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Challenging preservation options / Jessica Levin in EUROPEAN COATINGS JOURNAL (ECJ), N° 5 (05/2020)
[article]
Titre : Challenging preservation options : Towards biocide-free water-borne coatings via innovative binders and additives Type de document : texte imprimé Auteurs : Jessica Levin, Auteur ; Wenqin Wang, Auteur Année de publication : 2020 Article en page(s) : p. 28-33 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Antimicrobiens -- Suppression ou remplacement
Contamination microbienne
Copolymère styrène acrylique
Epaississants
Formulation (Génie chimique)
Liants en phase aqueuse
Peinture -- Conservation
Polyacryliques
Polyuréthane éthoxylé modifié de façon hydrophobe
Revêtements en phase aqueuse -- Additifs
Revêtements organiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : Increasing regulatory restrictions mean that there are limited preservation options currently available to the paint and coatings industry for both in-can and dry-film preservation. Experimental binders and thickeners that are more robust to microbial spoilage offer a potential solution and pass challenge testing even when formulated into water-borne paints. Note de contenu : - Regulations necessitate new preservation methods
- Commercially available solutions are limited
- Emergins technologies offer potential
- Development of robust raw materials for standard pH coatings
- Binders more robust against microbial spoilage
- Paint formulated with experimental binders passes challenge tests
- HEUR rheology modifiers that are less prone to microbial spoilage
- Path to reducing spoilage without biocides
- Fig. 1 : Paint performance data on paints based on commercial and experimental soft styrene acrylic binders
- Fig. 2 : Microbial challenge test plates 7 days after challenge 2
- Fig. 3 : A styrene acrylic paint was thickened with various HEURs added at 1.2 kg of polymer actives per 1000 I of paint. The bubble size is proportional to the Brookfield viscosity
- Table 1 : Rating system for estimating the level of microbial contamination on streak plates
- Table 2 : Microbial challenge test results for various acrylic and styrene acrylic binders at pH 7.0-9.5 supplied without biocide
- Table 3 : Paint formulation based on commercial and experimental soft styrene acrylic binders
- Table 4 : Microbial challenge test results for various HEUR rheology modifiers supplied without biocide added. Growth rating in parentheses as describes in Table 1
- Table 5 : Styrene acrylic screening formulation used to test type. 1. Type 2, and type 3 HEURs for thickening performanceEn ligne : https://drive.google.com/file/d/1qZ0eMaU48b8cVGe97f2VUowmbbfvbaSS/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=34174
in EUROPEAN COATINGS JOURNAL (ECJ) > N° 5 (05/2020) . - p. 28-33[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 21745 - Périodique Bibliothèque principale Documentaires Disponible
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Titre : Challenging preservation options : Towards biocide-free waterborne coatings via innovative binders and additives Type de document : texte imprimé Auteurs : Jessica Levin, Auteur ; Wenqin Wang, Auteur ; Stan Brownwell, Auteur ; Tara Conley, Auteur ; Erica Frankel, Auteur ; John J. Rabasco, Auteur ; Deb Graves, Auteur ; Adrian Ward, Auteur Année de publication : 2020 Article en page(s) : p. 40-45 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Antimicrobiens -- Suppression ou remplacement
Copolymère styrène acrylique
Epaississants
Formulation (Génie chimique)
Liants
Liants en phase aqueuse
Polyacryliques
Polyuréthane éthoxylé modifié de façon hydrophobe
Revêtements en phase aqueuse -- Additifs:Peinture en phase aqueuse -- Additifs
Revêtements organiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : Increasing regulatory restrictions mean that there are limited preservation options currently available to the paint and coatings industry for both in-can and dry-film preservation. Experimental binders and thickeners that are more robust to microbial spoilage offer a potential solution and pass challenge testing even when formulated into waterborne paints.
Water-based products are susceptible to microbial contamination. Contamination can be introduced during a variety of stages in the product life cycle, including manufacturing and packaging of the products ; "in can" during periods of storage, transportation, transfer, and usage; or on the dry film after application. Microbial susceptibility can cause product degradation, reduce product performance, or even induce hygiene and human health issues, which could result in a wide range of possible consequences, including product recall, customer complaints, reduced perception of product quality, production stoppage, etc. For these reasons, manufacturers add biocides to their waterborne products.
