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Effect of random and block copolypropylenes on structure and properties of uniaxially and biaxially oriented PP films / S. H. Tabatabaei in INTERNATIONAL POLYMER PROCESSING, Vol. XXVI, N° 1 (03/2011)
[article]
Titre : Effect of random and block copolypropylenes on structure and properties of uniaxially and biaxially oriented PP films Type de document : texte imprimé Auteurs : S. H. Tabatabaei, Auteur ; Abdellah Ajji, Auteur ; H. Ghasemi, Auteur Année de publication : 2011 Article en page(s) : p. 82-90 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse thermique
Copolymères séquencés
Films plastiques -- Propriétés mécaniques
Microscopie en lumière polarisée
Polypropylène
RhéologieIndex. décimale : 668.9 Polymères Résumé : Cast films of two linear polypropylenes (PP) having different molecular weights and their blends with 5, 20, and 40 wt.% random and block copolymers were prepared. The produced cast films were uniaxially and biaxially hot drawn at T = 155ºC using a biaxial stretcher and the changes in structure and morphology were examined and related to barrier, mechanical, haze, and tear properties. The crystallinity and crystal size distribution of the films were studied using differential scanning calorimetry (DSC). The uniaxial drawing generated a highly oriented fibrillar structure, resulting in an increase in the melting point of the films. A significant effect of the random copolymer on the size of crystallites was found using DSC, which was also confirmed from polarized optical microscopy (POM). Compared to the neat homopolymers, finer and numerous spherulites were observed for the blends. During drawing, the applied loads in the machine and transverse directions (MD and TD, respectively) were recorded and related to breaking up and tilting of the crystal lamellae. Adding the random copolymer appreciably decreased the haze of the films and hence drastically improved the clarity. Tensile properties and tear resistance of the cast films in MD and TD were evaluated. The addition of the random copolymer slightly reduced the Young modulus and tensile strength, but increased the elongation at break. A slight increase in the oxygen transmission rate (OTR) of the biaxially drawn films were observed by adding the copolymer. DOI : 10.3139/217.2404 En ligne : https://drive.google.com/file/d/1Wu4KRz4nPjaAKjV4g9qq6NTTQtVcnsce/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=11053
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Code-barres Cote Support Localisation Section Disponibilité 012871 - Périodique Bibliothèque principale Documentaires Disponible Effect of SEBS-g-MA on rheology, morphology and mechanical properties of PET/HDPE blends in INTERNATIONAL POLYMER PROCESSING, Vol. XXX, N° 1 (03/2015)
[article]
Titre : Effect of SEBS-g-MA on rheology, morphology and mechanical properties of PET/HDPE blends Type de document : texte imprimé Année de publication : 2015 Article en page(s) : p. 91-99 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Alliages polymères -- propriétés mécaniques
Anhydride maléique
Copolymère styrène-éthylène-butadiène
Morphologie (matériaux)
Polyéthylène haute densité
Polyéthylène téréphtalate
RhéologieIndex. décimale : 668.9 Polymères Résumé : The effects of additive styrene/ethylene-butylene/styrene copolymer grafted with maleic anhydride (SEBS-g-MA) were investigated on the rheology, morphology and mechanical properties of a polyethylene terephthalate (PET)/high density polyethylene (HDPE) blend. The ratio of the two components was changed in small increments to track phase inversion. The rheology measurements show that SEBS-g-MA acts differently on HDPE and PET, as different morphologies are formed due to viscosity ratio change. With the help of electron microscopy various phases after extrusion and after injection molding were revealed and identified. Because of the high viscosity of HDPE the co-continuous morphology was immediately formed when PET reached 30 vol%. The range of the co-continuous structure of the blend was wider when SEBS-g-MA was added, and the elongation at break also improved as additive content increased, without a significant strength decrease. The divergence of the mechanical properties from the theoretical value, i.e. the value determined by the mixing rule, can be explained by the changing phase structure. DOI : 10.3139/217.2970 En ligne : https://drive.google.com/file/d/1l51Lh2QBz_LqZLjHVg5JKn5gUWH09aS9/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=23426
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Code-barres Cote Support Localisation Section Disponibilité 17016 - Périodique Bibliothèque principale Documentaires Disponible Effect of sparse long-chain branching on the film-casting behavior for a series of well-defined HDPEs / C. D. McGrady in INTERNATIONAL POLYMER PROCESSING, Vol. XXIV, N° 5 (11/2009)
[article]
Titre : Effect of sparse long-chain branching on the film-casting behavior for a series of well-defined HDPEs Type de document : texte imprimé Auteurs : C. D. McGrady, Auteur ; C. W. Seay, Auteur ; D. G. Baird, Auteur Année de publication : 2009 Article en page(s) : p. 428-438 Note générale : Bibliogr. Langues : Anglais (eng) Index. décimale : 668.9 Polymères Résumé : The effect of sparse long chain branching, LCB, on the film-casting process is analyzed using a molecular model for the rheological behavior for a series of well-characterized, high-density polyethylene (HDPE) resins and a low-density polyethylene (LDPE) resin at various drawdown ratios. A full rheological characterization in both shear and shear-free flows is also presented. At low drawdown ratios, the LDPE exhibited the least degree of necking at distances less than the HDPE frostline. The sparsely-branched HDPE resins films had similar final film-widths that