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Preparation and performance of waterborne polyurethane modified by cross-linking of aziridine/carboxylated multi-walled carbon nanotubes / Ma Xingyuan in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 104, N° 4 (07-08/2020)
[article]
Titre : Preparation and performance of waterborne polyurethane modified by cross-linking of aziridine/carboxylated multi-walled carbon nanotubes Type de document : texte imprimé Auteurs : Ma Xingyuan, Auteur ; Wu Xiaozhen, Auteur ; Ding Bo, Auteur ; He Yuanxin, Auteur ; He Yinghua, Auteur ; Zheng Silong, Auteur Année de publication : 2020 Article en page(s) : p. 196-200 Note générale : Bibliogr.ZAZ Langues : Anglais (eng) Catégories : Allongement à la rupture
AziridineL'aziridine (n.f.) ou azacyclopropane est le composé organique cyclique de formule brute C2H5N. Elle est aussi le composé parent des aziridines et du groupe fonctionnel qui correspond à un hétérocycle à trois côtés composé d'une amine et de deux groupes méthylène.
Caractérisation
Carboxylation
Couches minces -- Propriétés mécaniques
Cuir
Essais (technologie)
Greffage (chimie)
Humidité -- Absorption:Eau -- Absorption
Nanotubes de carbone à parois multiplesUn nanotube de carbone multifeuillet est constitué de plusieurs feuillets de graphènes enroulés les uns autour des autres. Il existe deux modèles pour décrire la structure des nanotubes multifeuillets :
- le modèle poupée russe: les plans de graphène sont arrangés en cylindres concentriques ;
- le modèle parchemin: un seul feuillet de graphène est enroulé sur lui-même, comme une feuille de papier.
Polymères en émulsion
Polyuréthanes
Résistance à l'humidité:Résistance à l'eau
Résistance à la traction
Réticulation (polymérisation)Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : Carboxylated multi-walled carbon nanotubes (MWCNT-COOH) were prepared by treating multiwalled carbon nanotubes (MWCNT) with concentrated sulfuric acid (H,SO4) and concentrated nitric acid (HNO3) at a volume ratio of 3:1. Afterwards, taking MWCNT-COOH as the modified materials and aziridine (AZ) as the cross-linking agents were added to polyether-based waterborne polyurethane (WPU) thus preparing waterborne polyurethane modified by cross-linking of aziridine/carboxylated multi-walled carbon nanotubes (AZ-MWCNT-COOH-WPU) emulsion and films. The latter was applied to the surface treatment of natural leather and synthetic leather and other coating materials. The effects of different AZ contents on the water resistance and mechanical properties of AZ-MWCNT-COOH-WPU films were analysed and are discussed. The synthesised product was characterised by FTIR, XRD, SEM and other detection methods. The results showed that AZ successfully grafted MWCNT-COOH to the molecular chain of WPU and, when the content of AZ increased, the tensile strength of AZ-MWCNT-COOH-WPU film increased, firstly from 14.8MPa to 21.8MPa and then decreased to 12.1MPa. Elongation at break decreased from 570.2% to 198.4%, the water absorption decreased from 108.9% to 2.4% thus the water resistance was enhanced. Note de contenu : - EXPERIMENTAL PROCEDURE : Experiment materials and instrubments - Preparation of MWCNT-COOH - Preparation of AZ-MWCNT-COOH-WPU emulsion - Preparation of AZ-MWCNT-COOH-WPU film - Characterisation and test methods
- RESULTS AND DISCUSSIONS : FTIR analysis of MWCNT-COOH - Mechanical properties of AZ-MWCNT-COOH-WPU films - Water resistance analysis of AZ-MWCNT-COOH-WPU films - SEM analysis of AZ-MWCNT-COOH-WPU filmsEn ligne : https://drive.google.com/file/d/1-LHZ2ykQRApgvR0NWf-_GkwPDD_IfZWI/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=34333
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 104, N° 4 (07-08/2020) . - p. 196-200[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité 21881 - Périodique Bibliothèque principale Documentaires Disponible Preparation and properties of anti-biofouling zwitterionic polyurethane leather coating / Wang Chunhua in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 101, N° 1 (01-02/2017)
[article]
