Air-drying high solids green coatings / Syed Haseebuddin in PAINTINDIA, Vol. LIX, N° 11 (11/2009)

[article]  inPAINTINDIA > Vol. LIX, N° 11 (11/2009) . - p. 61-76 Titre : Air-drying high solids green coatings Type de document : texte imprimé Auteurs : Syed Haseebuddin, Auteur ; Kumar Ghosh Swapan, Auteur ; Gulzar Waghoo, Auteur ; Randhir Parmar, Auteur ; Vaibhav Dave, Auteur ; Harshal Navghare, Auteur Année de publication : 2009 Article en page(s) : p. 61-76 Note générale : Bibliogr. Langues : Anglais (eng) Tags : Résines  alkyd  Polymères  branches  vertes  Enduits  verts  Dipentaerythritol  Dessication  air  Résistance  corrosion  Brillant  Faibles  COV Index. décimale : 667.9 Revêtements et enduits Résumé : Green coatings have become the core research area ot the scientists to address the issues of the environment health and safety. A series of high solid alkyd polymers from soya and dehydrated castor oil fatty acid (SOFA and DCOFA respectively) combination with varying percentage of Dipentaerythritol (DPE ; a hexa-functional polyol), have been synthesized and characterized for their physico chemical, optical, thermal and mechanical properties. For the study purpose the polymers were prepared at 80 % solids keeping the oil length constant. The curing behaviour of the alkyds was studied using FT-IR and DSC. Increasing DPE content in resin backbone was found to increase gloss and hardness.The gloss improvement was also supported well by AFM pictures. Results of 500 hours of QUV exposure revealed higher gloss retention for DP based systems. When compared for the anticorrosive properties, the EIS spectrum reveals that alkyd film containing 100 % DPE has the higher value of impedance. The overall performance of the DPE based system reveals the excellent combination of green aspects with improved coatings which is the need of the day. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=8324 [article]

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Synthesis of polymeric dispersants from renewable DCO fatty acid and their multifunctional behavior in waterborne flat paint / Ravi Dara in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 6, N° 4 (12/2009)  

[article]  inJOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 6, N° 4 (12/2009) . - p. 493-499 Titre : Synthesis of polymeric dispersants from renewable DCO fatty acid and their multifunctional behavior in waterborne flat paint Type de document : texte imprimé Auteurs : Ravi Dara, Auteur ; Ghanshyam Jaiswal, Auteur ; Girish Mirchandani, Auteur ; Randhir Parmar, Auteur ; Syed Haseebuddin, Auteur ; Gulzar Waghoo, Auteur ; Kumar Ghosh Swapan, Auteur Année de publication : 2009 Article en page(s) : p. 493-499 Note générale : Bibliogr. Langues : Américain (ame) Tags : Dehydrated  castor  oil  fatty  acids  (DCOFA)  Maleic  anhydride  Polymeric-dispersant  Pigment  dispersant  Rheology  modifier  Zeta  potential  Minimum  film-forming  temperature  (MFFT)  Waterborne  flat  paint Index. décimale : 667.9 Revêtements et enduits Résumé : Copolymers containing 50% dehydrated castor oil fatty acids (DCOFA) derived from renewable resources, were synthesized via free radical solvents less polymerization with maleic anhydride, styrene, and butyl acrylate. The copolymer was crosslinked further with polyethylene glycol 400 (PEG 400) to increase its molecular weight. The copolymers with and without crosslinking were then neutralized with sodium hydroxide to prepare polymeric dispersants DFCD1 and DFCD2 respectively in aqueous medium. It was observed via surface-tension measurement that both DFCD1 and DFCD2 transfer to the air–water interface before forming any aggregates, and the ease of forming the aggregates is in the order of DFCD1 > DFCD2. The efficacy of these dispersants was examined in the dispersion of the titanium dioxide pigment and conventional extenders like calcite, talc, and china clay using flow point and zeta potential measurements. The results reveal that DFCD2 improved the dispersing ability for the pigment and extenders studied. The performance of these polymeric dispersants was also studied and compared in waterborne flat paint as a rheology modifier and pigment-dispersing agent. The paint rheology profile and dE data indicate the superior performance of the paint containing dispersant DFCD2. When used in combination with conventional styrene-acrylic latex, DFCD1 and DFCD2 reduced the minimum film-forming temperature (MFFT) of the polymer latex. DOI : 10.1007/s11998-008-9156-y En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-008-9156-y.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=7692 [article]

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