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Effect of nanoclay surface modifier chemical reactivity on morphology and rheological properties of PP/PA6 blend nanocomposite / G. R. Pircheraghi in INTERNATIONAL POLYMER PROCESSING, Vol. XXVIII, N° 4 (08/2013)
[article]
Titre : Effect of nanoclay surface modifier chemical reactivity on morphology and rheological properties of PP/PA6 blend nanocomposite Type de document : texte imprimé Auteurs : G. R. Pircheraghi, Auteur ; Hossein Nazockdast, Auteur ; M. M. Salehi, Auteur Année de publication : 2013 Article en page(s) : p. 354-360 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Alliages polymères
Argile
Cations
DiamineUne diamine est un type de polyamine contenant exactement deux groupes amine. Les diamines sont principalement utilisées comme monomères pour synthétiser des polyamides, des polyimides et des polyurées. La principale diamine produite est le 1,6-diaminohexane, précurseur du Nylon 6-6, suivie de l'éthylènediamine1. L'hydrazine (H2NNH2) n'est en général pas considérée comme une diamine puisque ce n'est ni une amine (pas de carbone), ni une dibase.
Morphologie (matériaux)
Nanoparticules
Polyamide 6
Polypropylène
Rhéologie
Traîtements de surfaceIndex. décimale : 668.4 Plastiques, vinyles Résumé : An attempt was made to explore the role of nanoclay surface modifier chemical reactivity on the morphology and the rheological properties of a polypropylene/polyamide6 (PP/PA6 75/25) nanocomposite blend. The Na-MMT surface was modified with two types of cations; a) diamine cation (D-Clay), and b) a combination of diamine and quaternary alkylammonium cations (A-Clay) via cation exchange reaction. The „nanocomposites samples compatibilized with PP-g-MA were prepared by melt compounding in an internal mixer. The XRD patterns indicated the intercalated/exfoliated microstructure for both nanocomposite samples. The SEM results showed a significant decreases in the PA6 droplet size, from 3.2?m of the simple blend to the 0.4?m in the D-Clay containing sample. Moreover, in the sample containing A-Clay the average droplet size was found to be 1?m. The D-Clay containing sample showed the rheological properties similar to a simple blend in high frequencies with a nonterminal be„havior in low frequencies storage modulus. This was explained by locating of D-Clay layers in the interphase and hence, significantly reducing the effective interfacial tension, ?/R. In contrast, the sample containing A-Clay showed an increased complex viscosity and storage modulus within a range of frequencies, which was attributed to presence of a large amount of A-Clay layers in the PP matrix. These types of nanoclay partitioning were explained by the possibility of chemical reaction between amine group of nanoclay surface modifier and maleic group of PP-g-MA compatibilizer or in-situ formed block copolymer. Consequently, the D-Clay layers bounded with PP-g-MA is preferentially located in the interphase, while, the non reactive nanoclay layers (containing alkylammonium cations) is dispersed in the PP matrix by assistance of PP-g-MA. These findings were also evidenced by TEM micrograph of both nanocomposite samples. Note de contenu : - EXPERIMENTAL/MODELING/SIMULATION : Materials - Na-MMT surface modification - Nanocomposite preparation
- CHARACTERIZATIONDOI : 10.3139/217.2680 En ligne : https://drive.google.com/file/d/1_UVNJId8hAvNEJDYdeG9PJdPTXD622Ly/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=19279
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Code-barres Cote Support Localisation Section Disponibilité 15396 - Périodique Bibliothèque principale Documentaires Disponible Effect of plasma treatment on the tribological and adhesion performance of a polymer coating deposited on different metallic substrates / Ahmed F. Abdelaal in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 6 (11/2022)
[article]
Titre : Effect of plasma treatment on the tribological and adhesion performance of a polymer coating deposited on different metallic substrates Type de document : texte imprimé Auteurs : Ahmed F. Abdelaal, Auteur ; M. Abdul Samad, Auteur ; Akeem Yusuf Adesina, Auteur ; M. M. A. Baig, Auteur Année de publication : 2022 Article en page(s) : p. 1673-1686 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Adhésion
Epaisseur -- Mesure
Métaux -- Revêtements poudre
Polyéthylène à ultra haut poids moléculaire
Revêtements organiques
Rugosité
Technique des plasmas
Traîtements de surface
Tribologie (technologie)
