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Auteur Bi Shi
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Sichuan University - Chengdu - China
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A deeper exploration of the relation between sulfonation degree and retanning performance of aromatic syntans / Qingyong Sun in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 3 (Année 2021)
[article]
Titre : A deeper exploration of the relation between sulfonation degree and retanning performance of aromatic syntans Type de document : texte imprimé Auteurs : Qingyong Sun, Auteur ; Yunhang Zeng, Auteur ; Ya-Nan Wang, Auteur ; Yue Yu, Auteur ; Bi Shi, Auteur Année de publication : 2021 Article en page(s) : 10 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Composés aromatiques
Dynamique moléculaire
Pénétration (physique)
Précipitation (chimie)
Retannage
Simulation, Méthode de
Sulfonation
Syntans
Tannage synthétiqueIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : It is well-known that the sulfonation degree (DS) of aromatic syntan is an important factor affecting its retanning performances. But the quantitative relation between DS and syntan property and the influencing mechanism of DS on syntan property are not clarified. In this work, five phenolic formaldehyde syntans (PFSs) with the same polymerization degree but varying DS were prepared to investigate the effect of DS on the properties of syntan and crust leather. It was found that the absolute value of zeta potential and the particle size of PFS decreased with increasing DS in aqueous solution. Molecular dynamic simulation results proved that the DS of PFS was a major contributor to electrostatic interaction and hydrogen bonding in the PFS–water system and greatly affected the aggregation and dispersion of PFS in aqueous solution. The PFS with a low DS was prone to aggregate to large particles in aqueous solution because of low intermolecular electrostatic repulsion and less hydrogen bonds and therefore can be used to increase the thickness and tightness of leather. The PFS with a high DS presented a small particle size with more anionic groups in aqueous solution, thereby sharply decreasing the positive charge of leather surface and facilitating the penetration of the post-tanning agents into the leather. These results might be scientifically valid for rational molecular design of syntans and more productive use of syntans in leather making. Note de contenu :
- MATERIALS AND METHODS : Materials - Preparation of PFSs with different DSs - Determination of DS of PFS - Determination of zeta potential and particle size of PFS - MD simulation - Retanning and fatliquoring - Determination of zeta potential and pIs of retanned leather - Analysis of PFS penetration in leather - Determination of uptake rate of PFS by leather - Determination of thickness increase rate of leather - Determination of leather softness
- RESULTS AND DISCUSSION : Effect of DS on zeta potential and particle size of PFS - Effect of DS of PFS on pI of retanned leather - Effect of DS on penetration of PFS in retanned leather - Effect of DS on uptake of PFS by leather - Effect of DS of PFS on thickness and softness of crust leather
- Table 1 : Simulation details
- Table 2 : Retanning process
- Table 3 : Retanning and fatliqouring processesDOI : https://doi.org/10.1186/s42825-021-00073-0 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-021-00073-0.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37556
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 3 (Année 2021) . - 10 p.[article]Determination of fatty spew on leather by BG-MS / Yanan Wang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVI, N° 6 (06/2011)
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Titre : Determination of fatty spew on leather by BG-MS Type de document : texte imprimé Auteurs : Yanan Wang, Auteur ; Xuepin Liao, Auteur ; Qiang He, Auteur ; Bi Shi, Auteur Année de publication : 2011 Article en page(s) : p. 179-183 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acides gras
Chromatographie en phase gazeuse
Cuirs et peaux -- Analyse
Esters méthyliques
Produits de nourriture du cuir
Spectrométrie de masseIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : The composition of fatty spew on leather was determined by gas chromatography-mass spectrometry (GC-MS). Meanwhile, the volatile substances in the fogging test of leather were identified by GC-MS. With the combination of all the data obtained, it was found that the predominant components of fatty spew were palmitic acid methyl ester, oleic acid methyl ester and stearic acid methyl ester, and their relative content ratio is approximately 8 : 1 : 1. An interesting phenomenon was that no fatty acids are detected in fatty spew although they are commonly regarded as the origin of this defect. These facts strongly suggest that the fatty acid methyl esters existing in fatliquors are the main origin of fatty spew defect in leather, and also one of the probable contributions to fogging. En ligne : https://drive.google.com/file/d/1mOQWty7kBC3ZCOVw9QEGKzDCKlIoWnBS/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=11716
