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[article]
Titre : Fast and versatile : Advantages of dual cure technology in automotive interior finishes Type de document : texte imprimé Auteurs : Paul Gevaert, Auteur ; Chi-Yan Lee, Auteur ; Robert Potzmann ; Arie Cornelis Année de publication : 2018 Article en page(s) : p. 20-25 Langues : Anglais (eng) Catégories : Acrylates hydroxy-fonctionnels
Automobiles -- Habitacles
Copolymérisation
Essais (technologie)
Formulation (Génie chimique)
Isocyanates
Matières plastiques -- Revêtement
Polycarbonates
Revêtement en phase solvant
Revêtements -- Séchage sous rayonnement ultraviolet
Revêtements bi-composant
Terpolymère acrylonitrile butadiène styrèneIndex. décimale : 667.9 Revêtements et enduits Résumé : Plastics are increasingly used in vehicle interiors. Here UV cured coatings offer rapid curing, but non-planar components require some form of dual cure. As an alternative to conventional isocyanates, some isocyanate-bearing acrylates with low residual NCO were evaluated in dual cure formulations. Note de contenu : - Principles and advantages of dual cure technology
- Performance requirements for automotive interiors
- Summary of the first dual cure system tested
- Dual cure coatings tested against standart 2k type
- Enchancing performance with 'dual acrylate' systems
- Better results, faster cure and low free isocyanates
- FIGURES : 1. Principle of SB 2K crosslinking (NCO - OH reaction) - 2. Principle of SB UV 2K curing (OH acrylate - NCO reaction) - 3. Reactions of SB UV 2K using NCO-bearing acrylated resin
- TABLES : 1. Summary of test requirements for automotive interiors used in the evaluations - 2. Formulation of SB 2K systems - 3. Isocyanate-bearing acrylates - 4. Test results comparing SB UV 2K hydroxy functional acrylate with different NCO-bearing acrylates - 5. Comparison of hydroxy functional acrylate with multifunctional isocyanateEn ligne : https://drive.google.com/file/d/1RKc2MMDHbVB5j59oRrFVEvLjYo5MoRX-/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=30233
in EUROPEAN COATINGS JOURNAL (ECJ) > N° 3 (03/2018) . - p. 20-25[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 19729 - Périodique Bibliothèque principale Documentaires Disponible
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Titre : Feeling the way forward : Developing UV-curable soft touch finishes Type de document : texte imprimé Auteurs : Lisa Spagnola, Auteur ; Jeffrey Klang, Auteur ; Manjuli Gupta, Auteur ; Xavier Drujon, Auteur Année de publication : 2017 Article en page(s) : p. 40-45 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Essais (technologie)
Formulation (Génie chimique)
Oligomères
Plan d'expérience
Revêtements -- Séchage sous rayonnement ultraviolet
Toucher softIndex. décimale : 667.9 Revêtements et enduits Résumé : Soft-touch coatings are used across a wide range of markets. They are often based on 2-part polyurethanes. UV curing formulations were tested to produce similar coatings without the disadvantages of isocyanate cure. A range of haptic properties was eventually obtained. Note de contenu : - How soft touch coatings are classified
- Technological challenges
- Key advantages of radiation curing
- Formulation variables in the experimental procedure
- Test procedures summarised
- Little relationship between feel and other properties
- Extreme cases studied to find relationships
- Additional acrylates extend range of properties
- Further formulation changes extend range of properties
- FIGURES : 1. Idealised two-part soft touch coating structure - 2. 'Extremes' selected from DDE for further analysis - 3. Range of properties in DDE formulations with low coating durability - 4. Range of properties in DDE formulations with higher coating durability - 5. Properties of UA6 as a function of crosslinker content, with UA5 formulation for comparison - 6. Properties of blends of UA7 as a function of crosslinker content, with UA4 formulation for comparison - 7. How feel can be tailored by adjusting oligomer type and crosslinker concentration
- TABLES : 1. Summary of test methods for soft touch coatings - 2. Storage modulus and Tg for selected formulations - 3. Feel vs durability for selected DDE 'extremes' - 4. Expanded DOE with selected oligomersEn ligne : https://drive.google.com/file/d/1CHQcFTJ52IGhh0DeKW1Obays7xhrcmwR/view?usp=drive [...] Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=27822
in EUROPEAN COATINGS JOURNAL (ECJ) > N° 2 (02/2017) . - p. 40-45[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 18679 - Périodique Bibliothèque principale Documentaires Disponible Formulating strategies for low migration and low odour products / Susan E. Bailey in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 204, N° 4602 (11/2014)
[article]
Titre : Formulating strategies for low migration and low odour products Type de document : texte imprimé Auteurs : Susan E. Bailey, Auteur Année de publication : 2014 Article en page(s) : p. 14-15 Langues : Anglais (eng) Catégories : Emballages
Monomères
Oligomères
Photoamorceurs (chimie)
Revêtements -- Séchage sous rayonnement électronique
Revêtements -- Séchage sous rayonnement ultravioletIndex. décimale : 667.9 Revêtements et enduits Résumé : How radiation curing, both ultraviolet (UV) and electron beam (EB), can provide printed packaging with desired final properties without the bulk removal of solvent or water from a liquid formulation that forms a final coating product.