There are three aspects of coating preservation. The first is in-can preservation, which protects all liquid-state products with preservatives. The second aspect of preserving coatings is dry-film protection, which protects coatings from microbes in application areas such as in bathrooms, kitchens, and on exterior surfaces. Lastly, plant hygiene is critical for coatings preservation. If a tank or a pipe becomes contaminated, it can contaminate the final product. Each of these three aspects requires a different approach for preservation. From the consumer’s perspective, the biocides that are present in the final product are the most important: both for in-can and dry-film preservation. Ideally, antimicrobial materials would maximize efficacy, while minimizing toxicity and environmental persistence. Active antimicrobial ingredients need to be stable within the shelf life of the product to maintain product quality, but also biodegradable when exposed to the environment to deliver eco-friendly products. Furthermore, they need to be effective against microbes but non-toxic to other life forms. Balancing these needs is difficult to achieve in reality.Note de contenu : - REGULATIONS NECESSITATE NEW PRESERVATION METHODS : Commercially available solutions are limited - Emerging technologies offer potential
- DEVELOPMENT OF ROBUST RAW MATERIALS FOR STANDARD PH COATINGS : Experimental - Binders more robust against microbial spoilage - Paint formulated with experimental binders passes challenge tests - HEUR rheology modifiers that are less prone to microbial spoilage - Path to reducing spoilage without biocides
- Table 1 : Rating system for estimating the level of microbial contamination on streak plates
- Table 2 : Microbial challenge test results for various acrylic and styrene acrylic binders at pH 7.0-9.5 supplied without biocide
- Table 3 : Paint formulation based on commercial and experimental soft styrene acrylic binders
- Table 4 : Microbial challenge test result for various HEUR rheology modifiers supplied without biocide added, including the growth rating in parentheses as described in table 1
- Table 5 : Styrene acrylic screening formultion used to test type 1, type 2, and type HEURs for thickening performance
- Fig. 1 : Paint performance data on paints based on commercial and experimental soft styrene acrylic binders
- Fig. 2 : Microbial challenge test plates seven days after challenge 2En ligne : https://drive.google.com/file/d/1B0ac2Mg2sNEOI-g5PpL-_xwhr9AZg14W/view?usp=share [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=34305
in COATINGS TECH > Vol. 17, N° 5 (05/2020) . - p. 40-45[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 21773 - Périodique Bibliothèque principale Documentaires Disponible Effect of copolymer composition on flow properties and film-forming of functionalised latex binders / J. Snuparek in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 89, B1 (03/2006)
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Titre : Effect of copolymer composition on flow properties and film-forming of functionalised latex binders Type de document : texte imprimé Auteurs : J. Snuparek, Auteur ; O. Quadrat, Auteur Année de publication : 2006 Article en page(s) : p. 15-22 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Copolymère styrène acrylique
Emulsion alcali soluble modifiée de façon hydrophobe
Epaississants
Formation de film
Latex
Liants
Plastification
Polyuréthane éthoxylé modifié de façon hydrophobe
RhéologieIndex. décimale : 667.9 Revêtements et enduits Résumé : Acrylic and styrene/acrylic latex binders comprising functional monomers such as acrylic acid, methacrylic acid, methacrylamide, methyl methacrylate, and hydroxyethyl methacrylate in different concentration levels were synthesised. It was shown that the extent of particle swelling and the hydroplasticisation of the alkali-swellable particles was affected by the polarity of the ‘hard’ comonomer. The effect of dissociated carboxylic groups on the increase in latex viscosity and on the lowering of its minimum film-forming temperature was much more pronounced in the case of the methyl methacrylate comonomer. The thickening of the latices with hydrophobe-modified ethylene oxide urethane (HEUR) associative thickeners was considerably affected by the hydrophobicity of the particles. Thickening with hydrophically-modified alkali-soluble emulsion (HASE) thickeners depends predominantly on the excluded volume of swollen thickener particles. The influence of the hydrophobic styrene content was negligible. Note de contenu : - EXPERIMENTAL : Monomers - Thickeners - Standard polymerisation recipe
- RESULTS AND DISCUSSION : Minimum film-forming temperature of functionalised latexes - Effect of polar functional groups on the latex viscosity