were larger than those of the linear HDPE. As the drawdown ratio was increased, film width profiles separated based on branching level. Small amounts of LCB were found to reduce the amount of necking at intermediate drawdown ratios. At higher drawdown ratios, the sparsely-branched HDPE resins of lower LCB content had film-widths that mimicked that of the linear HDPE, while the sparsely-branched HDPE resins of higher LCB content retained a larger film width. Molecular structural analysis via the Pom-Pom constitutive model suggested that branching that was distributed across a larger range of backbone lengths served to improve resistance to necking. As the drawdown ratio increased, the length of the backbones dominating the response decreased, so that the linear chains were controlling the necking behavior of the sparsely-branched resins of lower LCB content while remaining in the branched regime for higher LCB content HDPEs. Other processing variables such as shear viscosity magnitude, extrudate swell, and non-isothermal processing conditions were eliminated as contributing factors to the differences in the film width profile. DOI : 10.3139/217.2291 En ligne : https://drive.google.com/file/d/1Pb5a1KuePCmq0916W3J6UgkiB-hrU5Eu/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=6366
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Code-barres Cote Support Localisation Section Disponibilité 011702 - Périodique Bibliothèque principale Documentaires Disponible Effect of the chemical and morphological conditions of the die wall on the extrusion of linear polyolefins / H. J. Larrazabal in INTERNATIONAL POLYMER PROCESSING, Vol. XXI, N° 2 (05/2006)
[article]
Titre : Effect of the chemical and morphological conditions of the die wall on the extrusion of linear polyolefins Type de document : texte imprimé Auteurs : H. J. Larrazabal, Auteur ; John Vlachopoulos, Auteur ; Andrew N. Hrymak, Auteur Année de publication : 2006 Article en page(s) : p. 132-140 Note générale : Bibliogr. Langues : Anglais (eng) Index. décimale : 668.9 Polymères Résumé : This study examines the effects of average surface roughness and composition of the die wall surface on the critical shear stress for the onset of instabilities in die extrusion. Increasing the average surface roughness of the die wall from 0.1 to 15 lm produced an increase of the critical shear stress for the onset of flow instabilities by as much as 20% during the extrusion of HDPE. The surface of the extrudates obtained with dies having an average surface roughness greater than 5 lm showed lines and grooves along the direction of extrusion. Chrome-plated and nickel-plated dies showed an average 28% increase in the critical shear stress as compared to conventional steel dies. The chemical composition of uncoated steel dies wall surfaces, including the presence of iron oxide, did not affect the critical shear stress for the onset of sharkskin significantly regardless of the type of resin used. DOI : 10.3139/217.0067 En ligne : https://drive.google.com/file/d/1Yxiub4WHfm2v8T1JdUQyyg_03cF_TsAl/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=2906
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Code-barres Cote Support Localisation Section Disponibilité 004675 - Périodique Bibliothèque principale Documentaires Disponible Effect of the control of polymer flow in the vicinity of spinning nozzle on mechanical properties of poly(ethylene terephthalate) fibers / M. Masuda in INTERNATIONAL POLYMER PROCESSING, Vol. XXV, N° 2 (05/2010)
[article]
Titre : Effect of the control of polymer flow in the vicinity of spinning nozzle on mechanical properties of poly(ethylene terephthalate) fibers Type de document : texte imprimé Auteurs : M. Masuda, Auteur ; W. Takarada, Auteur ; Takeshi Kikutani, Auteur Année de publication : 2010 Article en page(s) : p. 159-169 Note générale : Bibliogr. Langues : Anglais (eng) Index. décimale : 668.9 Polymères Résumé : In the melt spinning of PET, effects of the variation of flow behavior in the vicinity of spinning nozzle on the mechanical properties of as-spun fibers and drawn fibers were investigated. The variation of flow behavior was introduced by the change of spinning nozzle diameter and by the irradiation of CO2 laser to the spin-line at a position immediately below the spinneret. The curve representing the correlation between strength and elongation at break of as-spun fibers shifted toward the upper-right direction by the applications of small diameter nozzle and laser irradiation, indicating that the toughness of as-spun fibers was improved. The two-stage continuous drawing of as-spun fibers with various draw ratios revealed that the correlation between strength and elongation of drawn fibers also shifted toward the upper-right direction by the application of small diameter nozzle and laser irradiation. In other words, improved toughness in the as-spun fibers was preserved in the drawn fibers. Accordingly, by the drawing of the as-spun fibers prepared by the combination of small-diameter nozzle and laser irradiation, high-strength and high-toughness PET fibers with the tensile strength of 1.68 GPa (12.1 cN/dtex) and the elongation at break of 9.1% was obtained. Numerical simulation of the melt spinning process incorporating the effects of nozzle diameter variation and laser irradiation heating indicated that the maximum Deborah number in the spin-line decreased by the applications of small diameter nozzle and laser irradiation heating. Accordingly, it was speculated that the variation of the state of molecular entanglement caused by the difference of polymer flow in the melt spinning process has significant effect on the mechanical properties of resultant fibers. Note de contenu : EXPERIMENTAL : Melt spinning process - Measurement of fiber properties - Numerical simulation of the melt spinning process.
