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Synthesis of xylitol-based hyperbranched polyurethane acrylate and its application in self-matting acrylate coatings / Ruijun Lin in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 20, N° 5 (09/2023)
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Titre : Synthesis of xylitol-based hyperbranched polyurethane acrylate and its application in self-matting acrylate coatings Type de document : texte imprimé Auteurs : Ruijun Lin, Auteur ; Xingshan Yin, Auteur ; Huameng Liu, Auteur ; Lijing Chen, Auteur ; Jianxin Wu, Auteur ; Liang Liu, Auteur ; Yuxin Gu, Auteur ; Yong Li, Auteur ; Xiaofeng Lin, Auteur ; Wenjing Lin, Auteur ; Guobin Yi, Auteur Année de publication : 2023 Article en page(s) : p. 1579-1594 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Agent mattant
Caractérisation
Copolymère uréthane acrylate
Copolymères -- Synthèse
Formulation (Génie chimique)
Polyacryliques
Polymères ramifiés
Potentiel zeta
Revêtements -- Propriétés mécaniques
Revêtements en phase aqueuse
Stabilité thermique
Taille des particules
XylitolIndex. décimale : 667.9 Revêtements et enduits Résumé : Self-matting acrylate has attracted much interest due to excellent weather resistance, hardness, water resistance, and chemical resistance. However, the poor mechanical properties of acrylate limit its application in coatings. To overcome this problem, a series of self-matting acrylate emulsions (SMAE) modified by xylitol-based hyperbranched urethane acrylate (HP-IH) were successfully synthesized. The results revealed that the amount of emulsifier was the primary factor affecting the gloss of the films. Upon the incorporation of HP-IH, the elongation at break and fracture energy of the SMAE films were significantly improved by 52.6% and 59.6%, respectively, due to the internal plastic effect and increased crosslink density induced by HP-IH. The S-2-1.5 sample exhibited the excellent comprehensive performance, i.e., tensile strength of 12.7 MPa, elongation at break of 952%, fracture energy of 71.1 MJ/m3, adhesion of 5B, temperature of 5% weight loss at 350 °C, and gloss at 60° of 14.8, respectively, indicating its great application potential in the field of low-gloss coatings. Note de contenu : - MATERIALS : Synthesis of hydroxyl-terminated hyperbranched polyester (HP-OH) - Synthesis of xylitol-based hyperbranched urethane acrylate (HP-IH) - Synthesis of self-matting acrylate emulsion (SMAE) - Preparation of self-matting acrylate films - Characterization
- RESULTS AND DISCUSSION : Chemical structural characterization
- Table 1 : Basic formulations for the preparation of self-matting acrylate emulsion
- Table 2 : Average particle size and zeta potential of SMAE with different amounts of HP-IH
- Table 3 : Thermal stabilities of the SMAE films
- Table 4 : Dynamic mechanical properties of the SMAE films
- Table 5 : Comprehensive properties of SMAEDOI : https://doi.org/10.1007/s11998-023-00764-9 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-023-00764-9.pdf?pdf=button Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39973
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 20, N° 5 (09/2023) . - p. 1579-1594[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 24242 - Périodique Bibliothèque principale Documentaires Disponible Synthesis of ZnS–Mn nano-luminescent pigment for ink applications in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 15, N° 6 (11/2018)
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Titre : Synthesis of ZnS–Mn nano-luminescent pigment for ink applications Type de document : texte imprimé Année de publication : 2018 Article en page(s) : p. 1325-1332 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
CotonLe coton est une fibre végétale qui entoure les graines des cotonniers "véritables"(Gossypium sp.), un arbuste de la famille des Malvacées. Cette fibre est généralement transformée en fil qui est tissé pour fabriquer des tissus. Le coton est la plus importante des fibres naturelles produites dans le monde. Depuis le XIXe siècle, il constitue, grâce aux progrès de l'industrialisation et de l'agronomie, la première fibre textile du monde (près de la moitié de la consommation mondiale de fibres textiles).