Titre : Preparation and properties of anti-biofouling zwitterionic polyurethane leather coating Type de document : texte imprimé Auteurs : Wang Chunhua, Auteur ; Mu Changdao, Auteur ; Lin Wei, Auteur Année de publication : 2017 Article en page(s) : p. 33-37 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Analyse thermique
Analyse thermomécanique dynamique
Humidité -- Absorption:Eau -- Absorption
Microscopie électronique à balayage
Perméabilité
Polymères -- Synthèse
Polymères en émulsion
Polyuréthanes
Résistance à l'humidité:Résistance à l'eau
Revêtements antisalissures
Revêtements protecteurs
Vapeur d'eau
ZwitterionsUn zwitterion (de l'allemand Zwitter — "hybride", "hermaphrodite » prononcé [t͜svɪtɛrjɔ̃]) est une espèce chimique moléculaire possédant des charges électriques formelles d’une unité, de signes opposés et situées en général sur des atomes non adjacents (dans le cas où les deux charges formelles sont portées par deux atomes adjacents, on parle d'ylures comme les ylures de phosphore). Les acides aminés, qui possèdent des groupements amine (sous forme d'ammonium NH3+ à pH =7) et acide carboxylique (sous forme de carboxylate COO- à pH =7) peuvent exister sous forme zwitterionique (à l'état solide, dans certaines gammes de pH en solution aqueuse) . Les bétaïnes sont d'autres exemples de zwitterions.Index. décimale : 675 Technologie du cuir et de la fourrure Résumé : Antifouling coatings are of great interest in many fields including the leather industry. Herein, the effects of zwitterionic groups on the preparation, structure, and performance of anti-biofouling zwitterionic polyurethanes have been investigated. The results show that the addition of excessive 1,3-propane sulfone (1,3-PS) contribute to the completion of the ionization reaction of the polyurethane in the preparation process. However, the residual 1,3-PS leads to the formation of micropores in the polyurethane films and this can be removed by the precipitation of the synthesized products in water. Differential scanning calorimetry (DSC) and dynamic mechanical thermal analysis (MITA) show the decreased T of polyurethanes with the increasing of zwitterionic groups, indicating the slightly enhanced microphase separation of the polyurethanes. The water vapour permeability (WVP) and water absorption rate (WAR) of polyurethane films increase with zwitterion groups, and thus the water-resistant property of the films needs to be improved for the purpose of leather coatings. In the emulsification of polyurethane, the presence of zwitterionic sulfobetaine causes the pH decrease of the emulsions, and proper neutralization may adjust it in the further investigations. Note de contenu : - EXPERIMENTAL SECTION : Materials - Synthesis of zwitterionic polyurethane (iNPU) - Preparation of the waterborne zwitterionic polyurethane (WZPU)
- RESULTS AND DISCUSSION : SEM analysis - DSC and DMTA analysis - Water resistant properties - Water vapour permeability (WVP) - Size analysis of WZPU polyurethane emulsionEn ligne : https://drive.google.com/file/d/1T9EJyPfc2Ev96dsoQRW2rHCP_aAHTKOW/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=27995
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Code-barres Cote Support Localisation Section Disponibilité 18711 - Périodique Bibliothèque principale Documentaires Disponible Preparation and properties of corn starch/polyacrylate emulsion finishing agent / Li Zeyang in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 108, N° 3 (05-06/2024)
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Titre : Preparation and properties of corn starch/polyacrylate emulsion finishing agent Type de document : texte imprimé Auteurs : Li Zeyang, Auteur ; Sui Zhihui, Auteur ; Zhang QI, Auteur ; Deng Lihua, Auteur ; Cao Xiangyu, Auteur ; Fang Hu, Auteur Année de publication : 2024 Article en page(s) : p. 122-126 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Acrylate de butyle
Amidons
Caractérisation
Chimie analytique
Croûte (cuir)On entend par "cuir en croûte" des cuirs ayant subi les opérations jusqu'au tannage, à l'exclusion de toute opération de corroyage ou de finissage, mais qui, par opposition aux wet-blue ont été séchés.
