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Aliphatic isocyanates blocked with volatile alcohols for decorative coatings / Yun Huang in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 67, N° 842 (03/1995)
[article]
Titre : Aliphatic isocyanates blocked with volatile alcohols for decorative coatings Type de document : texte imprimé Auteurs : Yun Huang, Auteur ; Guobei Chu, Auteur ; Frank N. Jones, Auteur ; Marjorie Nieh, Auteur Année de publication : 1995 Article en page(s) : p.33-40 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Alcool
Composés aliphatiques
Copolymères séquencés
Liants
Polyisocyanates
Réticulation (polymérisation)
Revêtements décoratifs:Peinture décorativeIndex. décimale : 667.9 Revêtements et enduits Résumé : Aliphatic polyisocyanates blocked with simple aliphatic alcohols, such as methanol and ethanol, are widely thought to require baking temperatures and times that are too high and/or too long for application of decorative coatings under production conditions. Here we show that polyisocyanates blocked with these alcohols can, when catalyzed with organotin catalysts, crosslink an acrylic polyol at temperatures comparable to those of commercial ε-caprolactam blocked crosslinkers. With 0.5% of dibutyl tin diacetate catalyst, methanol blocked 1,3-bis(1-isocyanato-1-methylethyl)benzene (TMXDI) and methanol blocked hexamethylene diisocyanate isocyanurate are effective crosslinkers for an acrylic polyol at 145 to 155°C. It is theorized that physical factors (blocking agent diffusion rate and volatility) strongly influence cure response. Note de contenu : - INTRODUCTION AND LITERATURE REVIEW : Overview of blocked polyisocyanates - "Cure Response" of blocked polyisocyanate coatings defined - Selected previous studies on cure response - Deblocking (Unblocking) temperatures - Other factors that can affect cure response
- RESULTS : Synthesis and characterization of blocked isocyanates - Formulations and catalyst studies - Blocking agent cure rate studies
- Discussion : Technological considerations - Mechanistic considerationsPermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=18580
in JOURNAL OF COATINGS TECHNOLOGY (JCT) > Vol. 67, N° 842 (03/1995) . - p.33-40[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 003500 - Périodique Bibliothèque principale Documentaires Disponible Color and appearance : I / Zeno W. Wicks in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 73, N° 917 (06/2001)
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Titre : Color and appearance : I Type de document : texte imprimé Auteurs : Zeno W. Wicks, Auteur ; Frank N. Jones, Auteur ; S. Peter Pappas, Auteur Année de publication : 2001 Article en page(s) : p. 49-56 Note générale : Bibliogr. Langues : Américain (ame) Tags : Matériau revêtement Peinture Propriété optique Feuil Couleur Aspect Observation visuelle Source lumineuse Contretypage couleur Index. décimale : 667.9 Revêtements et enduits Résumé : Color and the interrelated topic of gloss are important to the decorative aspects of the use of coatings and, sometimes, to the functional aspects of their use. We have all dealt with color since we were babies, but most people have little understanding of color. Many technical people think of it as an aspect of physics dealing with the distribution of visible light. While that is a factor, color is a psychophysical phenomenon. The difficulty of understanding color can be seen by considering the most rigorous definition of color that has been prepared: Color is that characteristic of light by which an observer may distinguish between two structure-free fields of view of the same size and shape. In effect, it says that color is what is left to distinguish between two objects when all the other variables are removed. Not a very satisfying definition. Color has three components: an observer, a light source, and an object. (The single exception is when the light source is the object being viewed.) There is no color on an uninhabited island. This is not just a semantic statement; color requires an observer. There is no color in the absence of light; in a completely darkened room there is no color, not because you cannot see it, but because it is not there. There must be an object; if you look out the window of a spaceship without looking at a planet or star, there is no color-there is an observer, there is light, but there is no object. Another major factor affecting appearance is surface roughness. If a surface is very smooth, it has a high gloss; if it is rough on a scale below the ability of the eye to resolve the roughness, it has a low gloss. If, however, the roughness can be resolved visually, a film may exhibit brush marks, orange peel, texture, and so forth. Furthermore, there can be a combination of small scale and larger scale roughness, so films can, for example, have a low gloss and brush marks or high gloss and orange peel. The eye can resolve irregularities in surface smoothness of approximately 25 mm, depending on the distance from the object. Adding to the complications, color and gloss interact, changing either changes the other. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5748