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CVI, N° 6 (06/2011) . - p. 179-183[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 16697 - Périodique Bibliothèque principale Documentaires Disponible Determination of free formaldehyde in leather chemicals / Yudan Yi in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIV, N° 10 (10/2019)
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Titre : Determination of free formaldehyde in leather chemicals Type de document : texte imprimé Auteurs : Yudan Yi, Auteur ; Wei Ding, Auteur ; Ya-Nan Wang, Auteur ; Bi Shi, Auteur Année de publication : 2019 Article en page(s) : p. 382-390 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Agents de tannage
Chimie analytique
Cuir -- Teneur en formaldéhyde
Polyamines
Produits chimiques -- Teneur en formaldéhyde
RetannageIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Formaldehyde is widely used in the synthesis of various leather chemicals due to its high reactivity and low cost. It is probably introduced into leather when applying the chemicals to processing, and then released during storage and use of leather, which may pose a potential risk to human health. Existing method for determining formaldehyde in leather is helpless to deal with the complicated chemicals. In this study, a method was optimized for determination of free formaldehyde in leather chemicals based on ISO 27587. A 0.5-2.0 g sample of leather chemical (formaldehyde could range from 1.25 to 1250 mg/kg) was heated at 90°C in nitrogen atmosphere. The released formaldehyde was purged at a flow rate of 300 mL/min for 30 min, captured and derivatized using a bubble absorption tube containing 2,4-dinitrophenylhydrazine absorption solution, and then detected by HPLC-diode array detector. The recovery rate of formaldehyde standard solution was 91.0% with relative standard deviation (RSD) of 4.87% in seven times repeated trials. The repeated determinations of aldehyde tanning agents showed the formaldehyde recoveries higher than 90% and RSD lower than 7%, indicating the accuracy and precision of the method. Powdery amino resins were determined to contain a tiny amount of free formaldehyde using this method. However, it should be noted that hydrolyzed formaldehyde will be formed when the amino resins were dissolved in water and used in retanning, leading to the potential for bringing leather with high content of formaldehyde. Note de contenu : - EXPERIMENTAL : Materials - Determination of formaldehyde in leather chemicals - Effects of extraction conditions on the determination of formaldehyde - Effect of derivative devices on the determination of formaldehyde - Determination of formaldehyde in amino resin and leather
- RESULTS AND DISCUSSION : Effect of extraction conditions on the determination of formaldehyde - Validation parameters of the proposed method - Effect of derivative devices on the determination of formaldehyde - Determination of formaldehyde content in amino resins and retanned leatherEn ligne : https://drive.google.com/file/d/1ovkzKqph88a5PaXbxWN0an2EWrZffTZZ/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=33034
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CXIV, N° 10 (10/2019) . - p. 382-390[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 21208 - Périodique Bibliothèque principale Documentaires Disponible Diagnosing the environmental impacts of typical fatliquors in leather manufacture from life cycle assessment perspective / Yue Yu in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 4 (Année 2022)
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Titre : Diagnosing the environmental impacts of typical fatliquors in leather manufacture from life cycle assessment perspective Type de document : texte imprimé Auteurs : Yue Yu, Auteur ; Qingyong Sun, Auteur ; Yunhang Zeng, Auteur ; Yirui Lin, Auteur ; Ya-Nan Wang, Auteur ; Bi Shi, Auteur Année de publication : 2022 Article en page(s) : 14 p. Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Cuirs et peaux -- Industrie -- Aspect de l'environnement
Durée de vie (Ingénierie)
Environnement -- Etudes d'impact
