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Study into the cold pad-batch application of monochloro-s-triazinyl and m-carboxypyridinium-s-triazinyl reactive dyes bearing various "second-leg" N-substituents / Huei-Chin Huang in COLORATION TECHNOLOGY, Vol. 137, N° 3 (06/2021)
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Titre : Study into the cold pad-batch application of monochloro-s-triazinyl and m-carboxypyridinium-s-triazinyl reactive dyes bearing various "second-leg" N-substituents Type de document : texte imprimé Auteurs : Huei-Chin Huang, Auteur ; Chun-Guey Wu, Auteur Année de publication : 2021 Article en page(s) : p. 292-298 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Colorants réactifs Tags : 'Teinture pad-batch à froid' 'Colorants réactifs' Index. décimale : 667.2 Colorants et pigments Résumé : A series of monochloro-s-triazinyl (MCT) and related m-carboxypyridinium-s-triazinyl (nicotinic acid [NTR]) reactive dyes based on the same red chromophore and bearing –NHCN, –OCH3, –N(CH3)SO2CH3, –N-methylphenyl and –OH “second-leg” substituents were evaluated in cold pad-batch dyeing. It was found that both the MCT and NTR dyes containing a cyanoamino second-leg substituent displayed a superior technical performance to the dyes bearing methoxy, N-methyl(methylsulphonyl)amino, hydroxyl and N-methylaniline substituents. The results suggest that these technical benefits of dyeing are derived from the smaller molecule size and electronic effect of the cyanoamino group compared with the other second-leg substituents commonly used in both MCT and NTR reactive dye synthesis. Indeed, the use of the cyanoamino second leg on the studied red NTR reactive dyes offered a combination of short batch time, high fixation efficiency, good build-up properties and good wet fastness properties. DOI : https://doi.org/10.1111/cote.12531 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12531 Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=36095
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