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Free volume distribution during consolidation and coalescence of latex films / A. J. Hill in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 73, N° 913 (02/2001)
[article]
Titre : Free volume distribution during consolidation and coalescence of latex films Type de document : texte imprimé Auteurs : A. J. Hill, Auteur ; J. D. Cloyd, Auteur ; D. L. Murray, Auteur ; R. R. Stockl, Auteur ; P. P. Shang, Auteur ; R. L. McGill, Auteur ; M. R. Tant, Auteur Année de publication : 2001 Article en page(s) : p. 115-124 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Coalescence (Sciences physiques)
Latex
Polyméthacrylates
Revêtements en phase aqueuse:Peinture en phase aqueuseTags : 'Peinture émulsion' Latex 'Formation de film' Consolidation Coalescence 'Polyméthacrylate butyle' d'isobutyle' 'Volume libre' Annihilation positon 'Microscopie à force atomique' Index. décimale : 667.9 Revêtements et enduits Résumé : The focus of the work is the effect of molecular architecture on free volume distribution during consolidation and coalescence of aqueous latex emulsions. Two series of model emulsion polymers, iso-butyl methacrylate (i-BMA) and normal-butyl methacrylate (n-BMA) dispersions with varying level of trimethylolpropanetriacrylate (TMPTA) crosslinker, are studied. Coatings are characterized by positron annihilation lifetime spectroscopy (PALS), and atomic force microscopy (AFM). Formation of coherent brittle films without significant interdiffusion is achieved by consolidation below the glass transition temperature (Tg). Consolidation, or ordering/compaction of films following water evaporation at temperatures below the MFFT, results in a decrease in the relative free volume element size, Tau 3, as measured by PALS. An increase in the characteristic relaxation time for the consolidation process is evident as TMPTA levels and corresponding gel fraction increase. Consolidation below Tg is accompanied by physical aging. Coalescence and interdiffusion are achieved by annealing films at or above Tg. Annealed coatings show a decrease in Tg and an increase in PALS free volume attributed to erasure of physical aging in combination with the action of the surfactant (sodium dodecyl sulfate) as a plasticizer. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5693
in JOURNAL OF COATINGS TECHNOLOGY (JCT) > Vol. 73, N° 913 (02/2001) . - p. 115-124[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 001221 - Périodique Bibliothèque principale Documentaires Disponible Implication of coalescing agents and associative thickeners on rheology of water borne coatings / Ritesh A. Bhavsar in PAINTINDIA, Vol. LXII, N° 6 (06/2012)
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Titre : Implication of coalescing agents and associative thickeners on rheology of water borne coatings Type de document : texte imprimé Auteurs : Ritesh A. Bhavsar, Auteur ; Vaibhav J. Dave, Auteur ; Randhirsinh Parmar, Auteur Année de publication : 2012 Article en page(s) : p. 49-54 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Coalescence (Sciences physiques)
Epaississants
Latex
Polyacryliques
Polymères en émulsion
Revêtements en phase aqueuse:Peinture en phase aqueuse
RhéologieIndex. décimale : 667.9 Revêtements et enduits Résumé : Screening specific concentration of ingredients is a difficult job while formulating a latex paint. It is the composition of binder and various ingredients such as pigments, coalescing agents, thickeners, surfactants, wetting agents, etc. The properties of paint are highly dependent upon the property of binder and its interactions with other ingredients. Rheology is one of the important property for paint, responsible for its performance during manufacture, storage and applications. In this study we discuss the theological interactions of acrylic emulsion (AE) with coalescing agents and associative thickeners to screen these ingredients for the paint formulation. Two hydrophobic coalescing agents and three types of HEUR (hydrophobically modified ethoxylated urethane thickener) and HASE (hydrophobically modified alkali swellahle emulsion thickeners) classified as high, mid and low shear thickener with different concentration are used in this study. Flow curve, 31TT (Three Interval Thixotropy Test), Oscillatory amplitude sweep test (AS) are carried out to study the influence of these ingredients on rheology. She viscosity increases as the concentration of coalescing agent and associative thickener increases. The mechanism of interaction and efficiency of ingredients with acrylic emulsion is discussed. Note de contenu : - EXPERIMENTAL : Materials and methods - Rheological measurements
- RESULTS AND DISCUSSION : Effect of coalescing agent - Interactions of associative thickener with acrylic emulsionPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=15650
