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Auteur Margarida M. S. M. Bastos
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Faculdade de Engenharia, Univesidade do Port - Portugal
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Incorporation of an acrylic fatty acid derivative as comonomer for oxidative cure in acrylic latex / Joana V. Barbosa in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 11, N° 5 (09/2014)
[article]
Titre : Incorporation of an acrylic fatty acid derivative as comonomer for oxidative cure in acrylic latex Type de document : texte imprimé Auteurs : Joana V. Barbosa, Auteur ; Jorge Moniz, Auteur ; Adélio Mendes, Auteur ; Fernà o D. Magalhà es, Auteur ; Margarida M. S. M. Bastos, Auteur Année de publication : 2014 Article en page(s) : p. 765-773 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Acides gras
Coalescence (Sciences physiques)
Latex
Nanoparticules
Polyacryliques
Polymérisation en émulsion
Polymérisation par oxydation
Revêtements en phase aqueuse:Peinture en phase aqueuse
SiliceLa silice est la forme naturelle du dioxyde de silicium (SiO2) qui entre dans la composition de nombreux minéraux.
La silice existe à l'état libre sous différentes formes cristallines ou amorphes et à l'état combiné dans les silicates, les groupes SiO2 étant alors liés à d'autres atomes (Al : Aluminium, Fe : Fer, Mg : Magnésium, Ca : Calcium, Na : Sodium, K : Potassium...).
Les silicates sont les constituants principaux du manteau et de l'écorce terrestre. La silice libre est également très abondante dans la nature, sous forme de quartz, de calcédoine et de terre de diatomée. La silice représente 60,6 % de la masse de la croûte terrestre continentale.
Traîtements de surfaceIndex. décimale : 667.9 Revêtements et enduits Résumé : An acrylic fatty acid derivative (AcFAD) was evaluated as comonomer for promotion of oxidative cure in waterborne latexes. AcFAD was polymerized by solvent homopolymerization and copolymerization and by emulsion copolymerization, and the final products characterized. In the two polymerization processes, NMR analyses confirmed that the reaction occurred involving both the terminal acrylic double bond and the conjugated double bonds of the aliphatic chain. Compared with a reference acrylic latex, the results obtained after AcFAD incorporation showed a time-dependent increase in gel content and in solvent resistance of dry films. These were ascribed to oxidative cure and consequent self-crosslinking of the acrylic polymer, involving the conjugated double bonds in AcFAD side chains. Oxidative cure was also confirmed by FTIR analyses. In addition, reduction in minimum film-forming temperature evidenced that AcFAD has an internal plasticization effect during film formation. Incorporation of this comonomer in acrylic paint binder formulations constitutes a promising alternative to the use of volatile coalescing agents. Note de contenu : - EXPERIMENTAL : 1. Materials
- Characterization methods : 1. Solution polymerization of AcFAD - 2. Emulsion copolymerization of AcFAD
- RESULTS AND DISCUSSION : 1. Solvent polymerization - 2. Emulsion polymerizationDOI : 10.1007/s11998-014-9582-y En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-014-9582-y.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=22059
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 11, N° 5 (09/2014) . - p. 765-773[article]Réservation
Réserver ce documentUse of fluoropolymer permanent release coatings for molded polyurethane foam production / Leandro Figueiredo in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH, Vol. 9, N° 6 (11/2012)
[article]
Titre : Use of fluoropolymer permanent release coatings for molded polyurethane foam production Type de document : texte imprimé Auteurs : Leandro Figueiredo, Auteur ; Pedro Bandeira, Auteur ; Adélio Mendes, Auteur ; Margarida M. S. M. Bastos, Auteur ; Fernà o D. Magalhà es, Auteur Année de publication : 2012 Article en page(s) : p. 757-764 Note générale : Bibliogr. Langues : Américain (ame) Catégories : Démoulage
Fluoropolymères
Isocyanates
Mousses plastiques
Polytétrafluoréthylène
Polyuréthanes
RevêtementsIndex. décimale : 667.9 Revêtements et enduits Résumé : The problem of adhesion of polyurethane foams to fluoropolymer permanent release mold coatings was studied. Two coatings, based on polytetrafluoroethylene (PTFE) and perfluoroalkoxy polymer (PFA) aqueous dispersions, respectively, were applied on aluminum plates, and the foam release performance evaluated. The PTFE coating displayed gradual loss of antiadhesion properties with consecutive exposure to the reactive mixture, which was associated with isocyanate surface penetration. Penetrant mass uptake experiments, performed on free films, indicated that PTFE retains about 10 times more isocyanate than PFA, probably because of its porous surface morphology. A synergistic effect was found by applying a very small quantity of a waterborne release agent on the PTFE coating, before every foam molding cycle. The release agent formed a protective barrier that minimized contact of the coating with the reactive mixture, allowing for stable and robust foam release performance. The problem of polyurea build-up, associated with the use of aqueous release agents, was not observed because of the small amounts of compound used. Note de contenu : - EXPERIMENTAL : Materials - Polyurethand foam formulation and molding - Evaluation - Evaluation of the release force and release force and release work - FTIR spectrocopy - Scanning electron microscopy - Penetrant mass uptake measurements
- RESULTS AND DISCUSSION : Surface morphology - Penetrant mass uptake - Foam release performance of PTFE and PFA coatings - Performance of PTFE coating combined with release agentDOI : 10.1007/s11998-012-9413-y En ligne : https://link.springer.com/content/pdf/10.1007%2Fs11998-012-9413-y.pdf Format de la ressource électronique : Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=16661
in JOURNAL OF COATINGS TECHNOLOGY AND RESEARCH > Vol. 9, N° 6 (11/2012) . - p. 757-764[article]Réservation
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