Effect of acid groups in hydroxyl functional resins on the properties of polyester-urethane powder coating / Bin Wu in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 72, N° 906 (07/2000)

[article]  inJOURNAL OF COATINGS TECHNOLOGY (JCT) > Vol. 72, N° 906 (07/2000) . - p. 55-62 Titre : Effect of acid groups in hydroxyl functional resins on the properties of polyester-urethane powder coating Type de document : texte imprimé Auteurs : Bin Wu, Auteur ; Sanjay Padaki, Auteur Année de publication : 2000 Article en page(s) : p. 55-62 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acidité Couches minces Essais de brouillard salin Formulation (Génie chimique) Groupement carboxyle Hydroxyle En chimie organique, un hydroxyle (ou oxhydryle) peut désigner deux entités. Un groupement -OH, appelé aussi hydroxy, qui se rencontre en particulier dans les alcools et les phénols. Un radical : HO^{\bullet}. Il est produit par exemple lors de réactions de dissociation de peroxydes, en présence d'ions de métaux de transition (Fe(II), Cu(I), réaction de Fenton), de chauffage ou de rayonnement. Liants Polyesters Polyuréthanes Résistance aux conditions climatiques Réticulation (polymérisation) Revêtements -- Propriétés mécaniques:Peinture -- Propriétés mécaniques Revêtements poudre:Peinture poudre Index. décimale : 667.9 Revêtements et enduits Résumé : Hydroxyl-terminated polyester resins with different acid numbers were synthesized and used in powder coating formulations. Coatings were formulated with isophorone diisocyanate (IPDI)-based hardeners and tested for mechanical performance, appearance, and weathering. This study found that resins containing a high concentration of residual acid groups (also referred to as undercondensed resins) had to be formulated according to their total reactive number, the sum of acid and hydroxyl numbers, in order to achieve complete cure. High acid numbers also caused poor overbake and salt spray resistance. The addition of adipic or benzoic acids to the powder formulation accelerated cure. Note de contenu : - RESULTS AND DISCUSSION: Resins - Powder formulation - Curing chemistry - Effect of AN and crosslinker stoichiometry on curing - Acid catalysis - Effect of residual acid groups on coating properties - Overbake resistance - Salt fog testing (ASTM B 117) - Curing residual carboxyl groups Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=17986 [article]

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Effect of spin-draw rate and stretching ratio on polypropylene hollow fiber membrane made by melt-spinning and stretching method / F.-J. Wei in INTERNATIONAL POLYMER PROCESSING, Vol. XXXIII, N° 1 (03/2018)  

[article]  inINTERNATIONAL POLYMER PROCESSING > Vol. XXXIII, N° 1 (03/2018) . - p. 13-19 Titre : Effect of spin-draw rate and stretching ratio on polypropylene hollow fiber membrane made by melt-spinning and stretching method Type de document : texte imprimé Auteurs : F.-J. Wei, Auteur ; H.-J. Shao, Auteur ; Bin Wu ; K.-Z. Zhang ; D.-J. Luo ; S.-H. Qin ; Z. Hao ; H.-J. Shao Année de publication : 2018 Article en page(s) : p. 13-19 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse thermique Diffusion aux petits angles Extrusion filage Fibres creuses Membranes (technologie) Microscopie électronique à balayage Perméabilité Polypropylène Porosité Procédés de fabrication Index. décimale : 668.4 Plastiques, vinyles Résumé : A series of polypropylene hollow fiber membranes was fabricated by melt-spinning and stretching. The crystalline behavior and hard elasticity of precursor hollow fibers were studied by differential scanning calorimetry (DSC), elastic recovery and strain-stress curves. The structure and properties of membranes were investigated in detail by scanning electron microscopy (SEM), optical microscopy, pure water flux, and so on. The results showed that membranes with excellent structure and properties can be obtained at a spin-draw rate of 350 m/min and a stretching ratio of 200 %. The evolution of crystal structure was explored during the annealing and stretching processes by two-dimensional small-angle X-ray scattering (2D-SAXS). Shish-kebab structure was obtained during annealing for hollow fibers at a spin-draw rate of 350 m/min. The crystalline lamellae were destroyed and micropores were formed during the fabrication of membranes by stretching. Note de contenu : - MATERIALS : Materials - Samples Preparation - Differential scanning calorimetry - Hard elasticity - Scanning electron microscopy - Optical microscopy - Mean pore size porosity - Pure water permeability - Two-dimensional small-angle x-ray scattering - RESULTS AND DISCUSSION : Effect of spin-draw rate on properties of polypropylene hollow fiber and membrane - Effect of stretching ratio on structure and properties of membranes - SAXS analysis DOI : 10.3139/217.3303 En ligne : https://drive.google.com/file/d/1abCYpLJTnLTRmCTM2mbZVQWFMnlpBStS/view?usp=drive [...] Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=30154 [article]

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