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Irradiation-cured graphene composite films : a comparison between UV and EB curing / Ziyue Wei in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 20, N° 5 (09/2023)
[article]
Titre : Irradiation-cured graphene composite films : a comparison between UV and EB curing Type de document : texte imprimé Auteurs : Ziyue Wei, Auteur ; Lingyun Wang, Auteur ; Ren Liu, Auteur ; Jing Luo, Auteur Année de publication : 2023 Article en page(s) : p. 1713-1726 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
GraphèneLe graphène est un cristal bidimensionnel (monoplan) de carbone dont l'empilement constitue le graphite. Il a été isolé en 2004 par Andre Geim, du département de physique de l'université de Manchester, qui a reçu pour cette découverte le prix Nobel de physique en 2010 avec Konstantin Novoselov. Il peut être produit de deux manières : par extraction mécanique du graphite (graphène exfolié) dont la technique a été mise au point en 2004, ou par chauffage d'un cristal de carbure de silicium, qui permet la libération des atomes de silicium (graphène epitaxié). Record en conduction thermique jusqu'à 5300 W.m-1.K-1. C'est aussi un matériaux conducteur.
Matériaux hybrides
Mesure
Revêtements -- Séchage sous rayonnement électronique
Revêtements -- Séchage sous rayonnement ultraviolet
Revêtements organiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : In this work, a series of graphene-based composite films were prepared via electron beam (EB) or ultraviolet (UV) irradiation. The influence of the graphene content as well as the irradiation dose on the curing behavior and properties of EB/UV-cured graphene composite films was systematically studied. The curing behavior of the composite films was investigated by the double bond conversion rate as well as the gel content, and the properties of the composite films were studied by TGA analysis and tensile tests. For EB-cured graphene composite films, the curing degree increased with the increase in the irradiation dose (60–360 kGy), and the upper and lower surface was uniformly cured. The curing degree and curing depth of the EB-cured films were not affected by the addition of graphene (0.0–5.0 wt.%). Compared to pure resin film, the EB-cured graphene composite film showed enhanced tensile properties. For UV-cured graphene composite films, the curing degree was also enhanced with the increasing irradiation dose, but it decreased significantly with the increase in graphene content (0.0–5.0 wt.%). The curing degrees of upper and lower surfaces of the UV-cured graphene composite film were not uniform, and the curing depth decreased with the increase in graphene concentration. The addition of graphene had an adverse effect on the thermal and mechanical properties of the UV-cured composite film. Note de contenu : - EXPERIMENT : Materials - The preparation of graphene composite films via UV/EB curing - Characterization and measurement
- RESULTS AND DISCUSSION : Curing Behavior of graphene composite films - Properties of irradiation-cured graphene composite films
- Table 1 : The curing depths of EB-cured graphene composite films
- Table 2 : The curing depths of UV-cured graphene composite films
Properties of irradiation-cured graphene composite filmsDOI : https://doi.org/10.1007/s11998-023-00776-5 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-023-00776-5.pdf?pdf=button Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39983
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 20, N° 5 (09/2023) . - p. 1713-1726[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 24242 - Périodique Bibliothèque principale Documentaires Disponible
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Titre : ISO 11890-2 revisited : Powerful, all-in-one, versatile test method for VOCs and SVOCs Type de document : texte imprimé Auteurs : Nicole M. Borho, Auteur ; Michael Braun, Auteur ; Jan Jaap de Roo, Auteur ; Ronald van de Nesse, Auteur Année de publication : 2022 Article en page(s) : p. 38-43 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Chromatographie en phase gazeuse
Revêtements -- Normes
Revêtements -- Teneur en composés organiques volatils
Revêtements organiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : A highly robust approach for correctly classifying substances as VOCs or SVOCs has been developed. Based on direct injection of a solvent extract of the coating matrix into a gas chromatograph, identification with a mass selective detector and quantification with a flame ionisation detector, it offers greater accuracy in the determination of VOC and SVOC contents. Note de contenu : - Procedure for detemrining VOC and SVOC content
- Sample preparation
- Separation by GC
- Identification of compounds by MS
- Quantification of compounds by FID
