| Titre : |
The three pot solution for chromium, tannins and solid waste : Recovery and reuse technique for spent semi-chrome liquor and chrome shavings |
| Type de document : |
texte imprimé |
| Auteurs : |
Subramanian Saravanabhavan, Auteur ; Kalarical Janardhanan Sreeram, Auteur ; Jonnalagadda Raghava Rao, Auteur ; Balachandran Unni Nair, Auteur |
| Année de publication : |
2004 |
| Article en page(s) : |
p. 202-207 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Absorbants et adsorbants
Absorption
Chrome -- Recyclage
Colorimétrie
Déchets -- Elimination
Eaux usées -- Décontamination
Eaux usées -- Epuration
Liqueurs de tannage
Récupération (Déchets, etc.)
Solides
Tanins
Tannage au chrome
Température de retrait
|
| Index. décimale : |
675 Technologie du cuir et de la fourrure |
| Résumé : |
The potential toxicity and environmental impact of chromium and tannins discharged from a tannery has become a key issue, in particular the wastewater generated from the semi-chrome process presents a problem of separating chromium from vegetable tannins by conventional precipitation. This work reports the removal of tannins and recovery of chromium from a spent semi-chrome wastewater using chrome shavings as the adsorbent. Batch mode treatment studies have been carried out to standardize the duration, quantity of chrome shaving and pH. A tannin removal efficiency of 96% has been observed. The tannin-free chromium bearing liquor after the adsorption process was subjected to conventional chromium recovery and re-use and was then used for tanning as a 40% replacement of commercial basic chromium sulphate. The tannin containing chrome shavings were used as a reductant for the preparation of basic chromium sulphate and this was also used for tanning trials. Tanning studies reveal that the quality of the wet blue leathers is on a par with leathers tanned with commercial BCS. Shrinkage temperatures and performance of the leathers, in comparison to a conventional leather, are comparable. Exhaustion of chromium was similar. The procedure described offers a viable solution for the removal of tannins and recovery/reuse of chromium from semi-chrome wastewater, as well as for the disposal of solid wastes such as chrome shavings. |
| Note de contenu : |
- Introduction : Bulk studies
- Experimental methods : Treatment studies
- Recovery and reuse studies
- Tanning studies : Recovery and reuse - Comparison of the control and experimental (E1 and E2) leathers
- Table 1 : Characteristics of spent semi-chrome liquor and chrome shavings
- Table 2 : Efficiency of tannin removal at various chrome shaving offers
- Table 3 : pH Vs of tannin removal
- Table 4 : Subjective assessment data for control (C) and experimental (E1 and E2) leathers
- Table 5 : Strength characteristics of control (C) and experimental (E1 and E2) leathers
- Table 6 : Shrinkage temperature (Ts) and chromium content of leather and uptake of chromium during control (C) and experimental (E1 and E2) tanning
- Table 7 : Colour measurement data for the control (C) and experimental (E1 and E2) leathers |
| En ligne : |
https://drive.google.com/file/d/1y9d25ULtq10cvxZWkfZOsCI8wjcmydJR/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39625 |
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 88, N° 5 (09-10/2004) . - p. 202-207
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The three pot solution for chromium, tannins and solid waste : Recovery and reuse technique for spent semi-chrome liquor and chrome shavings in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 88, N° 5 (09-10/2004)
