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INTERNATIONAL POLYMER PROCESSING / Polymer Processing Society . Vol. XXXI, N° 1Mention de date : 03/2016Paru le : 10/03/2016 |
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Ajouter le résultat dans votre panierInfluence of melt-mixing process conditions on mechanical performance of organoclay/fluoroelastomer nanocomposites / M. Khajehpour in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Influence of melt-mixing process conditions on mechanical performance of organoclay/fluoroelastomer nanocomposites Type de document : texte imprimé Auteurs : M. Khajehpour, Auteur ; Uttandaraman Sundaraj, Auteur Année de publication : 2016 Article en page(s) : p. 2-10 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Allongement (mécanique)
Composites -- Propriétés mécaniques
Composites -- Propriétés thermiques
Essais dynamiques
Etat fondu (matériaux)
Fluoroélastomères
Matériaux hybrides
Mélanges (chimie)
Montmorillonite
Réticulation (polymérisation)
Rhéologie
Stabilité thermique
Traction (mécanique)Index. décimale : 668.4 Plastiques, vinyles Résumé : In this study, Cloisite 20A, an organically modified Montmorillonite (Mnt), has been incorporated into Fluoroelastomer (FKM) through melt intercalation technique. Since the nanocomposite preparation method and conditions, and consequently, the resulting morphology play a critical role in the final properties, the effect of different process conditions such as time, temperature, and shear rate on the vulcanization, thermal and mechanical properties have been investigated. The morphology of nanocomposites, prepared at different melt-mixing conditions, was studied using X-ray diffraction (XRD). Rheological, thermal and mechanical behaviors were investigated by moving die rheometer (MDR), thermal gravimetric analysis (TGA), and tensile strength test respectively. Also, the crosslinking density has been measured for the nanocomposites. The best mechanical performance of clay/FKM nanocomposites was attained by optimization of the melt-mixing conditions. We achieved the following enhancements for FKM by clay incorporation: enhancement of tensile strength up to 70 %; elongation up to 94 %; and modulus up to 405 %. Process temperature was found to have a critical role in the final properties of the nanocomposites, while mixing residual time and shear rate had a moderate effect. The most desirable properties and curing behaviors, including highest maximum torques, cure rates, crosslinking densities, fast crosslinking kinetics, high intercalation and best improved tensile strengths, resulted with specific combination of melt-mixing parameters. Note de contenu : - EXPERIMENTAL : Materials - Clay/FKM nanocomposite preparation - Nanocomposite characterization - Crosslinking density measurement
- RESULTS AND DISCUSSION : Thermal stability - Morphology - Rheometry and crosslinking measurement - Mechanical propertiesDOI : 10.3139/217.3031 En ligne : https://drive.google.com/file/d/1J4A2CaajeU3z0mtGXbHLT5zFY2seSGER/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25760
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Melt creep recovery of polyamide 6 and polypropylene nanocomposites blended with layered silicate / G.-G. Lin in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Melt creep recovery of polyamide 6 and polypropylene nanocomposites blended with layered silicate Type de document : texte imprimé Auteurs : G.-G. Lin, Auteur ; Y.-F. Jang Jian, Auteur ; C.-T. Huang, Auteur Année de publication : 2016 Article en page(s) : p. 11-17 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Argile
Composites -- Fluage
Essais dynamiques
Etat fondu (matériaux)
Matériaux hybrides
Montmorillonite
Polyamide 6
Polypropylène
Rhéologie
SilicatesIndex. décimale : 668.4 Plastiques, vinyles Résumé : Nanocomposites of polyamide six (PA6) reinforced with organoclay were prepared in this study through melt mixing. The blended montmorillonite clay was organically modified with octadecylamine. The loadings of the clay were 1 wt%, 5 wt%, and 9 wt%. The obtained nanocomposites exhibited exfoliation (1 wt%) and intercalation (other compositions) structures. By contrast, if they were mixed with unmodified clay, the PA6 molecules could not enter the silicate interlayer. For polypropylene (PP), forming nanocomposites with organoclay was difficult but made feasible by incorporating the maleated PP. The results of dynamic rheological tests demonstrated that an end-tethered storage modulus was observed for the PA6/organoclay nanocomposites. However, the PP/organoclay exhibited terminal-zone behavior. In addition, the shear creep recovery was conducted on the molten polymer composites. The results indicated that the molten PA6/organoclay nanocomposite exhibited a higher creep-recovery ratio, a measure of the elastic property, than that of pristine PA6. The time constant in the Voigt-Kelvin constitutive model for the PA6/organoclay melts was lower than that of the pristine PA6 due to the superior elastic moduli, because it is defined as the ratio of viscosity to the modulus. However, the recovery ratios for most of the PP nanocomposites were found to be less than that for the pristine PP, indicating the fair reinforcing effect of the organoclay. Note de contenu : - EXPERIMENTAL : Materials - Clay modification - Preparing nanocomposites - Structure characterization - Rheological measurement - Constitutive model
