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The effect of nano polysiloxanes on the permanence of feel touch of finished leathers / Evrim Kadioglu in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVII, N° 3 (03/2012)
[article]
Titre : The effect of nano polysiloxanes on the permanence of feel touch of finished leathers Type de document : texte imprimé Auteurs : Evrim Kadioglu, Auteur ; Gökhan Zengin, Auteur ; Altan Afsar, Auteur Année de publication : 2012 Article en page(s) : p. 92-101 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Analyse sensorielle
Cuir
Cuirs et peaux -- Finition
Evaluation
Nanoparticules
Particules (matières)
PolydiméthylsiloxaneLe polydiméthylsiloxane —[O-Si(CH3)2]n—, ou poly(diméthylsiloxane) selon la nomenclature systématique, communément appelé PDMS ou diméthicone, est un polymère organominéral de la famille des siloxanes souvent présent dans les shampoings. On l'y ajoute pour augmenter le volume des cheveux mais il peut également aller boucher les pores du cuir chevelu et rendre les cheveux gras. C'est une des raisons pour lesquelles se laver les cheveux tous les jours est très déconseillé avec un shampooing contenant des silicones.
Il existe également de l'amodiméthicone, qui est un dérivé du diméthicone.
Le polydiméthylsiloxane est un additif alimentaire (E900), utilisé comme antimoussant dans les boissons (Coca-Cola BlāK).
La chaîne de poly(diméthylsiloxane) forme également la structure de base des huiles et des caoutchoucs silicones.
Polymères en émulsion
ToucherIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Nano sized aminofunctional and micron sized dimethyl polysiloxane emulsions were applied to garment leathers as topcoats, to investigate the improvement on feel touch permanency of finished leathers. Fourier Transform Infrared Spectroscopy (FTIR) and particle size analysis of these two polysiloxane emulsions were carried out. The optimum application amount of emulsions was determined to be 15% based on the results of organoleptic evaluation and dynamic friction coefficients. After the application of nano and micron sized polysiloxane, three different accelerated ageing processes were applied to leathers under controlled temperature, humidity and UV light conditions. For determining the effect of the ageing processes on these polysiloxanes, dynamic friction coefficient measurements, ICP-OES and SEM analysis were carried out. The results revealed that nano sized polysiloxanes clearly improved the feel touch permanency of finished leathers in comparison to the leathers coated with micron sized polysiloxanes. Thereby, it was demonstrated that nano polysiloxanes can maintain the appearance and feel touch of leather product for a longer periods of time. Note de contenu : - EXPERIMENTAL : Materials - Finishing application - Particle size analysis - Fourier Transform Infrared Spectroscopy (FTIR) analysis - Organoleptic evaluation and dynamic friction coefficient measurements of feel touch of finished leathers - Accelerated ageing process - Rub fastness of aged leathers - Determination of silicone content of leather samples by inductively coupled plasma optical emission spectrometer (ICP-OES) - Scanning electron microscopy (SEM) microcraphs of leather samples - Statistical analysis
- RESULTS AND DISCUSSION : Particle size analysis - Fourier Transform Infrared Spectrophotometer (FTIR) analysis - Organoleptic evaluations and dynamic friction coefficient measurements - Determination of silicone contents of leathers by ICP OES - Scanning electron microscopy micrographs of leathers samplesEn ligne : https://drive.google.com/file/d/1wNFJN8UG4CQqaiq2Nmjfrwx6NGnn1ByB/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=14421
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CVII, N° 3 (03/2012) . - p. 92-101[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 13825 - Périodique Bibliothèque principale Documentaires Disponible 13828 - Périodique Bibliothèque principale Documentaires Disponible The effect of nanosilicates on the performance of polyethylene terephthalate films prepared by twin-screw extrusion / A. Ghanbari in INTERNATIONAL POLYMER PROCESSING, Vol. 36, N° 4 (2021)
[article]
Titre : The effect of nanosilicates on the performance of polyethylene terephthalate films prepared by twin-screw extrusion Type de document : texte imprimé Auteurs : A. Ghanbari, Auteur ; M.-C. Heuzey, Auteur ; Pierre J. Carreau, Auteur Année de publication : 2021 Article en page(s) : p. 358-366 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Composites -- Propriétés mécaniques
Composites -- Propriétés optiques
Composites -- Propriétés thermiques
Extrudeuse bi-vis
Matières plastiques -- Extrusion
Montmorillonite
Nanoparticules
Polyéthylène téréphtalate