in PAINTINDIA > Vol. LXII, N° 6 (06/2012) . - p. 49-54[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 14083 - Périodique Bibliothèque principale Documentaires Disponible Improving web scrub resistance / Testa Carlo in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 202, N° 4576 (09/2012)
[article]
Titre : Improving web scrub resistance Type de document : texte imprimé Auteurs : Testa Carlo, Auteur Année de publication : 2012 Article en page(s) : p. 22-24 Langues : Anglais (eng) Catégories : Coalescence (Sciences physiques)
Esters d'alcool
Formulation (Génie chimique)
Frottements (mécanique)
Revêtement mural:Peinture murale
Revêtements -- Additifs:Peinture -- Additifs
Revêtements -- Propriétés mécaniques:Peinture -- Propriétés mécaniques
Revêtements décoratifs:Peinture décorative
Revêtements en bâtiment:Peinture en bâtimentIndex. décimale : 667.9 Revêtements et enduits Résumé : How research shows that Texanol ester alcohol significantly improves the wet scrub resistance of matte interior wall paints applied at temperatures above the polymer's Tg. Note de contenu : - Wet scrub resistance of architectural paint systems
- Technical evaluationsEn ligne : https://drive.google.com/file/d/1AOfkpKzfr9XCLn0PQXUuQMn6QeK32Hfr/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=15746
in POLYMERS PAINT COLOUR JOURNAL - PPCJ > Vol. 202, N° 4576 (09/2012) . - p. 22-24[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 14138 - Périodique Bibliothèque principale Documentaires Disponible Incorporation of an acrylic fatty acid derivative as comonomer for oxidative cure in acrylic latex / Joana V. Barbosa in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 11, N° 5 (09/2014)
[article]
Titre : Incorporation of an acrylic fatty acid derivative as comonomer for oxidative cure in acrylic latex Type de document : texte imprimé Auteurs : Joana V. Barbosa, Auteur ; Jorge Moniz, Auteur ; Adélio Mendes, Auteur ; Fernà o D. Magalhà es, Auteur ; Margarida M. S. M. Bastos, Auteur Année de publication : 2014 Article en page(s) : p. 765-773 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acides gras
Coalescence (Sciences physiques)
Latex
Nanoparticules
Polyacryliques
Polymérisation en émulsion
Polymérisation par oxydation
Revêtements en phase aqueuse:Peinture en phase aqueuse
SiliceLa silice est la forme naturelle du dioxyde de silicium (SiO2) qui entre dans la composition de nombreux minéraux.
La silice existe à l'état libre sous différentes formes cristallines ou amorphes et à l'état combiné dans les silicates, les groupes SiO2 étant alors liés à d'autres atomes (Al : Aluminium, Fe : Fer, Mg : Magnésium, Ca : Calcium, Na : Sodium, K : Potassium...).
Les silicates sont les constituants principaux du manteau et de l'écorce terrestre. La silice libre est également très abondante dans la nature, sous forme de quartz, de calcédoine et de terre de diatomée. La silice représente 60,6 % de la masse de la croûte terrestre continentale.
Traîtements de surfaceIndex. décimale : 667.9 Revêtements et enduits Résumé : An acrylic fatty acid derivative (AcFAD) was evaluated as comonomer for promotion of oxidative cure in waterborne latexes. AcFAD was polymerized by solvent homopolymerization and copolymerization and by emulsion copolymerization, and the final products characterized. In the two polymerization processes, NMR analyses confirmed that the reaction occurred involving both the terminal acrylic double bond and the conjugated double bonds of the aliphatic chain. Compared with a reference acrylic latex, the results obtained after AcFAD incorporation showed a time-dependent increase in gel content and in solvent resistance of dry films. These were ascribed to oxidative cure and consequent self-crosslinking of the acrylic polymer, involving the conjugated double bonds in AcFAD side chains. Oxidative cure was also confirmed by FTIR analyses. In addition, reduction in minimum film-forming temperature evidenced that AcFAD has an internal plasticization effect during film formation. Incorporation of this comonomer in acrylic paint binder formulations constitutes a promising alternative to the use of volatile coalescing agents. Note de contenu : - EXPERIMENTAL : 1. Materials
- Characterization methods : 1. Solution polymerization of AcFAD - 2. Emulsion copolymerization of AcFAD
- RESULTS AND DISCUSSION : 1. Solvent polymerization - 2. Emulsion polymerizationDOI : 10.1007/s11998-014-9582-y En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-014-9582-y.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=22059
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 11, N° 5 (09/2014) . - p. 765-773[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 16538 - Périodique Bibliothèque principale Documentaires Disponible Investigation of the effect of precoalescence or postcoalescence crosslinking on film formation, properties, and latex morphology / Ravi G. Joshi in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 6, N° 1 (03/2009)