- RESULTS AND DISCUSSION : X-ray diffraction patterns - Dynamic testing - Creep recoveryDOI : 10.3139/217.3041 En ligne : https://drive.google.com/file/d/1Hu1p5PTOyzSpFifWGlANMWkM2kqBy5SO/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25761
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Dielectric behavior of OPEFB reinforced polycaprolactone composites at X-band frequence / Ahmad Fahad in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Dielectric behavior of OPEFB reinforced polycaprolactone composites at X-band frequence Type de document : texte imprimé Auteurs : Ahmad Fahad, Auteur ; Z. Abbas, Auteur ; S. J. Obaiys, Auteur ; N. Ibrahim, Auteur ; A. Yakubu, Auteur Année de publication : 2016 Article en page(s) : p. 18-25 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Charges (matériaux)
Composites à fibres courtes
Diélectriques
Etat fondu (matériaux)
Huile de palme et constituants
Micro-ondes
Morphologie (matériaux)
Poly-e-caprolactoneIndex. décimale : 668.4 Plastiques, vinyles Résumé : Short fibres are often used as reinforcing materials with thermoplastic polymers to improve the dielectric properties of the composites. In this work, the effects of oil palm empty fruit bunch (OPEFB)-fibre loading on polycaprolactone (PCL) polymer were extensively studied. The synthesis of OPEFB-PCL composites were prepared via melt blend method. Theoretical and experimental analysis of electromagnetic (EMI) propagation, absorption and shielding effectiveness (SE) properties of the composite were also studied. The magnitudes of S-parameters for OPEFB fiber-reinforced PCL composites with different percentages of filler were measured by a rectangular waveguide connected with a microwave vector network analyzer (VNA) at (8 – 12) GHz frequency. Whilst the dielectric properties were studied using an open ended coaxial probe. The morphological characterization of the OPEFB-PCL composite was carried out using X-ray diffraction and scanning electron microscopy (SEM). This work showed that XRD profile patterns slightly changed duo to the filler loading increment which result a reduction in both dielectric constant and loss factor. However, the relative permittivity of pure oil palm fibre and PCL was measured as (1.8-j*0.08) and (2.929-j*0.3242) respectively. In addition, the composition of 12.5 wt% filler gave the highest dielectric constant and loss factor values. However, the reflection loss increases to filler content increments at the maximum frequency of 12 GHz. The excellent behavior of these polymer composites makes them superior nominees for microwave low absorption materials. Note de contenu : - THEORY : Transmission line method - Theory of network analyzers
- EXPERIMENTAL DETAILS : Preparation of OPEFB fibre - Preparation of OPEFB-PCL composites - Preparation of test sample - Measurements and characterization - S-parameter measurement
- RESULTS AND DISCUSSION : Morphology - Microwave resultsDOI : 10.3139/217.3069 En ligne : https://drive.google.com/file/d/1ZV4HwwyeHXgQBYiB6UnynFGgG4EQc2bo/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25762
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Numerical modeling of bubble growth inmicrocellular polypropylene produced in a core-back injection process using chemical blowing agents / José Antonio Reglero Ruiz in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Numerical modeling of bubble growth inmicrocellular polypropylene produced in a core-back injection process using chemical blowing agents Type de document : texte imprimé Auteurs : José Antonio Reglero Ruiz, Auteur ; M. Vincent, Auteur ; Jean-François Agassant, Auteur Année de publication : 2016 Article en page(s) : p. 26-36 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Agents d'expansion (chimie)
Analyse numérique
Matières plastiques -- Moulage par injection microcellulaire
Modèles numériques
Mousses plastiques -- Moulage par injection
