Facile synthesis of a cardanol-based levelling agent as a biodegradable alternative to tristyrylphenol ethoxylates for the dyeing of polyester fabric / Kun Chen in COLORATION TECHNOLOGY, Vol. 138, N° 3 (06/2022)  

[article]  inCOLORATION TECHNOLOGY > Vol. 138, N° 3 (06/2022) . - p. 266-277 Titre : Facile synthesis of a cardanol-based levelling agent as a biodegradable alternative to tristyrylphenol ethoxylates for the dyeing of polyester fabric Type de document : texte imprimé Auteurs : Kun Chen, Auteur ; Jiefang He, Auteur ; Benjamin Tawiah, Auteur ; Xiangdong Zhou, Auteur ; Yuyang Zhou, Auteur Année de publication : 2022 Article en page(s) : p. 266-277 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation Cardanol Éthoxylation alcools et phénols, généralement pour produire de puissants agents surfactants ou mouillants. Fibres polyesters Oligomères Produits chimiques -- Biodégradation Solidité de la couleur Surfactants -- Suppression ou remplacement Teinture -- Fibres textiles synthétiques Index. décimale : 667.3 Teinture et impression des tissus Résumé : To reduce the overdependence on petroleum-based surfactants for the dyeing of polyester fabrics, a series of biodegradable cardanol-based polyethoxylate oligomers (CPm, m = 5, 7 and 9) were synthesised by ethoxylation of cardanol with ethylene oxide. The synthesised compounds were characterised and confirmed by Fourier Transform–infrared spectroscopy and proton nuclear magnetic resonance spectroscopy. In addition, the physical, biodegradable and dyeing-assisting properties of CPm were evaluated through comparison with tristyrylphenol ethoxylates (A typical commercial surfactant). Results revealed that CPm showed a higher hydroxyl value, better dispersing capability and a higher migration percentage than tristyrylphenol ethoxylates. Specifically, CP5 (0.5 g/L) improved the migration percentage by 12.03% compared with tristyrylphenol ethoxylates. The migration performance of the surfactants followed a descending order of CP5 > CP7 > CP9 > tristyrylphenol ethoxylates. Importantly, CP5 displays a higher degradation propensity than tristyrylphenol ethoxylates, demonstrating its biodegradable merit. In summary, the cardanol-based polyethoxylates synthesised through this research are promising biodegradable and effective alternatives to conventional levelling agents for disperse dyeing, which contributes a new strategy to the sustainable development of the textile industry. Note de contenu : - EXPERIMENTAL : Materials - Synthesis - Characterisations - Dyeing process - RESULTS AND DISCUSSION : Characterisations of CPm - Dyeing performance - Table 1 : Physical properties and surface activity of the CP series and TSPEOs - Table 2 : Biodegradation capabilities of CP5 and TSPEOs - Table 3 : Colour fastness of dyed fabric using CP5 and TSPEOs DOI : https://doi.org/10.1111/cote.12588 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12588 Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37856 [article]

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Synthesis and application of nonionic Gemini surfactants based on grape seed oil / Kangwei Si in COLORATION TECHNOLOGY, Vol. 140, N° 1 (02/2024)  

[article]  inCOLORATION TECHNOLOGY > Vol. 140, N° 1 (02/2024) . - p. 42-51 Titre : Synthesis and application of nonionic Gemini surfactants based on grape seed oil Type de document : texte imprimé Auteurs : Kangwei Si, Auteur ; Zhiwei Xu, Auteur ; Xiangdong Zhou, Auteur Année de publication : 2024 Article en page(s) : p. 42-51 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Colorants acides Huiles et graisses végétales Mesure Pépins de raisins Polyamide 66 Surfactants -- Synthèse Teinture -- Fibres textiles synthétiques Index. décimale : 667.3 Teinture et impression des tissus Résumé : A series of vegetable oil-based nonionic Gemini surfactant (GPNGS) was prepared using grape seed oil and polyethylene glycol monomethyl ether (350, 550, 750) as the primary raw materials. The chemical structures of different types of GPNGS were characterised by Fourier Transform–infrared spectroscopy, elemental analysis, proton nuclear magnetic resonance and carbon-13 nuclear magnetic resonance. The critical micelle concentration (CMC) of GPNGS with different polyoxyethylene chain lengths was measured using the Wilhelmy ring method (CMC: ca. 1.4 × 10−4 to 5 × 10−4 mol/L). The results of wettability testing showed that the contact angle of GPNGS on polyamide film was ca. 46-49°. In addition, the interaction of surfactants with acid dyes was also investigated. The ultraviolet spectrum showed a balance between dyes, surfactants and the dye/surfactant complex. Next, the GPNGS was used as a nylon 66 acid dye levelling agent. After adding 0.2 mmol/L of surfactants, the standard deviations (S(λ)) of nylon 66 dyeing decreased from 0.084 to ca. 0.036-0.044, exhibiting a good levelling effect. Note de contenu : - MATERIALS AND METHODS : Materials - Synthesis - Dyeing process of nylon 66 fabric - Measurement - RESULTS AND DISCUSSION : Elemental analysis - Surface performance - Polyamide acid dyeing - Table 1 : Surface active parameters of GPNGS - Table 2 : The effect of different types of levelling agent on K/S and levelness S(λ) DOI : https://doi.org/10.1111/cote.12689 En ligne : https://drive.google.com/file/d/1jJ2QFloHYYkObwvaRLI8L3tVpnm3dEYE/view?usp=drive [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=40389 [article]

