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Mechanical, morphological, thermal and dynamic study of composites of unsaturated polyesters-Date palm leaf Fiber DPLF / Abir Berkouk in REVUE DES COMPOSITES ET DES MATERIAUX AVANCES, Vol. 31, N° 6 (12/2021)
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Titre : Mechanical, morphological, thermal and dynamic study of composites of unsaturated polyesters-Date palm leaf Fiber DPLF Type de document : texte imprimé Auteurs : Abir Berkouk, Auteur ; Ahmed Meghezzi, Auteur ; Hamza Chelali, Auteur ; Mohamed Toufik Soltani, Auteur Année de publication : 2021 Article en page(s) : p. 317-323 Note générale : Bibliogr. Langues : Français (fre) Catégories : Analyse mécanique dynamique
Analyse morphologique
Analyse thermique
Caractérisation
Composites à fibres végétales
Fibres de palmier dattier
Humidité -- Absorption:Eau -- Absorption
Polyesters insaturésLes résines de polyesters insaturés (UP) sont obtenues par polycondensation
d’un ou de plusieurs diacides avec un ou plusieurs glycols, l’un, au moins, des constituants contenant une double liaison éthylénique susceptible de réagir ultérieurement sur un composé vinylique, acrylique ou allylique.
Par le terme résine polyester, on désigne en fait la dissolution du prépolymère polyester insaturé dans un solvant copolymérisable, le plus utilisé étant le styrène. C’est sous cette forme liquide que les résines polyesters sont livrées aux transformateurs.
Après addition de différents adjuvants, charges et renforts, divers procédés de transformation provoquent, sous l’action d’un système catalytique approprié, la copolymérisation finale de la résine en un objet thermodurcissable.
Les polyesters insaturés sont d’un usage relativement ancien (1950), essentiellement
dans le bâtiment (moulage au contact). Ils ont connu un renouveau important à partir de 1980, en particulier au niveau des formulations et de la fiabilité des procédés grâce au développement de technologies industrielles de moulage par injection et par compression dans l’industrie automobile.Index. décimale : 668.4 Plastiques, vinyles Résumé : In order to improve the properties of unsaturated polyesters, this study discusses the possibilities of developing a natural waste, date palm leaf fiber DPLF, produced in the northern Algerian Sahara, associated with the polymer matrix of a thermosetting polyester resin UP. For this purpose, composite plates containing virgin fiber at rates of 6 and 10% were treated with an alkaline solution of 6% NaOH on the one hand, and a silane compound on the other. In this research, a mechanical study of strength and elongation at break was carried out. In addition, morphological behavior was followed by SEM scanning electron microscopy. ATG thermogravimetric analysis and energy flow were monitored by DSC differential scanning calorimetry. Also, a study of the water absorption capacity has been conducted. In addition, a dynamic mechanical analysis DMA was carried out. The findings of this study show that there is a favorable mechanical behavior for the composites containing the 6% and 10% DPLF fiber, with alkaline NaOH and Silane treatment. They also show that the chemical treatment with alkaline solution and silane gives composites certain thermal stability compared to those with untreated fiber. Findings also explore that the absorption of water by the various composites shows that the chemical treatment promotes some intermolecular associations with water. Findings also show that the storage modulus (E') increases when the composite contains 10% DPLF, treated and untreated, and the maximum value of the tangent moves towards the high temperature for the treated and untreated fiber composite. Note de contenu : - MATERIALS AND METHODS : Materials - Chemical treatments of date palm leaf fibers - Fabrication of UP composites - Characterization
- RESULTS AND DISCUSSION : Mechanical analysis of UP/DPLF composites - Morphological study of UP/DPLF composites - Thermogravimetric study of UP/DPLF composites - Differential scanning calorimeter study of UP/DPLF composites - Water absorption of UP/DPLF composites - Dynamic study of UP/DPLF composites
- Table 1. Chemical constituents of leaf date palm fibers
- Table 2. Residual masses at a temperature of 450℃ of the various composites
