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Effect of mixing conditions and polymer particle size on the properties of polypropylene/graphite nanoplatelets micromoldings / Renze Jiang in INTERNATIONAL POLYMER PROCESSING, Vol. 37, N° 4 (2022)
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Titre : Effect of mixing conditions and polymer particle size on the properties of polypropylene/graphite nanoplatelets micromoldings Type de document : texte imprimé Auteurs : Renze Jiang, Auteur ; Piyush Lashkari, Auteur ; Shengtai Zhou, Auteur ; Andrew N. Hrymak, Auteur Année de publication : 2022 Article en page(s) : p. 372-382 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Composites à fibres -- Moulage par micro-injection
Composites à fibres de graphite
Conducteurs organiques
Microstructures
Nanoparticules
Polypropylène
ThermocinétiqueIndex. décimale : 668.4 Plastiques, vinyles Résumé : In this study, properties of polypropylene/graphite nanoplatelets (PP/GNP) composites and corresponding micromoldings were systematically studied in terms of filler loading concentrations and mixing methods. PP of different forms, i.e., PP pellets and powders, were adopted to fabricate PP/GNP composites. Additionally, a comparative study of precoating GNP and PP powders using solvent-based solution blending and ultrasonication-assisted mixing was performed. Results showed that PP/GNP composites prepared using powder form PP resulted in at least one order of magnitude higher electrical conductivity than using pellet form PP and further reduced the percolation threshold from 12.5 to 10 wt%, which was related to the state of filler distribution within corresponding moldings. Morphology observations revealed that microparts prepared with powder-PP/GNP composites exhibited less preferential alignment of GNP particles along the flow direction when compared with those molded using pellet-PP/GNP counterparts, which was helpful in improving the overall electrical conductivity for PP/GNP micromoldings. Note de contenu : - EXPERIMENTAL SECTION : Materials - Sample preparation
- CHARACTERIZATION : Electrical conductivity - Morphology - Differential scanning calorimetry
- RESULTS AND DISCUSSION : Electrical conductivity - Morphology - Differential scanning calorimetry
- Table 1 : Characteristic Data from DSC Scans for PP/GNP feeds (top row) and µIM microparts (bottom row). Cycle 1: 1st heating cycle. Cycle 2: cooling cycle. Cycle 3: 2nd heating cycleDOI : https://doi.org/10.1515/ipp-2022-0004 En ligne : https://drive.google.com/file/d/1qw8Ibyf-E7sqUi1vjl_V9cgnu7o1L3jN/view?usp=shari [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37913
in INTERNATIONAL POLYMER PROCESSING > Vol. 37, N° 4 (2022) . - p. 372-382[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23739 - Périodique Bibliothèque principale Documentaires Disponible Effect of mutual interaction between high and low stereo-regularity components on structure formation in melt spinning process of isotactic polypropylene blend fibers / K. Kawai in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIII, N° 3 (07/2018)
[article]
Titre : Effect of mutual interaction between high and low stereo-regularity components on structure formation in melt spinning process of isotactic polypropylene blend fibers Type de document : texte imprimé Auteurs : K. Kawai, Auteur ; W. Takarada, Auteur ; Takeshi Kikutani Année de publication : 2018 Article en page(s) : p. 387-396 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse thermique
Diffraction des rayons X Ã grand angle
Extrusion filage
Mélanges de fibres
Mesures physiques
Polymères isotactiques
PolypropylèneIndex. décimale : 668.4 Plastiques, vinyles Résumé : Fiber formation behavior of the blend fibers consisting of two types of isotactic polypropylene (iPP), i. e. high stereo-regularity/high molecular weight iPP (HPP) and low stereo-regularity/low molecular weight iPP (LPP), was investigated. In the melt spinning of blend fibers of various HPP:LPP compositions, the spinnability was improved significantly not only by blending LPP into HPP but also by blending HPP into LPP. On-line diameter measurement of the spin-line revealed that the increase of LPP composition caused the shift of solidification point to downstream, indicating that the crystallization temperature was lowered. Wide-angle X-ray diffraction (WAXD) analysis of the as-spun fibers clarified that only the α-form crystal was formed, and the crystalline orientation increased with the increases of take-up velocity