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Investigation of cellulose nanocrystals (CNC) and cellulose nanofibers (CNF) as thermal barrier and strengthening agents in pigment-based paper coatings / Brenda Hutton-Prager in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 1 (01/2022)
[article]
Titre : Investigation of cellulose nanocrystals (CNC) and cellulose nanofibers (CNF) as thermal barrier and strengthening agents in pigment-based paper coatings Type de document : texte imprimé Auteurs : Brenda Hutton-Prager, Auteur ; Esteban Ureña-Benavides, Auteur ; Sanjiv Parajuli, Auteur ; Kolawole Adenekan, Auteur Année de publication : 2022 Article en page(s) : p. 337–346 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Aliments -- Emballages
Analyse mécanique dynamique
CelluloseLa cellulose est un glucide constitué d'une chaîne linéaire de molécules de D-Glucose (entre 200 et 14 000) et principal constituant des végétaux et en particulier de la paroi de leurs cellules.
Formulation (Génie chimique)
Nanofibres
Nanoparticules
Pigments
Protection thermique
Revêtements -- Propriétés mécaniques
Revêtements en papierIndex. décimale : 667.9 Revêtements et enduits Résumé : In response to food packaging improvements, this study investigates changes in mechanical and thermal barrier properties of pigment-based paper coatings when cellulose nanocrystals (CNC) and cellulose nanofibers (CNF) are added to the formulation. Stable dispersions of all coating components were formed between pH 7–9 (zeta potential > |30 mV|) except CNF, which favored stable dispersions at higher pH. Hydrodynamic diameters (Dh) of CNC and CNF decreased when interacting with calcium carbonate ions (Ca2+ and CO32-) ; however, latex binder and dispersant diameters were unaffected by the presence of CaCO3 in solution. Thermal barrier performance was quantified by measuring ΔT across coated samples, with and without nanoparticle additives. Both CNC and CNF additives significantly contributed to the ΔT measured, with the best result recorded for 2 wt% CNF, pH 7, and a drying rate of 25 °C/min. This sample recorded 37 ± 6 °C higher than the ΔT for baseline coatings (without additive). Dynamic mechanical analysis (DMA) showed a higher storage modulus for all samples containing CNC and/or CNF compared with the baseline coating, suggesting a material with greater resistance to deformation from applied load. Higher dissipation energy was also observed; however, lower tan delta values suggest improved mechanical properties with both additives. Note de contenu : - EXPERIMENTAL METHODS AND MATERIALS : Materials - Methods
- RESULTS AND DISCUSSION : Fundamental properties of the formulation - Thermal barrier performance of the coatings - Mechanical strength performance of the coatingsDOI : https://doi.org/10.1007/s11998-021-00538-1 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00538-1.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37162
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 19, N° 1 (01/2022) . - p. 337–346[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23313 - Périodique Bibliothèque principale Documentaires Disponible Investigation of edge formation during the coating process of Li-ion battery electrodes / Sandro Spiegel in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 1 (01/2022)
[article]
Titre : Investigation of edge formation during the coating process of Li-ion battery electrodes Type de document : texte imprimé Auteurs : Sandro Spiegel, Auteur ; Thilo Heckmann, Auteur ; Andreas Altvater, Auteur ; Ralf Diehm, Auteur ; Philip Scharfer, Auteur ; Wilhelm Schabel, Auteur Année de publication : 2022 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Accumulateurs lithium-ion
Caractérisation
Electrodes
Enduction par filière
Enrobage (technologie)
Formulation (Génie chimique)
MélangeIndex. décimale : 667.9 Revêtements et enduits Résumé : In this manuscript, a method to reduce superelevations of lateral edges in cross-web direction during slot die coating of shear-thinning slurries for Li-ion battery electrodes (LIB) was developed. Therefore, the impact of the inner slot die geometry on the edge elevations was investigated. These elevations of the coating could be almost eliminated by optimizing the flow profile at the outlet of the slot die by modification of the internal geometry. This adaption is an essential step in optimizing the coating quality of slot die coating for battery electrodes to significantly reduce coating edges and, hence, the resulting production reject during the coating step of the industrial roll-to-roll process. It was also shown that lateral edges of the coating can be influenced explicitly by