| Titre : |
An acrylic resin retanning agent with a reinforcing effect - Synthesised by hihg solids content microemulsion copolymerization |
| Type de document : |
texte imprimé |
| Auteurs : |
Wang Xuechuan, Auteur ; An Huari, Auteur ; Sun Ming, Auteur ; Luo Yanhong, Auteur ; Feng Jianyan, Auteur |
| Année de publication : |
2005 |
| Article en page(s) : |
p. 164-168 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Agents de tannage
Caractérisation
Copolymères en émulsion
Croûte (cuir)On entend par "cuir en croûte" des cuirs ayant subi les opérations jusqu'au tannage, à l'exclusion de toute opération de corroyage ou de finissage, mais qui, par opposition aux wet-blue ont été séchés.
Cuirs et peaux -- Propriétés mécaniques
Cuirs et peaux de porcs
Granulométrie laser
Haut extrait sec
Latex
Microémulsions
Polyacryliques
Polymérisation en émulsion
Retannage
Tannage organique
Wet-blue (tannage)Peau tannée au chrome (le chrome donne une couleur bleue)
|
| Index. décimale : |
675.2 Préparation du cuir naturel. Tannage |
| Résumé : |
An acrylic resin nano-size latex whose colloidal particle size was about 20nm and solids content about 25% was prepared by a high solids content semicontinuous microemulsion copolymerization. The experimental product was employed in retanning drop [bottom] splits of pigs aiming to reinforce the leather. The offer of cross-linking agent and functional monomer were varied in the copolymerization experiment and their effect on the reinforcing function was investigated. The effect of colloidal particle size and dosage of nano-size latex on the reinforcing function also was verified.
The particle size of the latex was tested with a laser particle size analyzer, and the composition of the copolymer was analyzed by infrared spectrometry. Multifunction material test equipment was used in the physical testing of the retanned leather.
The result of the experiment showed: when the dosage of divinylbenzene (DVB) was 1.2% and the dosage of acrylic acid (AA) 0.8%, the reinforcing performance was the highest. When the colloidal particle size decreased from 64.2nm to 16.3nm, the reinforcing effect was also enhanced.
The tensile strength increased by 68%, and the tear strength improved 44% after the drop splits of pigs were retanned with 2% acrylic resin nano-size latex (with respect to the shaved wet blue weight). The effect of the dosage of sodium lauryl sulphate (SLS), n-pentanol (PA), ammonium persulfate (ASP) and AA on the colloidal particle size was also studied. |
| Note de contenu : |
- EXPERIMENTAL DETAILS : Materials - Synthesis
- APPLICATION OF NANO-SIZE LATEX IN RETANNING CHROME TANNED PIG DROP SPLITS : Characterization
- RESULTS AND DISCUSSION : Colloidal particle size of the microemulsion copolymer - The IR spectra of BA/MMA/DVB copolymers prepared by microemulsion copolymerization - The effect of functional monomer on the reinforcing function - The effect of cross-linking agent on the reinforcing function - The effect of colloidal particle size on the reinforcing function - The relationship between dosage of retanning agent and reinforcing effect
- Table 1 : Recipes used in the series of experiments and average particle size of synthesized latexes
- Table 2 : Process details for the retanning applications of nano-size latex on wet blue pig drop splits |
| En ligne : |
https://drive.google.com/file/d/1GoIENUWkqhu85g-LTxdP-0cZzXD-IvPo/view?usp=share [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39249 |
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 89, N° 4 (07-08/2005) . - p. 164-168
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