Produits de nourriture du cuirIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : The environmental impacts of typical fatliquors were diagnosed by the life cycle assessment of industrial production and use (post-tanning) processes. Life cycle impact assessment and sensitivity analysis showed that fatliquor and fatliquoring operation were the major contributors to the environmental impacts of post-tanning because a large amount of fatliquors was consumed during fatliquoring operation. The environmental impacts of fatliquors decreased in the following order: chlorinated paraffin (CP) > sulfonated rape oil (SNR) > sulfated rape oil (SR) > phosphated rape oil (PR) > oxidized–sulfited rape oil (OSR). Sulfuric acid, fuming sulfuric acid, and chlorine used for fatliquor modification gave the main contribution to most impact categories for SR, SNR, and CP production, whereas rape oil contributed the most for PR and OSR production. OSR use process reduced the primary energy demand, abiotic depletion potential, and global warming potential by 38.5%, 56.0%, and 48.5%, respectively, compared with CP use process. These results suggested that biomass-derived fatliquors, especially oxidized–sulfited and phosphate modified fatiliquors, helped reduce the environmental burdens in leather manufacturing. Note de contenu : - MATERIALS AND METHODS : Materials - Goal and scope definition - Functional unit and system boundary - Life cycle inventory analysis - LCIA - Sensitivity and uncertainty analyses
- RESULTS AND DISCUSSION : Environmental impacts of fatliquor production process - Environmental impacts of fatliquor use process - Sensitivity and uncertainty analyses
- Table 1 Description of impact categories
- Table 2 Sensitivities of chemicals, energy, and effluents to impact categories for various fatliquor use processesDOI : https://doi.org/10.1186/s42825-022-00084-5 En ligne : https://link.springer.com/content/pdf/10.1186/s42825-022-00084-5.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37574
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 4 (Année 2022) . - 14 p.[article]Dissolution characteristics of protein in an ionic liquid / Xia Chunchun in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 97, N° 1 (01-02/2013)
[article]
Titre : Dissolution characteristics of protein in an ionic liquid Type de document : texte imprimé Auteurs : Xia Chunchun, Auteur ; Liu Shiyong, Auteur ; Chen Yi, Auteur ; Haojun Fan, Auteur ; Bi Shi, Auteur Année de publication : 2013 Article en page(s) : p. 11-17 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caséine
Collagène
GélatineLa gélatine est une substance solide translucide, transparente ou légèrement jaune, presque sans goût et sans odeur, obtenue par l'ébullition prolongée de tissus conjonctifs (peaux) ou d'os d'animaux (principalement porc, bœuf, poisson). Elle possède de nombreuses applications dans le domaine culinaire, la médecine, les industries agroalimentaire et pharmaceutique.
En matière d’étiquetage, la gélatine est considérée par la norme européenne3 comme un ingrédient et non pas comme un additif, c'est pourquoi elle n'a pas de numéro E. Hors Union européenne, elle est considérée par certains pays comme un additif gélifiant et on peut la trouver avec la dénomination E441.
La gélatine est un mélange de protéines obtenu par hydrolyse partielle du collagène extrait de la peau comme la peau de porc (cochon), des os, des cartilages, etc. Les liaisons moléculaires entre les fibres de collagène sont alors brisées. Mélangée à de l'eau, la gélatine forme un gel colloïdal semi-solide thermo-réversible (il fond lorsqu'il est chauffé et recouvre son aspect gélatineux lorsqu'il est refroidi). Sous forme déshydratée, par contre, la gélatine n'a pas de point de fusion et devient friable ou brûle quand elle est chauffée à trop haute températureLa rhéologie de la gélatine se caractérise par un comportement viscoélastique, et des contraintes trop élevées ou appliquées trop rapidement peuvent entraîner une rupture fragile (fracturation) ou ductile6. Le caractère plutôt élastique/fragile ou plutôt visqueux/ductile dépend de la concentration en gélatine de la solution aqueuse et de la température, ainsi que de la durée de la mise sous contrainteLes acides aminés constituant la gélatine sont : la glycine (21 %), la proline (12 %), l'hydroxyproline (12 %), l'acide glutamique (10 %), l'alanine (9 %), l'arginine (8 %), l'acide aspartique (6 %), la lysine (4 %), la sérine (4 %), la leucine (3 %), la valine, la phénylalanine et la thréonine (2 %), l'isoleucine et l'hydroxylysine (1 %), la méthionine et l'histidine (< 1 %) et la tyrosine (< 0,5 %). Ces valeurs sont variables (surtout pour les constituants minoritaires) et dépendent de la source de matériaux bruts et de la technique de préparation. La gélatine est constituée à environ 98-99 % (en poids sec) de protéines et contient 18 acides aminés dont huit des neuf acides aminés essentiels à l'Homme. Elle n'a qu'une relative valeur nutritionnelle du fait de l'absence de tryptophane et de son déficit en isoleucine, thréonine et méthionine; elle possède également un taux inhabituellement élevé d'acides aminés non essentiels, la glycine et la proline (qui sont produits par le corps humain). (Wikipedia)