process parameters such as volume flow and gap between slot die and substrate. This correlation has already been shown for other shear-thinning material systems in previous works, which is now confirmed for this material system. At the beginning, the influence of different internal geometries on the formation of the edge elevations was shown. Finally, for the shear-thinning electrode slurry used in this work, optimal dimensions of the previously determined inner geometry for the slot die outlet were found. The optimization was performed for a state-of-the-art electrode area capacity (approximately 2.2 mAh cm−2). The results enable a significant reduction of defects and reject in the coating step of large-scale production of LIB electrodes in the future, adding to a more sustainable battery production. Note de contenu : - EXPERIMENTAL METHODS AND MATERIALS : Formulation, mixing, and preparation - Experimental setup and process parameters - Characterization methods
- RESULTS AND DISCUSSION : Influence of coating speed - Influence of dimensionless gap - Influence of shim geometries
- Table 1 Composition of the solid components of the anode slurry
- Table 2 Process parameters and geometrical parameters used in the experiments for the different shim configurationsDOI : https://doi.org/10.1007/s11998-021-00521-w En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00521-w.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37150
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 19, N° 1 (01/2022)[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23313 - Périodique Bibliothèque principale Documentaires Disponible Investigation of the effects of formulation on selected properties of UV curable IPN coatings / L. N. Price in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 70, N° 885 (10/1998)
[article]
Titre : Investigation of the effects of formulation on selected properties of UV curable IPN coatings Type de document : texte imprimé Auteurs : L. N. Price, Auteur ; R. A. Ryntz, Auteur ; X. H. Li, Auteur ; A. H. Huetos, Auteur ; H. X. Xiao, Auteur ; K. C. Frisch, Auteur ; B. Suthar, Auteur Année de publication : 1998 Article en page(s) : p. 151-156 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Copolymère uréthane acrylique
Formulation (Génie chimique)
Photoamorceurs (chimie)
Polyaddition
Réseaux polymères
Réticulation (polymérisation)
Revêtements
Revêtements -- Séchage sous rayonnement ultravioletIndex. décimale : 667.9 Revêtements et enduits Résumé : Ultraviolet curable coatings based on urethane-acrylic resins were prepared by free radical polymerization. The effects of photoinitiators on the curing reaction and the influence of polyol types and dimethylopropionic acid (DMPA) amounts on the properties of UV curable coatings prepared by free radical polymerization (UVF) were investigated. The effects of polymerization (UVC) and the consequences of postcuring conditions on the properties of UVC were evaluated. The interpenetrating polymer network (IPN) containing UV curable coatings (UVIPN), which were composed of UVF and UVC at different ratios (by weight), were prepared. The properties of UVIPN with varied UVF/UVC ratios were studied. Note de contenu : - EXPERIMENTAL : Raw materials - Preparation of free radical UV curable coatings based on urethane-modified acrylics - Preparation of cationic UV curable coatings based on epoxy - Preparation of IPN UV curable coatings - Measurement of properties
- RESULTS : Free radical UV curable coatings based on urethane-modified acrylics - Cationic UV curable coatings based on epoxy - UV curable IPN coatings based on free-radical and cationic UV curable mechanismsPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=18045
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Code-barres Cote Support Localisation Section Disponibilité 003554 - Périodique Bibliothèque principale Documentaires Disponible Investigation of UV-curable alkyd coating properties / Qianhe Wang in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 20, N° 2 (03/2023)
[article]
Titre : Investigation of UV-curable alkyd coating properties Type de document : texte imprimé Auteurs : Qianhe Wang, Auteur ; Jomin Thomas, Auteur ; Mark D. Soucek, Auteur Année de publication : 2023 Article en page(s) : p. 545-557 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Diluants
Formulation (Génie chimique)
Huile de linL'huile de lin ou "huile de graines de lin" est une huile de couleur jaune d'or, tirée des graines mûres du lin cultivé, pressées à froid et/ou à chaud ; parfois elle est extraite par un solvant, en vue de l'usage industriel ou artistique, principalement comme siccatif, ou huile auto-siccative.
