| Titre : |
PVDF/carbon nanotubes/nanoclay composites for piezoelectric applications |
| Type de document : |
texte imprimé |
| Auteurs : |
F. Sadeghi, Auteur ; A. Sarvi, Auteur |
| Année de publication : |
2014 |
| Article en page(s) : |
p. 81-87 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Argile
Conduction électrique
Matériaux piézoélectriques
Nanoparticules
Nanotubes
Polyfluorure de vinylidène
|
| Index. décimale : |
668.4 Plastiques, vinyles |
| Résumé : |
Poly(vinylidene) fluoride (PVDF) nanocomposite samples were prepared by incorporation of carbon nanotubes (CNT) and nanoclay into PVDF using a twin screw extruder. Carbon nanotube was added to improve electrical conductivity and nanoclay was included to enhance ? crystal formation for piezoelectric property. X-ray diffraction (XRD) results showed that partial melt intercalation of PVDF in clay was achieved. The XRD results also revealed that CNT and nanoclay addition increased ? phase crystal amount in PVDF. FTIR spectroscopy measurements confirmed the XRD results and showed that the effect of nanoclay on ? phase crystal formation of PVDF was more prominent than CNT. It was found that shear rate applied during crystallization would improve ? phase crystal formation but only for the neat PVDF. Electrical conductivity results showed that addition of CNT improved conductivity as a percolation of 2 wt.% was observed. It was found that dispersion of CNT into PVDF matrix is very crucial for obtaining a higher conductivity. The results showed that clay incorporation into CNT nanocomposite improved electrical conductivity. The TEM micrographs showed bundles of CNT were adhered to clay particles. That was considered an indication of affinity between CNT and organically modified clay. The results of compounding of CNT and nanoclay with PVDF in batch mixer also revealed improvement in electrical conductivity when clay was added into PVDF/CNT composite in melt state. The conductivity improved with mixing time for both systems: PVDF/CNT and PVDF/CNT/nanoclay. |
| DOI : |
10.3139/217.2814 |
| En ligne : |
https://drive.google.com/file/d/1YsykA23ulz28dDPDMkD1Q1fvS2H_zcv4/view?usp=drive [...] |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=20578 |
in INTERNATIONAL POLYMER PROCESSING > Vol. XXIX, N° 1 (03/2014) . - p. 81-87
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PVDF/carbon nanotubes/nanoclay composites for piezoelectric applications in INTERNATIONAL POLYMER PROCESSING, Vol. XXIX, N° 1 (03/2014)