Usure (mécanique)Index. décimale : 667.9 Revêtements et enduits Résumé : Plasma treatment is a technique accepted universally for improving the adhesion of coatings to substrates because of its ease of use, environmental friendliness, and its adaptability. Hence, this research aims to further explore this technique and specifically investigate the effect of air–plasma treatment of different substrates (stainless steel, copper, brass, titanium, and aluminum) on the adhesion and tribological properties of an ultra-high molecular weight polyethylene polymer coating deposited on them. Several characterization techniques such as X-ray photoelectron spectroscopy, water contact angle, and roughness measurements are conducted to evaluate the surfaces before and after air–plasma treatment. Results showed that UHMWPE coating deposited on the plasma-treated stainless steel substrates demonstrated the best adhesion and tribological properties. This was attributed to the improved oxidation effect and the carbon cleaning effect of the plasma treatment on the stainless steel substrates as compared to other substrates. DOI : https://doi.org/10.1007/s11998-022-00639-5 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-022-00639-5.pdf?pdf=button% [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=38489
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Code-barres Cote Support Localisation Section Disponibilité 23804 - Périodique Bibliothèque principale Documentaires Disponible Effect of process conditions on the properties of surface-modified organic pigments encapsulated by UV-curable resins / Osama Abdel Hakeim in COLORATION TECHNOLOGY, Vol. 134, N° 1 (02/2018)
[article]
Titre : Effect of process conditions on the properties of surface-modified organic pigments encapsulated by UV-curable resins Type de document : texte imprimé Auteurs : Osama Abdel Hakeim, Auteur ; A. A. Arafa, Auteur ; M. K. Zahran, Auteur ; L. A. W. Abdou, Auteur Année de publication : 2018 Article en page(s) : p. 44-58 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Dispersions et suspensions
Encapsulation
Miniémulsions
Monomères
Pigments organiques
Polymères -- Effet du rayonnement ultraviolet
Traîtements de surfaceIndex. décimale : 667.3 Teinture et impression des tissus Résumé : Aqueous dispersions of nanoscale organic pigments were successfully prepared via ball milling and ultrasonication. The dispersed organic pigments were encapsulated into UV-curable resins via a mini-emulsion technique. Critical factors that affected the dispersion and encapsulation stability were investigated. The encapsulated organic pigments were characterised with transmission electron microscopy, thermogravimetric analyses, Fourier Transform-infrared spectra and zeta potential. The results clarified that the type of dispersing agent plays an important role in achieving maximal dispersion stability. Encapsulated organic pigments showed greater dispersion stability, and better wettability than the original pigments. Polyester tetra-acrylate oligomer can stabilise the mini-emulsion from diffusion degradation and inhibit phase separation with time. 1,6-Hexandiol dimethacrylate was the monomer of choice for ink-jet printing inks. Furthermore, it was found that monomer/oligomer and pigment/resin ratios were more influential and needed to be optimised. Thermal analysis, ultracentrifuge sedimentation and morphologies provided supporting evidence for the encapsulation of organic pigments into UV-curable resins. Note de contenu : - METHODS : Preparation of nanoscale organic pigment dispersions
- PREPARATION OF NANOPIGMENT DISPERSIONS : Effect of dispersing agent type - Effect of dispersing agent concentration
- ENCAPSULATION OF ORGANIC PIGMENT INTO UV-RESINS : Effect of encapsulation on pigment morphology and size distribution - Effect of encapsulation on dispersion stability - Effect of monomer type on encapsulation stability - Effect of monomer/oligomer ratio on encapsulation stability - Effect of pigment/resin ratio on encapsulation stability
- CHARACTERISATION OF ENCAPSULATED PIGMENTSDOI : 10.1111/cote.12318 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12318 Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=30126
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Code-barres Cote Support Localisation Section Disponibilité 19649 - Périodique Bibliothèque principale Documentaires Disponible Effect of surface treatments of titanium dioxide pigments on the cure of polyester/triglycidyl isocyanurate powder coatings / Stanley Affrossman in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 12, N° 6 (11/2015)
[article]
Titre : Effect of surface treatments of titanium dioxide pigments on the cure of polyester/triglycidyl isocyanurate powder coatings Type de document : texte imprimé Auteurs : Stanley Affrossman, Auteur ; Anthony McKee, Auteur ; Richard A. Pethrick, Auteur Année de publication : 2015 Article en page(s) : p. 1053-1064 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Analyse thermomécanique dynamique
Dioxyde de titane
Isocyanurate de triglycidyle
Pigments inorganiques
Polyesters
Revêtements poudre