Les utilisations de l'huile de lin dérivent de sa richesse en acides gras polyinsaturés, en particulier en acides linolénique et linoléique, qui lui doivent leur nom.
L'huile de lin polymérise spontanément à l'air, avec une réaction exothermique : un chiffon imbibé d'huile peut ainsi, dans certaines conditions, s'enflammer spontanément.
Pour ses propriétés de polymère, l'huile de lin est employée seule, ou mélangée à d'autres huiles, résines et solvants, et est utilisée en tant que : Imprégnateur et protecteur des bois à l'intérieur comme à l'extérieur : protection contre l'humidité, les champignons et insectes, et contre la poussière par son caractère antistatique, composant de certains vernis de finition, liant de broyage pour la peinture à l'huile, agent plastifiant du mastic de vitrier, agent durcisseur de diverses préparations, agent de cohérence et liant dans la fabrication du linoléum.
Méthacrylates
Photoréticulation
Polyalkydes
Polymères -- Synthèse
Réticulants
Revêtements -- Propriétés mécaniques
Revêtements -- Séchage sous rayonnement ultraviolet
Revêtements organiques
Triacrylate de glycérol
Triméthacrylate de glycérolIndex. décimale : 667.9 Revêtements et enduits Résumé : Four types of UV-(meth)acrylate curable alkyds were synthesized and formulated with two tri(meth)acrylate reactive diluents. Thermal, mechanical, and coating properties, including gloss, adhesion, hardness, impact resistance, and chemical resistance, were evaluated. In general, methacrylate-based UV-curable alkyd has higher modulus and toughness, whereas acrylate-based UV-curable alkyd has better flexibility and adhesion. In all four UV-curable alkyd resin systems, increasing reactive diluent content will enhance properties like tensile strength and modulus, hardness, and chemical resistance. However, there is a decrease in properties such as elongation at break, adhesion, and impact resistance. Among four UV-curable alkyd resin, acrylated medium linseed oil alkyd exhibited the best overall performance than other systems in terms of hardness, flexibility, and adhesion. Particularly, acrylated medium linseed oil alkyd formulations with 20–30 wt% of glycerol triacrylate as reactive diluent showed the best coating performance. It is possible to produce coating films with a good balance of crosslink density, flexibility, and adhesion using such UV-curable alkyd systems. Further, it has a huge potential in alkyds as an alternative for cobalt-based drier system. Note de contenu : - EXPERIMENTAL : Materials - Synthesis - Formulation of UV-curable alkyd resin - Instrumentation and properties measurement
- RESULTS AND DISCUSSION : Fracture toughness - Tensile test - Viscoelastic properties - Coatings properties
- Table 1 : Formulation of the long oil and medium oil linseed oil alkyd
- Table 2 : Formulation of the methacrylated and acrylated long and medium linseed oil alkyd
- Table 3 : Formulation of the glycerol trimethacrylate and glycerol triacrylate
- Table 4 : Coating properties of all UV-curable alkyd systemsDOI : https://doi.org/10.1007/s11998-022-00697-9 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-022-00697-9.pdf?pdf=button Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39298
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Code-barres Cote Support Localisation Section Disponibilité 24056 - Périodique Bibliothèque principale Documentaires Disponible Iodinated thermal-fused polymer as a biocidal additive to commercial and chemical-resistant coatings / L. di Ionno in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 87, B4 (12/2004)
[article]
Titre : Iodinated thermal-fused polymer as a biocidal additive to commercial and chemical-resistant coatings Type de document : texte imprimé Auteurs : L. di Ionno, Auteur ; P. J. Messier, Auteur Année de publication : 2004 Article en page(s) : p. 265-272 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Antimicrobiens
Formulation (Génie chimique)
HalogènesVIIA. Ces éléments chimiques sont : le fluor 9F, le chlore 17Cl, le brome 35Br, l’iode 53I et l’astate 85At.
