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668.1 : Agents tensioactifs : savons, détergents 668 Technologie des autres produits organiques
668.3 Adhésifs et produits semblables 668.4 Plastiques, vinyles 668.5 Parfums et cosmétiques 668.65 Pesticides 668.9 Polymères |
Ouvrages de la bibliothèque en indexation 668.1
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Kinetic and mechanistic study of the influence of micelles on the oxidation of acetone by N-bromophthalimide in aqueous acetic acid medium / Y. R. Katre in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 46, N° 4/2009 (07-8/2009)
[article]
Titre : Kinetic and mechanistic study of the influence of micelles on the oxidation of acetone by N-bromophthalimide in aqueous acetic acid medium Type de document : texte imprimé Auteurs : Y. R. Katre, Auteur ; K. Tripathi, Auteur ; G. K. Joshi, Auteur ; A. K. Singh, Auteur Année de publication : 2009 Article en page(s) : p. 218-227 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Surfactants Tags : N-bromophthalimide Cetyltrimethylammonium bromide Sodium dodecyl sulphate Acetone Oxidation Kinetics Index. décimale : 668.1 Agents tensioactifs : savons, détergents Résumé : The effect of cationic micelles of Cetyltrimethylammonium bromide (CTAB) and anionic micelles of Sodium dodecyl Sulphate (SDS) on the kinetics of oxidation of acetone by N-Bromophthalimide (NBP) was studied iodometrically at 308 K. In addition to kinetic experiments, conductivity measurements have also been done to obtain critical micelle concentration and other thermodynamic properties. The kinetic observations indicate fractional order and first order dependence, with respect to [Acetone] and [NBP] respectively. Cationic surfactant (CTAB) strongly catalysed the oxidation of acetone in aqueous acetic acid medium and typical kobs and [CTAB] profile was observed i.e. with the progressive increase in [CTAB], the reaction rate increased, at higher concentration constancy in kobs was observed, whereas anionic surfactant (SDS) was found to show no considerable effect on reaction rate. Mercuric acetate and phthalimide exhibited nil effect on the reaction rate. The presence of inorganic salts (KCl, KBr) exhibits positive effect in the reaction rate. The various activation parameters in presence of CTAB and SDS have been also evaluated. A suitable mechanism consistent with the experimental findings has been proposed. The binding constant with surfactants has been evaluated. DOI : 10.3139/113.110027 Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=6055
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Code-barres Cote Support Localisation Section Disponibilité 011484 - Périodique Bibliothèque principale Documentaires Disponible Kinetic Modelling and Equilibrium of Amphoteric Collector Adsorption on Silica and Hematite / K. A. Selim in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 46, N° 2/2009 (02-03/2009)
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Titre : Kinetic Modelling and Equilibrium of Amphoteric Collector Adsorption on Silica and Hematite Type de document : texte imprimé Auteurs : K. A. Selim, Auteur ; F. H. Abd El-Rahiem, Auteur ; Ayman A. El-Midany, Auteur Année de publication : 2009 Article en page(s) : p. 85-91 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adsorption
Hématite
SiliceLa silice est la forme naturelle du dioxyde de silicium (SiO2) qui entre dans la composition de nombreux minéraux.
La silice existe à l'état libre sous différentes formes cristallines ou amorphes et à l'état combiné dans les silicates, les groupes SiO2 étant alors liés à d'autres atomes (Al : Aluminium, Fe : Fer, Mg : Magnésium, Ca : Calcium, Na : Sodium, K : Potassium...).
Les silicates sont les constituants principaux du manteau et de l'écorce terrestre. La silice libre est également très abondante dans la nature, sous forme de quartz, de calcédoine et de terre de diatomée. La silice représente 60,6 % de la masse de la croûte terrestre continentale.