Encre
Lin et constituantsLe lin cultivé (Linum usitatissimum) est une plante annuelle de la famille des Linaceae cultivée principalement pour ses fibres, mais aussi pour ses graines oléagineuses. Les fibres du lin permettent de faire des cordes, du tissu (lin textile pour ses qualités anallergiques, isolantes et thermorégulateurs), ou plus récemment des charges isolantes pour des matériaux de construction. Les graines sont utilisées pour produire de l'huile de lin pour l'industrie de l'encre et de la peinture, pour la consommation humaine et animale, à cause de sa richesse en oméga 3.
Le lin est une des rares fibres textiles végétales européennes. Elle a comme caractéristiques la légereté, la rigidité et la résistance et comme particularité d'être une fibre longue (plusieurs dizaines de centimètres), par rapport aux fibres courtes (coton, chanvre) ou moyennes (laine).
Luminescence
Manganèse
Nanoparticules
Photoluminescence
Pigments à effets spéciaux
Polyamide 66
Polyvinylpyrrolidone
Rhéologie
Sérigraphie
Sulfure de zinc
Textiles et tissus
Textiles et tissus imprimésIndex. décimale : 667.9 Revêtements et enduits Résumé : In the present study, ZnS–Mn nano-luminescent pigments were synthesized, using co-precipitation method. Polyvinylpyrrolidine (PVP) surface modifier and Mn dopant concentrations were considered as affecting parameters. The luminescent ink was loaded with two different concentrations of pigments. The obtained ink was silk-screened on different types of fabrics mainly treated cotton, cotton and nylon. Structure, microstructure, luminescent properties of nano-pigments, inks and fabrics and also rheological properties of the inks were investigated. The results showed that the ceramic ink prepared with nano-luminescent pigment had high photoluminescence (PL) intensity. Moreover, the optimum concentrations of Mn and PVP for obtaining maximum PL intensity were found as 2 and 5 wt%, respectively. SEM images of fabrics indicated that nanoparticles were loaded, nonuniformly, on the fibers. The treated linen and nylon fabrics showed maximum and minimum PL intensity, respectively, due to ink penetration depth in the fabrics. Furthermore, washing fastness estimated for all fabrics was in the proper range. Note de contenu : - EXPERIMENTAL : Materials - Synthesis method - Characterization
- RESULTS AND DISCUSSION : Characterization of ZnS-Mn nanostructure pigments - Printed fabrics - Ink rheologyDOI : 10.1007/s11998-018-0081-4 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-018-0081-4.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=31346
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 15, N° 6 (11/2018) . - p. 1325-1332[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 20388 - Périodique Bibliothèque principale Documentaires Disponible Synthesis, spectroscopic characterisation, and potential application of dyes containing a carbostyril skeleton as sensors for thiols / Aleksandra Grzelakowska in COLORATION TECHNOLOGY, Vol. 132, N° 2 (04/2016)
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Titre : Synthesis, spectroscopic characterisation, and potential application of dyes containing a carbostyril skeleton as sensors for thiols Type de document : texte imprimé Auteurs : Aleksandra Grzelakowska, Auteur ; Jolanta Kolinska, Auteur ; Jolanta Sokolowska, Auteur Année de publication : 2016 Article en page(s) : p. 121-129 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse spectrale
Capteurs chimiques
Caractérisation
Colorants -- Synthèse
Photochimie
ThiolsIndex. décimale : 667.3 Teinture et impression des tissus Résumé : Several dyes based on a carbostyril skeleton were synthesised and characterised using proton nuclear magnetic resonance spectroscopy and electron ionisation mass spectrometry. Their basic spectroscopic properties, such as absorption and emission spectra, were also measured. The behaviour of the obtained dyes in the absence and presence of thiol amino acids and other compounds under various conditions were studied. These dyes contain various moieties in the structure, acting as Michael acceptors. Results show that the studied compounds have the potential to act as colorimetric sensors for thiols, but the benzothioazolium dyes are less effective than dicyanoethylene derivatives. Note de contenu : - EXPERIMENTAL : General - Synthesis - Photochemical experiments - Studies of the spectroscopic response to sulfhydryl and non-sulfhydryl amino acids and other thiol compounds