SilicatesIndex. décimale : 668.4 Plastiques, vinyles Résumé : Polyethylene terephthalate (PET) films were prepared by cast extrusion using a twin-screw extruder with a severe screw profile. The effect of an organically modified montmorillonite on thermal, mechanical, optical, and barrier properties of the PET films were investigated. Morphological characterization of the nanocomposite films was performed by employing wide angle X-ray diffraction (WAXD), scanning electron microscopy (SEM), and transmission electron microscopy (TEM) followed by image analysis. The results unfold a mixed morphology for the nanocomposite films with more than 95% exfoliated and intercalated silicate layer structures, depending on the screw rotation speed. The remarkable dispersion of the organoclay particles at the nano-level is discussed in terms of solubility parameter and favorable interactions between PET macromolecules and organic modifier of the nanoclay. The crystal content of the nanocomposite films and their cold and hot crystallization temperatures confirmed the role of silicate nanolayers as a heterogeneous nucleating agent. While all nanocomposite films exhibit higher haze values in comparison to the neat PET samples, incorporation of 2 wt% nanoclay brought about 25% increase in tensile modulus and barrier properties. A range of screw rotation speeds with optimized properties in terms of haze, morphology, thermal, mechanical, and barrier properties is suggested. Note de contenu : - Materials
- Sample preparation
- Characterization
- Table 1 : DSC analysis results of the neat PET and nanocomposite films at various screw rotation speedsDOI : https://doi.org/10.1515/ipp-2020-4044 En ligne : https://drive.google.com/file/d/1UF1Q7xDZbldM1DEaaAvzkMvJsgouDJwq/view?usp=shari [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=36708
in INTERNATIONAL POLYMER PROCESSING > Vol. 36, N° 4 (2021) . - p. 358-366[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23734 - Périodique Bibliothèque principale Documentaires Disponible The effect of plasma functionalization on the print performance and time stability of graphite nanoplatelet electrically conducting inks / Andrew Claypole in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 1 (01/2021)
[article]
Titre : The effect of plasma functionalization on the print performance and time stability of graphite nanoplatelet electrically conducting inks Type de document : texte imprimé Auteurs : Andrew Claypole, Auteur ; James Claypole, Auteur ; Tim Claypole, Auteur ; David Gethin, Auteur ; Liam Kilduff, Auteur Année de publication : 2021 Article en page(s) : p. 193-203 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Conduction électrique
Encre d'imprimerie
Encre électronique
Graphite
Nanoparticules
Rhéologie
Surfaces fonctionnelles
Technique des plasmasIndex. décimale : 667.4 Encres Résumé : Carbon-based pastes and inks are used extensively in a wide range of printed electronics because of their widespread availability, electrical conductivity and low cost. Overcoming the inherent tendency of the nano-carbon to agglomerate to form a stable dispersion is necessary if these inks are to be taken from the lab scale to industrial production. Plasma functionalization of graphite nanoplatelets (GNP) adds functional groups to their surface to improve their interaction with the polymer resin. This offers an attractive method to overcome these problems when creating next generation inks. Both dynamic and oscillatory rheology were used to evaluate the stability of inks made with different loadings of functionalized and unfunctionalized GNP in a thin resin, typical of a production ink. The rheology and the printability tests showed the same level of dispersion and electrical performance had been achieved with both functionalized and unfunctionalized GNPs. The unfunctionalized GNPs agglomerate to form larger, lower aspect particles, reducing interparticle interactions and particle–medium interactions. Over a 12-week period, the viscosity, shear thinning behavior and viscoelastic properties of the unfunctionalized GNP inks fell, with decreases in viscosity at 1.17 s−1 of 24, 30, 39% for the ϕ = 0.071, 0.098, 0.127 GNP suspensions, respectively. However, the rheological properties of the functionalized GNP suspensions remained stable as the GNPs interacted better with the polymer in the resin to create a steric barrier which prevented the GNPs from approaching close enough for van der Waals forces to be effective. Note de contenu : - Materials and ink synthesis
- Methods
- Table 1 : Composition of GNP inks, where GNP (graphite nanoplatelets, TPU (thermoplastic polyurethane resin), DAA (diacetone alcohol)
- Table 2 : Three roll millling procedureDOI : https://doi.org/10.1007/s11998-020-00414-4 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-020-00414-4.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=35363
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 18, N° 1 (01/2021) . - p. 193-203[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 22605 - Périodique Bibliothèque principale Documentaires Disponible The effect of precipitated calcium carbonate nanoparticles in coatings / W. S. Wu in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 13, N° 2 (03/2016)
[article]
Titre : The effect of precipitated calcium carbonate nanoparticles in coatings Type de document : texte imprimé Auteurs : W. S. Wu, Auteur ; M. E. Queiroz, Auteur ; N. D. S. Mohallem, Auteur Année de publication : 2016 Article en page(s) : p. 277-286 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Carbonate de calcium Le carbonate de calcium (CaCO3) est composé d'un ion carbonate (CO32-) et d'un ion calcium (Ca2+), sa masse molaire est de 100,1 g/mole.
