Fabrication and properties of polysilsesquioxane-based trilayer core–shell structure latex coatings with fluorinated polyacrylate and silica nanocomposite as the shell layer / Jiawei Li in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 15, N° 5 (09/2018)  

[article]  inJOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 15, N° 5 (09/2018) . - p. 1077-1088 Titre : Fabrication and properties of polysilsesquioxane-based trilayer core–shell structure latex coatings with fluorinated polyacrylate and silica nanocomposite as the shell layer Type de document : texte imprimé Auteurs : Jiawei Li, Auteur ; Shenjie Zhong, Auteur ; Wiaojie Yan ; Weixiang Li ; Lingmin Yi Année de publication : 2018 Article en page(s) : p. 1077-1088 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Core-Shell Couches minces Dioxyde de silicium Fluoropolymères Fourier, Spectroscopie infrarouge à transformée de Granulométrie Humidité -- Absorption:Eau -- Absorption Hydrophobie Latex Mesure Microscopie à force atomique Morphologie (matériaux) Mouillabilité Nanoparticules Polyacrylates Polymères -- Synthèse Stabilité thermique Index. décimale : 667.9 Revêtements et enduits Résumé : Polysilsesquioxanes (PSQ)-based core–shell fluorinated polyacrylate/silica hybrid latex coatings were synthesized with PSQ latex particles as the seeds, and methyl methacrylate, butyl acrylate, 3-(trimethoxysilyl) propyl methacrylate (MPS)-modified SiO2 nanoparticles (NPs), 1H,1H,2H,2H-perfluorooctyl methacrylate (PFOMA) as the shell monomers by emulsifier-free miniemulsion polymerization. The results of Fourier transform IR spectroscopy, transmission electron microscopy, and dynamic light scattering suggested the obtained hybrid particles emerged with trilayer core–shell pattern. Contact angle analysis, x-ray photoelectron spectroscopy, and atom force microscopy results indicated that the hybrid film containing SiO2 NPs showed higher hydrophobicity, lower surface free energy and water absorption, in comparison with the control system (without SiO2 NPs). Compared with the control system, the hybrid latex film containing SiO2 NPs in the fluorinated polyacrylate shell layer showed the higher content of fluorine atoms and a rougher morphology on the film surface. Additionally, thermogravimetric analysis demonstrated the enhanced thermostability of PSQ-based nanosilica composite fluorinated polyacrylate latex film. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of core-shell fluorinated polyacrylate/SiO2 NPs hybrid latex - Preparation of the latex film - Application of hybrid latex on fabrics - Measurements - RESULTS AND DISCUSSION : FTIR analysis - Particle morphologies and particle size of latexes - Surface property of latex films - Water absorption of latex fims - Surface wettability of the modified fabrics - XPS and AFM analysis - Thermal stability of latex films DOI : 10.1007/s11998-018-0044-9 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-018-0044-9.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=31136 [article]

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Waterborne corrosion-resistant hydrophobic alkyd resin composite coatings modified with fluorinated acrylate–siloxane and submicron-sheet zinc phosphate pigment / Shenjie Zhong in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 18, N° 5 (09/2021)  

[article]  inJOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 18, N° 5 (09/2021) . - p. 1309-1320 Titre : Waterborne corrosion-resistant hydrophobic alkyd resin composite coatings modified with fluorinated acrylate–siloxane and submicron-sheet zinc phosphate pigment Type de document : texte imprimé Auteurs : Shenjie Zhong, Auteur ; Kang Qin, Auteur ; Yi Hou, Auteur ; Tianqi Xu, Auteur ; Ying Cai, Auteur ; Lingmin Yi, Auteur Année de publication : 2021 Article en page(s) : p. 1309-1320 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Anticorrosifs Anticorrosion Hydrophobie Phosphate de zinc Pigments organiques Polyalkydes Revêtements en phase aqueuse Index. décimale : 667.9 Revêtements et enduits Résumé : Waterborne polymeric coating for corrosion protection has been of particular interest both in academia and industrial circles for years because of its low cost and low-volatile organic compound (VOC) emissions. However, organic coating is permeable to water and oxygen resulting in the reduction of anticorrosion properties during coating application. In this study, waterborne corrosion-resistant hydrophobic-modified alkyd resin composite coatings using fluorinated acrylate–siloxane (FASAR) and submicron-sheet zinc phosphate (Zn3(PO4)2) pigment were prepared. The results of hydrophobicity, thermal, and mechanical measurements indicated that the FASAR30/5%Zn3(PO4)2 had excellent performance. More importantly, the EIS and potentiodynamic polarization tests revealed that the acquired films also exhibited high anticorrosion property for carbon steel. The corrosion current density (icorr) was 7.20 × 10−7 A cm−2, with an inhibition efficiency of 99.92%, and a corrosion rate of 8.37 × 10−3 mm per year. On the other hand, the impedance modulus (Zf = 0.01 Hz) of FASAR30/5%Zn3(PO4)2 still had 5.68 × 104 Ω cm2 after 14-day immersion in the 3.5 wt% NaCl solution. Note de contenu : - EXPERIMENTAL : Materials - Synthesis of FASAR via emulsions miniemulsion polymerization - Preparation of waterborne FASAR and FASAR/submicron-sheet Zn3(PO4)2 composite latex films - Coating process for carbon steel - CHARACTERIZATIONS : Morphology and size distribution of emulsion - Chemical structure of hybrid composite films - Wettability of the composite latex films - Mechanical property tests and thermal stability of composite latex films - Anticorrosion tests of composite latex films - RESULTS AND DISCUSSION : The morphology and sizes of FASAR emulsions - FTIR analysis - Dispersion of Zn3(PO4)2 in the composite latex films - Hydrophobicity of composite latex films - Mechanical and thermal properties of composite latex films - The corrosion properties of composite latex films - Table 1 : Recipes and properties of the FASAR emulsions - Table 2 : Contact angle values and surface energies of the thin films of composite latexes - Table 3 : The mechanical properties of composite latex films - Table 4 : TGA data of the composite latex films - Table 5 : Electrochemical parameters obtained from PDP studies for FASAR0, FASAR30 and FASAR30/submicron-sheet Zn3(PO4)2 coated CS in 3.5 wt% NaCl at room temperature - Table 6 : Electrochemical impedance spectroscopy data for uncoated FASAR0, FASAR30 and FASAR30/submicron-sheet Zn3(PO4)2-coated CS in 3.5 wt% NaCl at room temperature DOI : https://doi.org/10.1007/s11998-021-00493-y En ligne : https://link.springer.com/content/pdf/10.1007/s11998-021-00493-x.pdf Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=36434 [article]

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