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Studies on the ethiopian camel hides for their suitability for making leather / M. Belay in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIV, N° 2 (02/2019)
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Titre : Studies on the ethiopian camel hides for their suitability for making leather Type de document : texte imprimé Auteurs : M. Belay, Auteur ; R. Karthikeyan, Auteur ; Victor John Sundar, Auteur ; Rathinam Aravindhan, Auteur Année de publication : 2019 Article en page(s) : p. 48-54 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Caractérisation
Croûte (cuir)On entend par "cuir en croûte" des cuirs ayant subi les opérations jusqu'au tannage, à l'exclusion de toute opération de corroyage ou de finissage, mais qui, par opposition aux wet-blue ont été séchés.
Cuirs et peaux -- Analyse
Cuirs et peaux -- Propriétés physiques
Cuirs et peaux -- Teinture
Cuirs et peaux de chameaux
Dichroïsme circulaire
Peau -- Histologie
Tannage
Wet-blue (tannage)Peau tannée au chrome (le chrome donne une couleur bleue)Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : Ethiopia has the largest livestock population in the African countries, providing a strong raw material base for the growing leather and leather products sector. The main source of raw material for the Ethiopian tanning industry comes from sheep, goat and cattle. Since the Ethiopian leather industry is booming, the industry is now looking to exploit the alternative raw materials available in the country. Camel (Camelus dromedarius) is one of the most important livestock in the East African countries. Due to lack of awareness and technology, most of the hides are not utilized fully by the tanners. Hence an attempt has been made in the present study to exploit the camel hides as an alternative source of raw material for the growing Ethiopian leather industry. Histological analysis of the camel hide has been carried out at different stages of processing. Based on the histological understanding, the strategy for making suitable leather from camel hide was established. The raw material has also been characterized for fat, nitrogen and collagen content. The raw material has been converted into finished leather by using suitable tanning methodology and the leathers were utilized for the preparation of different types of end products. Finished leathers have been developed and the physical and chemical properties have also been evaluated. The results obtained from the chemical and physical tests revealed that the raw material is suitable for the manufacture of upper leather. Note de contenu : - EXPERIMENTAL : Materials - Chemical and structural analysis of camel hides. Histological studies with hematoxyline-eosin (H & E) staining - Scanning electron microscopy (SEM) of wet blue camel leather - Determination of moisture content - Determination of fat content - Determination of nitrogen content - Determination of hydroxyproline content - SDS-polyacrylamide-gel electrophoresis (SDS-PAGE) - Circular dichroism (CD) of camel collagen - Development of upper crust leathers from camel hides - Physical testing of leathers - Organoleptic properties
- RESULTS AND DISCUSSION : Histological studies of camel hides using H & E staining - Effect of tanning on the fibre structure of camel hide using SEM - Characterization of camel hide : moisture, nitrogen and fat content - Estimation of collagen content - SDS-PAGE analysis - Circular dichroism analysis - Analysis of wet blue leathers - Physical testing of crust leathersEn ligne : https://drive.google.com/file/d/1_faeDLWoA28x8P2iiXztw7r1bsUE6vWu/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=31717
in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA) > Vol. CXIV, N° 2 (02/2019) . - p. 48-54[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 20607 - Périodique Bibliothèque principale Documentaires Disponible Studies on thermal and morphological characteristics of siloxane containing epoxy resins cured by microwave radiation / N. Uyanik in SURFACE COATINGS INTERNATIONAL. PART B : COATINGS TRANSACTIONS, Vol. 87, B2 (06/2004)
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Titre : Studies on thermal and morphological characteristics of siloxane containing epoxy resins cured by microwave radiation Type de document : texte imprimé Auteurs : N. Uyanik, Auteur ; C. Erbil, Auteur ; M. Karadayi, Auteur Année de publication : 2004 Article en page(s) : p. 91-96 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Copolymère silicone acrylate
Epoxydes
Micro-ondes
Microscopie électronique à balayage
Revêtements -- Séchage sous rayonnement ultraviolet
