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Smart coating with microencapsulation technology / Meghana Rajaram Rode in PAINTINDIA, Vol. LXIX, N° 2 (02/2019)
[article]
Titre : Smart coating with microencapsulation technology Type de document : texte imprimé Auteurs : Meghana Rajaram Rode, Auteur Année de publication : 2019 Article en page(s) : p. 53-67 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Amines Une amine est un composé organique dérivé de l'ammoniac dont certains hydrogènes ont été remplacés par un groupement carboné. Si l'un des carbones liés à l'atome d'azote fait partie d'un groupement carbonyle, la molécule appartient à la famille des amides. Découvertes en 1849, par Wurtz les amines furent initialement appelées alcaloïdes artificiels.
On parle d'amine primaire, secondaire ou tertiaire selon que l'on a un, deux ou trois hydrogènes substitués.
Par exemple, la triméthylamine est une amine tertiaire, de formule N(CH3)3.
Typiquement, les amines sont obtenues par alkylation d'amines de rang inférieur. En alkylant l'ammoniac, on obtient des amines primaires, qui peuvent être alkylées en amines secondaires puis amines tertiaires. L'alkylation de ces dernières permet d'obtenir des sels d'ammonium quaternaire.
D'autre méthodes existent : 1. Les amines primaires peuvent être obtenues par réduction d'un groupement azoture, 2. Les amines peuvent aussi être obtenues par la réduction d'un amide, à l'aide d'un hydrure, 3. L'amination réductrice permet l'obtention d'amines substituées à partir de composés carbonylés (aldéhydes ou cétones), 4. Les amines primaires peuvent être obtenues par la réaction de Gabriel.
Anticorrosifs
Anticorrosion
Encapsulation
Epoxydes
Formulation (Génie chimique)
Matériaux intelligents
Microémulsions
Polyisocyanates
Polymères à terminaison amine
RevêtementsIndex. décimale : 667.9 Revêtements et enduits Résumé : While there are various types of smart coating available, this paper is based on smart coating with pH-triggered release microcapsules which is one of the advanced techniques in coating system. These microcapsules can be incorporated into various coating systems for corrosion detection, protection and self-repair of mechanical coating damage. This paper will present the results from progress made to date in the controlled release properties of these microcapsules as well as in their corrosion indication and corrosion inhibition function. This paper covers the recent progress made in the encapsulation process, the characterization of these microcapsules as well as results showing the controlled release function & different techniques used for microencapsulation & its applications. Note de contenu : - INTRODUCTION : Structure of microcapsules - Core - Shell - Morphology of microcapsules
- PAINT FORMULATION WITH MICROENCAPSULATION : Compatibility study between paint formulation and the microcapsules - Solvents compatibility test - Formulation stability test - Microcapsules effect on coating adhesion - Paint formula and coating process effect on microcapsules - Microencapsulation process
- Oil - in - water microemulsion process - Water - in - oil microemulsion process
- ENHANCING COATING FUNCTIONALITIES WITH MICROCAPSULES
- COMMONLY USED COAT MATERIALS IN MICROENCAPSULATION : Coating material properties
- APPLICATIONS OF MICROENCAPSULATION TECHNOLOGY IN COATING SYSTEM : Corrosion control in coating - Self-healing coating based on microcapsules - Novel responsive surfaces based on active hybrid coatings utilizing encapsulation technologies - Encapsulated antifreeze agent for anti-ice coatings - Self-healing concrete with a microencapsulated healing agent
- CONTROLLED RELEASE OF THE MICROCAPSULES : pH controlled release properties of the microcapsules - Controlled release of microcapsule content at the onset of corrosion
- Fig. 1a : Schematic of microcapsule
- Fig. 1b : Shell categories
- Fig. 2 : Morphology of microcapsule
- Fig. 3 : PATTI adhesion test results of various commercial paint systems
- Fig. 4a : Microcapsules appear dispersed and stable inside the epoxy amine coating
- Fig. 4b : Color change observed when microcapsules in dry paint were exposed to basic pH conditions
- Fig. 5a : Steps involved in the interfacial polymerization of oil-in- water microemulsion process for making oil core microcapsules (oil is shown in yellow and water in blue)
- Fig. 5b : Steps involved in the interfacial polymerization of water-in-oil microemulsion process for water core microcapsules. Oil is shown in yellow and water in blue
- Fig. 6 : Schematic diagram showing pathways for microcapsule incorporation into coating
- Fig. 7 : The central component of the smart coating system : pH sensitive microcapsules which break down under basic pH conditions
- Fig. 8 : Smart coating with pH sensitive microcapsules for corrosion detection and protection application
- Fig. 9 : End-blocking of isocyanate groups for hindered reactivity of IPDI
- Fig. 10 : Time lapse pictures of microcapsules breaking down under basic pH
- Fig. 11 : A galvanic corrosion test cell consisting of a carbon steel disc in contact with copper tape was set up and immersed in gel with microcapsules containing a corrosion indicator. As the carbon steel corodes, the encapsulated corrosion indicator is released and its color change to purple shows the initiation and progress of corrosion