C'est le composant principal du calcaire et de la craie, mais également du marbre. C'est aussi le principal constituant des coquilles d'animaux marins, du corail et des escargots.
Mouillabilité
Nanoparticules
Revêtements -- Propriétés mécaniques:Peinture -- Propriétés mécaniques
Revêtements en bâtiment:Peinture en bâtiment
Revêtements en phase aqueuse -- Additifs:Peinture en phase aqueuse -- AdditifsIndex. décimale : 667.9 Revêtements et enduits Résumé : The insertion of nanoparticles into some industrial materials can give them special properties due to their high reactivity. These nanoparticles interact with other particles, changing and/or improving the final product properties. The aim of this work is to study the effects of nanoparticles of precipitated calcium carbonate (NPCC) with sizes between 40 and 60 nm on the characteristics of architectural paints when used as nanofillers together with micrometric fillers. For this study, two types of emulsion paints were prepared, one without and the other with NPCC. The emulsion paint prepared with NPCC showed better wet-state storage stability of the coating, greater abrasion resistance, lower roughness, and lower wettability than the conventional paint. DOI : 10.1007/s11998-015-9740-x En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-015-9740-x.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=26112
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Code-barres Cote Support Localisation Section Disponibilité 17962 - Périodique Bibliothèque principale Documentaires Disponible The effect of silica nanofiller on the physical and thermal characteristics of rubber-based composites / A. Chelli in INTERNATIONAL POLYMER PROCESSING, Vol. 36, N° 1 (2021)
[article]
Titre : The effect of silica nanofiller on the physical and thermal characteristics of rubber-based composites Type de document : texte imprimé Auteurs : A. Chelli, Auteur ; L. Hemmouche, Auteur ; H. Ait-Sadi, Auteur ; D. Trache, Auteur ; M. Benziane, Auteur ; R. Ait-Sadi, Auteur Année de publication : 2021 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse morphologique
Calorimétrie
Caoutchouc
Caoutchouc nitrile-butadiène
Caractérisation
Composites -- Propriétés mécaniques
Composites -- Propriétés thermiques
Dureté (matériaux)
Essais dynamiques
Formulation (Génie chimique)
Nanoparticules
SiliceLa silice est la forme naturelle du dioxyde de silicium (SiO2) qui entre dans la composition de nombreux minéraux.
La silice existe à l'état libre sous différentes formes cristallines ou amorphes et à l'état combiné dans les silicates, les groupes SiO2 étant alors liés à d'autres atomes (Al : Aluminium, Fe : Fer, Mg : Magnésium, Ca : Calcium, Na : Sodium, K : Potassium...).
Les silicates sont les constituants principaux du manteau et de l'écorce terrestre. La silice libre est également très abondante dans la nature, sous forme de quartz, de calcédoine et de terre de diatomée. La silice représente 60,6 % de la masse de la croûte terrestre continentale.Index. décimale : 668.4 Plastiques, vinyles Résumé : The use of nano composites in elastomer blends gives outstanding mechanical properties compared to the use of micro and macro composites, even with very low nano filler content. In this paper, we studied the influence of varying proportions of natural rubber (NR) and acrylonitrile butadiene rubber (NBR) reinforced with nano silica on the mechanical and thermal characteristics of the rubber. Mechanical characterizations were carried out with hardness, tensile strength, elongation at break, tear strength, modulus and toughness. For thermal analyses, we used differential scanning calorimetry (DSC) and Thermogravimetric Analysis (TGA). In most cases, the increase in the percentage of NBR with the presence of nano silica enhances hardness, modulus and toughness, however, it reduces tensile strength, tear strength and elongation at break. It was found that nano silica has a catalytic effect on the mixture, and NBR has a catalytic effect on the decomposition of NR. Note de contenu : - EXPERIMENTAL : Materials - Cure characteristics - Mechanical characterization - Morphological analysis - Thermal characterization
- RESULTS AND DISCUSSION : Mechanical properties of the rubber samples - Morphological analysis - Thermal proprieties of the rubber samples
- Table 1 : Compound formulations
- Table 2 : Properties of the rubber vulcanizates
- Table 3 : Temperature of onset of degradation and enthalpy of the samplesDOI : https://doi.org/10.1515/ipp-2020-3956 En ligne : https://drive.google.com/file/d/1e24UlfuwKoYy4IctQbcwb0VcWJfsyiTC/view?usp=shari [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=36347
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