and HPP weight fraction. The crystallinities obtained from the WAXD patterns of the as-spun fibers of various HPP/LPP compositions prepared at the take-up velocity of 1 and 5 km/min were lower than the values estimated based on the rule of additivity, where the difference was more prominent for the 1 km/min fibers. Analyses of crystallinity through differential scanning calorimetry measurements also suggested the suppression of the crystallization of HPP in the HPP/LPP blend fibers. The thermal analyses basically clarified that in the melt spinning process of the blends of HPP and LPP, both components crystallized independently even though the two polymers are considered to be miscible in the molten state, however, detailed analyses of melting behavior of the as-spun fibers suggested the possibility of the formation of crystals with a certain level of mixing of the HPP and LPP molecules, i. e. the mixing of a certain amount of LPP molecules into the HPP crystals and also the mixing of a certain amount of HPP molecules into the LPP crystals. Note de contenu : - EXPERIMENTAL : Materials - Melt spinning - On-line diameter measurement - Wide-angle X-ray diffraction - Differential scanning calorimetry
- RESULTS AN DISCUSSION : Spinning behavior - WAXD analysis of as-spun fibers - Thermal analysis of as-spun fibersDOI : 10.3139/217.3576 En ligne : https://www.degruyter.com/document/doi/10.3139/217.3576/pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=30808
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Code-barres Cote Support Localisation Section Disponibilité 20044 - Périodique Bibliothèque principale Documentaires Disponible Effect of nanoclay addition on morphology and elastomeric properties of dynamically vulcanized natural rubber/polypropylene nanocomposites / Natinee Lopattananon in INTERNATIONAL POLYMER PROCESSING, Vol. XXIX, N° 3 (07/2014)
[article]
Titre : Effect of nanoclay addition on morphology and elastomeric properties of dynamically vulcanized natural rubber/polypropylene nanocomposites Type de document : texte imprimé Auteurs : Natinee Lopattananon, Auteur ; S. Tanglakwaraskul, Auteur ; A. Kaesaman, Auteur ; M. Seadan, Auteur ; T. Sakai, Auteur Année de publication : 2014 Article en page(s) : p. 332-341 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Alliages polymères -- propriétés mécaniques
Argile
Caoutchouc
Matériaux hybrides
Mélanges-maîtres (chimie)
Montmorillonite
Nanoparticules
Polypropylène
VulcanisationIndex. décimale : 668.4 Plastiques, vinyles Résumé : Thermoplastic vulcanizate (TPV) nanocomposites based on 60/40 (%wt) natural rubber (NR)/polypropylene (PP) blends were prepared by melt blending in an internal mixer. Sodium montmorillonite (Na-MMT) was first added in natural rubber latex to obtain natural rubber/clay masterbatch, which was subsequently dynamically crosslinked while mixing with molten PP. The effect of Na-MMT content were examined concerning elastomeric properties of NR/PP blends dynamically vulcanized using phenolic resin as a curing agent. Morphology characterization observed by X-ray diffraction (XRD), transmission electron microscopy (TEM) and 3D microfocus X-ray computerized tomography showed that the dynamic vulcanization with nanoclay addition changed the blend morphology from a co-continuous-like structure to droplet-like phase one, and the clay remained within NR phase in intercalated and aggregated forms. Furthermore, the presence of clay induced the decrease in crosslinking of NR, but promoted the mixing between NR and PP during dynamic vulcanization. This suggested that nanoclay worked as a kind of morphology modifier during dynamic vulcanization. The addition of clay marginally enhanced the 100 % modulus and tensile strength, but led to the decrease of the elongation at break. The optimal level of tensile strength improvement was obtained with loading of 5 phr clay. The permanent set of the NR/PP/Clay TPV nanocomposites was well maintained at the acceptable level as elastomer. The resistances to oil and heat were improved with incorporation of clay, proportional to clay loading. The experimental results indicated that the nanoclay had a positive effect on improving the 60/40 NR/PP blend morphology, which provided a little benefit to strength of the TPVs. However, the addition of nanoclay offered an improvement in oil and thermal resistances due to a combined effect of the clay dispersion and improved morphology of NR and PP blends. Note de contenu : - EXPERIMENTAL : Materials - Preparation of TPV/clay nanocomposites - Characterization