SurfactantsIndex. décimale : 668.1 Agents tensioactifs : savons, détergents Résumé : Most of the world iron ores are associated with siliceous impurities. Upgrading schemes depend mostly on the removal of these impurities by flotation and/or selective flocculation techniques, which mainly influenced by the adsorption of collectors on both valuable and gangue minerals. In this study, the adsorption of amphoteric collector (dodecyl-N-carboxyethyl-N-hydroxyethyl-imidazoline) on silica and hematite was studied. The collector adsorption exhibits the preferential adsorption on silica at acidic pH range. While in case of hematite, the adsorption was the same over entire the studied pH range. The temperature was kept constant at 298 K and contact time of 60 min was found, from kinetic study, to be adequate to achieve equilibrium. In addition, two simplified kinetic models including a pseudo first-order equation and pseudo second-order equation were used to determine kinetic parameters, rate constants, and equilibrium sorption capacities. It was shown that the pseudo first-order equation perfectly describes the adsorption of collector. Moreover, the analysis of experimental isotherm data using the Langmuir, Freundlich, Temkin and Dubinin-Radushkevich equations showed that the Freundlich model reasonably fits the experimental data in the studied concentration range. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=4576
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Code-barres Cote Support Localisation Section Disponibilité 011181 - Périodique Bibliothèque principale Documentaires Disponible Kinetic studies of glutamic acid oxidation by hexavalent chromium in presence of surfactants / Ankita Basu in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 49, N° 6 (11-12/2012)
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Titre : Kinetic studies of glutamic acid oxidation by hexavalent chromium in presence of surfactants Type de document : texte imprimé Auteurs : Ankita Basu, Auteur ; Sumanta K. Ghosh, Auteur ; Saha Rumpa, Auteur ; Aniruddha Ghosh, Auteur ; Tuhin Ghosh, Auteur ; Kakali Mukherjee, Auteur ; Subhendu Sekhar Bhattacharyya, Auteur ; Bidyut Saha, Auteur Année de publication : 2012 Article en page(s) : p. 481-487 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Chrome hexavalent
Cinétique chimique
Glutamique, AcideL'acide glutamique ou glutamate (la forme anionique de l'acide glutamique) est l'un des 20 acides-α-aminés naturels constituant les protéines. Sa chaîne latérale contient un résidu carboxyle, ce qui en fait un acide aminé « acide », dicarboxylique, polaire.
Oxydation
SurfactantsIndex. décimale : 668.1 Agents tensioactifs : savons, détergents Résumé : Hexavalent chromium is a widespread environmental contaminant and a known human carcinogen. It is a very important to remove toxic Cr(VI) from industrial waste water. In human body Cr(VI) is reduced to Cr(III). Effective bio-molecule present in body contains a number of different functional groups. Kinetics of reduction of Cr(VI) by an important amino acid, glutamic acid in micellar media have been studied spectrophotometrically. Micellar media is a testing enviroment to establish the mechanistic paths of reduction of Cr(VI) to Cr(III). The catalyst and suitable surfactants enhance the reduction of Cr(VI). Note de contenu : - EXPERIMENTAL AND METHODS : Procedure and kinetics measurements - Product analysis
- RESULTS AND DISCUSSION : Dependence of [bipy]y - Dependence on the substrate [glutamic acid]T - Dependence on [H+] - Effect of surfactants - Evidence for the formation of free radicals
- MECHANISM AND INTERPRETATIONPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=16535
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Code-barres Cote Support Localisation Section Disponibilité 14334 - Périodique Bibliothèque principale Documentaires Disponible Kinetics and adsorption isotherms for the removal of tartrazine from aqueous solution by coal ash / M. Ishaq in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 48, N° 2/2011 (03-04/2011)
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Titre : Kinetics and adsorption isotherms for the removal of tartrazine from aqueous solution by coal ash Type de document : texte imprimé Auteurs : M. Ishaq, Auteur ; K. Saeed, Auteur ; S. Nadeem, Auteur Année de publication : 2011 Article en page(s) : p. 130-133 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adsorption
Charbon, Cendres de
Cinétique chimique
Séparation (technologie)
TartrazineIndex. décimale : 668.1 Agents tensioactifs : savons, détergents Résumé : The coal ash (Φ) was used as an adsorbent for the removal of tartrazine from aqueous solution at room temperature. The adsorption capacity of tartrazine increased as the adsorption time was increased and then remains constant after 30 min adsorption duration. It was found that the U removed more than 40% of tartrazine from the aqueous solution within 1 h contact time. The equilibrium adsorption was also analyzed by Langmuir isotherm and it was found that the data followed the Langmuir isotherm models. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=11121
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Code-barres Cote Support Localisation Section Disponibilité 012916 - Périodique Bibliothèque principale Documentaires Disponible Kinetics and mechanism of nucleophilic xubstitution in SnR2Cl2 × 2DMSO by chloride ions in micellar microenvironment / Abdul Moheman in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 49, N° 4 (07-08/2012)
