| Titre : |
Polymeric aziridines as benign crosslinkers for water-based coating applications |
| Type de document : |
texte imprimé |
| Année de publication : |
2022 |
| Article en page(s) : |
p. 1345-1355 |
| Note générale : |
Bibliogr. |
| Langues : |
Américain (ame) |
| Catégories : |
Formulation (Génie chimique)
Laque et laquage
Morphologie (matériaux)
Polyacryliques
Polyéthylèneimine
Réticulants en phase aqueuse
Revêtements en phase aqueuse -- Additifs
Revêtements organiques
|
| Index. décimale : |
667.9 Revêtements et enduits |
| Résumé : |
Polymeric aziridines are introduced as a new class of low toxicity two-component crosslinkers for carboxylic resins. Using a combination of industry-standard tests and modern biotechnological approaches, the non-genotoxic nature of these compounds was demonstrated. Mechanical analysis of acrylic films formulated with these polymeric aziridines demonstrated that the high crosslink densities typical for classical aziridine chemistry could be attained. Furthermore, distribution of crosslinker molecules in both wet formulation and dried coating could be controlled by adjusting the stabilizing group of the polymeric aziridine. By tuning this stabilization mechanism, we demonstrated customized functional performance for different coating applications. |
| Note de contenu : |
- EXPERIMENTAL : Materials - Synthesis - Formulation - DMTA - TTS - Particle size analysis by DLS - Coating preparation for AFM - AFM measurements - Formulation for application testing
- RESULTS AND DISCUSSION : Non-mutagenic aziridines - Analysis of network formation - Crosslinker distribution - Application testing
- Table 1 : Induction of biomarkers attributed to DNA damage
- Table 2 : Application testing results of aziridines in furniture coating formulation
- Table 3 : Application testing results of polymeric aziridines in wood lacquer |
| DOI : |
https://doi.org/10.1007/s11998-022-00626-w |
| En ligne : |
https://link.springer.com/content/pdf/10.1007/s11998-022-00626-w.pdf |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=38274 |
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 19, N° 5 (09/2022) . - p. 1345-1355
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Polymeric aziridines as benign crosslinkers for water-based coating applications in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 19, N° 5 (09/2022)