- RESULTS AND DISCUSSION : Dispersion of clay - Morphology of TPV/clay nanocomposites - Gel content of TPV/clay nanocomposites - Mechanical properties - Thermal stability - Oil swellingDOI : 10.3139/217.2935 En ligne : https://drive.google.com/file/d/1HcHWGqwmS10eZ3v8TTRo7EW18iPCsGxZ/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=21730
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Code-barres Cote Support Localisation Section Disponibilité 16404 - Périodique Bibliothèque principale Documentaires Disponible Effect of nanoclay surface modifier chemical reactivity on morphology and rheological properties of PP/PA6 blend nanocomposite / G. R. Pircheraghi in INTERNATIONAL POLYMER PROCESSING, Vol. XXVIII, N° 4 (08/2013)
[article]
Titre : Effect of nanoclay surface modifier chemical reactivity on morphology and rheological properties of PP/PA6 blend nanocomposite Type de document : texte imprimé Auteurs : G. R. Pircheraghi, Auteur ; Hossein Nazockdast, Auteur ; M. M. Salehi, Auteur Année de publication : 2013 Article en page(s) : p. 354-360 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Alliages polymères
Argile
Cations
DiamineUne diamine est un type de polyamine contenant exactement deux groupes amine. Les diamines sont principalement utilisées comme monomères pour synthétiser des polyamides, des polyimides et des polyurées. La principale diamine produite est le 1,6-diaminohexane, précurseur du Nylon 6-6, suivie de l'éthylènediamine1. L'hydrazine (H2NNH2) n'est en général pas considérée comme une diamine puisque ce n'est ni une amine (pas de carbone), ni une dibase.
Morphologie (matériaux)
Nanoparticules
Polyamide 6
Polypropylène
Rhéologie
Traîtements de surfaceIndex. décimale : 668.4 Plastiques, vinyles Résumé : An attempt was made to explore the role of nanoclay surface modifier chemical reactivity on the morphology and the rheological properties of a polypropylene/polyamide6 (PP/PA6 75/25) nanocomposite blend. The Na-MMT surface was modified with two types of cations; a) diamine cation (D-Clay), and b) a combination of diamine and quaternary alkylammonium cations (A-Clay) via cation exchange reaction. The „nanocomposites samples compatibilized with PP-g-MA were prepared by melt compounding in an internal mixer. The XRD patterns indicated the intercalated/exfoliated microstructure for both nanocomposite samples. The SEM results showed a significant decreases in the PA6 droplet size, from 3.2?m of the simple blend to the 0.4?m in the D-Clay containing sample. Moreover, in the sample containing A-Clay the average droplet size was found to be 1?m. The D-Clay containing sample showed the rheological properties similar to a simple blend in high frequencies with a nonterminal be„havior in low frequencies storage modulus. This was explained by locating of D-Clay layers in the interphase and hence, significantly reducing the effective interfacial tension, ?/R. In contrast, the sample containing A-Clay showed an increased complex viscosity and storage modulus within a range of frequencies, which was attributed to presence of a large amount of A-Clay layers in the PP matrix. These types of nanoclay partitioning were explained by the possibility of chemical reaction between amine group of nanoclay surface modifier and maleic group of PP-g-MA compatibilizer or in-situ formed block copolymer. Consequently, the D-Clay layers bounded with PP-g-MA is preferentially located in the interphase, while, the non reactive nanoclay layers (containing alkylammonium cations) is dispersed in the PP matrix by assistance of PP-g-MA. These findings were also evidenced by TEM micrograph of both nanocomposite samples. Note de contenu : - EXPERIMENTAL/MODELING/SIMULATION : Materials - Na-MMT surface modification - Nanocomposite preparation
- CHARACTERIZATIONDOI : 10.3139/217.2680 En ligne : https://drive.google.com/file/d/1_UVNJId8hAvNEJDYdeG9PJdPTXD622Ly/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=19279
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Code-barres Cote Support Localisation Section Disponibilité 15396 - Périodique Bibliothèque principale Documentaires Disponible Effect of pre-molding process and additive of injection molded wood/PP composites / Y. Yu in INTERNATIONAL POLYMER PROCESSING, Vol. XXIX, N° 4 (08/2014)
[article]
Titre : Effect of pre-molding process and additive of injection molded wood/PP composites Type de document : texte imprimé Auteurs : Y. Yu, Auteur ; Q. Y. Yang, Auteur ; M. Nomura, Auteur ; H. Hamada, Auteur Année de publication : 2014 Article en page(s) : p. 440-446 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Bois