- Classification and evaluation of the Sum of VOC and SVOC contentEn ligne : https://drive.google.com/file/d/1kwmLTt_O9rJJyHRRP5pv9b-FvJE4uiyf/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=38234
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Code-barres Cote Support Localisation Section Disponibilité 23653 - Périodique Bibliothèque principale Documentaires Disponible Isocyanate-free routes : / Jurgen van Hollen in EUROPEAN COATINGS JOURNAL (ECJ), N° 06-07/2007 (07-08/2007)
[article]
Titre : Isocyanate-free routes : : Environmentally friendly alternatives to high performance coatings Type de document : texte imprimé Auteurs : Jurgen van Hollen, Auteur Année de publication : 2007 Article en page(s) : p. 10-11 Note générale : Bibliogr. (encart de 12 p. entre les p. 18-19) Langues : Anglais (eng) Catégories : Copolymère uréthane acrylique
Isocyanates -- Suppression ou remplacement
Oligomères
Polyuréthanes
Revêtements organiques
Revêtements sans isocyanatesIndex. décimale : 667.9 Revêtements et enduits Résumé : Ever since polyurethanes were first discovered in the late thirties they have found an ever increasing number of applications due to they unique properties. Most of them are attributed to the ability to organize themselves in the so called hard and soft micro domains. As their production involves toxic raw materials such as isocyanates there has been a continuous search to find alternative routes which make use of safer chemicals. Despite many efforts no-one has been able to product high molecular weight linear polyurethanes. Acrylated oligourethanes have been produced in commercial quantities without using isocyanates and they have given rise to high performing coatings after cross linking initiated withultraviolet radiation. Note de contenu : - Several alternatives proposed
- The cyclic carbonate route
- Chemical and enzymatic transurethanisation
- Bright future
- Fig. 1 : Formation of a b-hydroxy-urethane group
- Fig. 2 : Production of a methacrylated carbonate with carbondioxideEn ligne : https://drive.google.com/file/d/1yJ_bncWP9bTc1q8AbmNRHOUqPJzB0TSt/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=40653
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Code-barres Cote Support Localisation Section Disponibilité 007770 - Périodique Bibliothèque principale Documentaires Disponible Isosorbide-derived boron- and phosphorus-containing precursors for flame-retardant epoxy coating / Sheth Parth in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 17, N° 1 (01/2020)
[article]
Titre : Isosorbide-derived boron- and phosphorus-containing precursors for flame-retardant epoxy coating Type de document : texte imprimé Auteurs : Sheth Parth, Auteur ; Siddhesh Mestry, Auteur ; Dwij Dave, Auteur ; Shashank T. Mhaske, Auteur Année de publication : 2020 Article en page(s) : p. 231-241 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Borique, Acide
Caractérisation
Epoxydes
Formulation (Génie chimique)
IgnifugeantsComposé chimique utilisé pour réduire l'inflammabilité. Il peut être incorporé au produit durant sa fabrication ou appliqué ultérieurement à sa surface.
IsosorbideL’isosorbide est un composé hétérocyclique obtenu à partir de la double réaction de déshydratation du sorbitol, lui-même issu de la réaction d’hydrogénation du glucose.
L’isosorbide est un diol issu des agro-ressources, non toxique, biodégradable et stable thermiquement.
L’isosorbide est un monomère qui peut être inséré dans des chaînes macromoléculaires de type polymères (polycarbonates, polyuréthanes, polyesters…). Il est également utilisé pour la synthèse de dérivés tels que les diesters, diéthers, dinitrates…
L’isosorbide est considéré comme synthon donnant accès à une nouvelle plateforme chimique d’intérêt puisqu’il est issu du végétal et permet d’obtenir de nombreux dérivés aux propriétés égales voire supérieures à leurs homologues de la pétrochimie.
Revêtements -- Analyse
Revêtements -- Propriétés mécaniques
Revêtements -- Propriétés thermiques
Revêtements organiques
Revêtements protecteurs
Trichlorure de phosphoryleLe trichlorure de phosphoryle, ou oxychlorure de phosphore, est un composé chimique de formule brute POCl3.
Le trichlorure de phosphoryle réagit avec l'eau et les alcools pour donner du chlorure d'hydrogène et respectivement de l'acide phosphorique et des esters de phosphate : POCl3 + 3 H2O → H3PO4 + 3 HCl.
POCl3 peut également réagir avec une base de Lewis pour former des composés d'addition avec différents acides de Lewis tels que le tétrachlorure de titane : Cl3P+-O- + TiCl4 → Cl3P+-O--TiCl4.
Le composé POCl3·AlCl3 résultant de l'addition de chlorure d'aluminium sur le trichlorure de phosphoryle est assez stable, de sorte que POCl3 peut être utilisé pour éliminer le chlorure d'aluminium du mélange résultant d'une réaction de Friedel-Crafts.