- Table 3. The decomposition temperature of the different compositesDOI : https://doi.org/10.18280/rcma.310602 En ligne : https://www.iieta.org/download/file/fid/66502 Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37689
in REVUE DES COMPOSITES ET DES MATERIAUX AVANCES > Vol. 31, N° 6 (12/2021) . - p. 317-323[article]Mechanically enhanced self-stratified acrylic/silicone antifouling coatings / Jingjing Xue in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 212, N° 4674 (04/2022)
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Titre : Mechanically enhanced self-stratified acrylic/silicone antifouling coatings Type de document : texte imprimé Auteurs : Jingjing Xue, Auteur ; Li Wang, Auteur ; Yong Fan, Auteur ; Jianing Xu, Auteur ; Jie Zhao, Auteur ; Limei Tian, Auteur ; Wenbo Du, Auteur Année de publication : 2022 Article en page(s) : p. 27-31 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Copolymère silicone acrylique
Essais d'adhésion
PolydiméthylsiloxaneLe polydiméthylsiloxane —[O-Si(CH3)2]n—, ou poly(diméthylsiloxane) selon la nomenclature systématique, communément appelé PDMS ou diméthicone, est un polymère organominéral de la famille des siloxanes souvent présent dans les shampoings. On l'y ajoute pour augmenter le volume des cheveux mais il peut également aller boucher les pores du cuir chevelu et rendre les cheveux gras. C'est une des raisons pour lesquelles se laver les cheveux tous les jours est très déconseillé avec un shampooing contenant des silicones.
Il existe également de l'amodiméthicone, qui est un dérivé du diméthicone.
Le polydiméthylsiloxane est un additif alimentaire (E900), utilisé comme antimoussant dans les boissons (Coca-Cola BlāK).
La chaîne de poly(diméthylsiloxane) forme également la structure de base des huiles et des caoutchoucs silicones.
Résistance à l'abrasion
Revêtements antisalissures
Revêtements autostratifiantsIndex. décimale : 667.9 Revêtements et enduits Résumé : Great attention has been paid to silicone-based fouling-release coatings (FRCs) in the realm of maritime antifouling due to their highly efficient and eco-friendly properties, but many challenges remain for developing a silicone-based FRC that improves its adhesion performance without reducing the antifouling property. Herein, a non-toxic silicone-based FRC has been developed by integrating acrylic resin (AR) with a silicone resin (PDMS) to spontaneously form a self-stratified AR/PDMS coating. The AR/PDMS antifouling coating stil) has the same fouling-release performance but improved adhesion strength (from 0.4 to 2.0 MPa) in comparison with pristine PDMS. Moreover, the antifouling coating has proven to be extremely stable in different environments (such as pH, heating, and ultraviolet exposure). The study provides a facile and convenient self-stratified strategy to develop antifouling coatings, contributing to environmentally friendly coatings in marine applications. Note de contenu : - MATERIALS AND METHODS : Materials - Stratified coating preparation - Adhesion force tests - Coating stability test - Mimetic measurement of barnacle adhesions strength - Antibacterial adhesion test - Other characterisation
- RESULTS AND DISCUSSION : Characterisation of acrylic/silicone coating - Self-stratification acrylic/silicone coating - Coating adhesion of AR-PDMS coatings - Coating stability and abrasion resistance - Antifouling property - Antibacterial adhesion performance - Mimetic measurement of barnacle removal strengthEn ligne : https://drive.google.com/file/d/1GIVhv-kFk0iGIfuj_mxeBkFio2QNARkN/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37391
in POLYMERS PAINT COLOUR JOURNAL - PPCJ > Vol. 212, N° 4674 (04/2022) . - p. 27-31[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 23336 - Périodique Bibliothèque principale Documentaires Disponible Mechanism and application of ozone fading: Oxidative decolorisation of disperse dyes and waste-dyed polyester fabrics / Jiangfei Lou in COLORATION TECHNOLOGY, Vol. 139, N° 3 (06/2023)
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Titre : Mechanism and application of ozone fading: Oxidative decolorisation of disperse dyes and waste-dyed polyester fabrics Type de document : texte imprimé Auteurs : Jiangfei Lou, Auteur ; Lamei Ren, Auteur ; Jiugang Yuan, Auteur ; Jing Xu, Auteur ; Zhengbiao Gu, Auteur ; Xuerong Fan, Auteur Année de publication : 2023 Article en page(s) : p. 338-349 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Bleu (couleur)
Caractérisation