Ces éléments chimiques peuvent se trouver liés à la quasi-totalité des autres éléments chimiques du tableau périodique, y compris quelques gaz nobles pour ce qui concerne le fluor. A 0 °C sous la pression atmosphérique, les corps simples correspondant sont sous forme de molécules diatomiques : à l'état gazeux pour le difluor F2 et le dichlore Cl2, liquide pour le dibrome Br2 et solide pour le diiode I2 et l’astate. Aucun ne se trouve dans la nature sous cette forme. La forme la plus courante, dans la nature est la forme ionique (ions fluorure, chlorure, bromure ou iodure) et, en quantité moins abondante, dans des combinaisons moléculaires, par exemple avec le carbone. C'est le cas des hormones thyroïdiennes iodées par exemple.
Iode
Latex
Polyacryliques
Polyalkydes
Polymères -- Additifs
Résistance chimique
Revêtement émail:Peinture-émail
Revêtements en phase aqueuse -- Additifs:Peinture en phase aqueuse -- Additifs
Revêtements organiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : This paper includes internal and external research demonstrating surface bioactivation by an iodinated thermalfused polymer. An antimicrobial technology based on the controlled release of iodine was demonstrated for medical, commercial mould contamination, outdoor environment contamination, and military chemical agent-resistant coatings (CARC). Results showed biocidal activity of CARC paint incorporating this antimicrobial system againstErwinia herbicola (Eh) andEscherichia coli (E coli). Water-based flat latex and alkyd oil-based enamel showed reductions >99.96% and 99.98%, respectively. Both formulations displayed significant biocidal activity againstE coli Bacteriophages MS2. Commercial paint formulations have demonstrated active anti-microbial activity againstbacillus subtilis and fungi. An analytical method was developed to determine the level of volatile iodine released from the iodinated thermal- fused polymer- painted surface at standard air exchanges. Iodine was collected and the resultant iodide was quantitated using the Leuco Crystal Violet method. A detection limit of 0.01 mg/m3 was achieved and was deemed adequately sensitive relative to the referenced threshold limit value (TLV) of 1.036 mg/m3. Iodine airborne concentrations for both latex and acrylic paints tested in the simulation chamber were observed to be equal to or less than the TLV with the exception of a few data points. Note de contenu : - METHOD : Biocidal activity screening - Surface bioactivation protocol developed by USMC - Standard method to determine resistance to mould - Toxicology protocol
- RESULTS AND DISCUSSION : USMC study - ASTM D3293-94 resistance to mould study - Toxicology study
- CONCLUSIONS : USMC study - Surface bioactivation - ASTM D3293-94 resistance to mould study - Toxicology study
- Table 1 : Percentage reduction ol Eco/iand Eh
- Table 2 : Solvent-borne CARC challenged with Eh suspension2
- Table 3 : Waler-borne CARC challenged with Eh suspension2
- Table 4 : Water-based flat latex challenged with Eh suspension2
- Table 5 : Alkyd oil-based enamel challenged with Eh suspension2
- Table 6 : Results of MS2 liquid spray challenge ot the Mil-C-2275O/iodinated thermal-fused polymer-impregnated coupons2
- Table 7 : Performance of iodinated thermal-fused polymer incorporated paint against Bacillus subtilis spores afler 24 and 48 hours of contact time
- Table 8 : Comparative ratings for mould growth observed on panels exposed in environmental chamber 1
- Table 9 : Comparalive ratings lor mould growth observed on panels exposed in environmental chamber2
DOI : 10.1007/BF02699675 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699675.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5447
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Code-barres Cote Support Localisation Section Disponibilité 000718 - Périodique Bibliothèque principale Documentaires Disponible PermalinkIsocyanate free polyurethane technology for wood coating applications : approaches to reducing VOC in clearcoat formulations / Jeffrey Wexler in COATINGS TECH, Vol. 14, N° 8 (08/2017)
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PermalinkLow-fat diet for decorative paints / Sebastian Roller in EUROPEAN COATINGS JOURNAL (ECJ), N° 6 (06/2012)
PermalinkLow-temperature washing without loss in performance / Juergen Franke in SOFW JOURNAL, Vol. 144, N° 5 (05/2018)
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