- Table 1 : Characteristics of Röhm & Has thickeners
- Table 2 : Appearence of different ethyl acrylate/styrene/acrylic acid copolymer latexes under alkaline conditions (25wt% solids)DOI : 10.1007/BF02699610 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699610.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5391
in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS > Vol. 89, B1 (03/2006) . - p. 15-22[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 003916 - Périodique Bibliothèque principale Documentaires Disponible Effects of latex and thickener polarities on rheology and phase stability of latex-HEUR mixtures / Travis B. Smith in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 20, N° 4 (07/2023)
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Titre : Effects of latex and thickener polarities on rheology and phase stability of latex-HEUR mixtures Type de document : texte imprimé Auteurs : Travis B. Smith, Auteur ; David Chisholm, Auteur ; Abby Cheng, Auteur ; Juan Ortiz Salazar, Auteur ; Lia Roccucci, Auteur ; Bailey Morales, Auteur ; Gary Dombrowski, Auteur ; John J. Rabasco, Auteur ; Patrick Hartnett, Auteur ; Ray Fernando, Auteur Année de publication : 2023 Article en page(s) : p. 1311-1324 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Cisaillement (mécanique)
Epaississants
Epaississement
Floculation
Latex
Polyuréthane éthoxylé modifié de façon hydrophobe
Revêtements en phase aqueuse:Peinture en phase aqueuse
Rhéologie
SynérèseEn chimie, la synérèse définit la séparation d'un liquide de son gel.Index. décimale : 667.9 Revêtements et enduits Résumé : In this study, hydrophobically modified, ethoxylate urethanes (HEURs) and latexes of well-defined structure and composition were used to examine the rheology and phase behavior of HEUR–latex mixtures. The mixtures comprised one of four HEURs that were synthesized with varying molecular weight polyethylene glycols (PEG 35 K, 20 K, 12 K, and 8 K) and end-capped with octadecyl hydrophobes, as well as one of two latexes (butyl acrylate/styrene [BA-Sty] and butyl acrylate/methyl methacrylate [BA-MMA]) that each contained a small amount of methacrylic acid. The two experimental latexes represent compositions commonly used in commercial paint formulations. The polarity of the HEURs decreases as the PEG molecular weight decreases and the surface of the styrene containing latex is less polar than that containing methyl methacrylate. In all HEUR–latex mixtures, the latex polymer volume fraction was maintained constant at 0.25 which provides a dispersed component spatial crowdedness that represents a fully formulated paint. All latex–HEUR mixtures were stable at very low (i.e., below 0.10% by weight) HEUR levels. At critical concentrations dependent on the polarity of thickener and latex, flocculation was accompanied by syneresis for latex-thickener mixtures prepared with all HEURs except the one with the longest PEG spacer. Further increase of HEUR levels revealed another critical concentration above which the mixtures were stable. Effects of the latex polarity diminished for the mixtures prepared with more hydrophobic HEURs. Note de contenu : - HEUR C18-EO795 and latex mixtures
- HEUR C18-EO455 and latex mixtures
- Table 1 : Compositions and molecular weights (determined by GPC) of model HEURs
- Table 2 : Properties of model latexes
- Table 3 : Compositions of representative latex–HEUR mixtures
- Table 4 : Visual assessment of stability of latex–HEUR samples after 6–8 days of equilibration
- Table 5 : Number of HEUR molecules available per BA-Sty latex particle
- Table 6 : Latex surface area (nm2) claimed by a HEUR hydrophobe, assuming one of the hydrophobes from every HEUR molecule is adsorbeDOI : https://doi.org/10.1007/s11998-022-00746-3 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-022-00746-3.pdf?pdf=button% [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39718
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 20, N° 4 (07/2023) . - p. 1311-1324[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 24153 - Périodique Bibliothèque principale Documentaires Disponible Influence of the association of hydrophobic end groups on the temperature insensitivity of HEUR-thickened latex/Fe2O3/Zn3(PO4)2/BaSO4 suspensions / Yating Lin in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 20, N° 2 (03/2023)
[article]
Titre : Influence of the association of hydrophobic end groups on the temperature insensitivity of HEUR-thickened latex/Fe2O3/Zn3(PO4)2/BaSO4 suspensions Type de document : texte imprimé Auteurs : Yating Lin, Auteur ; Chunmei Song, Auteur ; Xiong Xiao, Auteur ; Wan Bo, Auteur Année de publication : 2023 Article en page(s) : p. 587-601 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Dispersions et suspensions
Formulation (Génie chimique)
