[article]
Titre : |
Formulation freedom : A new amine-functional dimer technology creates formulation freedom for high-end polyamide adhesives |
Type de document : |
texte imprimé |
Auteurs : |
Angela Smits, Auteur ; Hans Ridderikhoff, Auteur |
Année de publication : |
2011 |
Article en page(s) : |
p. 2931 |
Langues : |
Américain (ame) |
Catégories : |
Acides gras Adhésion Biomatériaux Cisaillement (mécanique) DiamineUne diamine est un type de polyamine contenant exactement deux groupes amine. Les diamines sont principalement utilisées comme monomères pour synthétiser des polyamides, des polyimides et des polyurées. La principale diamine produite est le 1,6-diaminohexane, précurseur du Nylon 6-6, suivie de l'éthylènediamine1. L'hydrazine (H2NNH2) n'est en général pas considérée comme une diamine puisque ce n'est ni une amine (pas de carbone), ni une dibase. Dimère, Acide Formulation (Génie chimique) Huiles et graisses Polyamide 66 Polypropylène Terpolymère acrylonitrile butadiène styrène
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Index. décimale : |
668.3 Adhésifs et produits semblables |
Résumé : |
Dimerized fatty acids have been used for many years in polyamides, polyesters, epoxy resins and amine curatives. They are obtained through the conversion of unsaturated fatty acids (from natural oil and fat) by a combination of pressure, temperature and catalysis, followed by purification processes.
Starting from the C18 fatty acids that nature typically provides, the dimer acid is a molecule with 36 carbon atoms, which makes it the longest dioic acid available. The benefits that the hydrocarbon character and non-crystallinity of these C36 diacids add to coatings and adhesives are mainly related to the low glass-transition temperature (Tg) and their hydrophobic nature. These properties induce flexibility, hydrolytic resistance, thermo-oxidative resistance, moisture repellency and adhesion to a wide range of substrates.
For several years, dimer fatty diols and a range of polyester polyol derivatives of dimerized fatty acids have been available for use in various polyurethane applications to enhance durability, flexibility, and hydrophobicity.* New bio-based, amine-functional building blocks have been developed that extend the range of acid- and hydroxyl-functional fatty dimers and derived polyesters (see Figure 1).** This new technology provides benefits in many applications. |
Note de contenu : |
- FIGURES : 1. Extended range of dimer functionalities - 2. Improved moisture repellency - 3. Lap shear adhesion to ABS - 4. Lap shear adhesion to nylon - 5. Lap shear adhesion to PP
- TABLES : 1. Thermal properties and shore D hardness - 2. Comparison of several diamines |
En ligne : |
http://www.adhesivesmag.com/articles/90826-formulation-freedom |
Format de la ressource électronique : |
Web |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25702 |
in ADHESIVES & SEALANTS INDUSTRY (ASI) > Vol. 18, N° 11 (11/2011) . - p. 2931
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