsorption kinetics of Cu(II) was tested by first order kinetics, Elovich and parabolic diffusion kinetic equations which shows that adsorption is a diffusion controlled process. The rate of adsorption was high at high adsorption temperature. Thermodynamic parameters like ΔH°, ΔS° and ΔG° were calculated from the kinetic data. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=16533
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Code-barres Cote Support Localisation Section Disponibilité 14334 - Périodique Bibliothèque principale Documentaires Disponible Adsorption studies of basic green 4 from aqueous solution on Ca2+ exchanged clay / F. K. Bangash in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 48, N° 5 (09-10/2011)
[article]
Titre : Adsorption studies of basic green 4 from aqueous solution on Ca2+ exchanged clay Type de document : texte imprimé Auteurs : F. K. Bangash, Auteur ; S. Alam, Auteur ; M. Khan, Auteur Année de publication : 2011 Article en page(s) : p. 366-374 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Colorants -- Adsorption
Diffractométrie de rayons X
Fourier, Spectroscopie infrarouge à transformée de
Microscopie électronique à balayage
Spectrométrie à énergie dispersiveIndex. décimale : 668.1 Agents tensioactifs : savons, détergents Résumé : The adsorption of basic green 4 from aqueous solution on calcium exchanged clay (Attock-Ca and Swat-Ca) was studied. Clays were first purified and activated with H2SO4and then exchanged with Ca2+ions. Clay was characterized by BET surface area, XRD and SEM/EDS. The adsorption kinetic at 298 K and 306 K showed that the first order models were applied to the data. The rate constant increased with the rise in temperature of adsorption/activation. Thermodynamic properties (ΔE≠, ΔH≠, ΔS≠and ΔG≠) for the adsorption process were calculated. Positive values of ΔH≠showed that the adsorption of basic green 4 is endothermic. Positive values of ΔS≠reflected the increase in the disorder of the system at the solid-solution interface during adsorption. The Gibbs free energy, which is the driving force for adsorption is negative indicating spontaneous adsorption. Freundlich’s and Langmuir’s models described the equilibrium adsorption study and found to fit the experimental data. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=12550
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Code-barres Cote Support Localisation Section Disponibilité 13302 - Périodique Bibliothèque principale Documentaires Disponible Advances in design and manufacturing of environmentally friendly and biocide-free antifouling/foul-release coatings: replacement of fluorinate species / S. Vesco in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 16, N° 3 (05/2019)
[article]
Titre : Advances in design and manufacturing of environmentally friendly and biocide-free antifouling/foul-release coatings: replacement of fluorinate species Type de document : texte imprimé Auteurs : S. Vesco, Auteur ; C. Aversa, Auteur ; M. Puopolo, Auteur ; M. Barletta, Auteur Année de publication : 2019 Article en page(s) : p. 661-680 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Alkylsilane
Caractérisation
Composés amphiphiles
Composés fluorés -- Suppression ou remplacement
Essais d'adhésion
Evaluation
Formulation (Génie chimique)
Fourier, Spectroscopie infrarouge à transformée de
Revêtements antisalissures:Peinture antisalissures
SiliconesLes silicones, ou polysiloxanes, sont des composés inorganiques formés d'une chaine silicium-oxygène (...-Si-O-Si-O-Si-O-...) sur laquelle des groupes se fixent, sur les atomes de silicium. Certains groupes organiques peuvent être utilisés pour relier entre elles plusieurs de ces chaines (...-Si-O-...). Le type le plus courant est le poly(diméthylsiloxane) linéaire ou PDMS. Le second groupe en importance de matériaux en silicone est celui des résines de silicone, formées par des oligosiloxanes ramifiés ou en forme de cage (wiki).Index. décimale : 667.9 Revêtements et enduits Résumé : Amphiphilic coatings are nowadays described as the most promising strategy for the achievement of an effective and eco-friendly antifouling marine paint, based on a physical principle. Nevertheless, most of the preparations imply the introduction of fluorinate chemicals for the formation of the hydrophobic moieties, which are potentially toxic for the marine environment in the case of an accidental release. The present work evaluates the possibility of removing fluorinate species for the implementation of such coatings and their replacement with analogous long-alkyls. In particular, this work presents an easily implementable procedure for the manufacturing of an amphiphilic system that exploits the reactivity of a commercially available –OH-rich hybrid polysiloxane resin. The resin was first modified through sol–gel chemistry that was used in the grafting of a silane-bearing hydrophobic long-alkyl chain, while the introduction of the hydrophilic moieties was conducted contextually to the curing process, through the reaction with a commercially available PEG-ilate isocyanate hardener. The effective persistence of the amphiphilic character with respect to the replacement of the fluorinate silane by the alkylsilane was ensured by the measurement of the hysteresis contact angle. The effectiveness of the persistence of the antifouling/foul-release properties was assessed through testing against the adhesion and deposition of egg white, as a proteinaceous probe, Mytilus edulis (mussel) and Ulva intestinalis (algae). All the tests indicated that the amphiphilic coating prepared from long-alkyl silane performed even better than fluorinate silane-containing samples in this hybrid coating system resulting from the fusion of a xerogel and a resin. The results suggested that the use of a long alkyl silane was an effective alternative to the use of potentially noxious fluorinate silanes, with advantages that boost the ecological benefits and also include the performance of the coating. Note de contenu : - EXPERIMENTAL : Materials - Evaluation of reaction effectiveness - Analysis of amphiphilic character - Antifouling evaluation : egg whit test - Antifouling evaluation against marine organisms
- RESULTS AND DISCUSSION : Assessment of amphiphilic coating formulation - FTIR analysis of the effectiveness of grafting process - Evaluation of surficial patterning and amphiphilic properties - Antifouling characterizationDOI : 10.1007/s11998-018-0144-6 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-018-0144-6.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=32580
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Code-barres Cote Support Localisation Section Disponibilité 20953 - Périodique Bibliothèque principale Documentaires Disponible Aluminum tanning of hide powder and skin pieces under microwave irradiation / Yue Liu in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
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