Latex
Polymères -- Propriétés thermiques
Polymères -- Synthèse
Polyuréthane éthoxylé modifié de façon hydrophobe
Résistance thermique
Revêtements organiques
Rhéologie
Stabilité au stockage
ThixotropieIndex. décimale : 667.9 Revêtements et enduits Résumé : Hydrophobically modified ethoxylated urethane (HEUR) with different structures was synthesized and confirmed by gel permeation chromatography, Fourier transform infrared spectroscopy and nuclear magnetic resonance (1H NMR). We propose the relationship between the temperature insensitivity model and the thickening mechanism of HEUR/latex/Fe2O3/Zn3(PO4)2/BaSO4 suspensions. Meanwhile, the temperature insensitivity of HEUR/C suspensions is the result of two main associations: intermolecular interactions bridging the hydrophobic tails of HEURs and the hydrophobic groups tightly adsorbing onto the latex particle surfaces. A smaller ratio of viscosity (Rv) at 1 s−1 from the steady state condition indicates the better temperature insensitivity of viscosity. The higher degree of crystallinity and rheological activation energy corresponds to a great extent with better temperature insensitivity due to stronger association. The temperature insensitivity is consistent with the longer hydrophobic chain, which was proven by hysteresis tests and oscillatory shear measurements. The storage stability was enhanced in the lockstep with a hydrophobic length of HEUR, which is consistent with the rougher surfaces of HEUR/C films. As an appealing method, the results are meaningful and instructive for coating storage and application. Note de contenu : - EXPERIMENTAL : Materials - Measurements - Synthesis of HEURs - Preparation of HEUR/C suspensions
- RESULTS AND DISCUSSION : Characterization of HEURs - Melting temperature and crystallinity of HEURs - Rheological behavior of HEUR/C suspensions - Storage stability and aggregation structure of HEUR/C suspensions
- Table 1 : Description of the coating formulation
- Table 2 : Molecular characteristics of polymers
- Table 3 : Thermoproperties and crystallization of HEUR
- Table 4 : Rheological properties of HEUR/C suspensions with different hydrophobicities
- Table 5 : Storage stability of HEUR/C suspensions
- Table 6 : Non-Newtonian exponents of HEUR/C suspensions
- Table 7 : Roughness parameters of the sample filmsDOI : https://doi.org/10.1007/s11998-022-00692-0 En ligne : https://link.springer.com/content/pdf/10.1007/s11998-022-00692-0.pdf?pdf=button% [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39301
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Code-barres Cote Support Localisation Section Disponibilité 24056 - Périodique Bibliothèque principale Documentaires Disponible New generation water-based associative rheology modifiers to meet current market demands / Pol Storme in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 206, N° 4618 (03/2016)
PermalinkPermalinkOptimising pigment distribution / Immanuel Willerich in EUROPEAN COATINGS JOURNAL (ECJ), N° 5 (05/2018)
PermalinkPolymères associatifs téléchéliques : rhéofluidification et séparation de phase sous cisaillement / Jean-François Le Meins in LES CAHIERS DE RHEOLOGIE, Vol. XVII, N° 1 (10/2000)
PermalinkPolyurethane rheological additives for water based architectural paints / Ramakant Maurya in PAINTINDIA, Vol. LXXIII, N° 3 (03/2023)
PermalinkRheological approach to select most suitable associative thickener for water-based polymer dispersions and paints / Ritesh A. Bhavsar in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 16, N° 4 (07/2019)
PermalinkSaving rheology modifiers / Angela Cackovich in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 194, N° 4476 (05/2004)
PermalinkSpray applications. Part IV. Compositional influences of HEUR thickeners on the spray and velocity profiles of waterborne latex coatings / Peter T. Elliott in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 4, N° 4 (12/2007)
PermalinkStudy of the simultaneous effects of MMT nanoclay and hydrophobically modified ethoxylated urethane (HEUR) on viscoelastic and steady shear properties of water-based acrylic resins / Mohsen Sarrafi in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 10, N° 5 (09/2013)
PermalinkSyneresis and rheology mechanisms of a latex-HEUR associative thickener system / Franceska A. Santos in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 14, N° 1 (01/2017)
PermalinkPermalinkThe effects of color concentrates on the rheology of tint bases / Douglas J. Herrick in COATINGS TECH, Vol. 10, N° 9 (09/2013)
PermalinkThickening paints for any weather / John J. Rabasco in EUROPEAN COATINGS JOURNAL (ECJ), N° 6 (06/2019)
PermalinkVersatile chemistry for improved heurs / Pol Storme in EUROPEAN COATINGS JOURNAL (ECJ), N° 10 (10/2015)
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