PolypropylèneIndex. décimale : 668.4 Plastiques, vinyles Résumé : A core-back polypropylene foaming injection process using chemical blowing agents (CBA) has been studied. First, injection tests were carried out with two different CBAs and the different morphologies of the obtained samples have been analyzed. Structural parameters such as cell density and average radius size were calculated. Then, a bubble growth model was developed to predict the foaming development during the process, controlled by the depressurization of the mold cavity during the short core-back opening coupled with the evolution of the temperature during core-back and subsequent cooling. A good agreement is found between theoretical predictions and experimental results. DOI : 10.3139/217.3129 En ligne : https://drive.google.com/file/d/1olDU5r32PXtyiuzJRC4vrDlnJgdL1X-D/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25766
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Numerical simulation and experimental validation of granite powder filled jute epoxy composite for slurry jet erosive wear / M. J. Pawar in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Numerical simulation and experimental validation of granite powder filled jute epoxy composite for slurry jet erosive wear Type de document : texte imprimé Auteurs : M. J. Pawar, Auteur ; Amar Patnaik, Auteur ; R. Nagar, Auteur Année de publication : 2016 Article en page(s) : p. 37-50 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse de variance En statistique, l'analyse de la variance (terme souvent abrégé par le terme anglais ANOVA : ANalysis Of VAriance) est un ensemble de modèles statistiques utilisés pour vérifier si les moyennes des groupes proviennent d'une même population. Les groupes correspondent aux modalités d'une variable qualitative (p. ex. variable : traitement; modalités : programme d'entrainement sportif, suppléments alimentaires ; placebo) et les moyennes sont calculés à partir d'une variable continue (p. ex. gain musculaire).
Ce test s'applique lorsque l'on mesure une ou plusieurs variables explicatives catégorielles (appelées alors facteurs de variabilité, leurs différentes modalités étant parfois appelées "niveaux") qui ont de l'influence sur la loi d'une variable continue à expliquer. On parle d'analyse à un facteur lorsque l'analyse porte sur un modèle décrit par un seul facteur de variabilité, d'analyse à deux facteurs ou d'analyse multifactorielle sinon. (Wikipedia)
Analyse numérique
Charges (matériaux)
Composites à fibres végétales
Epoxydes
Granite
Morphologie (matériaux)
Plan d'expérience
Surfaces -- Analyse
Taguchi, Méthodes de (Contrôle de qualité)
Usure (mécanique)Index. décimale : 668.4 Plastiques, vinyles Résumé : In the polymer composite the benefits of utilizing the excellent wear resisting properties in terms of light weight structural design are immediately apparent. Hence, the focus of this study is to propose new sets of unfilled and particulate filled treated jute epoxy composites. Therefore, initially five different weight percentages of alkali treated jute epoxy composites are fabricated (10, 20, 30 40 and 50 wt.%) and studied their slurry erosive wear in experimentally at different operating conditions such as by varying impact velocity and impingement angle by keeping all other factors constant. The steady state erosion results for jute epoxy composites shows better wear resistant behavior for 40 wt.% jute fiber loading. Hence, for further fabrication of series of hybrid composite 40 wt.% jute fiber is kept constant and granite powder is varied in three different (8, 16 and 24 wt.%) weight percentages. The granite filler content in the jute epoxy composite played a major contribution for slurry erosion resistance. Finally, the obtained experimental results are compared with simulated model results by using a computational fluid dynamics tool. The eroded samples are observed through scanning electron microscope to study the wear mechanism. Note de contenu : - MATERIALS AND METHOD : Materials - Composite fabrication - Physical study - Slurry jet erosion wear test conditions and apparatus - Experimental design - Numerical analysis
- RESULTS AND DISCUSSION : Physical studies - Steady state slurry erosion rate - Erosion shape - Numerical analysis - Taguchi design of experiment - ANOVA and the effect of factors - Surface morphology - Comparison of wear rate, fiber/filler content and physical properties of polymer compositesDOI : 10.3139/217.3135 En ligne : https://drive.google.com/file/d/1v_L0YJ5ca8KEVb--MPR-cknqT9lbKRWr/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25767
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Rheological modeling of polymeric melts in extruders upon two-dimensional shear flow / H. Hosseini in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Rheological modeling of polymeric melts in extruders upon two-dimensional shear flow Type de document : texte imprimé Auteurs : H. Hosseini, Auteur ; V. Aseyev, Auteur ; B. V. Berdyshev, Auteur ; A. A. Borisov, Auteur Année de publication : 2016 Article en page(s) : p. 51-56 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Cinématique
Cisaillement (mécanique)
Etat fondu (matériaux)
Matières plastiques -- Extrusion:Polymères -- Extrusion