Revêtements organiquesIndex. décimale : 667.9 Revêtements et enduits Résumé : Microwave radiation was performed on a diglycidyl ether of a bisphenol-A type epoxy monomer with an aliphatic polyamino-curing agent. The ratio of epoxy monomer to curing agent was taken as 2. Two different molecular weights of silicone acrylates were used in various ratios for the modification of the system. The mechanical characterisation and hardness measurements of these samples were performed. As the siloxane content in the epoxy resin system was increased, Young’s modulus and hardness decreased. Further, the strength at Fmax, toughness and percentage elongation showed a maximum of about 10% for one kind of PDMS containing epoxy system. Thermal characterisations of the samples were determined with a thermogravimetric analyzer. The decomposition of the samples was a two-stage process with maximum weight loss rates in between 320 to 400°C or 330 to 430°C°C, depending on the molecular weights of PDMS modifier. The SEM photographs of the cold-fractured samples were taken. As the siloxane content in the epoxy resins was increased, the fractured surfaces became rougher and showed more irregular stripes in the matrix. Note de contenu : - EXPERIMENTAL : Materials - Analyses and methods - Preparation of the epoxy films
- RESULTS AND DISCUSSION : Mechanical characterisation of the epoxy films - Thermal characterisation of the epoxy films - Morphology of the epoxy films
- Table 1 : Preparation conditions of epoxy resins
- Table 2 : Average results of the film samples containing PDMS V-Si 21
- Table 3 : Average results of the film samples containing PDMS V-Si 22
- Table 4 : Average results of shore D hardness of the samplesDOI : 10.1007/BF02699602 En ligne : https://link.springer.com/content/pdf/10.1007/BF02699602.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=5468
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Code-barres Cote Support Localisation Section Disponibilité 000391 - Périodique Bibliothèque principale Documentaires Disponible Studies on water dispersible products based on sulphitation of wool wax by trichlorosilyl sulphite agent / El-Shahat H. A. Nashy in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 86, N° 5 (09-10/2002)
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Titre : Studies on water dispersible products based on sulphitation of wool wax by trichlorosilyl sulphite agent Type de document : texte imprimé Auteurs : El-Shahat H. A. Nashy, Auteur ; N. H. El-Sayed, Auteur ; S. S. Elmorsy, Auteur Année de publication : 2002 Article en page(s) : p. 212-218 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Caractérisation
Composition chimique
Huiles et graisses synthétiques
Lanoline
SulfitationIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Wool wax is an industrial by-product which has been investigated for further use in the leather industry. It was treated with trichlorosilyl sulphite (TCSS) as a new reagent to obtain an oil having sulphite groups. Trichlorosilyl sulphite (TCSS) can be generated in situ by the interaction of tetrachlorosilane with sodium sulphite or sodium bisulphite. This forms a basic raw material stock for the development of a range of synthetic fatliquors which can be used in the leather industry equivalent to those based on sulphochlorinated oils. Note de contenu : - MATERIALS AND METHODS : Materials - Methods - Scanning Electron Microscopy
- RESULTS AND DISCUSSION : A) - Wool wax acids - B) - USM Composition - 3) - FT-IR - Visual properties of fatliquored leather - Visual properties of fatliquored leather - Scanning Electron Microscopy (SEM)
- Table 1 : The physical and chemical characteristics of El-Bieda wool wax.
- Table 2 : Composition of wool wax fatty acids
- Table 3 : Composition of wool wax USM
- Table 4 : Sulphitation of wool wax under different conditions
- Table 5 : Visual properties of fatliquored leatherEn ligne : https://drive.google.com/file/d/1UJnqRYet2KTiIFwP-tsp67_sdpHjdYa-/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39861
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 86, N° 5 (09-10/2002) . - p. 212-218[article]Study of mechanical and moisture absorption behavior of epoxy/cloisite-15A nanocomposites processed using twin screw extruder / G. Angadi in INTERNATIONAL POLYMER PROCESSING, Vol. XXXV, N° 3 (07/2020)
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Titre : Study of mechanical and moisture absorption behavior of epoxy/cloisite-15A nanocomposites processed using twin screw extruder Type de document : texte imprimé Auteurs : G. Angadi, Auteur ; H. N. Narasimha Murthy, Auteur ; R. Sridhar, Auteur ; S. Firdosh, Auteur ; T. S. Roopa, Auteur Année de publication : 2020 Article en page(s) : p. 242-253 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse de variance En statistique, l'analyse de la variance (terme souvent abrégé par le terme anglais ANOVA : ANalysis Of VAriance) est un ensemble de modèles statistiques utilisés pour vérifier si les moyennes des groupes proviennent d'une même population. Les groupes correspondent aux modalités d'une variable qualitative (p. ex. variable : traitement; modalités : programme d'entrainement sportif, suppléments alimentaires ; placebo) et les moyennes sont calculés à partir d'une variable continue (p. ex. gain musculaire).
