| Titre : |
Titanium dioxide grafted with silane coupling agents and its use in blue light curing ink |
| Type de document : |
texte imprimé |
| Auteurs : |
Lili Wang, Auteur ; Xiaying Jiang, Auteur ; Chenglong Wang, Auteur ; Yi Huang, Auteur ; Yiding Meng, Auteur ; Jianzhong Shao, Auteur |
| Année de publication : |
2020 |
| Article en page(s) : |
p. 15-22 |
| Note générale : |
Bibliogr. |
| Langues : |
Anglais (eng) |
| Catégories : |
Angle de contact
Bleu (couleur)
Caractérisation
Dioxyde de titane
Dispersions et suspensions -- Stabilité
Encre
Encre -- Propriétés mécaniques
Fourier, Spectroscopie infrarouge à transformée de
Granulométrie
Greffage (chimie)
Photoréticulation
Réaction de couplage
Rhéologie
Silanes
Thermogravimétrie
|
| Index. décimale : |
667.2 Colorants et pigments |
| Résumé : |
To improve the properties of titanium dioxide particles and realise their firm anchorage in blue light curing film, three modified titanium dioxide particles were prepared by grafting 3-(trimethoxysilyl)propyl methacrylate, 3-aminopropyltriethoxysilane and hexadecyltrimethoxysilane. The surface changes of titanium dioxide particles after modification were characterised. The dispersion stability, photo-polymerisation, rheological and mechanical properties of modified titanium dioxide blue light curing inks were investigated. Results showed that compared with native titanium dioxide, modified titanium dioxide particles were more appropriate for blue light curing ink. The particle sizes of the three modified titanium dioxide particles became smaller, their surfaces exhibited hydrophobicity, and the viscosity of the modified titanium dioxide inks decreased slightly. Of the three modified titanium dioxide particles, 3-(trimethoxysilyl)propyl methacrylate- and hexadecyltrimethoxysilane-modified titanium dioxide particles exhibited better dispersion stability in blue light curing ink. In particular, 3-(trimethoxysilyl)propyl methacrylate-modified titanium dioxide blue light curing ink showed the best photo-polymerisation and mechanical properties, which indicated the participation of the pigment grafted by double bonds in the blue light curable polymerisation. Using modified titanium dioxide in blue light curing ink, the dry/wet rubbing fastness of the printed fabrics improved. |
| Note de contenu : |
- EXPERIMENTAL : Materials - Grafting of silane coupling agent onto the surface of titanium dioxide particles - Preparation of blue light curing ink - Preparation of blue light curing - Characterisations
- RESULTS AND DISCUSSION : FT-IR spectroscopy of modified titanium dioxide - Thermogravimetric analysis of modified titanium dioxide - Elemental analysis of modified titanium dioxide - Particle size analysis of modified titanium dioxide - Contact angle analysis of modified titanium dioxide - Dispersion stability of modified titanium dioxide - Rheological porperties of modified titanium dioxide bluelight curing ink |
| DOI : |
https://doi.org/10.1111/cote.12434 |
| En ligne : |
https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12434 |
| Format de la ressource électronique : |
Pdf |
| Permalink : |
https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=33696 |
in COLORATION TECHNOLOGY > Vol. 136, N° 1 (02/2020) . - p. 15-22
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