In the radiation curing process, UV light waves or high energy electrons impinge on the components of the formulated coating or ink to initiate the chemical reactions that form a crosslinked network of bonds between the components. Any components that do not react to incorporate into the polymer network are trapped within it ; however, they have the potential to migrate from the coating with exposure to heat, contact with similar materials or over time. Even though these components are minute constituents of the final film, they can migrate causing odour and impacting the coating performance. In certain applications,chemicals that can be released are regulated and need to be strictly controlled.
Figure 1 depicts a schematic of the liquid formulation containing monomers, oligomers and photoinitiator. After the cure reaction, many of the components are chemically bound. Residual monomer and photoinitiator molecules can remain unbound in the coating. Reactive end groups may still be present but bound to the polymer network through a different end of the molecule.
The strategies employed to create the desired look or performance of the coating or ink can often be in conflict with strategies to control the migration of materials in the final product. Considered selection of formulation components and the radiation curing system allow for both parts of the final product specification to be maintained.Note de contenu : - Photoinitiator considerations
- Monomer/oligomer selection
- Contributing factors
- Flexibility solution
- Balancing formulationEn ligne : https://drive.google.com/file/d/17YLrkbG6BsFu5WV3AVorWzixrxTlBjE0/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=22372
in POLYMERS PAINT COLOUR JOURNAL - PPCJ > Vol. 204, N° 4602 (11/2014) . - p. 14-15[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 16675 - Périodique Bibliothèque principale Documentaires Disponible Free radical and cationic photoinitiators in ultraviolet light curable coatings / Latoska N. Price in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 67, N° 849 (10/1995)
[article]
Titre : Free radical and cationic photoinitiators in ultraviolet light curable coatings Type de document : texte imprimé Auteurs : Latoska N. Price, Auteur Année de publication : 1995 Article en page(s) : p. 27-34 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Amorceurs (chimie)
Cations
DiazoniumUn diazonium est un cation formé d'un groupe de deux atomes d'azotes en position terminale sur une molécule. La structure R-N≡N+ est également considérée comme un groupe fonctionnel.
Iodonium
Photochimie
Polyaddition
Réticulation (polymérisation)
Revêtements
Revêtements -- Séchage sous rayonnement ultraviolet
Sulfonium
ToxicologieIndex. décimale : 667.9 Revêtements et enduits Résumé : The Environmental Protection Agency has legislated more stringent air quality laws which has created the need for new innovation in the development of low VOC coatings. In the quest for a more environmentally compliant coating, a number of new technologies have become available from coatings manufacturers. One field of study that has gained interest is that of radiation curable products initiated by either ultraviolet light (UV) or electron beam (EB). Ultraviolet light curable coatings are one component systems that combine the benefits of rapid film formation and low VOC into high quality coatings. This paper will discuss cationic and free radical polymerization, types of photoinitiators, toxicology, application, and potential markets. Note de contenu : - INTRODUCTION : Free radical versus cationic polymerization
- CATIONIC PHOTOINITIATORS : Aryldiazonium salts - Diaryliodonium salts - Sulphonium salts - Organometallic photoinitiators
- TOXICOLOGY : Applications and markets - Wood - Plastics - Flooring - MetalPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=18560
in JOURNAL OF COATINGS TECHNOLOGY (JCT) > Vol. 67, N° 849 (10/1995) . - p. 27-34[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 003495 - Périodique Bibliothèque principale Documentaires Disponible 003507 - Périodique Bibliothèque principale Documentaires Exclu du prêt Functional fillers in UV curing wood coatings / Hubert Oggermüller in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 203, N° 4591 (12/2013)
[article]
Titre : Functional fillers in UV curing wood coatings Type de document : texte imprimé Auteurs : Hubert Oggermüller, Auteur ; Félix Vicente Mondéjar, Auteur Année de publication : 2013 Article en page(s) : p. 26-28 Langues : Anglais (eng) Catégories : Agent mattant
Bois -- Finition
Brillance (optique)
Charges (matériaux)
Copolymère uréthane acrylate
Formulation (Génie chimique)
Laque et laquage
Liants
Matériaux -- Propriétés fonctionnelles
Nitrocellulose
Polymères aliphatiques
Résistance à l'abrasion
Revêtements -- Finition:Peinture -- Finition
Revêtements -- Propriétés mécaniques:Peinture -- Propriétés mécaniques
Revêtements -- Propriétés optiques:Peinture -- Propriétés optiques
Revêtements -- Séchage sous rayonnement ultraviolet:Peinture -- Séchage sous rayonnement ultraviolet
SiliceLa silice est la forme naturelle du dioxyde de silicium (SiO2) qui entre dans la composition de nombreux minéraux.