POCl3 réagit avec le bromure d'hydrogène en présence de chlorure d'aluminium pour former le tribromure de phosphoryle POBr3.Index. décimale : 667.9 Revêtements et enduits Résumé : The present study describes an attempt to induce the inherent flame retardancy to the epoxy resin by incorporation of phosphorous and boron atoms in the polymer backbone through the curing agents. Phosphorous (PPc)- and boron (BPc)-containing precursors were synthesized and incorporated into the commercial epoxy and hardener system with different molar ratios. The structures of the synthesized compounds were confirmed using hydroxyl value, Fourier transform infrared spectroscopy, and nuclear magnetic resonance spectroscopy. The thermal, physical, and mechanical properties of the cured films were performed using different testing methods. Thermogravimetric analysis and differential scanning calorimetry results showed the overall increased thermal stability and char yield along with the glass transition temperatures (Tg) due to the incorporation of newly synthesized phosphorus- and boron-containing compounds in the coating films. The mechanical properties and solvent resistance of the cured films were excellent. The flame-retardant properties of the cured films were increased with the incorporation of PPc and BPc. The highest limiting oxygen index was obtained for the formulation with equal amounts of PPc and BPc as 29 while UL-94 showed the self-extinguishing behavior within 10 s after ignition. Note de contenu : - MATERIALS AND METHODS : Materials - The reaction of isosorbide and POCl3 - The reaction of isosorbide and boric acid - Formulation of the epoxy coating films - Characterization
- RESULTS AND DISCUSSION : Physicochemical analysis - FTIR and NMR analysis - Thermal properties - Mechanical properties - Flame-retardant propertiesDOI : 10.1007/s11998-019-00262-x En ligne : https://link.springer.com/content/pdf/10.1007/s11998-019-00262-x.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=33741
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Code-barres Cote Support Localisation Section Disponibilité 21517 - Périodique Bibliothèque principale Documentaires Disponible Itaconic acid - Green material for adhesives and coatings / Chaitali R. Gadhave in PAINTINDIA, Vol. LXXII, N° 3 (03/2022)
[article]
Titre : Itaconic acid - Green material for adhesives and coatings Type de document : texte imprimé Auteurs : Chaitali R. Gadhave, Auteur Année de publication : 2022 Article en page(s) : p. 61-65 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Colles:Adhésifs
Itaconique, Acide
Revêtements organiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : Owing to the environmental issues, there is a moderate demand of renewable resources in the chemical industry. Conversely, as a rather decrease in side effect of this growth, new chemical building blocks are achieved, which are not commercially accomplished from petroleum sources. The substitution of materials from limited petroleum resources through renewable materials presents the necessary challenge. In this prospect, itaconic acid achieved prominent attention and its trifunctional structure leads to the synthesis of nove) sustainable polymeric materials. ltaconic acid, a carbohydrate derived aliphatic dicarboxylic acid, is a potential chemical for the synthesis of renewable resource-based adhesives and coatings. This material is the biobased mass product itaconic acid, which is structurally similar to monomers like acrylic and methacrylic acid. This paper aims to review the most relevant work in the field of adhesives and coatings derived from itaconic acid and to show the unique properties of these materials and identify the potential applications. Note de contenu : - Itaconic acid uses in adhesives
- Itaconic acid uses in coatings
- Fig. 1 : Structure of itaconic acidEn ligne : https://drive.google.com/file/d/1C06SHibtSF7M1oU9ESd5daluFC9bCz4f/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37515
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PermalinkNorme d'exécution des travaux. Réfection de façades en service par revêtements d'imperméabilité à base de polymères - Norme NF P 84-404-1 / Association Française de Normalisation (Paris) / Saint-Denis La Plaine : Association Française de Normalisation (AFNOR) (1993)
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PermalinkA novel hydroxyl polyacrylate latex modified by OvPOSS and its application in two-component waterborne polyurethane coatings / Wu Zeng in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 17, N° 1 (01/2020)
PermalinkNovel multilayer structural epoxy composite coating containing graphene oxide and silanized chromium carbide for the protection of steel structures / Joseph Raj Xavier in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 6 (11/2022)
PermalinkNovel natural additives for surface coatings / Richard Czarnecki in COATINGS TECH, Vol. 19, N° 6 (07/2022)
PermalinkA novel non-isocyanate and formaldehyde-free technology for solvent- and waterborne systems / Andreas Hermes in SURFACE COATINGS INTERNATIONAL, Vol. 104.6 (11-12/2021)
PermalinkNovel oil-modified acrylic multi-domain dispersions for wood coatings in SURFACE COATINGS INTERNATIONAL, Vol. 103.3 (05-06/2020)
PermalinkNovel path to hydroxyl-functional emulsions for high-performance waterborne two-component polyurethane coatings / Steven Mao in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 211, N° 4670 (08/2021)
PermalinkNovel procedure for polymer coatings of nanoscopic surface topology / C. D. Eisenbach in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 88, B3 (09/2005)
PermalinkNovel versatile oligomer for thermallly, UV-, and ambient curable organic-inorganic hybrid coatings / Tahereh Hayeri in COATINGS TECH, Vol. 20, N° 5 (09-10/2023)
PermalinkA novel waterborne fluorinated polyurethane–acrylate film for ultraviolet blocking and antiprotein fouling in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 5 (09/2021)
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