Cuirs et peaux -- Finition
Emulsions
Maïs et constituants
Méthacrylate de méthyle
PolyacrylatesIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Corn starch modified polyacrylate emulsion was prepared by semi-continuous seed emulsion polymerization with methyl methacrylate (MMA), butyl acrylate (BA) and oxidized starch (OSt) as the main raw materials and was subsequently used for leather finishing. The structure of starch/polyacrylate emulsion film was characterized by FT-IR, XPS and 1HNMR and the properties of leather coated with the emulsion were tested. The results showed that after corn starch was oxidized, the oxidized starch reacted with acrylate monomers, and the polyacrylate emulsion modified using oxidized starch was successfully prepared. Compared with a polyacrylate emulsion, the particle size distribution of modified composite emulsion is more concentrated. After finishing with polyacrylate emulsion containing oxidized starch, the leather was folded 20,000 times without developing cracks; In the wear resistance test, the gray scale of dry-wiped interlining cloth increased from 4.0 to 5.0, and the gray scale of wet-wiped interlining cloth increased from 3.5 to 4.5 ; The softness increased from 4.35 mm to the highest value at 5.23 mm; The tensile strength increased from 523N to 581N; The yellowing resistance is also obviously improved. Note de contenu : - EXPERIMENTAL PROCEDURES : Materials - Preparation of oxidized starch - Preparation of polyacrylate emulsion containing oxidized starch - Particle size analysis of emulsion - FTIR characterization of latex film - XPS characterization of latex film - 1H-NMR analysis - Testing of the crust leather applied performance
- RESULTS AND DISSCUSION : FT-IR analysis - XPS analysis - 1HNMR analysis - Particle size distribution test of emulsion - Testing of the crust leather’s applied performance
- Table 1 : Element content on the surface of latex film
- Table 2 : Test of latex film performance
- Table 3 : Testing of the finished leather applied performancePermalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=41137
in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC) > Vol. 108, N° 3 (05-06/2024) . - p. 122-126[article]Réservation
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Code-barres Cote Support Localisation Section Disponibilité - - Périodique Bibliothèque principale Documentaires Disponible Preparation and properties of matting waterborne polyurethane with polybutadiene / Ma Xingyuan in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 103, N° 5 (09-10/2019)
[article]
Titre : Preparation and properties of matting waterborne polyurethane with polybutadiene Type de document : texte imprimé Auteurs : Ma Xingyuan, Auteur ; Zhang Mingrui, Auteur ; Liu Shuai, Auteur Année de publication : 2019 Article en page(s) : p. 241-246 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Agent mattant
Caractérisation
Cuir
Emulsions -- Stabilité
Essais (technologie)
Humidité -- Absorption:Eau -- Absorption
Polybutadiène
Polybutylène téréphtalate
Polymères en émulsion
Polyuréthanes
Traîtements de surfaceIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : A matting waterborne polyurethane (MWPU) emulsion was prepared using polybutadiene diol (HTPB), polybutylene adipate diol (PBA) and isophorone diisocyanate (IPDI) as the main raw materials, dimethylolpropionic acid (DMPA) as a hydrophilic chain extender and ethylene diamine as a post chain extender, this was applied to the surface treatment of the leather. The surface microstructure of the MWPU film was studied by SEM. The results showed that when the content of HTPB increased, the particle size of MWPU emulsion increased, the stability decreased, the mechanical properties and surface roughness of MWPU film increased, the elongation at break, water absorption and light transmittance decreased. Combined with the matting effect, the gloss of the MWPU film was as low as 23GU, and the surface particles of the film were more obvious. The folding fastness was free from cracking, and the abrasion resistance could reach 154 circles [rubs], which meets the testing standard of leather. Note de contenu : - EXPERIMENTAL PROCEDURE : Experimental materials and instruments - Preparation of MWPU emulsion - Preparation of MWPU film - Effect of HTPB content on MWPU performance - Preparation of matting waterborne surface treatment agent - Characterisation and test methods
- RESULTS AND DISCUSSIONS : Effect of HTPB content on the appearance and stability of MWPU emulsion - Effect of HTPB content on water absorption rate of MWPU film - Effect of HTPB content on particle size of MWPU emulsion - Effect of HTPB content on light transmittance of MWPU film - SEM analysis - Surface treatment test results of MWPU film on leatherEn ligne : https://drive.google.com/file/d/1a7ysIBvAylOjF7xzoza9B0FDXMN8dg4j/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=32998
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Code-barres Cote Support Localisation Section Disponibilité 21222 - Périodique Bibliothèque principale Documentaires Disponible Preparation and properties of a methacrylic acid-co-modified maleic anhydride/montmorillonite nanocomposite for tanning / Yan Bao in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 95, N° 4 (07-08/2011)
[article]
Titre : Preparation and properties of a methacrylic acid-co-modified maleic anhydride/montmorillonite nanocomposite for tanning Type de document : texte imprimé Auteurs : Yan Bao, Auteur ; Jianzhong Ma, Auteur ; Zhang Jing, Auteur ; E. Tao, Auteur Année de publication : 2011 Article en page(s) : p. 147-151 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Anhydride maléique
Diffractométrie de rayons X
EthanolamineL'éthanolamine, également appelée 2-aminoéthanol ou monoéthanolamine, est un composé chimique organique qui est à la fois une amine primaire (par son groupe amine) et un alcool primaire (par son groupe hydroxyle). À l'instar des autres amines, la monoéthanolamine se comporte en base faible. L'éthanolamine est un liquide toxique, inflammable, corrosif, incolore et visqueux ; son odeur est similaire à celle de l'ammoniac.