- RESULTS AND DISCUSSION : Synthesis and spectroscopic characterisation of the dyes - Spectroscopic response of the studied dyes of thiolsDOI : 10.1111/cote.12187 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12187 Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=25855
in COLORATION TECHNOLOGY > Vol. 132, N° 2 (04/2016) . - p. 121-129[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 18025 - Périodique Bibliothèque principale Documentaires Disponible Synthesis, stability and printing properties of a novel 2-sulphophenoxy-4-chloro-s-triazine reactive dye for ink-jet printing of wool / Saira Faisal in COLORATION TECHNOLOGY, Vol. 136, N° 2 (04/2020)
[article]
Titre : Synthesis, stability and printing properties of a novel 2-sulphophenoxy-4-chloro-s-triazine reactive dye for ink-jet printing of wool Type de document : texte imprimé Auteurs : Saira Faisal, Auteur ; Long Lin, Auteur ; Matthew Clark, Auteur Année de publication : 2020 Article en page(s) : p. 153-166 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Colorants -- Synthèse
Colorants réactifs
Electrophorèse capillaire
Encre
Fourier, Spectroscopie infrarouge à transformée de
Impression sur étoffes
Jaune
Laine
Photostabilité
Résistance au lavage
Solidité de la couleurIndex. décimale : 667.3 Teinture et impression des tissus Résumé : We report here the synthesis and characterisation of a new medium-reactivity reactive dye containing 2-sulphophenoxy-4-chloro-s-triazine, having enhanced the activity of the chlorine atom for further substitution by the functional groups carried by wool fibre. In addition, a dichloro-s-triazine dye was also synthesised for the purpose of comparison. The progress of synthesis reactions and purity of the dyes were determined using capillary electrophoresis and thin layer chromatography. The molecular structure and the chemical compositions of the synthesised dyes were confirmed using Fourier Transform–infrared spectral data and elemental analyses. The inks containing the synthesised dyes were formulated and ink-jet-printed onto wool fabrics and then the printed fabrics were steamed at 102°C. Compared with the dichloro-s-triazine dye, superior performance in terms of ink stability, K/S and dye fixation was observed for the new 2-sulphophenoxy-4-chloro-s-triazine dye. In addition, the light fastness of the fabric printed with the inks containing the new dye was 0.5-grade greater than that of the fabric printed with the inks containing the dichloro-s-triazine dye, and no changes in shade and staining were observed following wash fastness tests of the fabrics printed with the inks containing the new dye. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of yellow 7-[(4-amino-2-methylphenyl)azo]-1,3-naphthalenedisulfonic-acid dye - Synthesis of yellow 7-[(2,4-dichloro-1,3,5-triazin-6-yl)amino-2-methylphenyl]azo]-1,3-naphthalenedisulphonic-acid dye - Synthesis of yellow 7-[(2-(4-sulphophenoxy)-4-chloro-1,3,5-triazin-6-yl)amino-2-methylphenyl]azo]-1,3-naphthalenedisulphonic-acid dye - Procedures - Application of the dyes - Physicochemical properties of the inks - Stability of the inks - K/S - Fixation - Colour fastness properties
- RESULTS AND DISCUSSION : Synthesis of reactive dyes - Capillary electrophoresis (MEKC) - FTIR analysis - Physicochemical properties of the inks - Stability of the inks - Printing properties - Wash fastness - Light fastnessDOI : https://doi.org/10.1111/cote.12457 Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=34235
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Code-barres Cote Support Localisation Section Disponibilité 21751 - Périodique Bibliothèque principale Documentaires Disponible Tactile friction and perception of UV-curable coatings and their relation to physical surface parameters and contact mechanic simulation / Thomas Ules in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 20, N° 6 (11/2023)
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Titre : Tactile friction and perception of UV-curable coatings and their relation to physical surface parameters and contact mechanic simulation Type de document : texte imprimé Auteurs : Thomas Ules, Auteur ; Michael GrieBer, Auteur ; Andreas Hausberger, Auteur ; Christian Schipfer, Auteur ; Mohammad Mansouri, Auteur ; Peter Fuchs, Auteur ; Sandra Schlögl, Auteur ; Dieter P. Gruber, Auteur Année de publication : 2023 Article en page(s) : p. 1803-1814 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
Chimie des surfaces
Dureté (matériaux)
Eléments finis, Méthode des
Revêtements -- Séchage sous rayonnement ultraviolet
Revêtements organiques
Simulation, Méthode de