in JOURNAL OF COATINGS TECHNOLOGY (JCT) > Vol. 73, N° 917 (06/2001) . - p. 49-56[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 001225 - Périodique Bibliothèque principale Documentaires Disponible Color and appearance : II / Zeno W. Wicks in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 73, N° 918 (07/2001)
[article]
Titre : Color and appearance : II Type de document : texte imprimé Auteurs : Zeno W. Wicks, Auteur ; Frank N. Jones, Auteur ; S. Peter Pappas, Auteur Année de publication : 2001 Article en page(s) : p. 73-81 Note générale : Bibliogr. Langues : Américain (ame) Tags : Matériau revêtement Peinture Propriété optique Feuil Couleur Aspect Observation visuelle Source lumineuse Contretypage couleur Index. décimale : 667.9 Revêtements et enduits Résumé : Color and the interrelated topic of gloss are important to the decorative aspects of the use of coatings and, sometimes, to the functional aspects of their use. We have all dealt with color since we were babies, but most people have little understanding of color. Many technical people think of it as an aspect of physics dealing with the distribution of visible light. While that is a factor, color is a psychophysical phenomenon. The difficulty of understanding color can be seen by considering the most rigorous definition of color that has been prepared: Color is that characteristic of light by which an observer may distinguish between two structure-free fields of view of the same size and shape. In effect, it says that color is what is left to distinguish between two objects when all the other variables are removed. Not a very satisfying definition. Color has three components: an observer, a light source, and an object. (The single exception is when the light source is the object being viewed.) There is no color on an uninhabited island. This is not just a semantic statement; color requires an observer. There is no color in the absence of light; in a completely darkened room there is no color, not because you cannot see it, but because it is not there. There must be an object; if you look out the window of a spaceship without looking at a planet or star, there is no color-there is an observer, there is light, but there is no object. Another major factor affecting appearance is surface roughness. If a surface is very smooth, it has a high gloss; if it is rough on a scale below the ability of the eye to resolve the roughness, it has a low gloss. If, however, the roughness can be resolved visually, a film may exhibit brush marks, orange peel, texture, and so forth. Furthermore, there can be a combination of small scale and larger scale roughness, so films can, for example, have a low gloss and brush marks or high gloss and orange peel. The eye can resolve irregularities in surface smoothness of approximately 25 mm, depending on the distance from the object. Adding to the complications, color and gloss interact, changing either changes the other. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5741
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Code-barres Cote Support Localisation Section Disponibilité 001226 - Périodique Bibliothèque principale Documentaires Disponible Color and appearance : III / Zeno W. Wicks in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 73, N° 919 (08/2001)
[article]
Titre : Color and appearance : III Type de document : texte imprimé Auteurs : Zeno W. Wicks, Auteur ; Frank N. Jones, Auteur ; S. Peter Pappas, Auteur Année de publication : 2001 Article en page(s) : p. 83-88 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Couleur
Photométrie
Revêtements décoratifs:Peinture décorativeIndex. décimale : 667.9 Revêtements et enduits Résumé : Color and the interrelated topic of gloss are important to the decorative aspects of the use of coatings and, sometimes, to the functional aspects of their use. We have all dealt with color since we were babies, but most people have little understanding of color. Many technical people think of it as an aspect of physics dealing with the distribution of visible light. While that is a factor, color is a psychophysical phenomenon. The difficulty of understanding color can be seen by considering the most rigorous definition of color that has been prepared: Color is that characteristic of light by which an observer may distinguish between two structure-free fields of view of the same size and shape. In effect, it says that color is what is left to distinguish between two objects when all the other variables are removed. Not a very satisfying definition.
Color has three components: an observer, a light source, and an object. (The single exception is when the tight source is the object being viewed.) There is no color on an uninhabited island. This is not just a semantic statement; color requires an observer. There is no color in the absence of light; in a completely darkened room there is no color, not because you cannot see it, but because it is not there. There must be an object; if you look out the window of a spaceship without looking at a planet or star, there is no color--there is an observer, there is light, but there is no object.
