The effect of nano polysiloxanes on the permanence of feel touch of finished leathers / Evrim Kadioglu in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVII, N° 3 (03/2012)  

[article]  inJOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CVII, N° 3 (03/2012) . - p. 92-101 Titre : The effect of nano polysiloxanes on the permanence of feel touch of finished leathers Type de document : texte imprimé Auteurs : Evrim Kadioglu, Auteur ; Gökhan Zengin, Auteur ; Altan Afsar, Auteur Année de publication : 2012 Article en page(s) : p. 92-101 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Analyse sensorielle Cuir Cuirs et peaux -- Finition Evaluation Nanoparticules Particules (matières) Polydiméthylsiloxane Le polydiméthylsiloxane —[O-Si(CH3)2]n—, ou poly(diméthylsiloxane) selon la nomenclature systématique, communément appelé PDMS ou diméthicone, est un polymère organominéral de la famille des siloxanes souvent présent dans les shampoings. On l'y ajoute pour augmenter le volume des cheveux mais il peut également aller boucher les pores du cuir chevelu et rendre les cheveux gras. C'est une des raisons pour lesquelles se laver les cheveux tous les jours est très déconseillé avec un shampooing contenant des silicones. Il existe également de l'amodiméthicone, qui est un dérivé du diméthicone. Le polydiméthylsiloxane est un additif alimentaire (E900), utilisé comme antimoussant dans les boissons (Coca-Cola BlāK). La chaîne de poly(diméthylsiloxane) forme également la structure de base des huiles et des caoutchoucs silicones. Polymères en émulsion Toucher Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : Nano sized aminofunctional and micron sized dimethyl polysiloxane emulsions were applied to garment leathers as topcoats, to investigate the improvement on feel touch permanency of finished leathers. Fourier Transform Infrared Spectroscopy (FTIR) and particle size analysis of these two polysiloxane emulsions were carried out. The optimum application amount of emulsions was determined to be 15% based on the results of organoleptic evaluation and dynamic friction coefficients. After the application of nano and micron sized polysiloxane, three different accelerated ageing processes were applied to leathers under controlled temperature, humidity and UV light conditions. For determining the effect of the ageing processes on these polysiloxanes, dynamic friction coefficient measurements, ICP-OES and SEM analysis were carried out. The results revealed that nano sized polysiloxanes clearly improved the feel touch permanency of finished leathers in comparison to the leathers coated with micron sized polysiloxanes. Thereby, it was demonstrated that nano polysiloxanes can maintain the appearance and feel touch of leather product for a longer periods of time. Note de contenu : - EXPERIMENTAL : Materials - Finishing application - Particle size analysis - Fourier Transform Infrared Spectroscopy (FTIR) analysis - Organoleptic evaluation and dynamic friction coefficient measurements of feel touch of finished leathers - Accelerated ageing process - Rub fastness of aged leathers - Determination of silicone content of leather samples by inductively coupled plasma optical emission spectrometer (ICP-OES) - Scanning electron microscopy (SEM) microcraphs of leather samples - Statistical analysis - RESULTS AND DISCUSSION : Particle size analysis - Fourier Transform Infrared Spectrophotometer (FTIR) analysis - Organoleptic evaluations and dynamic friction coefficient measurements - Determination of silicone contents of leathers by ICP OES - Scanning electron microscopy micrographs of leathers samples En ligne : https://drive.google.com/file/d/1wNFJN8UG4CQqaiq2Nmjfrwx6NGnn1ByB/view?usp=drive [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=14421 [article]

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Use of natural fat emulsions in fatliquoring process and investigation of fatty spue formation / Gökhan Zengin in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVI, N° 3 (03/2011)  

[article]  inJOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CVI, N° 3 (03/2011) . - p. 83-91 Titre : Use of natural fat emulsions in fatliquoring process and investigation of fatty spue formation Type de document : texte imprimé Auteurs : Gökhan Zengin, Auteur ; Altan Afsar, Auteur Année de publication : 2011 Article en page(s) : p. 83-91 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acides gras Cuirs et peaux -- Dégraissage Cuirs et peaux -- Finition Emulsions Fourier, Spectroscopie infrarouge à transformée de Huiles et graisses Iode Microscopie électronique à balayage Peroxydes Produits de nourriture du cuir Résonance magnétique nucléaire Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : Fatty spew is one of the most frequent defects appearing on finished leathers, especially sheepskins. Origins of this problem include an insufficient degreasing process, presence of excess residual natural fat in leather, quantity and quality of fatliquoring material added during the fatliquoring process and defective fatliquoring techniques. It is usually not easy to identify this problem during the processes. The aim of this study is to find out the limit value of natural fat that cause to fatty spew and its effect on leather quality. In the experiments Irish ovine sheepskins were used, as they are known for their high natural fat content. The experiments were carried out in three groups. The first group was processed without degreasing and fatliquoring. The second group was degreased and processed without fatliquoring and the third group was degreased; and fatliquored with 3, 5 and 7% of their own emulsified fat. The application of 3% fat emulsion is agreeable due to fatty spew formation in 5% and 7% fat emulsion application, as expected from preliminary tests. Some physical and chemical characteristics of natural and emulsified fats were investigated such as density, acid, peroxide and iodine values. Visual images of skin surfaces were obtained by Scanning Electron Microscopy (SEM). Gas Chromatography (GC), Nuclear Magnetic Resonance (NMR) and Fourier Transform Infrared Spectroscopy (FT-IR). Analyses were performed for the determination of fatty acids components that cause fatty spew defect. It was determined that double bond between C and C in the structure of the palmitoleic and linoleic acids was saturated, the ratio of palmitic and stearic acids was increased and palmitic and stearic acids were found to be the main reasons for fatty spew formation. Note de contenu : METHOD AND RESULTS AND DISCUSSION : Determination of fat content - acid, iodine and peroxide values - Scanning electron microscopy (SEM) - Gas chromatography (GC) analysis - C nuclear magnetic resonance (RMN) - Fourier transform infrared spectroscopy (FTIR) analysis. En ligne : https://drive.google.com/file/d/1S0CFlK1Qi1q2fgvStk1qcPHf4GB-6CyO/view?usp=drive [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=11237 [article]

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