| Résumé : |
In this study, a convenient method for the synthesis of thirteen novel disazo dyes containing 25,26,27-tribenzoyloxy-28-hydroxycalix[4]arene have been described. 5,11,17,23-Tetra-tert-butyl-25,26,27,28-tetrahydroxycalix[4]arene, 25,26,27,28-tetrahydroxycalix[4]arene and 25,26,27-tribenzoyloxy-28-hydroxycalix[4]arene were synthesised based on previously published literature. 2-Arylhdrazone-3-ketiminobutyronitriles were synthesised and reacted with hydrazine hydrate to afford the corresponding 5-amino-4-arylazo-3-methyl-1H-pyrazoles. Thirteen novel hetaryldisazocalix[4]arene derivatives were achieved by diazotisation of 5-amino-4-arylazo-3-methyl-1H-pyrazoles using nitrosylsulphuric acid, coupled with 25,26,27-tribenzoyloxy-28-hydroxycalix[4]arene. The obtained hetaryldisazocalix[4]arene dyes were characterised based on Fourier Transform–infrared, proton nuclear magnetic resonance and mass spectroscopic techniques, as well as elemental analysis. The solvatochromic behaviour of these dyes in various solvents was examined. Acid-base effects on the visible absorption maxima of the dyes were also reported. |
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Synthesis and absorption spectra of some novel hetaryldisazocalix[4]arene derivatives in COLORATION TECHNOLOGY, Vol. 127, N° 6 (2011)