Another major factor affecting appearance is surface roughness. If a surface is very smooth, it has a high gloss; if it is rough on a scale below the ability of the eye to resolve the roughness, it has a low gloss. If, however, the roughness can be resolved visually, a film may exhibit brush marks, orange peel, texture, and so forth. Furthermore, there can be a combination of small scale and larger scale roughness, so films can, for example, have a low gloss and brush marks or high gloss and orange peel. The eye can resolve irregularities in surface smoothness of approximately 25 mm, depending on the distance from the object. Adding to the complications, color and gloss interact, changing either changes the other.Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5747
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Code-barres Cote Support Localisation Section Disponibilité 001227 - Périodique Bibliothèque principale Documentaires Disponible Exterior durability : I / Zeno W. Wicks in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 71, N° 888 (01/1999)
[article]
Titre : Exterior durability : I Type de document : texte imprimé Auteurs : Zeno W. Wicks, Auteur ; Frank N. Jones, Auteur ; S. Peter Pappas, Auteur Année de publication : 1999 Article en page(s) : p. 53-55 Note générale : bibliogr. Langues : Américain (ame) Catégories : Durée de vie (Ingénierie)
Photo-oxydation
Résistance aux conditions climatiques
Revêtements
Revêtements -- DétériorationIndex. décimale : 667.9 Revêtements et enduits Résumé : Exterior durability of coatings refers to their resistance to change during outdoor exposure; such changes include changes of modulus, loss of strength, embrittlement, discoloration, loss of adhesion, chalking, loss of gloss, and environmental etching. Thus, both aesthetic and functional properties are involved. The terms outdoor durability and weatherability are also used. The most common chemical processes leading to degradation of coatings are photoinitiated oxidation and hydrolysis resulting from exposure to sunlight, air, and water. These processes are interrelated, including enhanced photoxidative degradation in high humidity and enhanced hydrolytic degradation during photoexposure. Furthermore, both processes are accelerated by higher temperatures. Hydrolytic degradation may be enhanced by exposure to acid, as from acid rain. Other atmospheric degradants include ozone and oxides of nitrogen and sulfur. Changes in temperature and humidity may result in cracking, which arises from the expansion and contraction of coatings or substrates. Rates at which these processes occur vary, depending on exposure site(s), time of year, coating composition, and substrate. Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=17814
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Code-barres Cote Support Localisation Section Disponibilité 003557 - Périodique Bibliothèque principale Documentaires Disponible 009602 - Périodique Bibliothèque principale Documentaires Exclu du prêt Exterior Durability : II / Zeno W. Wicks in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 71, N° 889 (02/1999)
PermalinkExterior durability : III / Zeno W. Wicks in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 71, N° 890 (03/1999)
PermalinkExterior durability : IV / Zeno W. Wicks in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 71, N° 891 (04/1999)
PermalinkHigh-solids nonaqueous dispersion coatings based on crystalline oligoesters / Ganghui Teng in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 66, N° 829 (02/1994)
PermalinkInvestigation of the effect of precoalescence or postcoalescence crosslinking on film formation, properties, and latex morphology / Ravi G. Joshi in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 6, N° 1 (03/2009)
PermalinkMeasurement of mar resistance and study of marring mechanism of polymeric coatings with scanning probe microscope / Weidian C. Shen in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 72, N° 907 (08/2000)
PermalinkMethods for studying the mechanical and tribological properties of hard and soft coatings with a nano-indenter / Weidian C. Shen in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 1, N° 2 (04/2004)
PermalinkNanolatex technology 1 : synthesis and characterization of nanosize acrylic latexes and comparison to their conventional size counterparts / Ravi G. Joshi in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 6 (11/2021)
PermalinkNanolatex technology 2 : blending polymer nanoparticles with conventional latexes for synergistic property improvement / Frank N. Jones in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 4 (07/2021)
PermalinkNovel coatings based on mixtures of blown soybean oil and acrylate prepolymers / Pehong Ni in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 73, N° 912 (01/2001)
PermalinkNovel synthesis of carboxy - functional soybean acrylic - alkyd resins for water - reducible coatings / Changchun Wang in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 72, N° 904 (05/2000)
PermalinkOrganic coatings / Zeno W. Wicks / New York [Etats-Unis] : John Wiley & Sons (2007)
PermalinkOutlook for zero-VOC resins / Frank N. Jones in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 73, N° 916 (05/2001)
PermalinkPigment dispersion : I / Zeno W. Wicks in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 73, N° 921 (10/2001)
PermalinkPigment dispersion : II / Zeno W. Wicks in JOURNAL OF COATINGS TECHNOLOGY (JCT), Vol. 73, N° 922 (11/2001)
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