RhéologieIndex. décimale : 668.4 Plastiques, vinyles Résumé : The rheological modeling of a polymer melt in the course of its extrusion through a circular cylindrical channel inside a shaping die equipped with a rotating mandrel and a rotating or stationary nozzle is investigated. This paper attempts to provide a detailed rheological description of the physical processes of a polymer melt based on Leonov model inside the channel of an extruder under its kinematic deformation upon two-dimensional shear flow. Based on the obtained rheological equations of state, the flow process can be described in a form of dependencies reflecting kinematics of complex polymer deformation in the die channel. These expressions allow estimation of the velocity distribution for the flow elements within the channel as well as of the flow-pressure characteristics of the process. A quantitative relation between flow characteristics, rheological properties of polymer, and technical parameters of the channel of an extruder was determined. Comparison of this theoretical model with experimental results validates the suggested model. DOI : 10.3139/217.3131 En ligne : https://drive.google.com/file/d/1S5rfU8v8kMOVLcZybv_Netlt9U1V1ojR/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25768
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Experimental investigation on curing stress in polymer composite using digital gradient sensing technique / W. Hao in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Experimental investigation on curing stress in polymer composite using digital gradient sensing technique Type de document : texte imprimé Auteurs : W. Hao, Auteur ; X. Chen, Auteur ; Y. Yuan, Auteur ; Y. Ma, Auteur Année de publication : 2016 Article en page(s) : p. 57-67 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse numérique
AramidesLes polyamides aromatiques, ou aramides, sont une classe de matériaux résistant à la chaleur et/ou présentant de bonnes propriétés mécaniques. Ils ne peuvent être utilisés que comme fibres, qui servent surtout à la fabrication de matériaux composites, en renfort de matrices.
Le mot-valise "aramide" vient de la contraction de l'anglais aromatic polyamide.
Les fibres sont obtenues par filage (étirage au travers d'une filière) à partir d'une dissolution. Les chaînes moléculaires sont fortement orientées dans le sens de l'axe de la fibre, de sorte que les forces des interactions moléculaires peuvent être exploitées pour la résistance thermique et/ou mécanique.
Composites à fibres -- Propriétés mécaniques
Contraintes (mécanique)
Déformations (mécanique)
Epoxydes
Réticulation (polymérisation)Index. décimale : 668.4 Plastiques, vinyles Résumé : The curing stress and deformation of epoxy resin and aramid fiber/epoxy composites was measured using Digital Gradient Sensing (DGS) technique. First, the working principle of the DGS method was explained, and the governing equations were derived based on angular deflections of light rays. Then the angle deflection of light rays due to curing stress of epoxy resin was measured, and the effect of the fiber bundle and aramid fiber fabric on the stress distribution during formation was analyzed. The experimental results show that angular deflections of light rays can be related to nonuniform distribution of curing stress in epoxy. The fiber bundles and fabric style have important effects on the curing stress distribution. These results play an important role for predicting curing stress and deformation of fiber reinforced composites. Note de contenu : - METHOD : Working principal of DGS - Stress estimation by numerical integration
- EXPERIMENTAL DETAILS : Experimental setup - Materials
- RESULTS AND DISCUSSION : Curing process of epoxy - Effect of fiber bundles on the curing process - Effect of fiber fabricon the curing processDOI : 10.3139/217.3140 En ligne : https://drive.google.com/file/d/1Rr9KviQQ-13rWbiQIHg-H2iWj-JjFM8y/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25769
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Experimental and numerical investigation of shrinkage and warpage of a U-shaped injection molded part / Stefan Kleindel in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Experimental and numerical investigation of shrinkage and warpage of a U-shaped injection molded part Type de document : texte imprimé Auteurs : Stefan Kleindel, Auteur ; R. Eder, Auteur ; H. Schretter, Auteur ; C. Hochenauer, Auteur Année de publication : 2016 Article en page(s) : p. 68-81 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Composites à fibres de verre
Composites à fibres de verre -- Moulage par injection
Gauchissement (matériaux)
Mesure
PolyamidesUn polyamide est un polymère contenant des fonctions amides -C(=O)-NH- résultant d'une réaction de polycondensation entre les fonctions acide carboxylique et amine.
