[article]
| Titre : |
Collagen hydrolysate : Soluble skin applied in post-tanning processes : Part 2 - Interaction with acyrlic retanning agents |
| Type de document : |
texte imprimé |
| Auteurs : |
Carlos S. Cantera, Auteur ; J. Martegani, Auteur ; G. Esterelles, Auteur ; Jorge A. Vergara, Auteur |
| Année de publication : |
2002 |
| Article en page(s) : |
p. 195-202 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
acrylique, Acide L'acide acrylique ou acide acroléïque ou acide prop-2-énoïque est un composé organique de formule brute C3H4O2 et de formule semi-développée CH2=CHCOOH. C'est un acide carboxylique et un alcène vinylique, et se présente comme un liquide incolore à l'odeur âcre.
L'acide acrylique et ses esters, les acrylates, sont utilisés dans la fabrication de matières plastiques, dans les peintures acryliques et dans divers autres polyacryliques qui ont de multiples usages.
Agents de tannage
Copolymères
Cuir pleine fleur
Cuirs et peaux de bovins
Hydrolysat de collagène
Post-tannage
Tannage synthétique
|
| Index. décimale : |
675.2 Préparation du cuir naturel. Tannage |
| Résumé : |
In the upgrading of tannery solid wastes, the commercial application of the by-products obtained is the key to attractive technological alternatives.
In the particular case of chrome shavings hydrolysed by an alkaline-enzyme process, the uses of collagen hydrolysate (CH) are the driving force for the start-up of a project when consideration is given to the amounts generated and to the diversity of applications, in addition to the fact that basic chrome salts -obtained from the dissolution of the chrome cake - may be used as trouble-free assistants to the fresh tanning agent.
The present paper, which follows the Part I of this study ; "Collagen Hydrolysate : ‘soluble skin’ applied in post-tanning processes I. Characterisation” (JSLTC, 2000, 84,29) shows the experimental results obtained from the manufacture of various types of bovine leathers carried out at the CITEC pilot plant and in tanneries using CH in the post-tanning processes. In addition, the interactions of CH with acrylic retanning agents, studied at laboratory scale, are included.
CH performs in a synergistic fashion with various retanning agents. In addition to its cosmetic-lubricating effect which enhances the leather grain properties and provides greater softness improving the resistance of the fibrous tissue, there is also a ‘restoring effect’ upon the grain surface of the semi-finished leather, masking preservation defects and damage marks on the skin. The interaction with dyes is evident from the intensified colours and improved homogeneity of the dyeing.
CITEC has developed, besides CH, a copolymer CH-acrylic acid : "acrylic-protein" retanning agent MCH-106, that shows good properties in the development of full grain leather and splits. The application of the CH and the acrylic-protein MCH-106 in processing full-grain leather generates leathers of similar or higher quality to the standard one.
The application of CH in leather manufacture is an attractive response to the question of how to use the by-products derived from the treatment of the chrome shavings. |
| Note de contenu : |
- EXPERIMENTAL DEVELOPMENT : Experiments at CITEC
- ANALYSIS OF THE RESULTS : CH application trials at the tannery
- Table 1 : Reduction in formic acid consumption in the 'mixture solutions' With regard to the sum of the individual values (expressed in %)
- Table 2 : Reduction in the salt KCr (SO4)2.12H2O consumption in the ‘mixture solutions’ with regard to the sum of the individual values (expressed in %)
- Table 3 : Physical properties of the upper leather prepared with acrylic-protein retanning agent MCH106 and CH |
| En ligne : |
https://drive.google.com/file/d/1ApP8ftPrxBi4iuQPgF3ZwC9qWN4r9ckE/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39859 |
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 86, N° 5 (09-10/2002) . - p. 195-202
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Copolymères à base de tannins et déchets lignocellulosiques avec des matériaux synthétiques en substitution des sels de chrome pour applications en substitution / 2002
