| Titre : |
Synthesis and application of fluorinated acrylate copolymer as a retanning agent |
| Type de document : |
texte imprimé |
| Auteurs : |
Jin Liqiang, Auteur ; Li Yanchun, Auteur ; Xu Qinghua, Auteur |
| Année de publication : |
2006 |
| Article en page(s) : |
p.159-163 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Agents de tannage
Allongement à la rupture
Caractérisation
Copolymères -- Synthèse
Copolymères acrylates fluorés
Cuirs et peaux -- Propriétés mécaniques
Cuirs et peaux -- Propriétés physiques
Formulation (Génie chimique)
Perméabilité
Polyaddition
Résistance à l'humidité:Résistance à l'eau
Résistance à la traction
Retannage
Tannage synthétique
|
| Index. décimale : |
675.2 Préparation du cuir naturel. Tannage |
| Résumé : |
A fluorinated acrylate copolymer of dodecafluoroheptyl methacrylate (FA) and methacrylic acid (MAA) has been synthesized by free radical copolymerization using azobisisobutyronitrile as the catalyst at 75°C for 6hrs in dioxane. The structure of this copolymer was characterized by Fourier transformation infrared spectrum (FTIR), proton nuclear magnetic resonance (1H-NMR), elemental analysis, differential scanning calorimetry (DSC), and gel permeation chromatography (GPC).
The characteristics and effects of the copolymer as a retanning material have been investigated by measuring such physical/mechanical indexes as the tensile strength, thickness increment ratio, elongation at break, static water resistance and air permeability Instrumental analysis such as scanning electron microscopy and X-ray energy spectrum (SEM-EDAX) was also employed. The results indicate that this fluorinated acrylate copolymer tanning agent has good filling cum retanning ability and can improve the treated leather’s physical/mechanical properties and water repellency. |
| Note de contenu : |
- EXPERIMENTAL PROCEDURE : Materials - Preparation of the copolymer - Characterization of the copolymer
- APPLICATION FORMULATIONS : Determination of leather properties
- RESULTS AND DISCUSSION : Synthesis of copolymer - Application results - Scanning electron microscopy and X-ray energy spectrum (SEM-EDAX) examination
- Table 1 : The reaction conditions and results for preparing Poly (FA-co-MAA)
- Table 2 : Retanning and fatliquoring formulation of blue goat shoe leather
- Table 3 : The composition of Poly (FA-co-MAA)
- Table 4 : Physical and mechanical properties of leather treated by fluorinated acrylic polymer
- Table 5 : The elemental analysis results through SEM-EDAX |
| En ligne : |
https://drive.google.com/file/d/1PHFsxXJ59Xvb2-q630r7ui_01idTr8aU/view?usp=share [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=39114 |
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 90, N° 4 (07-08/2006) . - p.159-163
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Synthesis and application of fluorinated acrylate copolymer as a retanning agent in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 90, N° 4 (07-08/2006)
