Titre : |
Synthesis and properties of a novel intumescent flame retardant and its application in LLDPE |
Type de document : |
texte imprimé |
Auteurs : |
W. Ye, Auteur ; L. Du, Auteur ; X. Tian, Auteur |
Année de publication : |
2014 |
Article en page(s) : |
p. 191-196 |
Note générale : |
Bibliogr. |
Langues : |
Anglais (eng) |
Catégories : |
Ignifugeants Composé chimique utilisé pour réduire l'inflammabilité. Il peut être incorporé au produit durant sa fabrication ou appliqué ultérieurement à sa surface. Intumescence (chimie) Matières plastiques -- Additifs Polyéthylène basse densité linéaire
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Index. décimale : |
668.9 Polymères |
Résumé : |
In this study, a novel phosphorus-containing flame retardant (IFR) of spirocyclic pentaerythritol diphosphonate dinitroguanidine (SPDD) was successfully synthesized, which was characterized by 1H?NMR, 31P?NMR and FTIR spectra. At the same time, the SPDD was used in LLDPE to prepare flame-retardant materials whose flammability and thermal behavior were studied by thermogravimetric analysis (TGA), limiting oxygen index (LOI) and scanning electron microscopy (SEM). The TGA data showed that SPDD could effectively enhance the thermal stability and char residue of LLDPE/IFR composite. And with the increase of SPDD, the LOI value of LLDPE/IFR increases obviously. When SPDD reached 30?wt%, the LOI value of LLDPE/IFR reaches 31?%. The SEM also shows the surface of intumescent chars of LLDPE/IFR (30?%) has many sphere-like swollen bubbles. |
Note de contenu : |
- EXPERIMENTAL : Materials - Synthesis of SPDD (spirocyclic pentaerythritol disphosphonate dinitroguanidine) - Preparation of LLDPE/IFR samples - Measurements
- RESULTS AND DISCUSSION : Characterization of SPDD - FTIR study of SPDD - Thermal degradation and charring behavior - Flame testing - Scanning electron microscopy |
DOI : |
10.3139/217.2716 |
En ligne : |
https://drive.google.com/file/d/1BF2ZgvyL65uClLaJqKtAAAJRywe7pJIP/view?usp=drive [...] |
Format de la ressource électronique : |
Pdf |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=21312 |
in INTERNATIONAL POLYMER PROCESSING > Vol. XXIX, N° 2 (05/2014) . - p. 191-196