RESULTS AND DISCUSSION : Structures and properties of as-spun fibers - Structure and properties of drawn fibersDOI : 10.3139/217.2330 En ligne : https://drive.google.com/file/d/16NB9uhQcItcg_weSFL4mE3JCiNRK28aa/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=9330
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Code-barres Cote Support Localisation Section Disponibilité 012158 - Périodique Bibliothèque principale Documentaires Disponible Effect of twin-screw extruder design and process conditions on ultrafine CaCO3 dispersion into PP / M. Bories in INTERNATIONAL POLYMER PROCESSING, Vol. XIV, N° 3 (09/1999)
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PermalinkElastomères - Butadiene - Nitrile acrylique - Classe 21 - Caractéristiques - Norme NF L 17-121A / Bureau de Normalisation de l'Aéronautique et de l'Espace / Issy-les-Moulineaux : BNAE (1985)
PermalinkElastomères - Butadiene - Nitrile acrylique - Classe 23 - Caractéristiques - Norme NF L 17-123A / Bureau de Normalisation de l'Aéronautique et de l'Espace / Issy-les-Moulineaux : BNAE (1985)
PermalinkElastomères - Butadiene - Nitrile acrylique - Classe 24 - Caractéristiques - Norme NF L 17-124A / Bureau de Normalisation de l'Aéronautique et de l'Espace / Issy-les-Moulineaux : BNAE (1985)
PermalinkElastomères fluorocarbones - Classe 60 - Caractéristiques - Norme NF L 17-160A / Bureau de Normalisation de l'Aéronautique et de l'Espace / Issy-les-Moulineaux : BNAE (1985)
PermalinkElastomères - Polychloroprène - Classe 31 - Caractéristiques - Norme NF L 17-131A / Bureau de Normalisation de l'Aéronautique et de l'Espace / Issy-les-Moulineaux : BNAE (1985)
PermalinkElastomères - Polychloroprène - Classe 32 - Caractéristiques - Norme NF L 17-132A / Bureau de Normalisation de l'Aéronautique et de l'Espace / Issy-les-Moulineaux : BNAE (1985)
PermalinkElastomères silicones - Classe 51 - Caractéristiques - Norme NF L 17-151 / Bureau de Normalisation de l'Aéronautique et de l'Espace / Issy-les-Moulineaux : BNAE (1985)
PermalinkElastomères silicones - Classe 53 - Caractéristiques - Norme NF L 17-153A / Bureau de Normalisation de l'Aéronautique et de l'Espace / Issy-les-Moulineaux : BNAE (1985)
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PermalinkExperimental investigation of the cooling flow in the film blowing process / F. Peters in INTERNATIONAL POLYMER PROCESSING, Vol. XXI, N° 3 (07/2006)
PermalinkExperimental investigation of the development of interfacial instabilities in two layer coextrusion dies / Rudy Valette in INTERNATIONAL POLYMER PROCESSING, Vol. XIX, N° 2 (06/2004)
PermalinkExperimental investigation of the effect of the bubble cone on the cooling jets used in the blown film manufacturing process / S. Li in INTERNATIONAL POLYMER PROCESSING, Vol. XX, N° 4 (12/2005)
PermalinkExperimental/numerical analysis of chaotic advection in a three-dimensional cavity flow / P. D. Anderson in INTERNATIONAL POLYMER PROCESSING, Vol. XXI, N° 4 (09/2006)
PermalinkExperimental studies and modeling of development of dispersion and fiber damage in continuous compounding / K. Shon in INTERNATIONAL POLYMER PROCESSING, Vol. XX, N° 3 (09/2005)
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