Matériaux hybrides
Méthacrylique, AcideL'histoire de l'acide méthacrylique commence en 1865, année où il est synthétisé pour la première fois à partir du méthacrylate d'éthyle.
L'acide méthacrylique est très réactif avec les groupes carboxyles, vinyles et esters.
Microscopie électronique en transmission
Montmorillonite
Persulfate de potassium
Polyaddition
Résistance à l'humidité
Résistance thermique
TannageIndex. décimale : 675 Technologie du cuir et de la fourrure Résumé : Methacrylic acid-co-modified anhydride/montmonrillonite (MAA-co-modified MA/MMT) nanocomposite was prepared via the free radical copolymerization of methacrylic acid and maleic anhydride in the presence of montmorillonite, in which maleic anhydride and montmorillonite were modified respectively by ethanolamine and the initiator (potassium persulfate). The influence of maleic anhydride modifier, the mass ration of MAA to MA and modified MMT contents on the application properties of nanocomposite was investigated.
The wet-heat resistance stability and the fullness of leather tanned by nanocomposite were improved with the increase of hydroxyl group of ethanolamine. The introduction of modified MA and modified MMT resulted in increase and then decrease of the wet-heat resistance stability and the fullness of leather. X-ray diffraction (XRD) and Transmission Electron Microscope (TEM) confirmed MAA-co-modified MA/MMT nanocomposite is categorized as exfoliated and intercalated one.Note de contenu : - EXPERIMENTAL PROCEDURES : Materials - Preparation of MAA-co-modified MA/MMT nanocomposite (see appendix for details) - Characterization of MAA-co-modified MA/MMT nanocomposite - Application of MAA-co-modified MA/MMT nanocomposite leather sampels.
- RESULTS AND DISCUSSION : Effect of maleic anhydride modifier -Effect of the mass ration of MAA to MA - Effect of modified MMT contents - The structure of MAA-co-modifed MA/MMT nanocompositeEn ligne : https://drive.google.com/file/d/17jvN5Q8x52orzKyQQbGiOLQOLVyOknE1/view?usp=drive [...] Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=11857
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Code-barres Cote Support Localisation Section Disponibilité 013212 - Périodique Bibliothèque principale Documentaires Disponible Preparation and properties of nano-ZnO/organic fluorine modified polyacrylate finishing agent / Sui Zhihui in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXV, N° 6 (06/2020)
PermalinkPreparation and properties of polyurethane finishing agent using butylamine as chain-extension agent / Keyong Tang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CIV, N° 9 (09/2009)
PermalinkPreparation and properties of starch modified by glutaraldehyde and citric acid / S. H. Lu in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVI, N° 10 (10/2011)
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PermalinkPreparation and property analysis of composite plate for furniture decoration made from regenerated leather, CR adhesive and pineapple leaf fibre (RL/CR/PLF) / Yali Ou in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 107, N° 4 (07-08/2023)
PermalinkPreparation, characterization and application of silica metal oxide nanoparticles for leather coating / Sivaraj Sudhahar in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVII, N° 7 (07/2012)
PermalinkPermalinkPermalinkPreparation of amino-terminated hyperbranched buffing dust and its adsorption property towards acid fuchsin : Use of an industry by-product to adsorb dyestuffs / Jie Liu in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 105, N° 1 (01-02/2021)
PermalinkPreparation of antibacterial fatliquoring agents containing zinc oxide nanoparticles for leather industry / Ali Yorgancioglu in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CXIV, N° 5 (05/2019)
PermalinkPreparation of antibacterial sheepskin with silver nanoparticles : potential for use as a mattress for pressure ulcer prevention / Weite Yang in JOURNAL OF THE AMERICAN LEATHER CHEMISTS ASSOCIATION (JALCA), Vol. CVII, N° 3 (03/2012)
PermalinkPreparation of a biomass adhesive based on bamboo and leather shavings / Yiwei Zhang in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 104, N° 2 (03-04/2020)
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PermalinkPreparation of chrometan using low carbon alcohol as the reducing agent / Baozhen Cheng in JOURNAL OF THE SOCIETY OF LEATHER TECHNOLOGISTS & CHEMISTS (JSLTC), Vol. 87, N° 3 (05-06/2003)
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