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Evaluation of structures and morphologies of recycled PC/PET blends fabricated by high-shear kneading processing / A. Ishigami in INTERNATIONAL POLYMER PROCESSING, Vol. XXXII, N° 5 (11/2017)
[article]
Titre : Evaluation of structures and morphologies of recycled PC/PET blends fabricated by high-shear kneading processing Type de document : texte imprimé Auteurs : A. Ishigami, Auteur ; Y. Kodama, Auteur ; T. Wagatsuma, Auteur ; H. Ito, Auteur Année de publication : 2017 Article en page(s) : p. 568-573 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Alliages polymères
Analyse thermique
Cisaillement (mécanique)
Essais dynamiques
Matières plastiques -- Recyclage
Morphologie (matériaux)
Polymères -- Structure
Résistance chimique
Traction (mécanique)
Transition vitreuseIndex. décimale : 668.4 Plastiques, vinyles Résumé : We fabricated polymer blends of recycled-PC (PC) and recycled-PET (PET) using high-shear processing technology. We also assessed its structure, morphology, and physical properties. Results of DSC measurements show that Tg of PC and Tc of PET shifted to higher temperatures by kneading under high-shear conditions. Results show further that the Tm of PET shifted to a lower temperature. Moreover, compatibilization progressed. TEM observations show that the PET domain was not confirmed completely under the kneading condition of 1 000 min?1/10 s or more. Compatibilization progressed. Tensile test results show that the PET ratio of 30 wt% (1 000 min?1/10 s) has higher breaking strain than neat PC does. Chemical resistance test results obtained by good solvent of PC demonstrated that blending of PET makes PC elution difficult. Note de contenu : - EXPERIMENTAL : Samples - High-shear processing technology and kneading/molding conditions - DSC measurement - Structure and morphology - Mechanical properties - Chemical resistance test
- RESULTS AND DISCUSSION : DSC measurement - Structure and morphology - Tensile test chemical resistance testDOI : 10.3139/217.3423 En ligne : https://drive.google.com/file/d/1PwOGVFFlaG2ec5rKAClyEn2ndVi3xJ2t/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=29423
in INTERNATIONAL POLYMER PROCESSING > Vol. XXXII, N° 5 (11/2017) . - p. 568-573[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 19371 - Périodique Bibliothèque principale Documentaires Disponible Optical properties of HDPE in injection molding and injection press molding for IR system lenses part II : Mold temperature and surface roughness effects on injection molding / R. Kaneda in INTERNATIONAL POLYMER PROCESSING, Vol. XXXII, N° 2 (05/2017)
[article]
Titre : Optical properties of HDPE in injection molding and injection press molding for IR system lenses part II : Mold temperature and surface roughness effects on injection molding Type de document : texte imprimé Auteurs : R. Kaneda, Auteur ; T. Takahashi, Auteur ; M. Takiguchi, Auteur ; M. Hijikata, Auteur ; H. Ito, Auteur Année de publication : 2017 Article en page(s) : p. 237-244 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Evaluation
Lentilles (optique)
Matières plastiques -- Moulage par injection
Mesure
Polyéthylène haute densité
Polymères -- Effets de la température
Polymères -- Propriétés optiques
Rayonnement infrarouge
Rugosité
TempératureIndex. décimale : 668.4 Plastiques, vinyles Résumé : An experimental investigation of injection molding was conducted to assess the high infrared radiation (IR) transmittance with an opaque state (low visibility ray (VR) transmittance) necessary for IR system lenses as a target high-density polyethylene (HDPE) IR transmission material. In our earlier investigation, experimental investigations of injection molding and injection press molding were conducted using the mold cavity of a disk-shaped finished mirror-like surface. For high mold temperature and long cooling time, the increased core-layer thickness improved the IR transmittance. Simultaneously, the VR transmittance decreased because the crystallinity became higher. Furthermore, when injection press molding was done, the VR transmittance decreased because the crystallinity increased. Using a 0.5-mm-thick mold cavity with disk shapes having different surface roughness, an injection molding experiment was conducted for this study while changing only the mold temperature of 20 to 80°C. Results show that when the mold surface roughness became high, the surface roughness of molded parts became high, too. Thereby the IR and VR transmittance were decreased. However, when the mold temperature was high, the influences of the so-called skin-core structure and crystallinity were stronger than the influence of the surface roughness of molded parts. The IR transmittance increased because of the decrease of the skin layer. Furthermore, the VR transmittance decreased because of a simultaneous rise of the crystallinity. The minimum value of obtained VR transmittance was 9.3% at mold temperature of 80°C using a mold of the highest surface roughness. This molded part reached an opaque state. Furthermore, a higher IR transmittance of 64.9% was obtained. When injection molding was conducted using a mold of a mirror-like surface with the same conditions as those in this investigation in our earlier investigation, the obtained IR and VR transmittances were 65.4% and 0.6%, respectively. Consequently, when the mold temperature was high, a few differences were found with transmittance of the molded parts using the mold of the mirror-like surface. Results showed that no difficulty arises when a mold having higher surface roughness is used at a higher mold temperature. Note de contenu : - EXPERIMENTAL : Material - Mold - Injection molding machine and molding conditions - Measurement and evaluation
- RESULTS AND DISCUSSION : Measurement results of IR and VR transmittance - Effects of surface roughness of molded parts on IR and VR transmittance - Effects of molded part thickness and crystallinity on IR and VR transmittance - Effects of the molded part internal structure and crystallinity on IR and VR transmittanceDOI : 10.3139/217.3333 En ligne : https://drive.google.com/file/d/1Km9R7qKK1h9ZzNdQ58IAKb92pAIbSz2s/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=28503
in INTERNATIONAL POLYMER PROCESSING > Vol. XXXII, N° 2 (05/2017) . - p. 237-244[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 18872 - Périodique Bibliothèque principale Documentaires Disponible