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Titre : Kinetics and mechanism of nucleophilic xubstitution in SnR2Cl2 × 2DMSO by chloride ions in micellar microenvironment Type de document : texte imprimé Auteurs : Abdul Moheman, Auteur ; Seema Yadav, Auteur ; Khwaja Salahuddin Siddiqi, Auteur Année de publication : 2012 Article en page(s) : p. 287 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Surfactants Tags : Surfactants 'Substitution nucléophilique' Solvatation' 'Dodécyle sulfate sodium' Micelles Index. décimale : 668.1 Agents tensioactifs : savons, détergents Résumé : The kinetics of nucleophilic substitution of dimethylsulfoxide by chloride ion in bis-dimethyl sulfoxide dimethyltin(IV) dichloride and bis-dimethyl sulfoxide diphenyltin(IV) dichloride in micellar microenvironment (1.0 × 10–2M SDS in aqueous solution of ethanol (1:1, v/v) has been studied conductometrically. The reactions have been carried out at 25 °C. Substitution follows first order path with respect to chloride ion concentration. A millimolar solution of the complexes in ethanolic solution of 1.0 × 10–2M SDS shows an increase in conductance with time due to solvation of the molecule. Sn(CH3)2Cl2× 2 DMSO shows high conductance as compared to Sn(C6H5)2Cl2× 2 DMSO. In the presence of the nucleophilic reagents, C6H5COCl and CH3COCl there is a greater enhancement in conductance due to substitution of DMSO by chloride ion. The data of rate constant for solvation (KS) and for nucleophilic substitution (K1and K2) have been calculated. It was found that the solvation is a slower process compared to the substitution by chloride ions i. e., K1, K2> Ks. A possible mechanism has been suggested. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=15546
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Code-barres Cote Support Localisation Section Disponibilité 14042 - Périodique Bibliothèque principale Documentaires Disponible Kinetics, equilibrium, and isotherm of the adsorption of chlorine by TDRP / Elles Timothy in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 49, N° 5 (09-10/2012)
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PermalinkKrafft points and Cloud points of polyoxyethylated nonionic surfactants / H. Schott in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 46, N° 1/1009 (01-02/2009)
PermalinkLaundry softener with colour care additives to protect against colour fading or colour changes of dyed textiles in the washing process / Klaus Henning in SOFW JOURNAL, Vol. 148, N° 6 (06/2022)
PermalinkLauryl trimethyl ammoniums with new type counteranions / B.-C. Xu in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 46, N° 6/2009 (11-12/2009)
PermalinkLes lessives en poudre. Un siècle d'innovations pour éliminer les taches / Véronique Nardello-Rataj in L'ACTUALITE CHIMIQUE, N° 3 (03/2003)
PermalinkLiquid chromatography with fluorescence detection as a tool for separation of endocrine disrupting alkylphenols and their mono- and diethoxylates in analysis of river water samples / A. Zgola-Grzeskowiak in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 46, N° 4/2009 (07-8/2009)
PermalinkLiquid foams, new approaches in raw materials, sustainability and product safety, forum for innovations in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 50, N° 1 (01-02/2013)
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PermalinkLow-temperature cleaning - A blessing or a curse ? / Fred Schambil in SOFW JOURNAL, Vol. 142, N° 7 (07/2016)
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PermalinkLyotropic liquid crystal formed in Brij35/copolymer/water system / Zhongni Wang in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 49, N° 3 (04-05/2012)
PermalinkMacroscopic Pipe Flow of Micellar Solutions Investigated by Ultrasound Doppler Velocimetry / Peter Fischer in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 46, N° 3/2009 (05-06/2009)
PermalinkManual direct two-phase titration method for anionic surface active agents determination with use of solvatochromic dye. The modification towards toxicity abatement / Monika Gasiorowska in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 49, N° 2 (03-04/2012)
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PermalinkMicellar behaviour of copper surfactants derived from fresh (untreated) sesame oil and used (treated at high temperature) sesame oil / R. Sharma in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 47, N° 2/2010 (03-04/2010)
PermalinkMicellar catalysis of chromic acid oxidation of methionine to industrially important methylthiol in aqueous media at room temperature / Ankita Basu in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 50, N° 2 (03-04/2013)
PermalinkMicellar catalysis on 1,10-phenanthroline promoted chromic acid oxidation of glycerol in aqueous media / Sumanta K. Ghosh in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 49, N° 5 (09-10/2012)
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PermalinkMicellar characteristics and surface properties of some sulfobetaine surfactants / N. Singh in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 48, N° 2/2011 (03-04/2011)
PermalinkMicellar studies of magnesium soaps using ion-selective electrode / Lal Chand Heda in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 45, N° 5/2008 (09-10/2008)
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PermalinkMicellization of gemini surfactants in polymer solutions / D. Tikariha in TENSIDE, SURFACTANTS, DETERGENTS, Vol. 47, N° 3/2010 (24/05/2010)
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PermalinkMoving towards green technologies in odour control for air care applications / Fiona Tham in SOFW JOURNAL, Vol. 149, N° 12 (12/2023)
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