Colorants -- Oxydation
Décoloration
Fibres textiles -- Surfaces
Mesure
Orange (couleur)
Ozone
Polyesters
Textiles et tissus teintsIndex. décimale : 667.3 Teinture et impression des tissus Résumé : As the most common synthetic fibre, polyester has consistently been in high demand and usage, but its recycling has always been a problem for the textile industry. The decolorisation of dyed polyester is the key to expanding its recycling use, and there is no rapid, effective and simple decolorisation method. In this study, ozone was used to decolorise dispersed dyes developed for polyester. Ozone was effective in decolorising CI Disperse Orange 30 and CI Disperse Blue 60, and the process was extended to the decolorisation of dyed polyester fabric. Based on single factor analysis, the optimum decolorisation technological conditions were: an ozone feed rate of 130 mg L−1 min−1, treatment time of 2 hours, wet pick-up of 100% and pH value of 3, with which the decolorisation rate and colour difference values could exceed 45% and 6%, respectively. The changes in dye structure during the process of ozone decolorisation were analysed using scanning electron microscopy, X-ray diffraction and Fourier Transform–infrared spectroscopy, and the mechanism of ozone decolorisation was also investigated. The results showed that the crystallinity decreased from 41.18% to 36.30% with a strength retention rate of above 80%, and demonstrated that ozone can be used on polyester fabric and dye simultaneously. The aim of entering the fibre was achieved by etching the polyester and decolorisation was achieved by oxidising the chromaticity groups. Note de contenu : - EXPERIMENTAL : Materials and chemicals - Dyeing of the PET fabrics - Monitoring of the ozone feed rate - Optimum decolorisation technological conditions - Exploration of the decolorisation mechanism - Characterisation and measurement
- RESULTS AND DISCUSSION : Optimum decolorisation technological conditions - Application of the optimum decolorisation technological conditions - Surface morphology of PET fabrics treated with ozone - Decolorisation of dispersed dye with ozone
- Table 1 : Names, classes and structures of the dyes used in this study
- Table 2 : Ozone feed rates used in this study
- Table 3 : Dyeing conditions of treated samples
- Table 4 : CIElab values of the ozone-treated and reference-dyed PETDOI : https://doi.org/10.1111/cote.12654 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12654 Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39543
in COLORATION TECHNOLOGY > Vol. 139, N° 3 (06/2023) . - p. 338-349[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 24086 - Périodique Bibliothèque principale Documentaires Disponible Melamine glyoxal resin as a retanning agent - preparation and application / Xie Heng in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 98, N° 1 (01-02/2014)
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Titre : Melamine glyoxal resin as a retanning agent - preparation and application Type de document : texte imprimé Auteurs : Xie Heng, Auteur ; Sun Qingyong, Auteur ; Xuepin Liao, Auteur ; Bi Shi, Auteur Année de publication : 2014 Article en page(s) : p. 17-22 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Cuir -- Teneur en formaldéhyde
Cuirs et peaux -- Propriétés mécaniques
Cuirs et peaux -- Propriétés organoleptiques
Cuirs et peaux -- Propriétés physiques
Formaldéhyde -- Suppression ou remplacement
Fourier, Spectroscopie infrarouge à transformée de
Mélamine glyoxal
RetannageIndex. décimale : 675.2 Préparation du cuir naturel. Tannage Résumé : Amino resins have played an important role in the manufacture of leather due to their outstanding filling and dyeing properties. However, a traditionally prepared amino resin usually contains free formaldehyde, which is strictly restricted in leather products. With increasing awareness of potential health problems with formaldehyde, there is a growing demand for formaldehyde-free leathers in the global leather market. In this study, a formaldehyde-free amino resin was synthesized by using glyoxal as condensing agent, and its retanning properties were investigated. It was found that the glyoxal can be used to replace formaldehyde to synthesize an amino resin, and the optimal reaction conditions were that the molar ratio of melamine to glyoxal was 1:6, reaction temperature was 333K and reaction time was 3 hours.
