[article]
| Titre : |
Influence of surface modification on thermal, adhesive properties and impact behavior of TPU films for laminated glass |
| Type de document : |
texte imprimé |
| Auteurs : |
Chenxing Zhang, Auteur ; Hongwu Wu, Auteur ; Liangfeng Xu, Auteur ; Mingyuan Ren, Auteur |
| Année de publication : |
2022 |
| Article en page(s) : |
p. 329-337 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Adhésion
Caractérisation
Essais d'adhésion
Essais de résilience
Essais dynamiques
Films adhésifs
Films plastiques
Films plastiques -- Propriétés mécaniques
Polyuréthanes
Stabilité thermique
Traîtements de surface
Verre -- Revêtements
|
| Index. décimale : |
668.4 Plastiques, vinyles |
| Résumé : |
The poor adhesion of TPU films limits their extensive application in lightweight laminated glass (LLG). A simple and effective method is reported in this paper to obtain modified TPU films by silane coupling agent (SCA) treatment. The polar groups (such as urethane groups, carboxyl groups, etc.) on the surface of TPU films reacted chemically with the reactive groups of SCA. Meanwhile, hydrogen bonds were formed between the silicon hydroxyl groups generated by the hydrolysis of SCA. Therefore, the adhesivity and thermal stability of TPU films were improved. Moreover, the surface of TPU films became rough after modification, hence the interfacial bonding area between TPU film and glass increased, which furthered the bonding effect of TPU film with glass plate. Compared with unmodified TPU films, the tensile shear bond strength (TSBS) of modified TPU films increased by nearly 28%, and the initial decomposition temperature increased from 277 °C to a maximum of 295.3 °C. The impact resistance of LLG was significantly improved due to the improvement of the adhesivity of TPU film. |
| Note de contenu : |
- EXPERIMENTAL : Materials and instruments - Preparation of TPU film - Surface modification of TPU film - Adhesion test and sample preparation - Impact test and sample preparation - Characterization of modified TPU film
- RESULTS AND DISCUSSION : FT-IR analysis - Thermogravimetric analysis - SEM microstructure of TPU film - Adhesive properties of TPU film - Impact properties of LLG
- Table 1 : Surface modified TPU film samples. A1, A2 and A3 represent hydrolysis time of 2h, 4h and 6h, respectively. B1, B2 and B3 represent ultrasonic treatment time of 2 min, 4min and 6min, respectively
- Table 2 : Different decomposition temperature of modified TPU film |
| DOI : |
https://doi.org/10.1515/ipp-2022-0001 |
| En ligne : |
https://drive.google.com/file/d/159a_u_N73b5qCKhSShmLt4x1sqZ-mc3k/view?usp=shari [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=37910 |
in INTERNATIONAL POLYMER PROCESSING > Vol. 37, N° 3 (2022) . - p. 329-337
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Influence of surface modification on thermal, adhesive properties and impact behavior of TPU films for laminated glass in INTERNATIONAL POLYMER PROCESSING, Vol. 37, N° 3 (2022)