Liquides ioniques
Protéines -- solubilité
solvantsIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : A new and highly efficient direct solvent, 1-butyl-3-methylimidazolium chloride ([BMIM]CI) was synthesized and used to dissolve three kinds of protein,gelatin, casein and skin collagen. The difference in solubility of three kinds of protein in [BMIM]CI was investigated. The result indicates that all proteins can be dissolved in the [BMIM]CI and the solubility is related to the temperature, high temperature is beneficial for improving the solubility. With the increase of concentration, the viscosity tends to increase. FTIR, XRD, TG were employed to characterize the structure and property changes of protein before and after dissolution, the results reveal that the chemical structure and thermal stability of proteins show almost no changes except for an obvious decrease of crystallinity of collagen, no chemical degradation can be observed which reveals that the dissolving process of protein in ionic liquid is purely physical process rather than a chemical one. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of [BMIM]CI - The dissolution of protein in [BMIM]CI - The viscosity of protein-[BMIM]CI in different mass fraction - Preparation of regenerated protein
- STRUCTURE AND PROPERTIES OF PROTEIN : FTIR - X-rai diffraction (XRD) - TGA
- RESULTS AND DISCUSSION : The solubility of protein in [BMIM]CI - The viscosity of protein-[BMIM]CI solution - FTIR spectra of protein - X-ray spectra of protein - The gel effect of different protein solution - TG spectra of protein - The possible dissolution mechanism of proteinEn ligne : https://drive.google.com/file/d/1WPXaLp0Xj8WvwTiEbm-wCbg1nUdqEMtX/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=17448
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 97, N° 1 (01-02/2013) . - p. 11-17[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 14631 - Périodique Bibliothèque principale Documentaires Disponible Diversified applications of tanning principles / Bi Shi in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CIII, N° 8 (08/2008)
PermalinkEffect of calcium in delimed hide on leather quality / Chao Lei in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXVIII, N° 3 (03/2023)
PermalinkEffect of cationic monomer structure on the aggregation behavior of amphoteric acrylic polymer around isoelectric point / Qijun Li in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 4 (Année 2022)
PermalinkEffect of co-combustion of tannery sludge and coal on the migration of Cr in the bottom ash / Jianfei Zhou in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 98, N° 1 (01-02/2014)
PermalinkEffect of histological feature of leather on acrylic resin retanning / Ying Song in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 102, N° 3 (05-06/2018)
PermalinkEffect of leather chemicals on Cr(III) removal from post tanning wastewater / Yuling Tang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIII, N° 3 (03/2018)
PermalinkEffect of molecular weight of acrylic resin retanning agent on properties of leather / Ying Song in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXII, N° 4 (04/2017)
PermalinkEffect of neutral salt on pickling and tanning - A study based on assembly behaviour of collagen / Wei Xiangyi in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 98, N° 1 (01-02/2014)
PermalinkEffect of pickling materials on leather quality from a hide surface charge perspective / Tianqi Yang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXVII, N° 7 (07/2022)
PermalinkEffect of prepolymerization of acrylic acid under high gravity on the properties of acrylic resin retanning agent / Xin Shu in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIV, N° 11 (11/2019)
PermalinkEffect of retanning agents on dry heat resistance of leathers / Chao Wu in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVIII, N° 8 (08/2013)
PermalinkEffect of sodium chloride on structure of collagen fiber network in pickling and tanning / Li Xinxin in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXI, N° 6 (06/2016)
PermalinkEffective component in a-amylase preparation for unhairing / Yunhang Zeng in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVIII, N° 3 (03/2013)
PermalinkEffects of bactericide-protease interactions on the protease-assisted soaking performance / Hao Liu in COLLAGEN AND LEATHER, Vol. 5 (2023)
PermalinkEffects of collagen fiber addition on the combustion and thermal stability of natural rubber / Weixing Xu in JOURNAL OF LEATHER SCIENCE AND ENGINEERING, Vol. 2 (Année 2020)
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