Selon la composition de leur chaîne squelettique, les polyamides sont classés en aliphatiques, semi-aromatiques et aromatiques. Selon le type d'unités répétitives, les polyamides peuvent être des homopolymères ou des copolymères.
Polyoxyméthylène
Retrait au moulage
Simulation par ordinateurIndex. décimale : 668.4 Plastiques, vinyles Résumé : Prediction of shrinkage and warpage of injection molded plastic parts is a key issue of injection molding simulation. In the present work a U-shaped part is investigated experimentally and by means of state of the art injection molding simulation software. The part has thick walls in the corner where inner defects such as voids and porous zones may appear. Experiments and simulations were performed with POM and glass fiber reinforced polyamide. Measurements of pressure in the cavities and temperature profiles around the cavities were used to validate the numerical model. In case of POM it was found that warpage predictions are way off when the void volume is high and in good agreement when the void volume is minimized. No such correlation was observed in case of fiber reinforced materials. Here, shrinkage and warpage are dominated by the fiber orientation state with minor influence of the processing conditions. Predicted warpage was found to be extremely dependent on the used closure approximation. Note de contenu : - PROBLEM DESCRIPTION
- EXPERIMENTAL : Mold design - Measurements
- NUMERICAL : Computational mesh - Material data - Boundary conditions
- RESULTS : Experimental results - Simulation results - DiscussionDOI : 10.3139/217.3148 En ligne : https://drive.google.com/file/d/1Lw0SrrPweDXNzbZ_k8OjnAguT44jH1tU/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25770
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Modeling for starve fed/flood fed mixing single-screw extruders / Krzysztof J. Wilczynski in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Modeling for starve fed/flood fed mixing single-screw extruders Type de document : texte imprimé Auteurs : Krzysztof J. Wilczynski, Auteur ; A. Lewandowski, Auteur ; A. Nastaj, Auteur ; Krzysztof J. Wilczynski, Auteur Année de publication : 2016 Article en page(s) : p. 82-91 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Alliages polymères
Calcul
Eléments finis, Méthode des
Extrudeuse monovis
Matières plastiques -- Extrusion
Polyéthylène basse densité
RhéologieIndex. décimale : 668.4 Plastiques, vinyles Résumé : A composite computer model has been proposed for starve fed/flood fed mixing single screw extruders. The model for starve fed extrusion has been developed by combining a new FEM based melt conveying model with recently developed melting models. Mixing screw equipped with distributive toothed disc mixing element has been considered as an example for modeling. An extensive fully three-dimensional non-Newtonian FEM computations have been carried-out to simulate the melt flow in mixing elements. Screw pumping characteristics have been developed for the elements at various power law indices, and these have been implemented into the composite model of the process. Simulations have been performed for low density polyethylene (LDPE) at various operating conditions, both for starve fed and flood fed extrusion. Fill factor, pressure, temperature and melting profiles have been computed and verified experimentally. Note de contenu : - Modeling
- FEM simulation
- Computation scheme
- Process simulations
- Experimental validation of the modelDOI : 10.3139/217.3154 En ligne : https://drive.google.com/file/d/1uq8f9Bqpf3KB3QKvCRIGo5ovDpUe3YI-/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25771
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible The comparative study of different mixing methods for microcrystalline cellulose/polyethylene composites / Sevda Boran in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
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Titre : The comparative study of different mixing methods for microcrystalline cellulose/polyethylene composites Type de document : texte imprimé Auteurs : Sevda Boran, Auteur ; A. Kiziltas, Auteur ; E. E. Kiziltas, Auteur ; D. J. Gardner, Auteur Année de publication : 2016 Article en page(s) : p. 92-103 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Cellulose La cellulose est un glucide constitué d'une chaîne linéaire de molécules de D-Glucose (entre 200 et 14 000) et principal constituant des végétaux et en particulier de la paroi de leurs cellules.
