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Biobased reactive diluent for UV-curable urethane acrylate oligomers for wood coatings / Dipak S. Tathe in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 12, N° 1 (01/2015)
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Titre : Biobased reactive diluent for UV-curable urethane acrylate oligomers for wood coatings Type de document : texte imprimé Auteurs : Dipak S. Tathe, Auteur ; Ramanand N. Jagtap, Auteur Année de publication : 2015 Article en page(s) : p. 187-196 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Biomatériaux
Bois -- Revêtements
Chloroformiate d'allyle
Copolymère uréthane acrylate
Diluants
Huile de ricin et constituants
Oligomères
Photoamorceurs (chimie)
Revêtements -- Séchage sous rayonnement ultravioletIndex. décimale : 667.9 Revêtements et enduits Résumé : Castor oil (CO)-based reactive diluent for UV-curable urethane acrylate oligomers was synthesized by the reaction of a CO with diethanolamine and the resultant product was subsequently reacted with allyl chloroformate. The reactive diluent was characterized by FTIR and 1H NMR techniques. This reactive diluent was incorporated in a urethane acrylate oligomer and photoinitiator at different weight fractions varying from 5 to 25 wt% for UV curing. The effects of reactive diluent concentrations on the viscosity of the formulations along with mechanical, chemical, and optical properties of UV-curable coatings were studied. Furthermore, the cured films were evaluated for glass transition temperature (T g) determined by differential scanning calorimetry and thermal stability by thermogravimetric analysis. Gel content and water absorption of UV-cured films were evaluated. Note de contenu : - EXPERIMENTAL : Material - Synthesis of diethanol fatty amide of castor oil (FACO) - Synthesis of triallyl format fatty amide (TFFA) - Formulation of UV-curable coating - Characterization - Testing of coatings
- RESULTS AND DISCUSSION : Physico-chemical analysis - FTIR analysis of CO, FACO, TFFA and UV-cured polymer - 1HNMR spectra of triallyl formate fatty amide (TFFA) - Effect of reactive diluent concentration on viscosity - Water absorption properties -Differential scanning calorimetry (DSC) - Thermogravimetric analysis of UV-cured films - Gloss of UV-cured coating - Coating propertiesDOI : 10.1007/s11998-014-9616-5 En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-014-9616-5.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=23217
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 12, N° 1 (01/2015) . - p. 187-196[article]Réservation
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