Composites à fibres -- Additifs
Composites à fibres végétales -- Moulage par injection
Composites à fibres végétales -- Propriétés mécaniques
Flexion trois points
Impact (mécanique)
Morphologie (matériaux)
Polyalphaoléfine
Polypropylène
Poudres
Traction (mécanique)Index. décimale : 668.4 Plastiques, vinyles Résumé : Injection molded composites are becoming more widespread in recent years because of their high quality and low cost. However, compared to synthetic fiber composites, it is difficult to maintain a constant fiber volume fraction and uniform distribution for natural fiber composites during the direct injection process. This is mainly because natural fibers are more easily twisted during feeding into the injection machine, owing to their rough surfaces. These feeding difficulties are particularly due to the low bulk densities of natural fibers, especially natural fillers. Additional challenges to the injection process include the concentration and, especially for natural filler reinforced composite. To address these problems, the current study investigates the mechanical properties and morphologies of polypropylene (PP) reinforced by wood powder. Two pre-molding processes, dry-blending and compounding, were compared, and the effects of an additive (crystalline polyalpha olefin (CPAO)) on the mechanical properties of the wood/PP composites were investigated. This investigation is based on tensile, three point bending, and Izod impact tests, and scanning electron microscope (SEM) observation of the fracture surfaces. Results indicated that the composites molded through compounding exhibited better mechanical properties than the samples molded through the direct dry-blending process. In addition, the tensile and bending properties of the composites produced through compounding were found to increase with the addition of CPAO content, because of improved wood powder distribution in the PP matrix. Note de contenu : - EXPERIMENTAL : Materials - Dry-blending and compounding - Injection molding - Tensile test - Three point bending test - Izod impact test - Etching process - Scanning electron microscopy (SEM)
- EXPERIMENTAL RESULTS AND DISCUSSION : Particle size distribution of wood powder - Effect of pre-molding process (dry-blending and compounding) - Effect of CPAO contentDOI : 10.3139/217.2826 En ligne : https://drive.google.com/file/d/1P3Hu1gTgnzQJFtF2RLYJWGwP7EzDsJci/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=21822
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Code-barres Cote Support Localisation Section Disponibilité 16454 - Périodique Bibliothèque principale Documentaires Disponible Effect of process parameters on mechanical properties of rice husk polypropylene composites / V. Kumar in INTERNATIONAL POLYMER PROCESSING, Vol. XXV, N° 4 (09/2010)
PermalinkEffect of process parameters on shear layer thickness in injection molded short-glass fiber reinforced polypropylene / Mirigul Altan in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIII, N° 5 (11/2018)
PermalinkEffect of random and block copolypropylenes on structure and properties of uniaxially and biaxially oriented PP films / S. H. Tabatabaei in INTERNATIONAL POLYMER PROCESSING, Vol. XXVI, N° 1 (03/2011)
PermalinkEffect of spin-draw rate and stretching ratio on polypropylene hollow fiber membrane made by melt-spinning and stretching method / F.-J. Wei in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIII, N° 1 (03/2018)
PermalinkEffect of the amount of oxazoline compatibilizer on the mechanical properties of liquid crystalline polymer/polypropylene blends / Shogo Takasuka in INTERNATIONAL POLYMER PROCESSING, Vol. 37, N° 1 (2022)
PermalinkEffect of the mandrel rotation speed and inner wall cooling Rate on the performance and structure of polypropylene block-copolymer pipe / R. Han in INTERNATIONAL POLYMER PROCESSING, Vol. XXVIII, N° 5 (11/2013)
PermalinkEffects of cooling ways on the structure of polypropylene hollow fiber membranes prepared by stretching / D.-J. Luo in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIV, N° 2 (05/2019)
PermalinkEffects of molecular structure on dyeing performance and colour fastness of yellow dyestuffs applied to polypropylene fibres in supercritical carbon dioxide / Keisuke Miyazaki in COLORATION TECHNOLOGY, Vol. 128, N° 1 (2012)
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