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Cr(VI) Formation in double-face sheepskins : Effect of chromium level and ironing / Bahri Basaran in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 91, N° 1 (01-02/2007)
[article]
Titre : Cr(VI) Formation in double-face sheepskins : Effect of chromium level and ironing Type de document : texte imprimé Auteurs : Bahri Basaran, Auteur ; Nuray Olcay Isik, Auteur Année de publication : 2007 Article en page(s) : p. 4-10 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Chrome hexavalent
Cuir -- Teneur en chrome hexavalent
Cuir double face
Cuirs et peaux de moutons
Décoloration
DibromeLe dibrome (Br2) est une molécule composée de deux atomes de brome. C'est l'unique forme moléculaire (allotrope) de l'élément brome.Le dibrome est un liquide rouge très volatil. Il est très toxique par inhalation et provoque de graves brûlures. Les vapeurs attaquent les muqueuses, la peau et le système respiratoire. Sa solution aqueuse s'appelle "l'eau de brome", qui est beaucoup moins nocive.
- Propriété oxydante : Le dibrome a un pouvoir oxydant élevé : E°(Br2/Br-) = 1,07 V.
Ainsi, l'eau de brome permet de mettre en évidence la présence d'une double liaison (voir Test au dibrome) en l'oxydant.
- Précautions : Du fait de son fort pouvoir oxydant, et parce qu'il est extrêmement volatil, le dibrome dégage des vapeurs toxiques, suffocantes et rougeâtres.
Au contact de la peau, il engendre des plaies qui cicatrisent très lentement.
Le dibrome est détruit par une solution de thiosulfate de sodium. (Wikipedia)
Eaux usées -- Teneur en chrome hexavalent
Laine -- Teneur en chrome hexavalent
Laine de mouton
Satinage
Solutions (chimie)Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : This study examines the relationship of Cr(VI) formation in leather and wool fibres to the level of Cr and the ironing temperature in double-face processing. The chromium oxide levels in both the leather and wool fibres of the skins were measured. An increase in the amount of basic chromium sulphate used was shown to increase the chromium content in both leather and wool fibres. Related to this increase, parallel increases in the amount of Cr(VI) in leather and wool fibres were detected by the analysis method - DIN 53314 (IUC 18: 1997).
Furthermore, higher temperatures during the ironing processes produced higher levels of Cr(VI) in leather and wool fibres. To eliminate any false-positive results due to the interference of dyestuffs in the Cr(VI) determination with dark coloured extracts, Br2/water solutions were added to extract solutions and the measurements were repeated in the transparent extracts. A comparison of the results revealed that in the extracts with Br2/water addition, Cr(VI) values were lower and it was concluded that Br2/water solution eliminated the dyestuff interference and, therefore the false-positive results.Note de contenu : - EXPERIMENTAL PROCEDURE : Double-face processing - Cr2O3 Analysis and Cr(VI) determinations - Decolorising the extract by Br2/water addition - Reaction mechanism of Br2/water
- RESULTS AND DISCUSSION : Decolorising with Br2/water addition - Calibration curve of standardized solutions - Recovery rates of sample groups - Absorbance values of Br2/water - Cr2O3 contents of the leather, wool fibres and exhausted floats - Cr(VI) contents determined in leather and wool sides of double-faces - Cr(VI) concentrations in leather and wool of double-face determined both with and without Br2 solution
- Table 1 : Experimental design of the study
- Table 2 : Process used for processing double-faces
- Table 3 : Absorbance values of Br2/water against water
- Table 4 : Chromium oxide contents of leathers, wool fibres and exhausted floatsEn ligne : https://drive.google.com/file/d/1thGG6QSg4zSkZyWj1M3wEV9rFED_1FdB/view?usp=share [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39039
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 91, N° 1 (01-02/2007) . - p. 4-10[article]Exemplaires
Code-barres Cote Support Localisation Section Disponibilité aucun exemplaire Leather surface refinement with application of the TIO2-SIO2-GLYMO Nanocomposite and lacquer coating / Meruyert Kaygusuz in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 102, N° 5 (09-10/2018)
[article]
Titre : Leather surface refinement with application of the TIO2-SIO2-GLYMO Nanocomposite and lacquer coating Type de document : texte imprimé Auteurs : Meruyert Kaygusuz, Auteur ; Nuray Olcay Isik, Auteur ; Michael Meyer ; Ahmet Aslan Année de publication : 2018 Article en page(s) : p. 234-240 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Adhésion
Caractérisation
Cuir
Cuirs et peaux -- Finition
Cuirs et peaux -- Propriétés mécaniques
Dépôt par pulvérisation
Matériaux hybrides
Oxydes métalliques
Photostabilité
Réaction de couplage
Résistance à l'abrasion
Revêtements
Sol-gel, Procédé
Solidité de la couleur
VernisIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : In the present study the effect of TiO2-SiO2-GLYMO nanocomposite on surface properties of leather was investigated. The TiO2-SiO2-GLYMO composite was prepared through the sol-gel route from tetraethoxysilane (TEOS) and titanium n-butoxide (TBO). 3-glycidoxypropyltrimethoxysilane (GLYMO) was added as coupling agent to provide a stable bond between metal oxides and leather substrate. The prepared composite was applied by spraying on the top coat of leathers in finishing. The surface properties observed by scanning electron microscopy (SEM) showed an even and homogenous coating obtained on leather by application of the composite in the presence of lacquer. The chemical structure of composite films was examined via Fourier transform infrared (FTIR) and Si-O-Ti bond and opening of epoxy rings of GLYMO were revealed. The presence of Ti and Si in the composite treated leather samples was ascertained by inductively coupled plasma optic emission spectrometer (ICP-OES). The results of the physical and fastness tests indicated that the use of TiO2-SiO2-GLYMO nanocomposite improves some performance characteristics of leather such as finish adhesion, dry and wet rubbing fastness, colour fastness to light and UV light. The results are promising for the refinement of leather surface with the application of the nanocomposite in the finishing process. Note de contenu : - EXPERIMENTAL PROCEDURES : Materials - Preparation and characterization of TiO2-SiO2-GLYMO composite - Application of TiO2-SiO2-GLYMO composite on leather - Characterisation and determination of surface properties of leathers treated with TiO2-SiO2-GLYMO nanocomposite
- RESULTS : Characterisation of the leather samples - Physical and fastness properties of leathersEn ligne : https://drive.google.com/file/d/1Q1a_bibn8FusdKXvK2TYDkFNIUZiIWKP/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=31094
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 102, N° 5 (09-10/2018) . - p. 234-240[article]Réservation
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