Dimerised heterobifunctional reactive dyes. Part 1 : characterisation using quadrupole time-of-light mass spectrometry / Nadia Sultana in COLORATION TECHNOLOGY, Vol. 134, N° 6 (12/2018)  

[article]  inCOLORATION TECHNOLOGY > Vol. 134, N° 6 (12/2018) . - p.470-477 Titre : Dimerised heterobifunctional reactive dyes. Part 1 : characterisation using quadrupole time-of-light mass spectrometry Type de document : texte imprimé Auteurs : Nadia Sultana, Auteur ; Yixin Liu, Auteur ; Harold S. Freeman, Auteur ; Nelson R. Vinueza, Auteur Année de publication : 2018 Article en page(s) : p.470-477 Note générale : Bibliogr. Langues : Anglais (eng) Catégories : Bleu (couleur) Colorants -- Analyse Colorants réactifs Dimères Hexaméthylène diamine Rouge (couleur) Spectrométrie de masse Index. décimale : 667.2 Colorants et pigments Résumé : As part of an approach to enhancing the efficiency of reactive dye adsorption on cellulosic fibres at low electrolyte levels, commercially available dyes were dimerised using hexamethylenediamine (HMDA) as a linking group. A key component of this work involved using high-resolution mass spectrometry (HRMS) to characterise a group of polysulphonated heterobifunctional monochlorotriazine/vinyl sulphone reactive dyes (CI Reactive Yellow 176, CI Reactive Red 239, CI Reactive Blue 221, CI Reactive Red 194 and CI Reactive Blue 222) and their dimeric analogs. In this respect, dimeric dye ions of differently charged states were observed using HRMS-negative electrospray ionisation in combination with quadrupole time-of-flight mass spectrometry. For example, HRMS showed that the HMDA-linked reaction products were mixtures of the target (unhydrolysed) dimers, hydrolysed dimers, monoreacted products and hydrolysed unreacted dyes, with CI Reactive Yellow 176 and CI Reactive Red 194 producing the desired unhydrolysed dimers. Note de contenu : - EXPERIMENTAL : Materials and reagents - Reactive dye dimer formation- Mass spectrometry - RESULTS AND DISCUSSION : Characterisation of parent dyes - Characterisation of dimeric structures DOI : 10.1111/cote.12368 En ligne : https://onlinelibrary.wiley.com/doi/epdf/10.1111/cote.12368 Format de la ressource électronique : Pdf Permalink : https://e-campus.itech.fr/pmb/opac_css/index.php?lvl=notice_display&id=31381 [article]

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