[article]
Titre : Investigation of the effect of precoalescence or postcoalescence crosslinking on film formation, properties, and latex morphology Type de document : texte imprimé Auteurs : Ravi G. Joshi, Auteur ; Frank N. Jones, Auteur ; Weidian C. Shen, Auteur ; Wenjing Mao, Auteur ; Paul D. Ziemer, Auteur ; Theodore Provder, Auteur Année de publication : 2009 Note générale : Erratum in Journal of coating technology and research Vol. 7, N° 4, p. 529-530 - Bibliogr. Langues : Américain (ame) Catégories : Coalescence (Sciences physiques)
Contraintes (mécanique)
Formation de film
Indentation des matériaux
Latex
Morphologie (matériaux)
Réticulation (polymérisation)
Revêtements:PeintureIndex. décimale : 667.9 Revêtements et enduits Résumé : Latexes have many product applications including functioning as a binder in coatings. For many years, coatings researchers in industry as well as in academe have been exploring various modes of crosslinking latexes. Quite often, the goal of preparing crosslinked latexes is to upgrade film properties relative to the film properties of uncrosslinked latexes. In the present report, the synthesis and properties of crosslinkable acrylic latexes prepared with either an internal crosslinker (1,3-butylene glycol dimethacrylate)—"precoalescence crosslinking"—or an external crosslinker (adipic dihydrazide)—"postcoalescence crosslinking"—at various levels of crosslinking were studied. For postcoalescence crosslinking, diacetone acrylamide was copolymerized into the latex to provide sites for subsequent reaction with adipic dihydrazide. Fundamental properties of films cast from the two types of latexes were systematically compared. These properties included gel content, dynamic mechanical properties, nano-indenter hardness and modulus, stress–strain properties as well as the characterization of latex morphology by atomic force microscopy (AFM). In addition, some specific end-use properties were determined. This study assesses the effect of type (precoalescence or postcoalescence) and level of crosslinking on the film formation process and the resulting fundamental and end-use properties as well as resulting latex film morphology. DOI : 10.1007/s11998-008-9115-7 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-008-9115-7.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=4859
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 6, N° 1 (03/2009)[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 011246 - Périodique Bibliothèque principale Documentaires Disponible 011271 - Périodique Bibliothèque principale Documentaires Disponible Mécanismes de coalescence des latex / Francis Dobler / 1991
PermalinkMeeting current and future legislation with Optifilm enhancer 400 / Carlo Testa in SURFACE COATINGS INTERNATIONAL, Vol. 99.2 (04-05/2016)
PermalinkMeeting current and future legislations / Carlo Testa in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 204, N° 4594 (03/2014)
PermalinkNanolatex technology 1 : synthesis and characterization of nanosize acrylic latexes and comparison to their conventional size counterparts / Ravi G. Joshi in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 6 (11/2021)
PermalinkPlasticizer : Need for emulsion polymer based coatings, adhesives & sealants / Ravindra V. Gadhave in PAINTINDIA, Vol. LXVII, N° 1 (01/2017)
PermalinkPreferred partitioning : the influence of coalescents on the build-up of mechanical properties in acrylic core–shell particles (I) / Bas Lohmeijer in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 9, N° 4 (07/2012)
PermalinkPreparation of 3-alkoxy-2-hydroxypropyl ester of 2-ethylhexanoic acid and its application in polymer latexes and coatings / Zou Xinru in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 20, N° 4 (07/2023)
PermalinkPermalinkRelation structure/procédé/propriétés finales de matériaux élaborés par rotomoulage / Estelle Perot in MATERIAUX & TECHNIQUES, Vol. 94, N° 5 (2006)
PermalinkRole of van der Waals force in latex film formation / Xiaobo Gong in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 5, N° 3 (09/2008)
PermalinkStabilité de bulle(s) au sein d’un fluide à seuil / Gabriel Samson in RHEOLOGIE, Vol. 26 (12/2014)
PermalinkStudy of bonding formation between the filaments of PLA in FFF process / Achraf Kallel in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIV, N° 4 (08/2019)
PermalinkSurface coverage by impact of droplets from a monodisperse spray / A. Dalili in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 17, N° 1 (01/2020)
PermalinkSustainable alternative to acrylic emulsions / Marcello Vitale in EUROPEAN COATINGS JOURNAL (ECJ), (03/2024)
PermalinkTailoring crosslinking performance / Pär Jörgensen in EUROPEAN COATINGS JOURNAL (ECJ), N° 6 (06/2015)
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