Composites -- Propriétés mécaniques
Composites -- Propriétés thermiques
Composites thermoplastiques
Extrudeuse bi-vis
Extrudeuse monovis
Matières plastiques -- Extrusion:Polymères -- Extrusion
Mélanges-maîtres (chimie)
Morphologie (matériaux)
Polyéthylène
Réaction de couplage
RhéologieIndex. décimale : 668.9 Polymères Résumé : Polymer composites with polyethylene (PE), microcrystalline cellulose (MCC), and coupling agent (PE-g-MA) were melt blended using a single screw extruder (SSE), twin screw extruder (TSE), and a combination of SSE and extensional flow mixer (EFM) and masterbatch method (MB). The rheological behavior, mechanical, thermal, and morphological properties were investigated to compare material behavior of the MCC-filled PE composites and to evaluate the dispersive mixing efficiency. The composite samples prepared using a single pass method in SSE had relatively larger storage moduli (G?) while those from the TSE and SSE + EFM were smaller. The complex viscosities (?*) of composites with processed using EFM was higher than that of neat PE, indicating better dispersion of the MCC.MCC-filled PE composites processed with EFM showed higher tan delta compared to those of composites. In general, MCC-filled PE composites from the EFM process showed higher viscosity compared to all other composites at all shear rates. The EFM method improved flexural properties more than the other processing methods. The effect of EFM on impact strength of the composites was improved with coupling agent. Addition of MCC, couple agent, and different mixing methods did not significantly affect the thermal properties of the MCC-filled PE composites. Note de contenu : - EXPERIMENTAL : Materials - Preparation of PE composites - Testing of the samples
- RESULTS AND DISCUSSIONS : Rheological properties of the samples - Mechanical properties of the samples - Thermal properties of the samples - Morphological properties of the samplesDOI : 10.3139/217.3156 En ligne : https://drive.google.com/file/d/1v16I-UezHHCsQUqgybBgyNKu1YCYVbyR/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25774
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Fabrication of superhydrophobic polyethylene parts by rotomolding / Zaita Ortega in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
[article]
Titre : Fabrication of superhydrophobic polyethylene parts by rotomolding Type de document : texte imprimé Auteurs : Zaita Ortega, Auteur ; N. Diaz, Auteur ; M. E. Alemán-DomÃnguez, Auteur ; A. Romero, Auteur ; M. D. Monzón, Auteur ; J. A. Gómez-Tejedor, Auteur Année de publication : 2016 Article en page(s) : p. 104-107 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Aluminium L'aluminium est un élément chimique, de symbole Al et de numéro atomique 13. C’est un métal pauvre, malléable, de couleur argent, qui est remarquable pour sa résistance à l’oxydation13 et sa faible densité. C'est le métal le plus abondant de l'écorce terrestre et le troisième élément le plus abondant après l'oxygène et le silicium ; il représente en moyenne 8 % de la masse des matériaux de la surface solide de notre planète. L'aluminium est trop réactif pour exister à l'état natif dans le milieu naturel : on le trouve au contraire sous forme combinée dans plus de 270 minéraux différents, son minerai principal étant la bauxite, où il est présent sous forme d’oxyde hydraté dont on extrait l’alumine. Il peut aussi être extrait de la néphéline, de la leucite, de la sillimanite, de l'andalousite et de la muscovite.
L'aluminium métallique est très oxydable, mais est immédiatement passivé par une fine couche d'alumine Al2O3 imperméable de quelques micromètres d'épaisseur qui protège la masse métallique de la corrosion. On parle de protection cinétique, par opposition à une protection thermodynamique, car l’aluminium reste en tout état de cause très sensible à l'oxydation. Cette résistance à la corrosion et sa remarquable légèreté en ont fait un matériau très utilisé industriellement.