ToucherIndex. décimale : 667.9 Revêtements et enduits Résumé : In this paper, the results of new investigations on the relationship between physical surface parameters of polymer-based coatings, skin hydration levels and tactile friction are presented. For this purpose, the chemical composition of the investigated coatings was varied on the basis of the curing and binding agent and also with respect to the addition of selected fillers. This allowed the adjustment of various surface parameters such as hardness, surface wettability and roughness over a wide range. Tribological tests were carried out in which the coefficient of friction between the finger pad and the respective coating was measured for different skin hydration levels. A specially developed setup was used that minimized changing skin hydration levels during the experiments that would impede reproducible friction measurements. While for dry skin the perceived friction correlates well to the coefficient of friction and surface hardness, this is not the case for moist finger skin. The results are explained under the assumption of adhesion dominated friction and the application of the Hertz contact theory. This finding was further investigated through contact mechanic simulations using the finite element method (FEM). To this end, the contact area formation dependence on the reaction force was studied for surfaces of different hardness and skin with different mechanical properties reflecting various hydration levels. The results qualitatively confirmed the experimental findings and the analysis based on the Hertz contact theory. Note de contenu : - EXPERIMENTAL : Materials - Methods - FEM contact model
- RESULTS & DISCUSSION : Physical characterization - Tactile friction - Perception studies - Contact simulation
- Table 1 : Chemical composition of the UV-curable coatings (all formulations contained 2 wt% Irgacure TPO-L)
- Table 2 : Physical surface parameters of the investigated sample coatings
- Table 3 : Elastic moduli (in kPa) of the hyperelastic material model (neo-Hookean solid) for the single skin layers Stratum Corneum (SC), Epidermis (ED) and Dermis (D)DOI : https://doi.org/10.1007/s11998-023-00792-5 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-023-00792-5.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=40162
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Code-barres Cote Support Localisation Section Disponibilité 24337 - Périodique Bibliothèque principale Documentaires Disponible PermalinkTailored polymer coatings as corrosion inhibitor for mild steel in acid medium / Ghada M. Abd El-Hafeez in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 2 (03/2021)
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PermalinkTamarind shell tannin-doped hybrid sol-gel coatings on mild steel in acidic medium toward improved corrosion protection / Abdullahi Abdulmajid in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 2 (03/2022)
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PermalinkTest de traction in situ d'un polymère injecté / Jean-Pierre Gazonnet in CAOUTCHOUCS & PLASTIQUES, N° 747 (02/1996)
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PermalinkThe characterisation of vertical fibre and high weave structures of Hereford cattle hide / D. E. Peters in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 67 (Année 1983)
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PermalinkThe characterization of the semi-solid W/O/W emulsions with low concentrations of the primary polymeric emulsifier / D. Vasiljevic in INTERNATIONAL JOURNAL OF COSMETIC SCIENCE, Vol. 27, N° 2 (04/2005)
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PermalinkThe non-collagenous proteins of skin - Their characterisation and significance in leather processing / G. A. Balian in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 54, N° 5 (05/1970)
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PermalinkThe novel synthesis and characterisation of hydroxyapatite and its application in leather making / Y. Z. Wang in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 102, N° 4 (07-08/2018)
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PermalinkThe preparation and application of a montmorillonite-based nanocomposite in leather making / Jianzhong Ma in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 87, N° 4 (07-08/2003)
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PermalinkThe preparation and application of a nanocomposite tanning agent-MPNS-SMA / Hui Pan in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 89, N° 4 (07-08/2005)
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