[article]
| Titre : |
A chrome-free combination tanning strategy : based on silicic acid and plant tannin |
| Type de document : |
texte imprimé |
| Auteurs : |
Zetian Zhang, Auteur ; Yang Liu, Auteur ; Junchao Wang, Auteur ; Taoling Xie, Auteur ; Liying Sun, Auteur ; Zhengjun Li, Auteur |
| Année de publication : |
2021 |
| Article en page(s) : |
13 p. |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Angle de contact
Caractérisation
Cuirs et peaux -- Propriétés mécaniques
Cuirs et peaux -- Propriétés physiques
Eaux usées -- Analyse
Humidité -- Absorption:Eau -- Absorption
Silicique, Acide
Stabilité au stockage
Stabilité thermique
Tanins végétaux
Tannage chrome free
Tannage combinéLe tannage combiné se dit des tannages qui allient deux familles ou genre de tannage pour obtenir un résultat additionnant les qualités complémentaires des tannins mis en œuvre par exemple Chrome-Végétal ou Chrome-Synthétique
Température de retrait
|
| Index. décimale : |
675.2 Préparation du cuir naturel. Tannage |
| Résumé : |
Silicic acid, commonly derived from cheap and easily available sodium silicate, has recently received great attention for application in leather industry to produce ecological leather with a cleaner approach. However, leather tanned with silicic acid alone is poor in storage stability, which limits its practical application in leather production. In this work, a new environment-friendly combination tannage based on silicic acid and plant tannin was developed to address this issue along with improving the comprehensive performances of leather. The obtained leather was characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy and so on. The results showed that compared with leather tanned with silicic acid alone, the leather tanned with this combination method possessed improved thermal stability, enhanced mechanical properties, acceptable softness, appropriate hydrophilicity, and especially enhanced storage stability. More importantly, the combination tanned leather with 1:1 of the mass ratio of silicic acid to vegetable tannin (composed of valonea extract and mimosa extract with the same weight) had more prominent comprehensive performances. In addition, the results demonstrated that hydrogen bonding played an important role in the combination tanning process. Furthermore, the hydrogen bonds generated between phenolic hydroxyl groups of polyphenols with silicon hydroxyl groups of silicic acid molecules inhibited the excessive condensation of Si-OH groups between themselves. Subsequently, the assessment of environmental impact revealed the value of BOD5/COD of the wastewater produced in this combination tanning process is more than 0.3, indicating the chrome-free combination tannage based on silicic acid and plant tannin was an environment-friendly tanning technology. These findings therefore indicated that a new chrome-free tanning method with silicon and biomass materials as main tanning agents has potential practical application prospect in leather production. |
| Note de contenu : |
- EXPERIMENTAL : Materials - Tanning process - Characterization
- RESULTS AND DISCUSSION : Thermal stability - Physical and mechanical properties - Water absorption and contact angle - Porous structure and micromorphology - Chemical structure characterization - Waste water assessment
- Table 1 : Silicic acid-vegetable tannin combination tanning process
- Table 2 : Shrinkage temperature of the samples
- Table 3 : Weight loss rate and Tmax of the samples at different storage time
- Table 4 : Analysis results of tannery wastewater |
| DOI : |
https://doi.org/10.1186/s42825-021-00058-z |
| En ligne : |
https://link.springer.com/content/pdf/10.1186/s42825-021-00058-z.pdf |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37541 |
in JOURNAL OF LEATHER SCIENCE AND ENGINEERING > Vol. 3 (Année 2021) . - 13 p.
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