Ce test s'applique lorsque l'on mesure une ou plusieurs variables explicatives catégorielles (appelées alors facteurs de variabilité, leurs différentes modalités étant parfois appelées "niveaux") qui ont de l'influence sur la loi d'une variable continue à expliquer. On parle d'analyse à un facteur lorsque l'analyse porte sur un modèle décrit par un seul facteur de variabilité, d'analyse à deux facteurs ou d'analyse multifactorielle sinon. (Wikipedia)
Caractérisation
Cloisite
Composites -- Propriétés mécaniques
Extrudeuse bi-vis
Humidité -- Absorption
Matériaux hybrides -- Extrusion
Stabilité thermiqueIndex. décimale : 668.4 Plastiques, vinyles Résumé : This paper presents the effect of process parameters of twin screw extruder and addition of Cloisite-15A on mechanical, thermal and moisture barrier properties of epoxy/Cloisite-15A nanocomposites. Four lobed kneading blocks were used the in shearing zone of the extruder, based on their effectiveness in dispersing nanofillers in epoxy. Screw speeds from 100 min−1 to 400 min−1, number of passes up to 15, temperature from 5°C to 80°C and Cloisite-15A contents from 1 wt.% to 2.5 wt.% were considered for designing the L12 Orthogonal Array. Improvements in tensile strength, compression strength, flexural strength, impact strength, hardness and moisture diffusivity in the nanocomposites were 11.89%, 20.06%, 27.73%, 37.26%, 25.48% and 56.22% respectively, when compared to neat epoxy. The improvements were achieved for screw speed of 400 min–1, 5 passes through the extruder, processing temperature of 5°C and 2 wt.% of Cloisite-15A. Dispersion of Cloisite-15A in epoxy was studied by XRD, SEM and TEM. Thermal stability and moisture barrier properties were superior in the nanocomposites. Note de contenu : - EXPERIMENTAL DETAILS : Materials - Twin screw extruder and screw configuration - Design of experiments - Preparation of nanocomposite specimens - Characterization of specimens
- RESULTS AND DISCUSSION : XRD - SEM - TEM - Thermal studies - Signal-to-noise ratio - ANOVA - Moisture uptake of epoxy/C-15A nanocompositesDOI : https://doi.org/10.3139/217.3875 En ligne : https://drive.google.com/file/d/1Nq55FOt7HTS9nSJAA0aORNMdmtUnsUGd/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=34491
in INTERNATIONAL POLYMER PROCESSING > Vol. XXXV, N° 3 (07/2020) . - p. 242-253[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 21818 - Périodique Bibliothèque principale Documentaires Disponible A study of non-isothermal kinetic reaction for vulcanization of chloride butyl rubber via phenol formaldehyde resin / X. R. He in INTERNATIONAL POLYMER PROCESSING, Vol. XXIX, N° 3 (07/2014)
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Titre : A study of non-isothermal kinetic reaction for vulcanization of chloride butyl rubber via phenol formaldehyde resin Type de document : texte imprimé Auteurs : X. R. He, Auteur ; H. Yu, Auteur ; Y. Q. Rong, Auteur ; R. Zhang, Auteur ; G. S. Huang, Auteur Année de publication : 2014 Article en page(s) : p. 342-349 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse mécanique dynamique
Caoutchouc -- Propriétés mécaniques
Caoutchouc butyle chloré
Caractérisation
Formaldéhyde
Mélange
Phénoplastes
Réticulation (polymérisation)
Thermocinétique
VulcanisationIndex. décimale : 668.4 Plastiques, vinyles Résumé : Brominated tert octyl phenol formaldehyde resin (PR) is an important cross linker for chlorinated butyl rubber (CIIR). There are two competitive reactions in the vulcanization process of CIIR, the cross-linking reaction and the self-poly-condensation reaction of PR. The cross-linking density was measured by the equilibrium swelling method. The results showed: with the increasing of PR content, the cross-linking density increased when it was less than 10 phr, and decreased when the PR content exceeded 10 phr. The kinetics equation of cross-linking reaction and the self-poly-condensation reaction was obtained by non-isothermal DSC method. The results showed that the concentration index n2 of PR in the cross-linking reaction was far less than the concentration index n3 of PR in the self-poly-condensation reaction. The self-poly-condensation reaction was more sensitive to the concentration of PR. This explained that the cross-linking density was out of proportion with the cross linker PR content. The mechanical properties and the dynamic mechanical properties were investigated by the universal testing machine and the dynamic mechanical performance analysis (DMA), respectively. The results showed that the cross-linking density had a great impact on the mechanical properties and the dynamic mechanical properties, and the variation trend of the cross-linking density was further confirmed by the corresponding variation of the properties. When the PR content was 5 phr, the CIIR vulcanizates had better mechanical properties. Note de contenu : - EXPERIMENTAL : Materials - Mixing and vulcanization - Preparation of PR blend - Testing and characterization
- RESULTS AND DISCUSSION : The effect of PR content on cross-linking - The research of non-isothermal kinetic equation - The effect of PR content on mechanical properties of vulcanizates - Dynamic mechanical properties of CIIR vulcanizatesDOI : 10.3139/217.2722 En ligne : https://drive.google.com/file/d/1sAVFBUSz3CyRTxKyUuWbcp5qkAGZKqaE/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=21731
in INTERNATIONAL POLYMER PROCESSING > Vol. XXIX, N° 3 (07/2014) . - p. 342-349[article]Réservation
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