La silice existe à l'état libre sous différentes formes cristallines ou amorphes et à l'état combiné dans les silicates, les groupes SiO2 étant alors liés à d'autres atomes (Al : Aluminium, Fe : Fer, Mg : Magnésium, Ca : Calcium, Na : Sodium, K : Potassium...).
Les silicates sont les constituants principaux du manteau et de l'écorce terrestre. La silice libre est également très abondante dans la nature, sous forme de quartz, de calcédoine et de terre de diatomée. La silice représente 60,6 % de la masse de la croûte terrestre continentale.
ViscositéIndex. décimale : 667.9 Revêtements et enduits Résumé : The market for wood paints is growing strongly, particularly in Asian regions, where, in the Far East, Indonesia, China, Malaysia and Vietnam represent the four biggest exporters of wood furniture. The growing export volume of wood furniture gives rise to an icreasing demand for easy-to-process, high quality wood coatings. In addition, new developments should offer lowest possible content of environmentally harmful volatile organic solvents.
UV curing wood paints offer an environnementally friendly alternative to conventional nitrocellulose-based coatings or acid curing lacquers. Binders are products that rapidly undergo radiation induced polymerisation and cure in a fraction of a second.
In addition, they offer advantages with respect tohigh throughput rates, outstanding film properties and economics in space, energy and material requirements. The coatings also distinguish themselves by improved scratch and wear resistance compared with conventional systems.
The objective of the present study was to assess the influence of functional fillers upon the mechanical and optical properties of UV curing coatings systems. This was done by comparing Neuburg Siliceous Earth (Neuburger Kieselerde) with a commercial matting, as well as their blends in a topcoat on an aliphatic urethane acrylate.Note de contenu : - UV curing topcoat based on an aliphatic urethane acrylate
- Filler characteristics and test design
- Base formulation
- Experimental
- Viscosity
- Colour change
- Gloss
- Abrasion resistance
- Raw material costs
- Summary and comparisonEn ligne : https://drive.google.com/file/d/1GTT-B2uw8nv5LZouYqt7e6Hn2t1KffiT/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=20209
in POLYMERS PAINT COLOUR JOURNAL - PPCJ > Vol. 203, N° 4591 (12/2013) . - p. 26-28[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 15825 - Périodique Bibliothèque principale Documentaires Disponible Futuristic photo-initiators that can upgrade conventional ultra-violet curing technology / Pradeep S. Verma in PAINTINDIA, Vol. LXVIII, N° 2 (02/2018)
PermalinkGlycolytic depolymerization of PET waste using MP-diol and utilization of recycled product for UV-curable wood coating / Vandana Jamdar in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 15, N° 2 (03/2018)
PermalinkGood prospects for UV LEDs in INTERNATIONAL SURFACE TECHNOLOGY (IST), Vol. 13, N° 2 (2020)
PermalinkPermalinkGreening radiation curing / Hugues van den Bergen in EUROPEAN COATINGS JOURNAL (ECJ), N° 9 (09/2015)
PermalinkHeat resistant, ultra-smooth UV curable alkyd primers for PVD / Akio Umino in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 207, N° 4636 (11/2017)
PermalinkHigh speed cure / John Maitland in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 192, N° 4458 (11/2002)
PermalinkHighlighting the importance of homogeneous curing / David Ivarsson in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 210, N° 4666 (12/2020)
PermalinkHighly improved UV-shielding and mechanical properties of UV-curable epoxy acrylate nanocomposites by incorporating functionalized aramid nanofibers / Ying Wang in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 21, N° 1 (01/2024)
PermalinkHow to speed up the UV curing of water-based acrylic coatings / C. Decker in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 1, N° 2 (04/2004)
PermalinkHybrid organic/inorganic coatings produced using a dual-cure mechanism / Jie He in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 9, N° 4 (07/2012)
PermalinkHydrophobic, transparent waterborne UV-curable polyurethane nanocomposites based on polycarbonate and PCL-PDMS-PCL reinforced with colloidal silica / Shengven Zhang in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 13, N° 6 (11/2016)
PermalinkImproving the application and performance of UV-cured, field applied coatings / Jo Ann Arceneaux in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 204, N° 4601 (10/2014)
PermalinkIn a new light / Tom Molamphy in POLYMERS PAINT COLOUR JOURNAL - PPCJ, Vol. 196, N° 4502 (07/2006)
PermalinkIncreasing productivity and reducing emissions in INTERNATIONAL SURFACE TECHNOLOGY (IST), Vol. 13, N° 2 (2020)
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