L'aluminium est un produit industriel important, sous forme pure ou alliée, notamment dans l'aéronautique, les transports et la construction. Sa nature réactive en fait également un catalyseur et un additif dans l'industrie chimique ; il est ainsi utilisé pour accroître la puissance explosive du nitrate d'ammonium.
Angle de contact
Hydrophobie
Matières plastiques -- Rotomoulage
Moules d'injection
Polyéthylène
Surfaces -- AnalyseIndex. décimale : 668.9 Polymères Résumé : In this study, the feasibility of obtaining superhydrophobic polyethylene parts by rotational molding has been confirmed. The superhydrophobicity is obtained through the surface modification of the thermoplastic by using a microrough aluminium mold. The treatment used to create the microroughness of the mold was an electrochemical process followed by heating at 180 °C. Once the superhydrophobic aluminium mold has been prepared, several rotomolding cycles were carried out. The mold was then used for obtaining rotomolded test cube parts using a conventional polyethylene grade. The behavior of the parts under a water jet show a superhydrophobic behavior of the surface, fact confirmed by the measurement of contact angles above 145°. Note de contenu : - MATERIALS AND METHODS : Preparation of the aluminum substrate - Electrochemical treatment of the mold - Activation of the surface - Replication of superhydrophobic polyethylene parts - Measurement of the contact angle - SEM observation of the polyethylene surface
- RESULTS AND DISCUSSION : Replication of superhydrophobic polyethylene parts - Measurement of the contact angle - SEM observation of the polyethylene surfaceDOI : 10.3139/217.3161 En ligne : https://drive.google.com/file/d/1vmzwL8x669PPLnQxsFO5Dx3TpQ-Obvqc/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25775
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible Numerical simulation of chaotic mixing in single screw extruders with different baffle heights in INTERNATIONAL POLYMER PROCESSING, Vol. XXXI, N° 1 (03/2016)
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Titre : Numerical simulation of chaotic mixing in single screw extruders with different baffle heights Type de document : texte imprimé Année de publication : 2016 Article en page(s) : p. 108-118 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Extrudeuse monovis
Fluides non newtoniens
Imagerie tridimensionnelle
Matières plastiques -- Extrusion:Polymères -- Extrusion
Mélanges (chimie)
Rhéologie
Simulation par ordinateurIndex. décimale : 668.9 Polymères Résumé : A kind of discontinuous baffle, which had the same length as the non-baffle zone distance, was inserted in the unwound channel of a single screw extruder to enhance mixing in the screw channel. The periodic unit of the flow channel was modeled as a dynamic system of complex duct flow. The finite volume method was used to solve the three-dimensional flow of purely viscous non-Newtonian fluid. Fluid particle tracking was performed by a fourth-order Runge–Kutta scheme. The effect of the baffle height on the mixing kinematics was investigated numerically. Poincaré sections were applied to reveal the different patterns and sizes of the KAM tubes. Distributive mixing was then visualized by the evolution of passive tracers initially located at different positions. The variance index and residence time distribution (RTD) were used to evaluate the statistical results. Among the four test cases, the results showed that the case with the baffle height equal to the screw depth had the largest chaotic mixing region, but the shortest mean residence time and the narrowest broadening of RTD under the same pressure gradient. Note de contenu : - NUMERICAL METHOD : General and geometric parameters - Modeling - Numerical simulation - Velocity fields - Particle tracking method and front tracing
- RESULTS AND DISCUSSION : Period Poincaré sections - Variance as a mixing measure - Residence time distributionDOI : 10.3139/217.3167 En ligne : https://drive.google.com/file/d/1zF3qVtiS9MogovUw3Xd3h9F17nWJCv7w/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25776
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Code-barres Cote Support Localisation Section Disponibilité 17899 - Périodique Bibliothèque principale Documentaires Disponible
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Code-barres | Cote | Support | Localisation | Section | Disponibilité |
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17899 | - | Périodique | Bibliothèque principale | Documentaires | Disponible |