- Table 1 : Compatibility of microcapsules with commercial resins formulations
- Table 2 : Commonly used coat materials in microencapsulation
- Table 3 : Concentration of cerium released from microcapsules in pH 7 and 14 solutions over timeEn ligne : https://drive.google.com/file/d/1ytdqxFE9xYJh9bfOXGQ04xoC4lCuNUxI/view?usp=share [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=31953
in PAINTINDIA > Vol. LXIX, N° 2 (02/2019) . - p. 53-67[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 20676 - Périodique Bibliothèque principale Documentaires Disponible La solution innovante proposée par Grolman in INFOCHIMIE MAGAZINE, N° 560 (06/2020)
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Titre : La solution innovante proposée par Grolman Type de document : texte imprimé Année de publication : 2020 Article en page(s) : p. 44-46 Langues : Français (fre) Catégories : Anticorrosifs
Anticorrosion
Cahier des charges
Métaux -- Revêtements protecteursIndex. décimale : 667.6 Peintures Résumé : Nombre de bâtiments sont revêtus de bardages métalliques, choisis pour leur robustesse aux intempéries, aux variations de températures et aux UV. Ces caractéristiques sont essentiellement apportées par leur revêtement, qui doit être entretenu ou repeint régulièrement, dès la première apparition de corrosion, pour conserver la durabilité de l'ensemble. Note de contenu : - Fig. 1 : Comparaison de résistance à la corrosion d'un test de brouillard salin et du test Grolman
- Fig. 2 : Etat bardage sans revêtement, formula Grolman avant et après 48 heures de test de corrosion interne, formule benchmark après 48h de test
- Fig. 3 : Adhésion avant et après 48h d'immersion dans la solution saline de la peinture bardage Grolman
- Tableau 1 : Cahier des charges de la peinture bardage du laboratoire Grolman et résultats obtenus
- Tableau 2 : Formule peinture anticorrosive approuvée par la laboratoire GrolmanPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=34365
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Code-barres Cote Support Localisation Section Disponibilité 21902 - Périodique Bibliothèque principale Documentaires Disponible Solvent-free rigid 2K polyurethanes for protective coatings / Matthias Wintermantel in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 204, N° 4592 (01/2014)
[article]
Titre : Solvent-free rigid 2K polyurethanes for protective coatings Type de document : texte imprimé Auteurs : Matthias Wintermantel, Auteur ; Andreas aus der Wieschen, Auteur Année de publication : 2014 Article en page(s) : p. 44-50 Langues : Anglais (eng) Catégories : Anticorrosifs
Anticorrosion
Corrosion
Décollement cathodique (revêtement)
Etudes comparatives
Polyisocyanates
Polyuréthanes
Résistance au décollement
Revêtements -- Propriétés mécaniques:Peinture -- Propriétés mécaniques
Revêtements bi-composant:Peinture bi-composant
Revêtements protecteurs
Revêtements:Peinture
Test d'immersionIndex. décimale : 667.9 Revêtements et enduits Résumé : Liquid polyurethane coating systems are of growing importance in the field of protective. Exernal liner systems based on aromatic polyisocyanates and pre-polymers are being used in new construction and maintenance. Major divers in most applications are their favourable and reliable cure characteristics and the superior mechanical properties especially under hars conditions. Note de contenu : - Chemistry
- Corrosion categories and type of coatings
- ADVANTAGES OF SOLVENT-FREE 2K-PU COATINGS : Building blocks - Application properties - Curing time reactivity - Mechanical properties - Cathodic disbonding properties
- RIGID 2K POLYURETHANE COATINGS : Rigid solvent-free polyurethane system N° 1 - Rigid solvent-free polyurethane systems N° 2 - Field trial of system N° 2 in wet soil solutions - Inspection of the test coating immersed in wet soil conditions - Comparison of polyurethane systemsEn ligne : https://drive.google.com/file/d/1i-KUJM64sdhLXYuNMcgLXNzIM2niWdhC/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=20262
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Code-barres Cote Support Localisation Section Disponibilité 15900 - Périodique Bibliothèque principale Documentaires Disponible Solventborne paint systems on carbon steel and hot-dip galvanized steel for a wide range of atmospheric exposures / F. Fragata in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 4, N° 1 (03/2007)
[article]
Titre : Solventborne paint systems on carbon steel and hot-dip galvanized steel for a wide range of atmospheric exposures Type de document : texte imprimé Auteurs : F. Fragata, Auteur ; D. de La Fuente, Auteur ; E. Almeida, Auteur ; D. Santos, Auteur ; M. Morcillo, Auteur Année de publication : 2007 Article en page(s) : p. 75-87 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acier au carbone
Anticorrosifs
Anticorrosion
Essais accélérés (technologie)
Matériaux -- Propriétés barrières
Métaux -- Revêtements:Métaux -- Peinture
Pigments
Polymères
