Titre : |
Synthesis and application of nano-organosilicon coating through cyclonic plasma deposition on a polymeric separator for lithium-ion batteries |
Type de document : |
texte imprimé |
Auteurs : |
Li-Yu Wu, Auteur ; Fang-Yi Chung, Auteur ; Chun Huang, Auteur |
Année de publication : |
2022 |
Article en page(s) : |
p. 1159-1170 |
Note générale : |
Bibliogr. |
Langues : |
Américain (ame) |
Catégories : |
Accumulateurs lithium-ion Electrochimie Enrobage (technologie) Organosilicones Plasma à pression atmosphériqueUn plasma à pression atmosphérique (ou plasma à PA ou plasma froid) est le nom donné à une catégorie spéciale de plasma pour lequel la pression approche celle de l’atmosphère.
Le plasma à pression atmosphérique marque une nette différence avec le plasma basse et haute pression. En effet, contrairement à ces derniers aucune enceinte de traitement n'est nécessaire. Ce type de plasma peut donc être utilisé directement sur ligne de production, évitant ainsi l'utilisation de vide qui est extrêmement onéreuse. Résistance thermique Revêtements organiques
|
Index. décimale : |
667.9 Revêtements et enduits |
Résumé : |
This study focuses on the vacuum-free deposition of nano-organosilicon coating through cyclonic plasma deposition on polymeric separators for application in lithium-ion batteries. Optical emission spectroscopy was used to determine various chemical plasma species and the association of the cyclonic plasma deposition of nano-organosilicon coating. The surface detections by ATR-FTIR and XPS revealed that the plasma power is the main reason affecting nano-organosilicon coating from organic to more inorganic features. The cyclonic-plasma-deposited nano-organosilicon coating was applied to the surface of a polymeric lithium-ion battery separator. The surface characteristics of the altered separator were analyzed through ATR-FTIR, TGA, EIS, and uptake test. The results indicated that the deposition of the nano-organosilicon coating on the separator surface improved the heat resistance and electrochemical performance of the polymeric separator. The synergistic effect of the cyclonic-plasma-coated separator was observed; that is, the electrolyte uptake of the cyclonic-plasma-coated separators was larger than that of a commercial separator. |
Note de contenu : |
- Table 1 : Porosity of the Ar/HMDSN mixture cyclonic-atmospheric-pressure-plasma-deposited organosilicon coating as a function of plasma power inputs
- Table 2 : Atomic percentage ratio of Ar/HMDSN mixture atmospheric pressure plasma cyclone-deposited organosilicon coating with different as a function of plasma power inputs
- Table 3 : Curve fit of XPS Si2p spectra of the Ar/HMDSN mixture cyclonic atmospheric pressure plasma deposited organosilicon coating as a function of plasma power inputs
- Table 4 : Components and related parameters of the equivalent circuits containing the uncoated and Ar/HMDSN mixture cyclonic-atmospheric-pressure-plasma-coated separators |
DOI : |
https://doi.org/10.1007/s11998-021-00595-6 |
En ligne : |
https://link.springer.com/content/pdf/10.1007/s11998-021-00595-6.pdf |
Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=38044 |
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 19, N° 4 (07/2022) . - p. 1159-1170