Traîtements de surfaceIndex. décimale : 667.9 Revêtements et enduits Résumé : Titanium dioxide pigments will typically have an inorganic surface coating based on a blend of alumina and silica and an organic treatment. Both the organic and inorganic treatments can influence the cure characteristics of polyester powder coatings. This paper attempts to explore the connectivity between the nature of the coating and the cure behavior of a typical heat-cured epoxidized isocyanurate formulation. It is found that a high silica:alumina content in the inorganic pacification layer significantly retards the cure process, but is influenced by the nature of the organic treatment. The organic surface treatment may accelerate or retard the initial cure process and gelation times. Elemental analysis indicates that some of the pigments studied have a significantly higher zirconium content and exhibited enhanced cure rates compared with those with the lower zirconium content. This paper illustrates the potential effects of different grades of titanium dioxide on the cure of polyester powder coatings. Note de contenu : - EXPERIMENTAL : Materials - Titanium dioxide pigments - Surface area measurements - Powder coating production - Strathclyde curometer - Thermally stimulated discharge measurements - Dynamic mechanical thermal analysis
- RESULTS AND DISCUSSION : Curometer measurements - Effects of organic surface treatment of the pigment on the cure behavior - Trimethyol propane (TMP)- Triethylamine (TEA) - Trimethyol propane (TMP)/polyethylene wax - Modaflow effects on cure - Effect of pigment loading in a Modaflow-free coating - Effect of pigment loading with 1% Modaflow being present - Effect of pigment loading with 4% Modaflow being present - Conclusion from the curometer study - Thermally stimulated discharge spectroscopy TSD - Dynamic mechanical thermal analysisDOI : 10.1007/s11998-015-9697-9 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-015-9697-9.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=24957
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Code-barres Cote Support Localisation Section Disponibilité 17585 - Périodique Bibliothèque principale Documentaires Disponible Effect of TiO2 surface treatment on the mechanical properties of cured epoxy resin / Hamad Al-Turaif in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 8, N° 6 (11/2011)
[article]
Titre : Effect of TiO2 surface treatment on the mechanical properties of cured epoxy resin Type de document : texte imprimé Auteurs : Hamad Al-Turaif, Auteur Année de publication : 2011 Article en page(s) : p. 727-733 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Dioxyde de titane
Epoxydes
Particules (matières)
Polymères -- Propriétés mécaniques
Traîtements de surfaceIndex. décimale : 667.9 Revêtements et enduits Résumé : Mechanical properties of epoxy resin toughened with two different submicron particles of TiO2 at different weight fractions (1, 3, and 5%, respectively) were investigated. The first TiO2 particles are surface treated with Al2O3–SiO2, and the second are surface treated with Al2O3–ZrO2. The composites were characterized by tensile, flexural, pull off and abrasion tests, followed by X-ray photoelectron spectroscopy and scanning electron spectroscopy of the fracture surfaces. A small amount of TiO2 (~1%) submicron particles improves the flexural, abrasion and pull-off strengths, while amounts up to 5% significantly enhance tensile properties only. TiO2 particles surface treated with Al2O3–ZrO2 produce an epoxy composite with higher strength and weight loss but lower pull off strength and more brittle than that prepared with Al2O3–SiO2 particles. The TiO2 particles surface treated with Al2O3–SiO2 have a higher adherence to the epoxy composite matrix than the particles treated with Al2O3–ZrO2 as shown by scanning electron spectroscopy. Note de contenu : - Materials
- Sample preparation
- X-ray photoelectron spectroscopy
- Tensile test
- Flexural test
- Abrasion test
- Pull-off test
- Scanning electron microscopyDOI : 10.1007/s11998-011-9351-0 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-011-9351-0.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=12599
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Code-barres Cote Support Localisation Section Disponibilité 13484 - Périodique Bibliothèque principale Documentaires Disponible Effect on the corrosion resistance property of aluminum substrate by altering the wetting behavior / Poonam Chauhan in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 20, N° 5 (09/2023)
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PermalinkEffects of surface pretreatment and deposition conditions on the gas permeation properties and flexibility of Al2O3 films on polymer substrates by atomic layer deposition / Dung-Yue Su in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 16, N° 6 (11/2019)
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