Revêtement en phase solvant:Peinture en phase solvantIndex. décimale : 667.6 Peintures Résumé : The paper analyzes the performance of solventborne paint systems applied on carbon steel and hot-dip galvanized steel in a wide range of atmospheric exposures. The study has involved paint systems exposure for 3.5 years in eight natural atmospheres. The atmospheric conditions cover from temperate rural climates to tropical severe marine and Antarctic coastal regions. The paint systems included several alkyds formulated with a variety of pigments (anticorrosive and barrier), epoxies, chlorinated rubber, and zinc-rich (ethyl silicate and epoxy). It has been concluded that in rural and urban atmospheres alkyd systems afford equivalent anticorrosive protection of steel to the epoxy/polyurethane system. The toxic red lead pigment may be replaced in long linseed-oil alkyd primer paints by non-toxic pigments, such as a mixture of micaceous iron oxides (MIO) and black iron oxides or zinc phosphate, without affecting the anticorrosive properties of the paint system. In aggressive atmospheres (industrial, marine), paint systems including zinc-rich primers or applied on galvanized steel must be used, especially in surface regions with coating faults (scribes). DOI : 10.1007/s11998-007-9003-6 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-007-9003-6.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=3673
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Code-barres Cote Support Localisation Section Disponibilité 007149 - Périodique Bibliothèque principale Documentaires Disponible 008267 - Périodique Bibliothèque principale Documentaires Disponible Spectroscopie d'impédance électrochimique appliquée à l'étude de la corrosion / C. Gabrielli in MATERIAUX & TECHNIQUES, Vol. 95, Hors série (2007)
[article]
Titre : Spectroscopie d'impédance électrochimique appliquée à l'étude de la corrosion Type de document : texte imprimé Auteurs : C. Gabrielli, Auteur ; M. Keddam, Auteur ; H. Takenouti, Auteur Année de publication : 2008 Article en page(s) : p. 385-395 Note générale : Bibliogr. Langues : Français (fre) Catégories : Anticorrosifs
Antiquités (objets anciens) -- Conservation et restauration
Bronze
Corrosion électrochimique
Spectroscopie d'impédance électrochimiqueIndex. décimale : 620.11 Matériaux (propriétés, résistance) Résumé : Nous allons présenter différentes applications de la spectroscopie d'impédance électrochimique réalisées depuis 40 ans. Au début de cette longue histoire, l'emploi de signaux alternatifs était destiné à remplacer la méthode stationnaire dite de Stern et Geary, c'est-à -dire la mesure de la résistance de polarisation. Cependant, rapidement nous avons constaté que le spectre d'impédance contenait plusieurs informations sur les phénomènes se déroulant à l'interface métal | électrolyte. Ils se manifestent par une constante de temps propre à chaque processus, donc généralement distinguables par une analyse en fréquence. Après avoir présenté la différence majeure entre la méthode stationnaire et la méthode d'impédance dans l'étude de la corrosion à la fois en termes de compréhension des mécanismes et de prévision de sa vitesse, nous aborderons plusieurs applications de cette dernière méthode : la résistance d'électrolyte, l'effet protecteur d'inhibiteurs organiques et la protection de bronzes archéologiques recouverts de patine. DOI : http://dx.doi.org/10.1051/mattech:2008035 En ligne : http://www.mattech-journal.org/articles/mattech/pdf/2007/06/mt08030.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=26416
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PermalinkWater absorption of water-based anticorrosive coatings and its effect on mechanical property and adhesive performance / Takuya Kamisho ; Yukitoshi Takeshita ; Seizo Sakata ; Takashi Sawada in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 11, N° 2 (03/2014)
PermalinkWater-based coatings powered by NANO-VpCI / Ron Camp in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 205, N° 4604 (01/2015)
PermalinkWater-borne versus solvent-borne paints for protection of steel to atmospheric exposure / F. Fragata in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 89, B3 (09/2006)
PermalinkWater permeation and corrosion resistance of single- and two-component hydrophobic polysiloxane barrier coatings / X. Sun in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 14, N° 6 (11/2017)
PermalinkWaterbased epoxy technologies for metal coating applications / Daniel Suckley in PAINTINDIA, Vol. LXX, N° 12 (12/2020)
PermalinkWaterborne coatings based on acrylic latex containing nanostructured ZnO as an active additive / Martina Dankova in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 17, N° 2 (03/2020)
PermalinkWaterborne corrosion-resistant hydrophobic alkyd resin composite coatings modified with fluorinated acrylate–siloxane and submicron-sheet zinc phosphate pigment / Shenjie Zhong in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 5 (09/2021)
PermalinkPermalinkPermalinkPermalinkWhat type of anti-corrosive plasticizer is applicable for RMC concrete for bridge and road construction applications / Harish Agrawal in PAINTINDIA, Vol. LXXIII, N° 6 (06/2023)
PermalinkPermalinkWorld class thixotropic gelled sulfonates. The most innovative corrosion inhibitors / Ninad Kondekar in PAINTINDIA, Vol. LX, N° 1 (01/2010)
PermalinkZinc chromate primer / Mukund Hulyalkar in PAINTINDIA, Vol. LXII, N° 1 (01/2012)
PermalinkZinc flake technology broadens horizons for corrosion protection / NOF Metal Coatings Europe SA (Creil, France) in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 201, N° 4560 (05/2011)
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