Retanning experiments with the prepared amino resin indicated that its retanning properties, including fullness, softness, general appearance of the leather and mechanical strength, are better or equal to those that of a traditionally prepared amino resin.Note de contenu : - EXPERIMENTAL PROCEDURE : Materials - Preparation of MG - Characterization of MG - FTIR analysis
- APPLICATION PERFORMANCE OF MG : Physical and mechanical tests - Organoleptic properties - Colour differences - Shrinkage temperature determination - Free formaldehyde content in leather
- RESULTS AND DISCUSSION : Orthogonal experimental results - FTIR analysis of MG resin - Application experiments of MG (trial 1)
- COMPARISON WITH COMMERCIAL AMINO RESIN : Comparison of organoleptic properties - Comparison of physical and mechanical properties - Comparison of chemical indexes of leather and spent liquor - Comparison of dyeing propertiesEn ligne : https://drive.google.com/file/d/1zoUkMI38NeJsf4Tz9PVrvw1r38ou6drW/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=21010
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 98, N° 1 (01-02/2014) . - p. 17-22[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 16162 - Périodique Bibliothèque principale Documentaires Disponible Mesoporous magnesium carbonate for use in powder cosmetics / Erik Bamford in INTERNATIONAL JOURNAL OF COSMETIC SCIENCE, Vol. 43, N° 1 (02/2021)
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Titre : Mesoporous magnesium carbonate for use in powder cosmetics Type de document : document électronique Auteurs : Erik Bamford, Auteur ; Alexander Grahn, Auteur ; Cecilia Arhammar, Auteur ; Ingrid Ajaxon, Auteur ; Cecilia Annerén, Auteur Année de publication : 2021 Article en page(s) : p. 57-67 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Agent mattant
Caractérisation
Huiles et graisses -- Absorption
Humidité -- Absorption
Ingrédients cosmétiques
Matériaux -- Propriétés fonctionnelles
Matériaux mésoporeux
Poudres -- Emploi en cosmétologieIndex. décimale : 668.5 Parfums et cosmétiques Résumé : - Objective : In the present study, we describe the features and functional properties of a new powder cosmetic ingredient, an amorphous mesoporous magnesium carbonate (MMC, also named Upsalite®) with regard to physical characteristics as well as functional attributes.
- Methods : Physical and functional characterization of MMC, as compared to other common powder cosmetic ingredients (silica, mica, kaolin, talc and starch), was assessed using nitrogen gas adsorption, powder X-ray diffraction, particle size distribution by laser diffraction, scanning electron microscopy (SEM), and oil and moisture uptake tests. The powder ingredients were also applied on human skin and analysed for short- and long-term mattifying effect, and a new method was developed to measure flashback effect. MMC was tested for skin irritation using an in vitro cell model as well as in vivo, through the Human Repeated Insult Patch Test on 50 human volunteers.
- Results : Mesoporous magnesium carbonate has a high surface area and pore volume. It has an excellent absorption capacity and can take up both oil and water simultaneously. It provides instant and long-lasting mattifying effect when applied on human skin without drying or irritating skin and exhibits no measured flashback effect.
- Conclusion : Mesoporous magnesium carbonate has good sensory and visual characteristics as well as excellent absorbing and mattifying properties, suggesting that it has great potential to replace other powder ingredients currently used as fillers and absorbers in powder cosmetics.Note de contenu : - MATERIALS AND METHODS
- RESULTS : Characteristics - Oil and moisture absorption - Long-lasting shine control of skin - Flashback effect - Dermatological tests
- Table : Specific surface area and pore volume of cosmetic powders as determined using nitrogen adsorptionDOI : https://doi.org/10.1111/ics.12670 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/ics.12670 Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=35444
in INTERNATIONAL JOURNAL OF COSMETIC SCIENCE > Vol. 43, N° 1 (02/2021) . - p. 57-67[article]Mesure de la taille des nanoparticules : retour sur une comparaison interlaboratoires et intertechniques / Georges Favre in HYGIENE & SECURITE DU TRAVAIL, N° 260 (07-08-09/2020)
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