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Synthesis and application of novel glucose derived nonionic gemini surfactant / Zhiwei Xu in COLORATION TECHNOLOGY, Vol. 138, N° 5 (10/2022)  

[article]  inCOLORATION TECHNOLOGY > Vol. 138, N° 5 (10/2022) . - p. 565-578 Titre : Synthesis and application of novel glucose derived nonionic gemini surfactant Type de document : texte imprimé Auteurs : Zhiwei Xu, Auteur ; Qianqian Cheng, Auteur ; Xiangdong Zhou, Auteur Année de publication : 2022 Article en page(s) : p. 565-578 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse thermique Caractérisation Colorants dispersés Catégorie de colorants très peu solubles dans l'eau, utilisés à l'origine comme colorants pour l'acétate, et qui généralement sont appliqués sous forme de suspensions aqueuses de faible concentration.Les colorants dispersés sont largement utilisés dans la teinture de la plupart des fibres manufacturées, surtout le polyester. Fibres polyesters Mesure Surfactants -- Synthèse Teinture -- Fibres textiles synthétiques Index. décimale : 667.3 Teinture et impression des tissus Résumé : A novel group of nonionic gemini surfactant (GTPEA) with ethylidene spacer structure was prepared from glucose-lactone, triethylenetetramine, alkyl epoxy polyether and acyl chloride of different alkyl chain lengths. The chemical structure of GTPEA were characterised by Fourier-transform infrared (FTIR) spectroscopy, nuclear magnetic resonance (NMR) and high-resolution mass spectrometry (HRMS). The thermal properties of the three surfactants were characterised by thermogravimetric analysis (TGA). The critical micelle concentrations (cmc values) of GTPEA with different hydrophobic chain lengths were measured using the Wilhelmy plate method (cmc: 1.58 × 10−5 to 5.01 × 10−6 mol/L). The solubilisation, emulsification and solubilisation performance tests showed the excellent surface properties of nonionic gemini surfactants. GTPEA-12 with a hydrophobic carbon chain length of 12 carbon atoms was selected to explore the dispersing performance of surfactants on disperse dyes and the levelling performance of polyester fibre disperse dyes. The test results have shown that the dispersion force was 96%, and the particle size of 0.1 g disperse dye was 196 nm in 100 ml of 4 g/L GTPEA-12 solutions. Finally, GTPEA-12 was used as a levelling agent in the dispersion dyeing of polyester fabrics. GTPEA-12 of 0.1 g/L can provide an excellent levelling effect of S(λ) = 0.026 for polyester and has little impact on the colour yield (K/S = 5.0) of polyester fabric. Note de contenu : - EXPERIMENTAL SECTION : Materials - Synthesis of nonionic gemini surfactant - Dyeing process of polyester fabric - Measurements - RESULTS AND DISCUSSION : Thermal analysis - Surface performance - Used in the dyeing of polyester disperse dyes - Table 1 : Surface active parameters of GTPEA - Table 2 : Maximum solubilisation volume and solubilisation power of different surfactants - Table 3 : The effect of K/S value and levelness S(λ) by levelling agent DOI : https://doi.org/10.1111/cote.12614 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12614 Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=38129 [article]

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